Nama Puri Nurul Chasanah

NIM 21160039

Suatu komponen sebanyak 4200 lb/jam

Maksimum 3% berat n-C4 keluar di destilat

Maksiumum 1% berat i-C4 keluar di bottom

Kondisi operasi Destilat P = 112.5

Kondisi operasi Tengah P = 115 ∆P = 5 antara atas (destilat) dan bawah (bottom)
Kondisi operasi Bottom P = 117.5

komponen wtv% lb/jam mol/berat mol/jam % mol

propane 5 210 44.1 4.7619047619 0.0724614341
n-butan 25 1050 58.1 18.072289157 0.275004238
i-butan 15 630 58.1 10.843373494 0.1650025428
i-pentan 20 840 72.1 11.650485437 0.1772842855
pentan 35 1470 72.1 20.388349515 0.3102474996
Σ= 100 4200 65.716402364 1

BM rata-rata= berat komponen/(jumlah mol/jam) Berat komponen = 4200 lb/in

= 4200/65,71640236 Jumlah mol/jam = 65.716402364
= 63.910984913

n-C4 di D 3% total produk destilat

i-C4 di B 1% total produk bottom

komponen feed destilat bottom

propane 210 210 0
n-butan 1050 1050 -X X
i-butan 630 630 Y 630 -Y
i-pentan 840 0 840
pentan 1470 0 1470
Σ= 1890 -X+Y 2940 +X-Y

Y(1890-X+Y) = 3/100 X(2840+X-Y) = 1/100

Y = (1890*0,03) - (x*0,03) + (Y*0,03) X = (2940*0,01) + (X*0,01) - (Y*0,01)
0,97Y = 56,7 - 0,03X 0,99X = 29,4 - 0,01Y
Y = 58,54 - 0,0393X X = 29,697 - 0,0101Y
sehingga sehingga
X = 29,697 - 0,0101Y Y = 58,45 - 0,0393X
X = 26,697 - (0,0101*(58,45 - 0,0393)) Y = 58,45 - (0,0393*29,12)
X = 29,697 - 0,59 + 0,0004X Y = 57.31
X = 29.12

Distribusi komponennya

komponen feed destilat lb/jam BM bottom lb/jam

propane 210 210 44.1 0

n-butan 1050 57.31 58.1 992.69
i-butan 630 600.88 58.1 29.12
i-pentan 840 0 72.1 840
pentan 1470 0 72.1 1470

destilat bottom
komponen feed mole/jam mole/jam
propane 4.7619047619 4.7619 0
n-butan 18.072289157 0.9864 17.08589
i-butan 10.843373494 10.3422 0.501205
i-pentan 11.650485437 0 11.65049
pentan 20.388349515 0 20.3885
Σ = 65.716402364 16.0905 49.626085
 Destilat P = 112.5 lb/in
komponen fraksi mol K 110°F x = Y/K
propane 0.29594555 1.95 0.15176695
n-butan 0.06130352 0.98 0.06255461
i-butan 0.64275094 0.72 0.89270964
i-pentan 0 0.33 0
pentan 0 0.27 0
Σ= 1.00000001 1.1070

Bottom P = 117.5 lb/in

komponen fraksi mol K 200°F y = K*x
propane 0 3.65 0
n-butan 0.34429355 1.5 0.516440325
i-butan 0.01009966 1.95 0.019694337
i-pentan 0.23476611 0.77 0.1807699047
pentan 0.41084069 6.6 2.711548554
Σ= 1.00000001 14.47 3.4284531207

Kondisi Operasi
suhu tekanan lb/in
op atas 110 112.5
op tengah 165 115
op bawah 200 117.5

maka
point 1 atas point 2 umpan point 3 bawah
komponen α rata-rata
K α K α K α
propane 1.95 1.9897959184 3.65 2.4333333333 2.9 2.6363636364 2.353164296
n-butan Hk 0.98 1 1.5 1 1.1 1 1
i-butan Lk 0.72 0.7346938776 1.95 1.3 1.5 1.3636363636 1.1327767471
i-pentan 0.33 0.3367346939 0.77 0.5133333333 5.3 4.8181818182 1.8894166151
pentan 0.27 0.2755102041 6.6 4.4 4.5 4.0909090909 2.922139765
log⁡〖 (���/�ℎ�)𝐷.⁡(𝑥ℎ𝑘/𝑥�𝑘)� 〗 /log⁡〖 α�𝑘‐
ℎ𝑘 〗
 log⁡〖 (���/�ℎ�)𝐷.⁡(𝑥ℎ𝑘/𝑥�𝑘)� 〗 /log⁡〖 α�𝑘‐
ℎ𝑘 〗
αlk = 1.1327767471
Nmin = αhk = 1
αlk-hk = log 1,1/1

Nmin = 642.54948838 -1.813461039

Jika umpan masuk pada bubble point maka q = 1

komponen feed fraksi mol α rata-rata
propane 4.7619047619 2.353164296
n-butan 18.072289157 1
i-butan 10.843373494 1.1327767471
i-pentan 11.650485437 1.8894166151
pentan 20.388349515 2.922139765
Σ = 65.716402364 9.2974974232

komponen Xf α rata-rata ɸ trial α*x α-ɸ (α*x)/(α-ɸ)

propane
n-butan Hk
i-butan Lk
i-pentan
pentan
Nama Puri Nurul Chasanah
NIM 21160039

