Professional Documents
Culture Documents
Implementation
IN
Textile Sector
Submitted by:
Sr. Page
Chapter
No. No.
8 References 73
1. Best available techniques
The term “best available techniques” is defined as “the most effective and
advanced stage in the development of activities and their methods of operation
which indicate the practical suitability of particular techniques for providing in
principle the basis for emission limit values designed to prevent and, where that
is not practicable, generally to reduce emissions and the impact on the
environment as a whole.”
“Techniques” includes both the technology used and the way in which the
installation is designed, built, maintained, operated and decommissioned;
“Best” means most effective in achieving a high general level of protection of the
environment as a whole.
The techniques and associated emission and/or consumption levels, or ranges of
levels, have been assessed through an iterative process involving the following
steps:
On the basis of this assessment, techniques, and as far as possible emission and
consumption levels associated with the use of BAT, are presented that are
considered to be appropriate to the sector as a whole and in many cases reflect
current performance of some installations within the sector. Where emission or
consumption levels “associated with best available techniques” are presented,
this is to be understood as meaning that those levels represent the
environmental performance that could be anticipated as a result of the
application, in this sector, of the techniques described, bearing in mind the
balance of costs and advantages inherent within the definition of BAT.
However, they are neither emission nor consumption limit values and should not
be understood as such. In some cases it may be technically possible to achieve
better emission or consumption levels but due to the costs involved or cross-
media considerations, they are not considered to be appropriate as BAT for the
sector as a whole. However, such levels may be considered to be justified in
more specific cases where there are special driving forces.
Where available, data concerning costs have been given together with the
description of the techniques. These give a rough indication about the magnitude
of costs involved. However, the actual cost of applying a technique will depend
strongly on the specific situation regarding, for example, taxes, fees, and the
technical characteristics of the installation concerned. It is not possible to
2
evaluate such site-specific factors fully in this document. In the absence of data
concerning costs, conclusions on economic viability of techniques are drawn from
observations on existing installations.
It is intended that the general BAT is a reference point against which to judge the
current performance of an existing installation or to judge a proposal for a new
installation. In this way they will assist in the determination of appropriate "BAT-
based" conditions for the installation. It is foreseen that new installations can be
designed to perform at or even better than the general BAT levels presented
here. It is also considered that existing installations could move towards the
general BAT levels or do better, subject to the technical and economic
applicability of the techniques in each case.
While the BAT reference documents do not set legally binding standards, they are
meant to give information for the guidance of industry, Member States and the
public on achievable emission and consumption levels when using specified
techniques.
3
2. Scenario of Indian Textile Industry
Background
Indian textile industry is one of the largest textile industries in the world. Today,
the textile manufacturing and exports is making significant contribution to the
Indian economy. India earns around 27% of the foreign exchange from exports
of textiles. Further, Indian textile industry contributes about 14% of the total
industrial production of India. Indian textile industry involves around 35 million
workers directly and it accounts for 21% of the total employment generated in
the economy.
Huge
Use of outdated
unorganized and
Efficient multi- manufacturing
decentralized
Strengths of fibre raw technology
Huge export sector
Indian Textile material Weaknesses of
potential Indian Textile
Industry manufacturing
capacity Industry
4
close physical proximity to production sites. Consumers across the world are
becoming increasingly aware of environmental issues, as well as more sensitive
to the conditions in which the products they consume are produced. Pro-active
approaches in protecting environment and health, and taking safety measures,
will be will be the key steps in ensuring long term competitiveness of the Indian
textile and craft sectors.
The top five textiles and garment exporting nation are US, China, India,
Germany and Japan and United kingdom. USA is the largest importer with a
share of 17% of the total global trade. The Indian textile and garment industry
has an important presence in the country’s economy through its contribution to
industrial output, employment generation, and the export earnings. It
contributes almost 5% to the $ 1.8 trillion Indian economy whereas its share in
Indian exports.
Introduction
India Textile Industry is one of the leading textile industries in the world. There
are more than 70 textiles and clothing clusters in India. These clusters contribute
about 80% of total production. There are 39 power loom clusters and 13
readymade garment clusters in India. Bhiwandi and Malegaon are the two largest
power loom clusters.
The total textile exports during 2013-14 was valued at INR 239221.80 crore (in
2013-14) as against INR 189940.65 crore (in 2012-13) and registered growth of
25.95% in Rupee term. During the year 2013-14, Readymade Garments account
for almost 37% of the total textiles exports. As per latest available statistics
5
during the first nine months of 2014-15, exports of RMG account for 47% of the
total textiles exports. Cotton textiles (35%) and Man-made textiles (18%).
In 2012, Apparel had a share of 69% of overall market, textile contributed the
remaining 61%.The top five textiles and garment exporting nation are China,
India, Italy, Germany and Turkey.
Tamil Nadu is the leading state in India in terms of number of factories for
textiles and garments industry in India.
India is the one of the world’s largest producers of textile and garments. The
potential size of the indian textiles and apparel industry is expected to reach
14,718 billion by 2021. The industry realised export earnings worth 2742.17
billion in 2013-14. It is also one of the largest contributing sectors of India’s
exports contributing 11 per cent to the country’s total exports basket. The sector
contributes about 14% to the industrial production, 4% to the gross domestic
product (GDP), and 27% to the country’s foreign exchange inflows. It provides
direct employment to over 45 million people. The textile sector is the second
largest provider of employment after agriculture.
