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A. Research Title
Synthesis of Environmental Friendly Biopolymers Using Cassava Skin Starch
(Manihot utilissima) and Speargrass Cellulose (Imperatacy lindrica-linn)
B. Background
Garbage is a bad factor for the health of the body is very disturbing if it
continues to be ignored. Garbage can be divided into two types, namely organic
and non-organic waste. Some are biodegradable and some cannot unravel.
Especially plastic waste when burned will cause air pollution and if allowed to
disrupt the natural ecosystem. So far, the handling of municipal solid waste in
developing countries such as Indonesia only accumulates and burns direct waste
in the open air at landfill (landfill).
It also can not reduce waste in large quantities and will cause problems
that is the production of pollutants that can pollute the environment of combustion
gases such as CO2, NOx, SO2, and others (Himawanto et al, 2010). In general,
plastic is made of polyethylene and polyprophylene which is difficult to
decompose by microorganisms environment (Gonzales-Gutierrez, 2010 in
Nugroho, 2012).
Plastic waste has become a global environmental problem because it has
advantages such as strong, lightweight and stable, hence the plastics are widely
used in everyday life which ultimately leads to environmental problems of waste.
Plastic needs in Indonesia continue to increase to an average of 200 tons per year.
In 2002 it was recorded 1.9 million tons, in 2003 rose to 2.1 million tons, 2004
rose another 2.3 million tons, and in 2011 has risen to 2.6 million tons. In 2013
there was a 22.58% increase from 1.55 million tons to 1.9 tons (Kemenperin,
2013 in Nindita, 2015).
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subconsciously consume the substances that migrate it. The longer the product is
stored, the maximum limits of the migrating components are exceeded.
For that reason the description of the expiration time threshold for the
plastic-packed product needs to be clearly communicated to the consumer
(Sulchan et al., 2007). Therefore, in this study, researchers tried to make natural
bioplastics by replacing some or all polymer synthesis with natural polymers that
have advantages such as the nature of which can be renewable, recyclable,
biodegradable in the environment and more economical.
C. Problem Formulation
1. How is the process of making bioplastic from cassava and speargrass skin?
2. How is bioplastic morphology made of cassava leather material and
speargrass?
3. How is the optimum attractiveness and durability in the treatment of
materials made from raw cassava leather and speargrass?
4. What are the different characteristics of the power spectrum before and
after passing through the bioplastic composite of cassava and speargrass
skins?
D. Research Purposes
1. Describe the process of making bioplastik from cassava and speargrass
skin.
2. Describe bioplastic morphology made of cassava leather material and
speargrass.
3. Describe the optimum attractiveness and durability in the treatment of
materials made from raw cassava leather and speargrass.
4. Describe the characteristic differences of power spectrum before and after
the composition of bioplastic composite of cassava leather and speargrass.
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E. Research Benefits
1. Can be informed to the public about the potential of cassava and
speargrass skin as a material that can minimize the environmental
problems caused by plastic waste.
2. Can be more developed model material of cassava and speargrass skin
with organic molecule through consideration of aesthetic aspect.
3. Can be the basis for further research.
F. Theoritical Review
1. Plastic
Plasticc is a high polymer formed from the polymerization process.
According to Shereve and Brink, plastics are defined as materials whose main
ingredient is organic molecules that are polymerized with high molecular
weight. The product is ultimately solid, and in some parts the production stage
can be formed as desired (Akbar, 2013).
The majority of PET plastic materials in the world for synthetic fibers
(about 60%), in PET textile commonly referred to as polyester (bottle
packaging bottle 30%). This type of PET Bottle is recommended only
disposable. If used too much, let alone used to store warm water let alone heat,
will result in the polymer layer on the bottle will melt and remove carcinogenic
substances (can cause cancer) (Karuniastuti, 2016).
Various types of lax packaging materials such as polyethylene,
polypropylene, nylon polyester and vinyl film may be used singly to wrap food
or in layers with other materials glued together. This combination is called
lamination. The properties produced by laminated packaging of two or more
films can have unique properties. For example, packaging consisting of layers
of paper, polyethylene, aluminum foil, and polypropylene is excellent for dry
food packaging. The outer layer consisting of paper serves to mold the surface
Economical and inexpensive. Polyethylene serves as glue between aluminum
foil and paper, while inner polyethylene is capable of providing strength and
ability to be sealed or covered with heat. With the concept of lamination, each
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layer overlaps its flaws resulting in high quality packaging sheets (Sulchan et
al., 2007).
In addition to having many advantages, it turns out plastic packaging
stores the weakness of the possibility of migration or removal of monomer
substances from plastic materials into food, especially if the food does not
match the packaging or container penyim-pannya. In foods packed in plastic
packaging, the presence of this migration is unlikely to be prevented 100%
(especially if the plastic used does not match the type of food). Monomer
migration occurs because it is influenced by food temperature or storage and its
processing. The higher the temperature, the more monomers can migrate into
the food. The longer the contact between the food and plastic packaging, the
number of migrating monomers may be higher (Sulchan et al., 2007).
2. Styrofoam
Styrofoam or foam plastics still belong to the plastic family. The basic
ingredients of Styrofoam are polisterin, a type of plastic that is very light, stiff,
translucent and cheap but quickly brittle. Because of its weakness, polisterin is
mixed with zinc and butadiene compounds. This causes the polisterin to lose its
clear nature and change its color to milk white. Then for elasticity, plasticizers
such as dioktyl pthalate (DOP), butyl hydroxy toluene or n-butyl stearate were
added. Foam plastics that break down easily into small cell structures are the
result of blowing process by using chlorofluorocarbon gas (CFC) (Sulchan et
al, 2007).