1 Campuran terdiri dari CH4 20%, C2H6 3%, C3H8 30%, i-CH4 10%, n-CH4 10%. Persen dalam mol.
hitung titik didih dan titik embun campuran, tekanan campuran jika
a. Tekanan 5 atm (dicari suhunya)
b. Berapa tekanan campuran suhunya adalah -10%

2 Kerjakan contoh dengan Antoin di atas jika komposisi hasil atas C5 0,1; C6 0,7; C7 0,2
Hasil bawah C6 0,5; C7 0,95
Tekanan operasi 1,5 atm

Penyelesaian :
1a mencari titi embun (x)
Tekanan = 5 atm
suhu = 278.39139 K

ln = Ant A - (𝐴𝑛𝑡⁡�)/
(263⁡𝐾+𝐴𝑛𝑡⁡𝐶)

Komponen % massa fraksi mol Ant A Ant B Ant C ln Po

CH4 20% 0.2 15.2243 597.04 -7.16 13.0230799
C2H6 30% 0.3 15.6637 1511.42 -17.16 9.87794813
C3H8 30% 0.3 15.726 1872.46 -25.16 8.331735
i-C4H10 10% 0.1 15.5381 2032.73 -32.15 7.28307024
n-C4H10 10% 0.1 15.6782 2154.9 -34.42 6.84560695

komponen Y K = Po/Pt x = Y/K

CH4 0.2 119.1428871 0.00167866
C2H6 0.3 5.130441862 0.0584745
C3H8 0.3 1.093057329 0.27445953
i-C4H10 0.1 0.383013092 0.26108768
n-C4H10 0.1 0.247300918 0.40436566
Σ= 1.00006603

mencari titik didih (y)

Tekanan = 5 atm
suhu = 80.1015439 K
Komponen % massa fraksi mol Ant A Ant B Ant C ln Po
CH4 20% 0.2 15.2243 597.04 -7.16 7.03911543
C2H6 30% 0.3 15.6637 1511.42 -17.16 -8.3493748
C3H8 30% 0.3 15.726 1872.46 -25.16 -18.35495
i-C4H10 10% 0.1 15.5381 2032.73 -32.15 -26.853236
n-C4H10 10% 0.1 15.6782 2154.9 -34.42 -31.494024

komponen X K = Po/Pt y = K*X

CH4 0.2 5.001659706 1.00033194
 C2H6 0.3 1.037475E-06 3.1124E-07
C3H8 0.3 4.683945E-11 1.4052E-11
i-C4H10 0.1 9.546695E-15 9.5467E-16
n-C4H10 0.1 9.212649E-17 9.2126E-18
Σ= 1.00033225

1b mencari tekanan campuran

suhu = -10 C 263 K
tekanan = 2216.46114 atm
Komponen % massa fraksi mol Ant A Ant B Ant C ln Po
CH4 20% 0.2 15.2243 597.04 -7.16 12.890654
C2H6 30% 0.3 15.6637 1511.42 -17.16 9.51571757
C3H8 30% 0.3 15.726 1872.46 -25.16 7.85322839
i-C4H10 10% 0.1 15.5381 2032.73 -32.15 6.73268523
n-C4H10 10% 0.1 15.6782 2154.9 -34.42 6.25086603

komponen Y K = Po/Pt X = Y/K

CH4 0.2 178.9286009 0.00111776
C2H6 0.3 6.122989453 0.04899567
C3H8 0.3 1.161324619 0.2583257
i-C4H10 0.1 0.378711001 0.26405359
n-C4H10 0.1 0.233914153 0.42750727
Σ= 1

suhu = -10 C 263 K

tekanan = 110.907364 atm
Komponen % massa fraksi mol Ant A Ant B Ant C ln Po
CH4 20% 0.2 15.2243 597.04 -7.16 12.890654
C2H6 30% 0.3 15.6637 1511.42 -17.16 9.51571757
C3H8 30% 0.3 15.726 1872.46 -25.16 7.85322839
i-C4H10 10% 0.1 15.5381 2032.73 -32.15 6.73268523
n-C4H10 10% 0.1 15.6782 2154.9 -34.42 6.25086603

komponen X K = Po/Pt y = K*X

CH4 0.2 4.705068068 0.94101361
C2H6 0.3 0.161008816 0.04830264
C3H8 0.3 0.030537943 0.00916138
i-C4H10 0.1 0.009958503 0.00099585
n-C4H10 0.1 0.006150956 0.0006151
Σ= 1.00008859
en dalam mol.

Po (mmHg) Po atm
452742.971 595.71443561
19495.6791 25.652209309
4153.61785 5.4652866472
1455.44975 1.9150654602
939.743487 1.2365045882

Po (mmHg) Po atm
1140.37841 1.5004979119
0.00023654 3.112426E-07
1.0679E-08 1.405183E-11
2.1766E-12 2.864008E-15
2.1005E-14 2.763795E-17
Po (mmHg) Po atm
396588.291 521.82669871
13571.3682 17.857063409
2574.03089 3.3868827499
839.398218 1.1044713401
518.461631 0.6821863566

Po (mmHg) Po atm
396588.291 521.82669871
13571.3682 17.857063409
2574.03089 3.3868827499
839.398218 1.1044713401
518.461631 0.6821863566