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Outline

25.1 Nucleus
25.2 Radioactivity
25.3 Nuclear reactions
25 NUCLEAR PHYSICS
Liew Sau Poh

Objectives
a) describe the discovery of neutrons
b) explain mass defect and binding energy
Atomic number and mass c) use the formula for mass-energy equivalence
E = mc2
number
d) relate and use the units u and eV
e) sketch and interpret a graph of binding energy
per nucleon against nucleon number
f) explain radioactive decay as a spontaneous and
random process
g) define radioactive activity

Objectives Objectives
h) state and use the exponential law dN/dt N n) apply the principle of mass-energy
for radioactive decay conservation to calculate the energy released
i) define decay constant (Q value) in a nuclear reaction
j) derive and use the formula N = N0e- t o) relate the occurrence of fission and fusion to
k) define half- the graph of binding energy per nucleon
ln2/t1/2 against nucleon number;
l) solve problems involving the applications of p) explain the conditions for a chain reaction to
radioisotopes as tracers in medical physics occur
m) state and apply the conservation of nucleon q) describe a controlled fission process in a
number and charge in nuclear reactions reactor
r) describe a nuclear fusion process which occurs
in the Sun.

Discovery of neutrons
the
Rutherford model of the atom, where electrons
orbit around a nucleus.
And now we know that it takes Quantum
25.1 Nucleus Mechanics to correctly describe the nature of
these orbits.
But what about the nucleus? Well, so far we just
know about protons.
But, in 1932 scattering experiments by English
physicist James Chadwick discovered another
particle in the nucleus which had no charge
neutron.
Discovery of neutrons Nuclear Structure
9 4 He 12 C 1 Nucleus is composed of positive protons and neutral
4Be + 2 (alpha particle) + 0n (neutron)
6 neutrons.
When Beryllium is bombarded by alpha These are called nucleons.
particle, a beam of high penetrating power
What distinguishes different elements in the periodic
is produced. table is the # of protons they have in their nucleus,
This beam is not deflected by electric and which is the Atomic Number (Z).
magnetic fields. Each element also has an Atomic Weight or Atomic
Mass Number (A).
Further experiments show that this is a
beam of natural particles namely neutrons. Let N be the # of neutrons in the nucleus, then: A = Z
+N

Nuclear Structure Nuclear Structure

Atomic
mass Shorthand notation for element representation:
Atomic
number
number
A
8 15.9994
Z X
-2
Symbol
90.18
MP
BP
50.15
1.429
O So oxygen would be:
16
O
1s2 2s 2 2p4 8
Oxygen
Density
Name
Electronic The mass of the elements is usually given in
configuratio
So oxygen has
n 8 atomic mass units (u).
protons and
N = A Z = 16 8=8
1u 1.6605 10-27 kg
8 Neutrons!

Nuclear Structure Neutrons


James Chadwick in 1932 analyzed the
Nuclei that contain the same number of protons results of -particle scattering on thin Be
but a different number of neutrons are called films.
isotopes.
For example, boron exists in nature as two stable
Chadwick recognized existence of massive
isotopes: neutral particles which he called neutrons.
11 10
5 B 5 B Chadwick discovered the neutron.
Most boron atoms have 6 neutrons (81.1%), but
some (18.9%) have only 5 neutrons.
The atomic mass number (A) listed on the periodic
table is the average atomic mass of the isotopes,
for boron this is 10.811.

Mass Number Mass defect and binding energy


Mass number is given the symbol A. The protons and neutrons are
A is the sum of the number of protons and clustered together in a blob
neutrons. that is approximately
spherical. The radius of the
Z = proton number N = neutron number nucleus is ~ 1 fm = 1 10-15 m.
A=Z+N
Experiments show that:
A common symbolism used to show mass and 15
proton numbers is r (1.2 10 m) A1 / 3
A
E for example 126 C, 20
48
Ca, 197 The Nucleon Density, which is
Z 79 Au the # of protons and neutrons
Can be shortened to this symbolism
per unit volume, is the same
14
N, 63Cu, 107Ag, etc. for all atoms.
Mass defect and binding energy He nucleus, 2 protons and 2 neutrons.
+
So we have this spherical blob of positive 2 protons very close together. +

protons and neutral neutrons. How does it We know that like charges repel, and we
stay together??? can calculate the repulsive force between

one proton. Assuming the charges are separated by 1


But what about the next simplest element, fm, we get a force of 231 N. This results in
helium (He)? an acceleration of the protons = 1.4 × 1029
2 protons and 2 neutrons: m/s2. HUGE.

+
He nucleus, 2 protons and 2 neutrons. + Characteristics of the strong nuclear force
1. It is independent of charge. Thus, the
nucleus, just fly apart? attractive force between 2 protons is the
There must be an attractive force holding same as that between 2 neutrons or
between a neutron and a proton.
the gravitational attraction between to 2. The range of the force is extremely short.
subatomic particles is very small: ~1.9 × 10- It is very strong for distances ~1 fm and
34 N.
essentially zero at farther distances.
It is one of the fundamental forces, along
with gravity and the electroweak force.

Periodic Table of Elements


Most nuclei listed in the periodic table are
stable, but some are not.
The stability of a nucleus depends on the
balancing between the electrostatic
repulsion between protons and the strong
nuclear attractive force between all
nucleons.
Every proton in the nucleus feels
Coulombic repulsion from every other
proton, since the electro-static force is
long-ranged.

