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Especies Cu O S kcal/mol
1 Cu 1,000 0.000 0.000 0.000
2 CuO 1,000 1,000 0.000 -16,376
3 Cu2O 2,000 1,000 0.000 -23,310
4 CuO*CuSO4 2,000 5,000 1,000 -115,167
5 CuS 1,000 0.000 1,000 -11,192
6 Cu2S 2,000 0.000 1,000 -24,532
7 CuSO4 1,000 4,000 1,000 -97,408
X= O2(g) 0.000 2,000 0.000 0.000
Y= SO2(g) 0.000 2,000 1,000 -69,513
REACTIONS at T = 973.000
1 1.000 Cu + 0.500 O2(g) -> CuO
2 2.000 Cu + 0.500 O2(g) -> Cu2O
3 2.000 Cu + 1.500 O2(g) + 1.000 SO2(g) -> CuO*CuSO4
4 1.000 Cu + 1.000 SO2(g) -> 1.000 O2(g) + CuS
5 2.000 Cu + 1.000 SO2(g) -> 1.000 O2(g) + Cu2S
6 1.000 Cu + 1.000 O2(g) + 1.000 SO2(g) -> CuSO4
7 2.000 CuO -> 0.500 O2(g) + Cu2O
8 2.000 CuO + 0.500 O2(g) + 1.000 SO2(g) -> CuO*CuSO4
9 1.000 CuO + 1.000 SO2(g) -> 1.500 O2(g) + CuS
10 2.000 CuO + 1.000 SO2(g) -> 2.000 O2(g) + Cu2S
11 1.000 CuO + 0.500 O2(g) + 1.000 SO2(g) -> CuSO4
12 1.000 Cu2O + 1.000 O2(g) + 1.000 SO2(g) -> CuO*CuSO4
13 0.500 Cu2O + 1.000 SO2(g) -> 1.250 O2(g) + CuS
14 1.000 Cu2O + 1.000 SO2(g) -> 1.500 O2(g) + Cu2S
15 0.500 Cu2O + 0.750 O2(g) + 1.000 SO2(g) -> CuSO4
16 0.500 CuO*CuSO4 + 0.500 SO2(g) -> 1.750 O2(g) + CuS
17 1.000 CuO*CuSO4 -> 2.500 O2(g) + Cu2S
18 0.500 CuO*CuSO4 + 0.250 O2(g) + 0.500 SO2(g) -> CuSO4
19 2.000 CuS + 1.000 O2(g) -> 1.000 SO2(g) + Cu2S
20 1.000 CuS + 2.000 O2(g) -> CuSO4
21 0.500 Cu2S + 1.500 O2(g) + 0.500 SO2(g) -> CuSO4
Log pSO2(g)
-0.368
-0.777
0.465
2681
6413
Log pSO2(g)
2681
0.465
2681
6413
-0.368
-0.368
-0.777
-0.777
0.465
6413
6413
DeltaG,
Especies Cu O S kcal/mol
1 Cu 1,000 0.000 0.000 0.000
2 CuO 1,000 1,000 0.000 -16,376
3 Cu2O 2,000 1,000 0.000 -23,310
4 CuO*CuSO4 2,000 5,000 1,000 -115,167
5 CuS 1,000 0.000 1,000 -11,192
6 Cu2S 2,000 0.000 1,000 -24,532
7 CuSO4 1,000 4,000 1,000 -97,408
X= O2(g) 0.000 2,000 0.000 0.000
Y= SO2(g) 0.000 2,000 1,000 -69,513