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SOLID STATE PHYSICS SOLUTIONS
GATE-2010
Q1. The valence electrons do not directly determine the following property of a metal
(a) Electrical conductivity (b) Thermal conductivity
(c) Shear modulus (d) Metallic luster
Ans: (c)
Q2. Consider X-ray diffraction from a crystal with a face-centered-cubic (fcc) lattice. The
lattice plane for which there is NO diffraction peak is
(a) (2, 1, 2) (b) (1, 1, 1) (c) (2, 0, 0) (d) (3, 1, 1)
Ans: (a)
Q3. The Hall coefficient, RH, of sodium depends on
(a) The effective charge carrier mass and carrier density
(b) The charge carrier density and relaxation time
(c) The charge carrier density only
(d) The effective charge carrier mass
Ans: (c)
Q4. The Bloch theorem states that within a crystal, the wavefunction, ψ( r ), of an electron has
the form
(a) r u r e i k .r where u( r ) is an arbitrary function and k is an arbitrary vector
(b) r u r e i G r
where u( r ) is an arbitrary function and G is a reciprocal lattice vector
(c) r u r e i G r
where u r u r , is a lattice vector and G is a reciprocal
lattice vector
(d) r u r e i k .r where u r u r , is a lattice vector and k is an arbitrary
vector
Ans: (d)
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Q5. In an experiment involving a ferromagnetic medium, the following observations were
made. Which one of the plots does NOT correctly represent the property of the medium?
(TC is the Curie temperature)
(a) (b)
1 / TC 1/ T
(c) (d)
TC T TC T
Ans: (c)
Q6. The thermal conductivity of a given material reduces when it undergoes a transition from
its normal state to the superconducting state. The reason is:
(a) The Cooper pairs cannot transfer energy to the lattice
(b) Upon the formation of Cooper pairs, the lattice becomes less efficient in heat transfer
(c) The electrons in the normal state lose their ability to transfer heat because of their
coupling to the Cooper pairs
(d) The heat capacity increases on transition to the superconducting state leading to a
reduction in thermal conductivity
Ans: (d)
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Q7. For a two-dimensional free electron gas, the electronic density n, and the Fermi energy
EF, are related by
2mE F 2 mE F 3
3 1 1
mE F mE F 2 3
(a) n (b) n (c) n (d) n
3 2 3 2 2 2
Ans: (b)
Solution: For two dimensional gas, the number of possible k-states between k and k+dk is
2 2
L L
g k dk 2 k dk 2 2 k dk it is multiplied by 2 for electron gas
2 2
2mE 2m 2m
Since k 2 2
2k dk 2 dE 2 k dk 2 dE
2
L 2m
g E dE 2 2 dE
2
The total number of electrons at T 0 0 K is
EF EF 2 EF
2m 1 2m L2
N g E dE F E
0
g E dE 2
0
2 2 dE 2
0
2 4 2
EF
m 2 N
2
mE F
N L2
E E F n n
2
F
2 m L2 m
Q8. Far away from any of the resonance frequencies of a medium, the real part of the
dielectric permittivity is
(a) Always independent of frequency (b) Monotonically decreasing with frequency
(c) Monotonically increasing with frequency (d) A non-monotonic function of frequency
Ans: (a)
dipolar
1 ionic
2
electronics
frequency
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C C
(c) , for T Tc (d) , for all temperatures
T Tc T Tc
where C is constant .