Number of
Sr. Percentage
States Factories in
No. share (%)
Operation
1 Tamil Nadu 5601 34.78
2 Maharashtra 1811 11.25
3 Gujarat 1660 10.31
4 Rajasthan 1237 7.68
6
5 Punjab 899 5.58
6 Karnataka 893 5.55
7 Uttar Pradesh 881 5.47
8 Haryana 663 4.12
9 Delhi 619 3.84
10 Kerala 400 2.48
11 Andhra Pradesh 394 2.45
12 West Bengal 305 1.89
13 Dadra and Nagar Haveli 205 1.27
14 Madhya Pradesh 175 1.09
15 Daman and Diu 131 0.81
16 Himachal Pradesh 43 0.27
17 Orissa 39 0.24
18 Assam 26 0.16
19 Jammu and Kashmir 28 0.17
20 Pondicherry 24 0.15
21 Bihar 17 0.11
22 Uttaranchal 16 0.10
23 Goa 15 0.09
24 Chhattisgarh 13 0.08
25 Jharkhand 9 0.06
26 Total 16104 100.00
Source: Annual Survey of India
Gujarat is one of the leading industrial states in India and textile industry in
particular had contributed in a big way to the industrialization of the State. In
fact, overall economic growth of the State is very much dependent on this sector.
Gujarat is the leader in textile comprising of 1,560 medium and large textile
units. Textile Industry plays an important role in Indian economy, as well. It is
an employment oriented industry, occupying the second position i.e. after
Agriculture. Around 25% of fixed investment, production value and employment
of the SSI sector are from textiles alone. Further, 23% of GDP comes out of
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textiles in the State, 16% of the cultivated land area of the state is for cotton
and Gujarat is the largest cotton producer in the country.
Large Fabric Process Houses are concentrated in Ahmedabad (250) and Surat
(450) in the State. The State accounts for 12% share of the total textile exports
of the country. A large number of Garment Units and Garment Processing Units
are developed in urban areas of the State. Clusters of processing units are
located at Surat, Ahmedabad (Narol) and Jetpur. Though these units fall under
decentralized sector, some of them operate on medium scale production capacity
having good capability of processing wide range of fabrics.
8
By 1950, nearly 0.125 million workers were employed in the textile mills. Around
1960 nearly two thirds of the industrial production was in textile and allied
industries. It also generated directly half of the total industrial employment in the
state. Prior to 1985 there were 85 textile mills in Ahmedabad city. While
Ahmedabad continued to be dominated by its textile industries, the state also
created infrastructure for industrial development in Naroda, Odhav and Vatva
which led to a significant diversification in the small and medium industries,
related to engineering goods and chemicals.
Textile Processing Industry has flourised leaps and bound in South Gujarat
particularly in Surat district. There are nearly five lakhs of power looms in Surat,
which consumes yarn of about four lakhs of metric tons in preparing the grey
fabrics. About two crores meters of grey textile is manufacture daily in Surat.
Today there are about 450 Dyeing and Printing Units located in and around Surat
in various clusters - Pandesara, Sachin, Kadodara and Palsana.
These Dyeing and Printing Units are engaged in processing of manmade fabrics,
i.e. Dyeing, Bleaching, Printing, Finishing of grey fabrics. Mostly these units are
processing the grey fabrics on job work basis. They receive the grey fabrics from
the Traders / Merchant Manufacturers of the market and process the fabrics as
per their requirement. There are about 150 wholesale markets in Surat. The city
of Surat is now known as "Silk City".
The power loom sector gives employment to about 6 lakhs people. Similarly, the
processing industry gives employment to about 5 lakhs people. Besides, lakhs of
people are engaged in trade, transport, cutting, packing and ancillary industries
like dyes, colour, chemicals, textile engineering etc. Of the total production of
cloth in India, the synthetics fabrics accounts for about 90%.
9
Surat alone accounts for 40% exports of fabrics generating revenue of more than
Rs. 500 crores. It produces cheap fabrics affordable to poor people. Surat is
having a major petrochemical industrial area at Hajira, which is facilitating
production of yarn from petroleum, which is basic raw material for polyester
based textile industry.
10
3. Manufacturing Process of Textile Products
The production processes in textile and garment industries involve following five
stages:
Yarn Manufacturing
Textile Fibers Yarn
(Spinning Mill)
Fabric Manufacturing
Yarn (Weaving / Knitting industry) Grey Fabrics
Wet Processing
Grey Fabrics Finished Fabrics
(Dying / Printing & Finishing industry)
11
Flow Diagram of Wet process in textile industry
Grey Cloth
Shearing / Croping
Singeing
Desizing
Scouring
Bleaching
Stentering
Finishing
Calendaring
12
Textile manufacturing wet process
13
with sodium hydroxide to create lustre, more
strength and higher affinity for dyes in the fabric.
This process could be applied to woven or knitted
cotton fabrics.
This process is the finishing process in which the
yarn, fabrics, or garments are treated to add colour
and intricacy to the product, using dyestuffs,
auxiliaries, reductants, oxidants, etc. This process
Dyeing
is well known to be a major source of pollution due
to the many chemicals used, and the large
quantities of wastewater resulting from the process,
and loaded with pollutants.
In this process the fabric is printed with colour and
patterns, using pigments, dyes, acids, alkalis,
Printing
softener, binder and emulsifier solvents. Printing is
also one of the major sources for pollution.
