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Class 32
Section 8.4,5
Finish up latent heat H1 = air at 50o C = .71
Heats of solution H2 = air at 20oC = -.144
Q = -478.5 kJ
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References: Air at 25oC and 1 atm Water(l) at 20oC References: Air at 25oC and 1 atm Water(l) at 20oC
Substa nin Hin nout Hout Substa nin Hin nout Hout
nce nce
Air (v) 89 0.71 89 -.144 Air (v) 89 0.71 89 -.144
H2O (l) 0 ----- 8.9 ----- H2O (l) 0 ----- 8.9 -----
H2O(v) 11 44.987 2.1 43.98 H2O(v) 11 44.987 2.1 43.98
Calculate kg H2O condensed/m3 of air and Calculate kg H2O condensed/m3 of air and
kJ transferred/m3 air fed. kJ transferred/m3 air fed.
H2O (l) 0 ----- 8.9 -40.8 For non-ideal mixtures, you look up heat of
solution (or mixing), as function of r (moles of
H2O(v) 11 .85 2.1 -.17 solvent/moles of solute)
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2.00 moles of 100% sulfuric acid is diluted 2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole % with enough water to produce a 30 mole %
aqueous solution. The acid and water are aqueous solution. The water is initially at 25o
initially at 25o C. How much heat would have C. Calculate the heat produced when the acid
to be removed to keep the final solution at is at 15oC and the solution is at 45oC.
25oC?
What will happen to the Q?
a) It will increase
b) It will decrease
c) We don’t have enough information
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2.00 moles of 100% sulfuric acid is diluted 2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole % with enough water to produce a 30 mole %
aqueous solution. The water is initially at 25o aqueous solution. The water is initially at 25o
C. Calculate the heat produced when the acid C. Calculate the heat produced when the acid
is at 15oC and the solution is at 45oC. is at 15oC and the solution is at 45oC.
Consider the heat capacity of the solution to Consider the heat capacity of the solution to
be identical to that of water. What should the be identical to that of water.
reference state for the acid be?
a) 15oC
b) 25oC
c) 45oC
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