Ans: (b)
Q10. The order of magnitude of the energy gap of a typical superconductor is
(a) 1 MeV (b) 1 KeV (c) 1 eV (d) 1 meV
Ans: (d)
Q11. For a three-dimensional crystal having N primitive unit cells with a basis of p atoms, the
number of optical branches is
(a) 3 (b) 3p (c) 3p – 3 (d) 3N – 3p
Ans: (c)
Q12. For an intrinsic semiconductor, me* and mh* are respectively the effective masses of
electrons and holes near the corresponding band edges. At a finite temperature the
position of the Fermi level
(a) depends on me* but not on mh* (b) depends on mh* but not on me*
(c) depends on both me* and mh* (d) depends neither on me* nor on mh*
Ans: (c)
Ec Ev 3 mh*
Solution: The Fermi level for intrinsic semicondutor is E F k B T ln *
2 4 me
Q13. A metal with body centered cubic (bcc) structure show the first (i.e. smallest angle)
diffraction peak at a Bragg angle of θ = 30o. The wavelength of X-ray used is 2.1 Ǻ. The
volume of the PRIMITIVE unit cell of the metal is
(a) 26.2 (Ǻ)3 (b) 13.1(Ǻ)3 (c) 9.3 (Ǻ)3 (d) 4.6 (Ǻ)3
Ans: (b)
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a
Solution: According to Bragg’s law 2d sin where d
h2 k 2 l 2
For BCC structure the first diffraction peak appear for (110) plane.
a 2a
d sin 30 0 2a sin 30 0 2.1A 0
2 2
1
2 a 2.1A 0 a 2 2.1A 0 a 2.97 A 0 .
2
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Q16. For an ideal Fermi gas in three dimensions, the electron velocity VF at the Fermi surface
is related to electron concentration n as,
(a) V F n 2 / 3 (b) V F n (c) VF n1 / 2 (d) V F n1 / 3
Ans: (d)
Solution: V F
m
3 2 n
1/ 3
Q17. The total energy, E of an ideal non-relativistic Fermi gas in three dimensions is given by
N 5/3
E where N is the number of particles and V is the volume of the gas. Identify the
V 2/3
CORRECT equation of state (P being the pressure),
1 2 5
(a) PV E (b) PV E (c) PV E (d) PV E
3 3 3
Ans: (b)
Q18. Which one of the following CANNOT be explained by considering a harmonic
approximation for the lattice vibrations in solids?
(a) Deby’s T3 law (b) Dulong Petit’s law
(c) Optical branches in lattices (d) Thermal expansion
Ans: (d)
Solution: Thermal expansion in solid can only be explained if solid behave as a anharmonic
oscillator.
Q19. A simple cubic crystal with lattice parameter a c undergoes transition into a tetragonal
1 1 3 3
(a) (b) (c) (d)
6 6 8 8
Ans: (c)
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a a
Solution: For Cubic Lattice d c c
h2 k 2 l 2 2
a 2a c
For Tetragonal lattice d t
h k
2
l 2 2
3
2
2
a c
dc 3
Therefore the ratio is
dt 8
Q20. Inverse susceptibility (1/χ) as a function of temperature, T for a material undergoing
paramagnetic to ferromagnetic transition is given in the figure, where O is the origin. The
values of the Curie constant, C, and the Weiss molecular field constant, λ, in CGS units,
are
1
600 K
(a) C 5 10 5 , 3 10 2
(b) C 3 10 2 , 5 10 5 O T
(c) C 3 10 2 , 2 10 4
2 10 4
(d) C 2 10 , 3 10
4 2
(CGS unit)
Ans: (c)
1 T TC 1
Solution: and TC C . Here TC 600 K and 2 10 4
C
Thus C 3 10 2 and 2 10 4 .
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Aa 2 1 Aa 2
(a) 0 (b) 1 (c) (d)
2 2 2
Ans: (a)
Solution: At the first Brillouin zone the frequency is maximum and the group velocity which is
the derivative of the angular frequency is zero.
Q22. The force constant between the nearest neighbour of the lattice is (M is the mass of the
atom)
MA 2 MA 2
(a) (b) (c) MA2 (d) 2MA2
4 2
Ans: (a)
4K MA 2
Solution: A K
M 4
GATE-2013
Q23. A phosphorous doped silicon semiconductor (doping density: 1017/cm3) is heated from
100C to 200C. Which one of the following statements is CORRECT?
(a) Position of Fermi level moves towards conduction band
(b) Position of dopant level moves towards conduction band
(c) Position of Fermi level moves towards middle of energy gap
(d) Position of dopant level moves towards middle of energy gap
Ans: (c)
Solution: Phosphorous doped silicon semiconductors behave as a n-type semiconductor. In
n-type semiconductor Fermi level lies near conduction band and moves toward middle of
the band gap upon heating. At a very high temperature the Fermi level is near the middle
of the band gap and semiconductor behaves as intrinsic semiconductor.