In this process (for wool), woven or knitted wool
fabrics are treated with sulphuric acid to remove
Carbonizing
the vegetable cellulosic matter naturally existing in
wool fibres.
In the special finishing process (moth-proofing,
water repellent, stain resist, …etc.), the fabric is
Special
chemically treated to achieve certain characteristics
finishing
in the finished fabric giving it special performance,
such as water-proof, crease resistance, etc.
This process is considered as a mechanical finishing
Brushing and process, in which the fabric surface is subjected to
napping a brushing action to raise fibres from the yarns and
create a hairy surface in the fabric. This process
14
may be applied to both woven and knitted fabrics.
This process is also a mechanical finishing process
that is applied to woven fabric, to shear the
Shearing protruding fibres from fabric surface and create
smooth surface fabrics. This process is a source for
fibre particulates
This is a mechanical finishing process simulating,
the ironing process of fabric to produce smooth
Softening by unwrinkled surface. The woven fabric is passed
calendaring between smooth pressed rollers to remove surface
fibres and reduce friction between fibres, resulting
in soft feel in the fabric
This is a mechanical finishing process applied to
woven fabrics to compact the structure by passing
Sanforizing
the fabric between smooth heavy rollers, and
produce compacted fabrics
Source: Rajasthan State Pollution Control Board Environmental Guidance Manual –
Textiles Project
It is essential to control inputs to get right out puts from each process and to
reduce wastes. As the environmental impacts arise from the inputs into
processes, we need to understand the inputs in terms of raw material and
chemicals including dyes used in the processes. Table 5 provides information on
basic input materials requirement in different processes.
15
Table 4: Inputs to wet process
16
4. Environmental Issues in Textile Sector
17
Dye bath effluents may contain heavy metals, ammonia, alkali salts, toxic
solids and large amounts of pigments - many of which are toxic
Emissions of CO2, SOx, NOx and particulates associated with the on-site
burning of fossil fuels to produce thermal energy are also to be taken into
account.
Lint can originate from many textile production steps, particularly from
preparation, dying and washing operations. Usually removing lint is fairly easy
using primary control measures such as filters, which can be placed in the
circulation line of dyeing and other equipment. The filters must be maintained
and cleaned out on a regular basis to ensure proper operation. The collected
lint usually can be dried and then land filled or incinerated. Higher quality lint
can be marketed.
Stain remover (Carry solvents like CC14) : Ozone depletion, Capacity of ten
times more than CFC
Oxalic acid (Used for rust stain removal): Toxic to aquatic organism, Boosts
COD
Printing gums (Preservative pentachlorophenol): Dermatitis, Liver and Kidney
damage, Carcinogenic
Fixing agent like Formaldehyde and Benzindie is Harmful
Bleaching (Chlorine bleaching): Skin diseases (itching), harmful
Dyeing like Amino acid is Carcinogenic
Size is a mixture of primary and auxiliary chemicals. Three main types of size are
currently used.
18
Semi synthetic products (blends) (modified starch, starch ether, starch ester,
carboxy methyl cellulose (CMC), hydroxy ethyl cellulose (HEC), carboxy methyl
starch (CMS).
Adhesives and binders: Natural gum, (locust bean gum, tragasol, gelatine,
soya protein casein, acrylates, PVA, CMC).
Antistatic agents: To suppress static in high speed weaving.
Anti-sticking agents: To reduce fouling of dry cans and guide rollers (waxes,
oil, sulfatedtallow, pine oil, kerosene, and stoddard solvent.
Biocides: (preservative) o-phenyl phenol (OPP).
Deformers: Zinc and Calcium chloride, light mineral oil, isooctyl alcohol.
Deliquescent: Zinc and Calcium chloride, polyalcohol's (PEG), glycerine,
polypropylene glycol, Diethylene glycol (DEG), Urea.
Emulsifier, dispersants and surfactants: Non-ionic ethylene oxide
compounds
Humectants: To protect against drying.
Lubricants and Softeners: Fasts, waxes, oils, tallow, sulfated tallow, butyl
stearate, glycerine, mineral oil.
Thinning agents: enzyme, oxidizers, per borates, persulfats, peroxides,
chloramides.
Weighers: Clay
Any of these additives that are present in the size mixture will later be removed
in wet processing and thus all of these materials will appear in waste streams
from de-sizing operations. Most of these additives have very high BOD values
and the sizing agents are also responsible for up to 80% of the total COD load in
the wastewater. The toxicity of few of these additives has been recorded. In
19
addition to size and de-size chemicals removed from textile, sizing and de-sizing
operations generate additional wastes that deserve attention, including:
De-sizing: Artificial fibres are generally sized with water-soluble sizes that are
easily removed by a hot water wash or in the scouring process. On the other
hand natural fibres such as cotton are most often sized with water insoluble
starches or mixture of starch and other size materials. Enzymes are used to
break these starches into water-soluble sugars. Bacteria in waste treatment can
easily attack the water-soluble sugars and these are very degradable and have
high BOD.
Scouring: Cleaning process that removes impurities from fibres, yarn or cloth.
The impurities include lubricants, dirt and other natural materials, water-soluble
sizes, antistatic agents and fugitive tints used for yarn identification. Scouring
uses alkali to saponify natural oils and surfactants to emulsify and suspend non-
saponifiable impurities in the scouring bath.
