Professional Documents
Culture Documents
Known by :
Responsibility Lectuter
The parameter A, which corresponds to the intercept of the line at 1/T=0 (at
infinite temperature) is called the pre-exponential factor or the ‘frequency factor’.
The parameter Ea, which is obtained from the slope of the line (−Ea/R), is called
the activation energy. Collectively the two quantities are called the Arrhenius
parameters (Atkins, 2006 : 807).
The Arrhenius equation holds rather well for nearly all elementary
homogeneous reactions and for most composite reactions. A simple interpretation
of is that two colliding molecules require a certain minimum kinetic energy of
relative motion to initiate the breaking of the appropriate bonds and allow new
compounds to be formed. (For a unimolecular reaction, a certain minimum energy
is needed to isomerize or decompose the molecule; the source of this energy is
collisions. Note that a low activation energy means a fast reaction and a high
activation energy means a slow reaction. The rapid increase in k as T increases is
due mainly to the increase in the number of collisions whose energy exceeds the
activation energy. In the Arrhenius equation both A and Ea are constants.
Sophisticated theories of reaction rates yield an equation similar, except that A
and Ea both depend on temperature. When Ea ≫ RT (which is true for most
chemical reactions), the temperature dependences of Ea and A are usually too
small to be detected by the rather inaccurate kinetic data available, unless a wide
temperature range is studied (Levine, 2009 : 543).
The quantitative relationship between the reaction rate constant and
temperature is :
k = ae-Aa H/RT
This can be appreciated by looking at a Boltzmann distribution of reactant
molecules. The area under the Boltzmann curve that surpasses the activation
barrier at r increases sharply (exponentially) with temperature, leading to the
observed exponential increase in k. The exponential relationship between k and T
is called the Arrhenius rate law. The exponential relationship between k and T is
called the Arrhenius rate law. The number of activated molecules rises
exponentially with temperature (Rogers, 2011 : 157-158).
Activation energy is an energy minimum that must through of a reaction.
For example A → product.
G. DATA ANALYSIS
Ea
ln k1 = ln A - RT2
Ea
ln k2 = ln A - RT1
Ea Ea
ln k2- ln k1 = - RT2 + RT1
k2 Ea 1 1
ln k1 =- (T2 - T1)
R
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
1. 1st system
a. known : ln k1 = -8,857
ln k2 = -9,026
1
= 3,333 × 10-3
T1
1
= 3,413 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
-8,857-(-9,026) = (3,413 × 10-3 - 3,333 × 10-3) K
8,314J/mol K
Ea
0,169 = 8,314J/mol K (8 × 10-5 K-1)
1,405 J mol−1 K−1
Ea = 8 × 10−5 K−1
= 17563,325 J/mol
= 17,563 kJ/mol
b. Known : ln k1 = -8,636
ln k2 = -8,857
1
= 3,195 × 10-3
T1
1
= 3,333 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
-8,636-(-8,857) = (3,333 × 10-3- 3,195 × 10-3) K
8,314J/mol K
Ea
0,221 = 8,314J/mol K (1,38 × 10-4 K-1)
1,837 J mol−1 K−1
Ea = 1,38 × 10−4 K−1
= 13311,594 J/mol
= 13,311 kJ/mol
c. Known ln k1 = -8,462
ln k2 = -8,636
1
= 3,096 × 10-3
T1
1