Q24. Considering the BCS theory of superconductors, which one of the following statements is
NOT CORRECT? ( h is the Plank’s constant and e is the electronic charge)
(a) Presence of energy gap at temperature below the critical temperature
(b) Different critical temperature for isotopes
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h
(c) Quantization of magnetic flux in superconduction ring in the unit of
e
(d) Presence of Meissner effect
Ans: (c)
h
Solution: Quantization of magnetic flux in superconduction ring in the unit of
2e
Q25. Group I contains elementary excitations in solids. Group II gives the associated field with
these exciations. MATCH the excitations with their associated field and select your
answer as per codes given below.
Group I Group II
(P) phonon (i) photon + lattice vibration
(Q) plasmon (ii) electron +elastic deformation
(R) polaron (iii) collective electron oscillations
(S) polariton (iv) elastic wave
Codes
(a) P iv , Q iii , R i , S ii (b) P iv , Q iii , R ii , S i
(c) P i , Q iii , R ii , S iv (d) P iii , Q iv , R ii , S i
Ans: (b)
Solution: Phonon: Quantum of energy of the elastic wave in solid, produced due to the vibration
of atoms in solid.
Plasmon: Quantum of energy of the wave produced due to the oscillation of plasma,
which contains charged particles (positive ions and negative electrons or ions).
Polaron: A charge placed in a polarizable medium will be screened. The induced
polarization will follow the charge carrier when it is moving through the medium. The
carrier together with the induced polarization is considered as one entity, which is called
a polaron.
Polariton: A polariton is a quasiparticle resulting from the mixing of a photon with
phonon.
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Q26.
A lattice has the following primitive vector in Å : a 2 ˆj kˆ , b 2 kˆ iˆ , c 2 iˆ ˆj .
The reciprocal lattice corresponding to the above lattice is
(a) BCC lattice with cube edge of Å -1
2
(b) BCC lattice with cube edge of 2 Å -1
(c) FCC lattice with cube edge of Å -1
2
(d) FCC lattice with cube edge of 2 Å -1
Ans: (a)
Solution: The reciprocal lattice vectors are
b c
a 2 - î ĵ k̂ Å -1
a b c 2
ca
b 2 î ĵ k̂ Å -1
a b c 2
a b
c 2 î ĵ k̂ Å -1
a b c 2
e2 B
Q27. The total energy of an ionic solid is given by an expression E 9 where
4 0 r r
is Madelung constant, r is the distance between the nearest neighbours in the crystal and
B is a constant. If r0 is the equilibrium separation between the nearest neighbours then
the value of B is
e 2 r08 e 2 r08 2 e 2 r010 e 2 r010
(a) (b) (c) (d)
36 0 4 0 9 0 36 0
Ans: (a)
dE e2 9B e 2 r08
Solution: At r r0 , 0 10 B
dr r r0 4 0 r0 r0
2
36 0
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Q28. The Miller indices of a plane passing through the three points having coordinates (0, 0, 1)
1, 0, 0 1 , 1 , 1 are
2 2 4
(a) (212) (b) (111) (c) (121) (d) (211)
Ans: (a)
Q29. The plot of specifies heat versus temperature across the superconducting transition
temperature Tc is most appropriately represented by
(a) (b)
Cp Cp
TC T TC T
(c) (d)
Cp Cp
TC T TC T
Ans: (a)
Solution: CV e 2kT
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Q30. The energy k for band electrons as a function of the wave vector k in the first Brillouin
zone k of a one dimensional monatomic lattice is shown as ( a is lattice
a a
k
constant)
k
/a O /a
(a) vg (b) vg
/a k /a k
O /a O /a
(c) (d)
vg vg
/a k /a k
O /a O /a
Ans: (b)
ka
Solution: E E0 cos