20
Pollutants Associated with Dyeing Process
Many pollutants are associated with the dyes and chemicals used in dyeing
processes. These may originate from the dyes themselves (e.g. salt, surfactant,
levelers, lubricants, and alkalinity). Pollutant impacts are also associated with
chemicals used during dyeing, equipment maintenance and cleaning. Dyeing
contributes most of the metals and essential all of the salts and colour in effluent
from textiles operations, and these are priority areas for pollution prevention.
There are certain reports stating that dyeing consumes 7% of the water and
contributes 5% of the BOD in a typical cotton finishing operation.
Source: Impact of Textile in Environmental Issues and Environmental Legislation (Part I) By:
Karthik T. and Gopalakrishnan D.
21
Pollutants Associated with Printing Process
Textile printing, like dyeing also generates varying amounts and types of
pollutants.
The Table 6 presents the main pollutant associated with printing and identifies
their sources.
Source: Impact of Textile in Environmental Issues and Environmental Legislation (Part I) By:
Karthik T. and Gopalakrishnan D.
22
Pollutants Associated with Finishing Process
Solid wastes: Fabric scraps and trimmings from salvages and seams; fibre dust
and fragments from napping, shearing and related operation, paper tubes and
empty chemical drums.
Liquid: Discarded finishing mixes and rinse water from finishing implements and
equipment as well as facility clean up.
Vapours: Exhaust gases from drying and curing.
Apart from above pollutants in various processes the hazardous chemicals can
cause health hazards to workers
23
5. Existing Environment Management Techniques
The environmental concerns of the textile industry are centered on the textile
processing which generates water pollution (in the form of effluents) during the
process - mainly dyeing. Some ways in which textiles affect the environment
uniquely are: Wet treatments like de-sizing and scouring using oxygen-depleting
substances reduce the cleanliness of the water; Absorbable Organic Halides
(AOX) emissions, caused by less biodegradable organic halogenated compounds
result from bleaching processes; high Chemical Oxygen Demand (COD) arising
from cotton de-sizing; strong alkaline effluent from mercerization; Dyeing
process produces effluent with high COD, metals, toxic substances, salts, etc.,
originating from the dyes and dispersing agents. Such effluent is released to
water sources such as river, resulting in pollution. Though textile industry
produces both air and water pollution, it pollutes water more significantly than
air.
There are numerous technologies developed across the world, even in India, to
mitigate pollution in the textile sector. Water pollution in textile processing sector
has been addressed in India, mainly by treating the effluents, through the ETPs
and CETPs. These plants involve physico-chemical treatment of the waste-water
using lime and ferrous sulphate. However these are not widespread and the
pollution-related parameters in the treated water are still not within the safe
limits at certain locations. There is a scope of improving the infrastructure and
functioning of these plants.
The main environmental impacts of the textile chain derive from the so-called
"wet processes", mainly implemented by the textile finishing industry. Water is
used as the principal medium to apply dyes and various finishes. On average,
90% of the water input in textile finishing operations needs to be treated end-of-
pipe.
24
Dye bath wastewater from textile mills is highly polluting in nature. The pollution
load is characterized by high colour content, suspended solids, salts, nutrients
and toxic substances such as heavy metals and chlorinated organic compounds.
Many textile mills in India currently discharge their wastewater to local
wastewater treatment plants with minimum treatment such as pH neutralization.
This process removes much of the residual dye colour. Larger mills can discharge
more than two million gallons of wastewater of this kind each day.
There are many textile industries which have gone for water recovery from
treated waste water through Reverse Osmosis process and also recovery of brine
through nano-filtration from concentrated dye effluent generated during cotton
textile dyeing operation. Some industries have even achieved zero discharge by
subjecting R.O. reject through multiple effect evaporators.
25
Table 7: Environment Management Techniques in Indian Textile
Industries
26
Operation Existing Technology / Technique
27
Operation Existing Technology / Technique
Chemicking From the economy point of water, the chemicking and the
scouring operations are carried out in cisterns. This
method is useful in conserving water. Where cisterns are
not available, storage tanks near the washing machine can
be equipped with a pump to remove the water from the
washing machine and stored. The used batch may be
replenished and used again wherever required.
28
Operation Existing Technology / Technique
29
Operation Existing Technology / Technique
30
Operation Existing Technology / Technique
31
Operation Existing Technology / Technique
Methods of Effluent Several methods are employed for the treatment and
Treatment disposal of waste water from textile industries. The
treatment procedures are neutralization, chemical
treatment (precipitation), biological treatment and
advanced treatment systems. The choice of method differs
from plant to plant and the method best suited for a
particular plant has to be evaluated with reference to the
type of wastes to be handled and the degree of treatment
required in the particular situation.
32
6. CP Option for Textile Industry
GOOD HOUSEKEEPING
GHK
Sr. No. CP option
1 Worker train for correct measurement and application techniques.
33
12 Repair of broken and steam pipe and connections.
34
BETTER PROCESS CONTROL
BPC
SR. NO. CP OPTIONS
1 Use calibrated service tank for addition of water to the drums
4 Increase rate of feed water by changing the pipe size from 2” to 3” at the
delivery point of the over head tank
10 Optimize & use of minimum acid quantity based on the strength required
35
14 Use dedicated drums for each recipe
29 Hot air control through graduated knob to be made so that the distribution
can be controlled
36
35 Develop proper cleaning method. Use of nozzle based cleaning should be
practiced.