The results of the Japan Food Safety Division study in July 2001
revealed that the residue of Styrofoam in food was extremely dangerous. The
residue can cause endocrine disrupter (EDC) a disease that occurs due to
disturbances in endocrinology and reproductive systems due to carcinogenic
chemicals in the diet. The results of various studies that have been done since
the 1930s, it is known that styrene, Styrofoam base material, is mutagenic
(Capable of altering genes) and the potential of carcinogen (Sulchan et al.,
2007).
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The longer packing time with styrofoam and the higher the temperature,
the greater the migration or displacement of these toxic ingredients into food or
drink. Especially if the food or drink contains a lot of fat or oil. The toxicity
caused is not immediately apparent. It is accumulative and in the long run there
are new consequences. Meanwhile, CFC as a blowing material in the
manufacture of styrofoam is a gas that is non-toxic and highly flammable and
very stable. Once stable, this new gas can decompose about 65-130 years. This
gas will float in the air reaches the ozone layer in the atmosphere and there will
be a reaction and will break down the protective layer of the earth. If the ozone
layer is eroded, there will be a greenhouse effect. When the earth's temperature
increases, sun's ultraviolet rays will continue to penetrate the earth that can
cause cancer (Sulchan et al., 2007).
3. Bioplastics
Bioplastics (biopolymers) are plastics that can be used like
conventional plastics, but will be destroyed by the activity of microorganisms
into the final result of water and carbon dioxide gas after being used up and
discharged into the environment without leaving a poisonous residue. Due to
its biodegradable nature, biodegrable plastics are environmentally friendly
plastic materials. Bioplastics can be obtained through varied sources. Such as
protein, lipids and polysaccharides Gonzales-Gutierrez (2010) in Nugroho
(2012).
Bioplastics (biopolymers) are derived from emerging microbes as a
promising alternative to plastics derived from fossil fuel oils. The development
of a simple and eco-friendly strategy for the production of bioplastics with high
productivity and yield, produced in a cost-effective way utilizing the widely
available newest carbon sources, will have the potential to generate an endless
source of global energy (Sawant et al., 2016).
Its nature can return to nature, biodegradation plastic is environmentally
friendly plastic (Akbar et al, 2013). Eco-friendly plastic is a plastic that can
decompose by the activity of decomposing microorganisms. Eco-friendly
plastic has the same utility as synthetic plastic or conventional plastic. An
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G. Research Methods
1. Place of Research
This research will be conducted in Physics Laboratory of Materials
FMIPA, University of Brawijaya, Malang, Central Laboratory of Mineral and
Material, State University of Malang, and Integrated Laboratory, FMIPA, State
University of Surabaya.
3. Research Variable
Control variables : type of cassava leather and type of reeds.
Variable manipulation : composition of bioplastic composites.
Response variable : tensile strength, absorption coefficient, crystal
structure, Morphology, functional groups, and
composition elements.
4. Experimental Procedure
a. Determination of Formulation
The formulation was carried out by using the extract of cassava
starch and cellulose speargrass biopolymer.
Cassava
Peeled
Scraped mucus
Diminished in size
Shredded
Brood 3 days
Milled
Sieved 80 mesh Dried Drained
Sieved
Dried
Milled
Milled
Sieved
Sieved
Mocaf Flour
Cuted Drained
Refined
Drained
Weighed
Filtered
Pure Cellulose
Drained
Saved
Cellulose Dry
Weighed
Stirred
Printed
Dried Cut
5. Prosedur Pengujian
a. Gas Chromatography-Mass Spectrometry Test (GC-MS)
Determination of bioplastic components of cassava starch starch and
aloe-cellulose using Gas Chromatography-Mass Spectrometry (GC-MS)
Shimadzu QP2010S at Integrated Laboratory, FMIPA, Universitas Negeri
Surabaya. The type of column used is AGILENT HP 5MS, column length
30 meters and ID of 0.25 mm. The operating conditions of the apparatus use
column heating temperature: 60oC for 5 minutes, injection temperature:
310oC for 17 minutes, injection mode with a split ratio of 142.4 and a
carrier gas of helium at a pressure of 15.0 kPa, total flow: 80.0 mL / Min,
column flow: 0.54 mL / min and linear speed: 26.7 cm / sec.
While for SM with the following conditions: (start time) 3 minutes
later lasts up to 70 minute (end time), interval 0,50 seconds with scan speed
1250, initial m/v of 28 and ending m/v 600. The determination of the type of
compound is done with the help of database tools database Willey 7, Willey
229, and NIST 12 NIST 62 Library.
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Drained
Cut
Gas Chromatography-
Mass Spectrometry Test Determination of compound type
Conclusion
With:
L = crystal size
𝜆 = wavelength of X-ray beam radiation used
𝛽 = the width of the highest half of the wave peak
𝜃 = peak angle
c. SEM-EDX Test
The structure of film morphology was analyzed using scanning
electron microscopy. Samples are cut in small size and placed on carbon
tape. After that the sample in coating using platinum. The goal is to provide
conductor properties to the sample (Ardiansyah, 2011). The purpose of the
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Lambert-beerlaw:
𝐴
A = a.b.c , maka 𝑎 = 𝑏.𝑐
H. Research Schedule
Months
Number Activity 1 2
1 2 3 4 1 2 3 4
1. Prepare tools and
materials
2. Process production
biopolymer
3. GC-MS test
4. SEM-EDX Test
5. XRD test
6. Power-Pull test
7. Spectroscopy UV-Vis
test
8. Data Analysis
9. Arrange report
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