1 dE ka
Vg sin
dk
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Q31. For Nickel the number density is 8 10 atoms / cm 3 and electronic configuration is
23
GATE-2015
Q31. The energy dependence of the density of states for a two dimensional non-relativistic
electron gas is given by, g E CE n , where C is constant. The value of n
is____________
Ans.: 0
Solution: We know that
g E E1/ 2 for 3 D , g E E 0 for 2 D , g E E 1/ 2 for 1 D
n 0 for 2 D
Q32. The lattice parameters a, b, c of an orthorhombic crystal are related by a 2b 3c . In
units of a the interplanar separation between the 110 planes is ____________. (Upto
three decimal places)
Ans.: 0.447
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1 1 a
Solution: d hkl d110 0.447 a 2b 3c
2
h k 2
l 2
1 1 5
0
a 2 b2 c2 a 2 a 2
2
Q33. The dispersion relation for phonons in a one dimensional monatomic Bravais lattice with
lattice spacing a and consisting of ions of masses M is given by
2c
k 1 coska , where is the frequency of oscillation, k is the wavevector
M
and C is the spring constant. For the long wavelength modes a , the ratio of the
phase velocity to the group velocity is_________
Ans.: 1
2C
Solution: k 1 cos ka
M
For long wavelength modes a
ka 2C ka
2 2
C
cos ka 1 k 1 1 a k
2 M 2 M
C d C
Phase velocity vP a and Group velocity vg a
k M dk M
vP
1
vg
Q34. In a Hall effect experiment, the hall voltage for an intrinsic semiconductor is negative.
This is because (symbols carry usual meaning)
(a) n p (b) n p (c) * h (d) m* mn*
Ans.: (c)
Solution: The Hall voltage is V H RH JB
where J : current density, B : magnetic field and R H : Hall constant
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1 p p n n p n n p B
2 2 2 2 2
RH
e n p 2 p n 2 2 2 B 2
n p n p
1 p n
For intrinsic semiconductor n p ni RH
eni p n
Q35. Which one of the following represents the electron occupancy for a superconductor in its
normal and superconducting states?
E E E E
f E f E f E f E
Ans. : (d) E E E E
Solution: In normal slide, some states below Fermi levels are empty and equal number of states
above Fermi levels are filled. If material converts into a superconductor, electrons above
the Fermi Level makes cooper pair and they fall back below level Fermi level as same
energy released during cooper pair formation. Therefore, correct option is (d).
Q36. Given that the Fermi energy of gold is 5.54 eV , the number density of electrons is
2 9.110 kg
31 3/ 2
1
5.54 1.6 109 J
3/ 2
n
3 3.14 1.0546 10 J s
2 34
(a) R H E 2
F (b) R H E 3
F
3
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(c) Both types of atoms vibrate with equal amplitudes in the optical as well as in the
acoustical modes.
(d) Both types of atoms vibrate, but with unequal, non-zero amplitudes in the optical as
well as in the acoustical modes.
Ans.: (a)
Solution: In optical mode, at Brillouin zone boundary atom of heavier mass m2 is at rest,
1 1
2
optical mode m
1 m2
2 2 / m1
Acoustic 1 2 / m2
mode
2a k 2a
Q39. A solid material is found to have a temperature independent magnetic susceptibility,
C . Which of the following statements is correct?
(a) If C is positive, the material is a diamagnet.
(b) If C is positive, the material is a ferromagnet.
(c) If C is negative, the material could be a type I superconductor.
(d) If C is positive, the material could be a type I superconductor.
Ans.: (b)
Solution: Susceptibility is defined as 1 , where 0 is permeability of medium and
0
vacuum respectively.