45 Water meter installation to control material to liquor ratio and for further
data generation on water consumption
37
54 Change of the process of dyeing can help in water conservation
55 The after wash is required to remove the un-fixed dyes from the fabrics in
drying operation
56 Change of the process of dyeing can help in water conservation
Change of raw material options includes the use of less hazardous materials or
raw materials of higher quality aimed at reducing the quantity/toxicity of
waste generated from the process.
RMC
SR. NO. CP OPTIONS
1 Use of the bi / poly functional dyes can reduce the water
consumption and waste load in effluent.
TECHNOLOGY CHANGE
TC
SR. NO. CP OPTIONS
1 Auto cut off mechanism to ascertain predetermined water
addition to the drums.
38
Standardize colour and gum stock preparation
Computer controlled system for delivering the exact
quantities of colour and gum for a given recipe
11 Finishing techniques :
33.1 Enzyme catalysed finishing processes
33.2 Plasma technology
33.3 Electron-ray treatment
33.4 Supercritical Carbondioxide
33.5 Ultrasonic treatment
13 Electrochemical dyeing
RECYCLING
Recycling is the onsite recovery and reuse of wasted materials and energy. The
recovered materials may either be reused in the same process or another
purpose.
RECYCLE
SR. NO. CP OPTIONS
1 Keep the wet cloth in a basket and allow water to drain which
39
has to be collected back for recycle
Hang it on the steel wire and allow water to drain which has to
2 be collected back for recycle
40
Dye bath reuse
18
Reuse of neutralization(after scouring and washing) bath of
19 dyeing batches
EQUIPMENT MODIFICATION
EM
SR. NO. CP OPTIONS
1 Install water meters and practice the usage of the meters to add
required quantity per batch
41
2 Calibrate the existing dip measuring system
6 Install water meters for all the jet-dyeing machines and practice
the usage of the meters to add required quantity per batch
42
intermittently
20 Use of press switch for view glass light in jet dyeing machine
43
GENERAL WASTE MINIMIZATION OPTIONS
44
Cooling water is relatively uncontaminated and can be reused as make-up or
rinse water. This will also save energy as this water will not require as much
heating.
Sweeping Floors
Instead of washing the floors of the dye house and kitchens, rather sweep up any
spillages and wash down only when essential. Not only will this reduce water use,
but also the concentration of contaminants to drain as the waste is disposed of as
solids.
The majority of chemicals applied to the fabric are washed off and sent to drain.
Therefore, reducing chemical consumption can lead to a reduction in effluent
strength and therefore lower treatment costs, as well as overall savings in
chemical costs. Various options for reducing chemical use are listed below:
Recipe Optimization
Recipes are generally fail-safe designed which results in the over-use of
chemicals. Optimizing the quantity of chemicals required will lead to more
efficient chemical use and lower costs. Continual updating of recipes should be
carried out when new dyestuffs enter the market as, in general, less of these
chemicals are required.
45
Dosing Control
Overdosing and spillages can be reduced by mixing chemicals centrally and
pumping them to the machines. Check that manual measuring and mixing is
carried out efficiently and automatic dispensers are properly calibrated.
Improve Scheduling
Review the scheduling of continuous processes such as sizing, desizing, padding
etc. to ensure that the same chemical bath is used as many times as possible,
thus reducing the number of dumps to drain per day
ENERGY CONSERVATION
46
STEAM GENERATION
Boiler blowdown
It is necessary to control the build-up of total dissolved solids (TDS) within any
steam-raising boiler, through periodic blowing-down. It is essential that boiler
TDS is monitored regularly in order that excessive blowing down is avoided.
Increasing blow down by 5% will increase fuel consumption by between 1% and
1.5%.
Economizers
Boiler efficiency may be increased by preheating feed water through the use of
an economized installed within the boiler flue. In general, increases in feedwater
temperature will results in 1% less fuel being burned at the boiler.
Boiler efficiency can be increased by recovering waste heat from the flue gas and
preheating combustion air. An increase in combustion air temperature will result
in about 2% efficiency increase.
Insulation
47
Flash steam recovery
In terms of volume, solid waste is the second largest waste stream in the textile
industry next to liquid effluent. There are a number of waste minimization options
available to reduce solid waste, and these include:
48
Reducing the amount of packaging material by improved purchasing practices
such as ordering raw materials in bulk or returnable intermediate bulk
containers (IBCs). This reduces spillages, handling costs, exposure of workers
to chemicals and the amount of storage space required.
Purchasing chemicals in returnable drums. Enquire if vendors will accept
unwashed drums as this will reduce the waste water generated in the factory.
If possible, ordering chemicals in IBCs rather than bags as these are easily
broken, causing spillages.
Purchasing yarn on reusable plastic cones rather than cardboard cones.
Reducing seam waste through effective training programmes.
Selling waste fibres, sweeps, rags, yarn and cloth scraps.
Selling used pallets to a recycler.
Donating damaged pallets to institutions (e.g. schools) for the wood.
REDUCING TOXICITY
Compounds that contribute to the aquatic toxicity of textile effluent include salit,
metals, surfactants, toxic organic chemicals, biocides and toxic anions. Some
methods of reducing the use of these compounds are to:
Reduce metal content through careful pre-screening of chemicals and dyes for
metal content and using alternatives where possible.
Eliminate galvanized plumbing as reactions with brass fittings can take place
in the presence of acids, alkalis or salit and lead to the release of zinc.