= 3,195 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
-8,462-(-8,636) = (3,195 × 10-3- 3,096 × 10-3) K
8,314J/mol K
Ea
0,174 = 8,314J/mol K (9,9 × 10-5 K-1)
1,447 J mol−1 K−1
Ea = 9,9 × 10−5 K−1
= 14616,616 J/mol
= 14,616 kJ/mol
d. Known ln k1 = -7,762
ln k2 = -8,462
1
= 3,003 × 10-3
T1
1
= 3,096 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
-7,762-(-8,462) = (3,096 × 10-3- 3,003 × 10-3) K
8,314J/mol K
Ea
0,7 = 8,314J/mol K (9,3 × 10-5 K-1)
5,820 J mol−1 K−1
Ea = 9,3 × 10−5 K−1
= 62580,645 J/mol
= 62,581 kJ/mol
e. Known ln k1 = - 9,026
ln k2 = -7,762
1
= 3,413 × 10-3
T1
1
= 3,003 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
- 9,026-(-7,762) = (3,003 × 10-3- 3,413 × 10-3) K
8,314J/mol K
Ea
-1,264 = 8,314J/mol K (-4,1× 10-5 K-1)
−10,509 J mol−1 K−1
Ea = −4,1× 10−5 K−1
= 25631,707 J/mol
= 25,63 kJ/mol
So, the average Ea in 1st system
17,563+13,311+14,616+62,581+25,631
Ea =( ) kJ/mol
5
133,702
= kJ/mol
5
= 26,740 kJ/mol
The graph of 1st system
y
0.0035
0.0034
0.0033
y = -0.0003x + 0.0008
1/T
0.0032
R² = 0.8868
y
0.0031
Linear (y)
0.003
0.0029
-9.5 -9 -8.5 -8 -7.5
In 1/t
= 1633,037 K-1
Ea
1633,037 K= 8,314 J/mol K
Ea = 13610,326 J/mol
= 13,610 kJ/mol
2. 2nd system
a. Known ln k1 = - 8,813
ln k2 = -8,875
1
= 3,333 × 10-3
T1
1
= 3,413 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
- 8,813-(-8,875) = (3,413 × 10-3- 3,333 × 10-3) K
8,314J/mol K
Ea
0,062 = 8,314J/mol K (8× 10-5 K-1)
0,515 J mol−1 K−1
Ea = 8 × 10−5 K−1
= 6437,512 J/mol
= 6,437 kJ/mol
b. Known ln k1 = - 8,541
ln k2 = -8,813
1
= 3,195 × 10-3
T1
1
= 3,333 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
- 8,541-(-8,813) = (3,333 × 10-3- 3,195 × 10-3) K
8,314J/mol K
Ea
0,272 = 8,314J/mol K (1,38× 10-5 K-1)
2,261 J mol−1 K−1
Ea = 1,38 × 10−5 K−1
= 16384,058 J/mol
= 16,384 kJ/mol
c. known : ln k1 = - 8,371
ln k2 = -8,541
1
= 3,096 × 10-3
T1
1
= 3,195 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
- 8,371-(-8,541) = (3,195 × 10-3- 3,096 × 10-3) K
8,314J/mol K
Ea
0,17 = 8,314J/mol K (9,9 × 10-5 K-1)
1,413 J mol−1 K−1
Ea = 9,9 × 10−5 K−1
= 14272,727 J/mol
= 14,272 kJ/mol
d. known : ln k1 = -7,586
ln k2 = -8,371
1
= 3,003 × 10-3
T1
1
= 3,096 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
-7,586-(-8,371) = (3,096 × 10-3- 3,003 × 10-3) K
8,314J/mol K
Ea
-0,785 = 8,314J/mol K (9,3× 10-5 K-1)
6,526 J mol−1 K−1
Ea = 9,3 × 10−5 K−1
= 70177,312 J/mol
= 70,177 kJ/mol
e. known : ln k1 = - 8,857
ln k2 = -7,586
1
= 3,413 × 10-3
T1
1
= 3,003 × 10-3
T2
Question : Ea = …?
Problem solving :
Ea 1 1
ln k1- ln k2 = (T2 – T1)
R
Ea
-8,857-(-7,586) = (3,003 × 10-3- 3,413 × 10-3) K
8,314J/mol K
Ea
-1,289 = 8,314J/mol K (-4,1× 10-5 K-1)
−10,717 J mol−1 K−1
Ea = −4,1 × 10−5 K−1
= 26138,405 J/mol
= 26,138 kJ/mol
So, the average Ea in 2nd system
6,437+16,384+14,272+70,177+26,138
Ea =( ) kJ/mol
5
133,408
= kJ/mol
5
= 26,682 kJ/mol
The graph of 2nd system
y
0.0035
0.0034
0.0033
y = -0.0003x + 0.0007
1/T
0.0032 R² = 0.8339
y
0.0031
Linear (y)
0.003
0.0029
-9 -8.5 -8 -7.5
In 1/t
y2−y1
Slope : tan 𝜃 = x2−x1
−8,813−(−8,284)
= 0,003195−0,00323
−0,529
= −1,35 x 10−4 K
= 3918,519 K-1
Ea
Slope = - RT
Ea
3918,519 K= - 8,314 J/mol K
Ea = 32578,567 J/mol
= 32,578 kJ/mol