(i) For Diamagnet; 0 , thus 0 i.e. is negative
2a
Position of new r
x
a a
atom 0, , 0 a new atom at 0, ,0
figure (i) 2 2
2
figure (ii)
If new atom of radius r fit without distorting the original lattice, then from figure (ii) we get
a
Rr (i)
2
4
whereas for FCC 2a 4 R a R 2 2R (ii)
2
Thus from (i) and (ii)
2 2
2
R Rr
2 1 R r
r
R
2 1 1.414 1 0.414
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Q41. The energy vs. wave vector E k relationship near the bottom of a band for a solid can
values of A and B are 6.3 10 19 J and 3.2 10 20 J , respectively. At the bottom of
the conduction band, the ratio of the effective mass of the electron to the mass of free
electron is _______. (Give your answer upto two decimal places)
(Take 1.05 10 34 J s , mass of free electron 9.110 31 kg )
Ans.: 0.22
Solution: E A ka B ka
2 4
E 2 E
2 Aa 2 k 4 Ba 4 k 3 and 2 Aa 2 12 Ba 4 k 2
k k 2
m* 19.84 1032 kg
19.84 1032 kg 31
2.18 101 0.218 0.22
m 9.1 10 kg
Q42. The Fermi energies of two metals X and Y are 5 eV and 7 eV and their Debye
temperatures are 170 K and 340 K , respectively. The molar specific heats of these
metals at constant volume at low temperatures can be written as
CV X X T AX T 3 and CV Y Y T AY T 3 where and A are constants. Assuming
that the thermal effective mass of the electrons in the two metals are same, which of the
following is correct?
X 7 AX X 7 AX 1
(a) , 8 (b) ,
Y 5 AY Y 5 AY 8
X 5 AX 1 X 5 AX
(c) , (d) , 8
Y 7 AY 8 Y 7 AY
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Ans.: (a)
Solution: Heat capacity is defined as CV T AT 3
3 2 1 12 4 1 1
where Nk B and A Nk B 3 234 Nk B 3
2 EF 5 D D
3 2 1
Nk B
x 2 EFx EF y 7eV 7
Thus,
y 3 Nk 2 1 EFx 5eV 5
B
2 EFy
1
234 Nk B 3
Ax D3 x Dy 340 3
2 8
3
and
Ay 234 Nk 1 D 170
B 3 x
Dy
x 7 A
Thus, and x 8
y 5 Ay
GATE-2017
Q43. The atomic mass and mass density of Sodium are 23 and 0.968 g cm 3 , respectively. The
Ans. : 2.54
neff M neff NA
Solution: n
NA a 3
a 3
M
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Institute for NET/JRF, GATE, IIT‐JAM, JEST, TIFR and GRE in PHYSICAL SCIENCES
2 x
Q44. Consider a one dimensional lattice with a weak periodic potential U x U 0 cos .
a
The gap at the edge of the Brillouin zone k is:
a
U0 U0
(a) U 0 (b) (c) 2U 0 (d)
2 4
Ans. : (c)
2
Solution: U U 0 cos x
a
2 a
Energy at the edge of Brillouin Zone is U t U 0 cos .
a
Energy at the k 0 is U b U 0
2
nh 2 1019 6.6 1034
EF 0.37 1018 J 2.32eV
4 m 4 3.14 9.311031
Ans. : 2.34
1.055 1034 J s
2
2
Solution: EF 2 n 31
2 3.142 1019
2 m 2 9.31 10
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Institute for NET/JRF, GATE, IIT‐JAM, JEST, TIFR and GRE in PHYSICAL SCIENCES
Q46.
a
The real space primitive lattice vectors are a1 axˆ and a2 xˆ 3 yˆ . The reciprocal
2
space unit vectors b1 and b2 for this lattice are, respectively
2 yˆ 4 2 yˆ 4
(a)
a xˆ and yˆ (b)
a xˆ and yˆ
3 a 3 3 a 3
2 4 xˆ 2 4 xˆ
(c) xˆ and yˆ (d) xˆ and yˆ
a 3 a 3 a 3 a 3
Ans. (a)
Solution:
a1 axˆ ,
a
a2 xˆ 3 yˆ
2
assume, a3 zˆ
a
Now, a1 a2 a3 axˆ. xˆ 3 yˆ zˆ
2
a 2 xˆ
2
a2
yˆ 3xˆ 0 3
2
3a 2
2
a2 a3 3 xˆ yˆ a2
b 2 2
a1 a2 a3 3 2
a
3
2 yˆ
b1 xˆ
a 3
a3 a1 4
Similarly, b2 2 yˆ
a1 a2 a3 3a
Thus correct option is (a)
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