Reduce the amount of salit in the effluent by optimizing recipes, using low-
salit dyes, reusing dyebaths and optimizing dyeing temperatures.
Use biodegradable surfactants such as linear alcohol ethoxylates.
Replace chlorinated solvents with unchlorinated alternatives.
49
Replace the use of biocides with ultraviolet light as a disinfectant for cooling
towers.
Carefully pre-screen chemicals for their toxic nature using MSDS.
50
7. Best Available Techniques Case studies
Problem: Cooling water and condensate water are non-process water uses.
Many cooling water systems are operated on a once-through basis. Condensate
water includes water from heat exchangers in dyeing machines, drying ranges,
cooling cans on continuous ranges, while cooling water includes hot water from
jet dyeing machine and compressors (if water cooled).In the knit industry for
example, the amount of cooling water utilized in the process is equivalent to
13% of total fill and rinse water. Traditionally, jet dyeing machines are equipped
with common heat exchangers that are used for both heating and cooling which
is normally drained with other effluent and thus increasing fresh water
consumption as well as effluent quantity & load at ETP.
Pilot measure: Both the cooling water and the condensate is recovered
completely from jet dyeing machines and reused as boiler feed water in Rinkoo
Processors. While cooling water from jet dyeing machines is reused as process
hot wash water on soft flow dyeing machines, RFD (Ready For Dyeing) machines,
etc. in KomalTexfab.
51
Benefits:
The total boiler feed water is being now catered by recovered condensate &
cooling water amounting to 50 KL per day
Boiler feed water consumption reduction: 100%
Recovery of energy in form of heat from hot water: 15%
Reduction in boiler emissions
Reduction in waste water generation (quality & quantity)
Capital costs for implementation was Rs. 3,00,000, operating costs includes the
pumps operation of 10 HP for transfer amounting to Rs. 3,13,000 per annum,
resulted in saving of Rs. 33,00,000 per annum with payback period of 3 months
(Rinkoo Processors).
Capital costs for implementation was Rs. 11,00,000, while operating costs
includes the pumps operation of 10 HP for transfer amounting to Rs. 1,96,000
per annum, resulted in saving of Rs. 12,12,000 (Rs. 5,94,750 fuel cost + Rs.
6,17,760 fresh water pumping cost) per annum with payback period of 13
months (KomalTexfab).
Problem: Screen is used for printing designs. When designs or colours on design
are changed then screen is washed. Similarly the frames also need washing on
change over. One Printing machine requires 1500 lit/hr for continuous cleaning of
the blanket and screens, therefore in it requires 150 KL of water per day. During
washing wash water is generated, which is treated in ETP.
Pilot measure: The ETP plant treated water is recycled for its use in cleaning
process of screen & frames. In house piping arrangements were made to divert
the ETP treated water for cleaning at printing machines through an overhead
tank.
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Benefits:
When implemented: Industries started using the ETP water for washing
purposes in 2010 & started using the ETP treated water for washing purpose in
2013.
Capital cost for implementation was Rs. 1, 00,000, Operating cost for running
pumps of 6 HP for water transfer of Rs 1, 69,000 per annum giving total savings
of Rs 3, 46,500 with payback period of 10 months.
Capital cost for implementation was Rs. 3, 00,000, Operating cost for running
pumps of 7.5 HP for water transfer of Rs 86,000 per annum giving total savings
of Rs 2, 58,000 with payback period of 21 months.
Problem: In overflow rinsing, clean water is fed into a machine and drained
through an overflow weir usually set near a normal running level. Overflow
rinsing is inefficient in terms of water use as clean water is often fed into a
machine with the control valve fully opened thus having 3 times (1200
litre/batch) higher flow rate of overflow water required.
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Pilot measure: In order to reduce water consumption and effluent generation
two separate water lines for jigger machines, for water filling (1.5 inch) with auto
timer based controller to fill required quantity of water into jigger, for overflow
(0.5 inch) line with auto timer controller which allows only 400 litre per 20
minutes and stops the water flow after one turn. Also the water supplied to the
jigger is from condenser cooling water of caustic recovery plant which in turn
saves the 30 KL/yr of additional fresh water consumption.
Benefits:
Economic savings with reduced fresh water consumption by 360 KL per year
Reduction in effluent generation due to reuse of cooling water.
Reduces the load on ETP and reduction of CETP charges in future for the volume
of waste water reduced
Cost benefit analysis: Capital cost for the modification was Rs. 2,00,000 per
jigger with water saving of 360 KL/yr. Although the fresh water cost is not
significant, the payback in this case is not fast considering the fresh water cost
only.
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Pilot Measure 4: Caustic soda Recovery System
Pilot measure: Caustic Soda Recovery System separates the weak lye (wash
liquor) into strong lye and vapour condensate (slightly alkaline soft water). The
condensate can be used for pre-washing and the caustic soda can be reused in
the mercerizing process.
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Benefits:
Cost benefit analysis: Total savings of Rs. 1,42,00,000 with payback period of
12 months. (Operational data). Payback time depends on plant size and
operating time per day.
Problem: In Jet Dyeing Machine, the washing is carried out with continuous flow
of fresh water in order to remove the unexhausted dyes and chemicals without
any control. During continuous washing 5000 litre / batch of water is consumed
without any real requirement and as a normal practice.
Pilot measure: Batch / Intermittent washing is applied with fresh water intake
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of three cycles in batch manner instead of continuous flow of water. Achieved by
giving appropriate instruction to dyeing master and & operating staff.
Benefits:
The same washing quality is achieved in batch washing with 3500 litre / batch of
water.
This is a reduction of water consumption of 30%.
The reduction in water consumption was approx. 39600 KL per annum on 11 nos.
machine without any capital cost or operating costs, with saving of Rs. 3,05,000
per annum (pumping cost only) with immediate return.
Problem: Scouring is carried out to remove impurities that are present in cotton.
This is usually done at high temperatures (above 100 °C) with sodium hydroxide.
Produces strongly alkaline effluents (around pH 12.5) with high organic loads,
tend to be dark in colour and have high concentrations of Total Dissolved Solids
(TDS), oil and grease in wastewater. The processing cost of fabric was Rs. 5.15
per kg of fabric
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Benefits: Bio-scouring process provides many advantages, such as reduced
water and wastewater costs, reduced treatment time and lower energy
consumption because of lower treatment temperature. Commercial bio-scouring
enzyme products are based on pectinases which are used for enzymetic scouring.
Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) of
enzymatic scouring process are 20-45 % as compared to alkaline scouring (100
%). Total Dissolved Solid (TDS) of enzymatic scouring process is 20-50% as
compared to alkaline scouring (100%).
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When implemented: Industry took the trails on number of batches with new
bio scouring product and on the basis of results with no risk to product quality
industry replaced the alkaline scouring with bio scouring in 2013.
The processing cost of fabric reduced to Rs. 3.91 per kg of fabric. There is no
capital cost required since only replacement of chemical is required (although
with 10 % additional cost compared to existing chemicals), the total savings
achieved was Rs. 50, 22,000 per annum.
Pilot measure: Industry has gone through the process waste stream
identification and probable processes for reuse of the waste streams and after
process modification, the alkaline stream is collected in underground tanks of
which 50O caustic stream is collected and reused for next batch while the 20 O
caustic stream is pumped to overhead tank and is supplied through common line
with tapings to individual jigger machines for use during next process i.e., dyeing
process where the alkaline stream is used for boiling and bleaching of fabrics.
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Benefits:
Cost benefit analysis: Capital cost for implementation was Rs. 5, 00,000, with
negligible operating cost giving total savings of Rs. 5, 40,000 per annum with
payback period of 12 months.
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Pilot Measure 8: Efficient Boiler operation
Problem: Boiler efficiencies will vary over a wide range, depending on a great
variety of factors and conditions. The highest efficiencies that have been secured
with coal are in the range of 50-82%. It is being observed that the combustion
efficiency of the boiler is lower than the current standard boilers delivering, the
combustion efficiency of the boiler was found to be only 80 % while the
combustion efficiency of efficient boilers is more than 90 %. The reasons for low
combustion efficiency are:
The heat transfer is poor due to low heat transfer area and short contact time
between flue gas and the water.
The fuel charging door remains more or less open during the entire operation
due to various reasons, mostly human errors
There is no control over fuel firing in combustion chamber
Pilot measures: After detailed investigation industry has decided to replace the
existing boiler which is not efficient with the efficient 6 TPH capacity boiler with
ESP system to take care the air emissions as well. The performance of the
existing boiler was evaluated and comparison with the efficient boiler for same
amount of steam generation was carried out, on the basis of calculations industry
placed the order for new boiler.
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Benefits:
Cost benefit analysis: The capital cost of the boiler is Approx. Rs. 85,00,000
(excluding ESP), while the operating cost remains the same while it will reduce
due to consideration of latest technologies and control of the boiler system, the
total estimated savings of Rs. 50,00,000 giving payback period of 21 months.
Problem: Hot water is required for Dye application, Dye fixation, soaping etc. in
a Jigger Dyeing Machine. The Jigger Dyeing Machine is required for Dyeing of
cotton fabric or cotton content of the blended fabric. Dyeing of cotton fabric
requires hot water at temperatures 80°C to 96°C depending upon the type of dye
used. Heat for raising this hot water was drawn from steam raised in boiler by
direct injection to water in jigger machine at approx. 3 kg/cm 2g, thus significant
amount of heat was required to raise the water temperature also the high steam
pressure leads to higher velocity which escapes from the water bath of jigger to
atmosphere without delivering the heat and increase the steam consumption
further due to losses. Average specific steam consumption at jigger machine was
1.5 to 2 kg of steam per kg of fabric.
Pilot measure: The water supplied to the jigger is from condenser cooling water
(soft water) of caustic recovery plant at 50 0C, thus the water is preheated and
will need steam only to raise temperature from 50 0C to average 85 0C. This hot
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water is further heated in closed tank with direct steam injection at 1 kg/cm 2g
pressure only to utilise the full heat content of the steam. The machines are
supplied with hot water directly instead of heating water at machines. To
maintain the required temperature during the process there are seamless SS
coils at bottom of the jigger machines to provide indirect heating through thermic
oil available.
Benefits:
Cost benefit analysis: Capital cost invested for the various modifications was
Rs. 13, 50,000 with total savings of Rs. 8, 70,000, with negligible operating cost
giving payback period of 18 months.
Problem: Jet dyeing machine dyes the cloth by forcibly contacting the jet flow of
dye stuff solution. It executes efficient dyeing in such a manner that the tension
on the cloth is decreased as much as possible, and that the cloth dyes evenly
with a relatively small amount of dyestuff. Current Jet dyeing machines operate
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at a liquor ratio of 10:1, thus resulting in excess water consumption and in turn
excess waste water generation. One factor limiting implementation is the high
cost of the new machines, which favours use at new facilities rather than as
replacements for older machines
Benefits:
Capital cost of 900 kg/hr machine was Rs. 1.25 crore, with reduced operating
cost than conventional jet dyeing machines total savings achieved was of Rs.
18,90,000 per annum giving payback period of 80 months (Excluding cost of
chemicals saving & waste water treatment & disposal cost).
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Pilot Measure 11: Auto Colour Dispensing Through Spectrometer &
Chemical Dispensing System
Problem: The correlation between the formula developed in the lab and the
formula used in production cannot be done manually thus resulting in excess
chemical usage and increased rework. Reproducing colour accurately and cost-
effectively in all of these instances is difficult. Number of problems associated
with using traditional manual methods of preparing solutions is as following:
Errors can occur when manually calculating the amount of dyestuff, auxiliary and
water required when making up solutions.
Manually weighing out the precise amount of the required dye takes time and
skill, and the risk of mistakes in a busy production environment is high.
Manually dispensing auxiliaries and water accurately is very time consuming.
Variations in the temperature of water used can affect the stability and accuracy
of solutions for certain dyestuffs.
Inaccuracies in the amount of auxiliary added in solutions can affect the stability
and reliability of solutions for certain dyestuffs
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Benefits:
Cost benefit analysis: The capital cost invested by industry was Rs. 2,
00,00,000, with minimum operating and maintenance cost, the total savings
achieved by industry is Rs. 62,64,000 per annum giving simple payback of 3.5
years.
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Pilot measure: The system proposed is retro fitment of a VFD armed with PLC
based control gear to the Jet Dyeing Machine so as to implement time based and
requirement oriented change in RPM of the pump. The PLC based system can be
integrated with existing control gear or can be installed as a package.
Benefits:
When implemented: The VFDs were installed on 11 nos. pumps of Jet Dyeing
Machine in 2010.
Cost benefit analysis: Capital cost of one 12.5 HP VFD is Rs. 30,000, operating
costs is negligible, giving total savings of Rs. 55,000 per annum with return of
investments of 7 months.
Pilot measure: The industry designed a simple system to recover this flash
steam and raise the temperature of boiler feed water to reduce the fuel input at
boiler by supplying heated water. A additional tank is constructed above the
condensate recovery tank and flash steam generated is allowed to be passed
through coils in the top tank to heat the water, when the water temperature
reaches the required feed water temperature an automatic valve opens the flow
to condensate tank and the heated water with hot condensate is pumped to the
boiler feed water tank.
Benefits:
When implemented: The system for heat content utilization from flash steam is
designed In-house by the industry and was implemented in 2012, the schematic
of the system is shown below:
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Cost benefit analysis: Capital cost for the modification was Rs.1, 00,000 with
savings due to reduction in fuel consumption of Rs. 35, 67,000 per annum with
negligible operating cost giving payback period of 10 days.
Problem: A typical 16 cylinder dryer requires 110 kg steam input per hour for
2400 m/hr fabric running rate, i.e., approximately 0.30 kg of steam per kg of
water evaporated. The side plates of cylinders, non-covered cylinder surfaces
and non-isolated piping emit heat to the surrounding area and thus loss of
energy. The major challenges for insulating the side plates of a cylinder dryer are
following:
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Pilot measure: Side plates of drying range can be insulated with more durable
(life & properties) mineral/rock wool, which can result in reduction of steam
consumption. This non-combustible mineral wool is a composition of inorganic
components which are melted in a furnace, and then spun and bonded with a
resin to form various insulation products. Mineral wool comes in various forms.
Meter sections come in preformed sections and vary in density from 160 kg/m³
to 185 kg/m³, depending on the pipe size. The Wired Mattress, rigid and semi-
rigid board and flexible felt comes in a matt form, or reinforced mat depending
on the requirements.
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Also, there are heat resistive coatings available in market which are polymer
based coatings with special thermal insulation properties and are applicable for
the hot surfaces where the installation of conventional insulation is not practical
due to various reasons. These heat resistive coatings claims reduction of heat
losses upto 20 % and surface temperature reduction up to 40 %.
Benefits:
Cost benefit analysis: Capital costs of the insulation will be Rs. 35,000 for 12
m2 surface area, No operating costs involved and estimated saving is Rs. 1,
16,000with payback period of 4 months.
Problem: In Cotton Printing, Stenter is used before printing but after pre-
treatment. In case of Polyester or PC Dyeing, stenter is used twice, once for heat
setting and then again for final finish. Only 5.4% of heat given to stenter is
utilized in heating the fabric in case of Heat Setting. Heat gained by fabric in any
typical stenter operation is 4.6% only. It is further evident that approx. 95%
stenters are used for the purpose of moisture evaporation, released to
atmosphere or wasted.
Benefits:
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Cost benefit analysis: Capital costs of the equipment is Rs. 1,65,000, No
operating costs involved, Estimated saving is Rs. 1,85,000 (@ 5 % savings) with
return of investments in 11 months.
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8. References:
BAT Guidance Note on Best Available Techniques for the Textile Processing
Sector (1st Edition) by EPA (Environmental Protection Agency).
Overview of textile industry in Gujarat, Enpro Enviro Tech and engineer Ltd.
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