Periodic Table of Elements Periodic Table of Elements


But each proton and As a larger and larger
neutron only feels the nuclei is created, the
strong nuclear force from neutron number keeps
its closest neighbors. getting bigger and
To compensate for this, bigger.
the more protons I add to Notice how the neutron
the nucleus, an even # deviates from the N =
greater number of Z line for large nuclei.
neutrons must be added
to try and balance the
electrostatic force.
Periodic Table of Elements Periodic Table of Elements
Eventually, as more and Any element with an
more protons are atomic number Z > 83
added, no # of extra will be unstable and
neutrons can break apart over time.
compensate for the It will rearrange itself
large electrostatic into a stable nuclei.
repulsion, and the This process is called
nucleus breaks apart. Radioactivity.
This occurs at Z = 83,
which is bismuth (Bi).

Strong Nuclear Force


Smaller is Bigger!
(Binding energy)
Hydrogen atom: Binding energy =13.6eV Comparing Nuclear and Atomic sizes
Coulomb force (of electron to nucleus) Hydrogen Atom: Bohr radius = 5.29 11
10 m
proton
electron Nucleus with nucl number A: r A 1/3 (1.2 10 15
m)
neutron proton A
27 15
13 Al r 3.6 10 m
Simplest Nucleus: has radius
Deuteron Z
= neutron + proton Very strong force Note the TREMENDOUS difference

Binding energy of deuteron = 2.2 106 eV or Nucleus is 10 4 times smaller and binding energy
2.2Mev! is 105 times larger!

Binding Energy

E = m c2 Where does the energy released in


the nuclear reactions of the sun
come from?
Proton: mc2 = 938.3MeV Adding these,
get 1877.8MeV (1) covalent bonds between atoms
Neutron: mc 2= 939.5MeV
(2) binding energy of electrons to the nucleus
Difference is
Binding energy, (3) binding energy of nucleons
Deuteron: mc2 =1875.6MeV
2.2MeV
MDeuteron = MProton + MNeutron |Binding Energy|

-Energy Equivalence -Energy Equivalence


Relationship Relationship
In 1905, while developing his special theory where c is the speed of light.
of relativity, Einstein made the startling Everyday examples of energy gain are
suggestion that energy and mass are much too small to produce detectable
equivalent. changes of mass.
He predicted that if the energy of a body The changes of mass accompanying energy
changes by an amount E, its mass changes changes in chemical reactions are not
by an amount m given by the equation much greater and cannot be used to prove
E = mc2 Einstein's equation.
-Energy Equivalence -Energy Equivalence
Relationship Relationship
However, radioactive decay, which is a Mass appears as energy and the two can be
spontaneous nuclear reaction, is more helpful. regarded as equivalent.
Thus for a radium atom, the combined mass of In nuclear physics mass is measured in
the alpha particle it emits and the radon (Rn)
unified atomic mass units (u),
atom to which it decays is, by atomic standards,
appreciably less than the mass of the original 1 u being one twelfth of the mass of the
radium atom. carbon-12 atom
Atomic masses can now be measured to a very and equals 1.66 x 10-27 kg.
high degree of accuracy by mass spectrographs.
It can readily be shown using E = mc2 that
931 MeV has mass 1 u
-Energy Equivalence -Energy Equivalence
Relationship Relationship
A unit of energy may therefore be If the principle of conservation of energy is
considered to be a unit of mass, and in to hold for nuclear reactions it is clear that
tables of physical constants the masses of mass and energy must be regarded as
various atomic particles are often given in equivalent.
MeV as well as in kg and u. The implication of E = mc2 is that any
For example, the electron has a rest mass reaction producing an appreciable mass
of about 0.5 MeV decrease is a possible source of energy.
Shortly we will consider two types of
nuclear reaction in this category.

Isotopes Isotopes
Isotopes are atoms of the same
element but with different neutron
numbers.
Isotopes have different masses and A
values but are the same element.
Almost all elements exist as isotopes.

Example 1: Carbon isotopes Example 1: Carbon isotopes


There are three different Carbon-12 Carbon-14 is produced by cosmic ray
accounts for 98.89% of all carbon atoms bombardment of nitrogen (Unstable)
(Stable) Carbon-14 is radioactive (half-life 5760
Carbon-13 is the only magnetic carbon years), and it is used to date ancient
isotope (Stable) objects by studying the mounts of C-14 in
Carbon-14 is produced by cosmic ray them.
bombardment of nitrogen (Unstable)
Example 1: Carbon isotopes

Example 1: Carbon isotopes Example 1: hydrogen isotopes


12C 1H or protium is the most common
6 proton and 6 neutrons hydrogen isotope.
13C 1 proton and no neutrons
2H or deuterium is the second most
6 proton and 7 neutron
14C abundant hydrogen isotope.
6 proton and 8 neutrons 1 proton and 1 neutron
3H or tritium is a radioactive hydrogen

isotope.
1 proton and 2 neutrons

Example 2: oxygen isotopes


16O is the most abundant stable O isotope.
8 protons and 8 neutrons
17O is the least abundant stable O isotope.
Mass spectrometry
8 protons and 9 neutrons
18O is the second most abundant stable O

isotope.
8 protons and 10 neutrons

Mass Spectrometry Mass Spectrometry


Research into cathode rays showed that a In mass spectrometry a stream of positive ions
having equal velocities is brought into a
cathode-ray tube also produced positive magnetic field.
particles. All the ions are deflected from their straight line
Unlike cathode rays, these paths.
positive particles were ions. The lightest ions are deflected the most; the
heaviest ions are deflected the least.
The metal of the cathode: The ions are thus separated by mass.
M e + M+ Positive Actually, separation is by mass-to-charge
particles ratio (m/e), but the mass spectrometer is
Cathode rays designed so that most particles attain a 1+
charge.
Mass Spectrometer Mass Spectrum
for Mercury
Light ions are Heavy ions are
Mass spectrum of
deflected greatly. deflected a little bit.
an element shows
the abundance of its
Ions are separated isotopes. What are
according to mass. the three most
abundant isotopes
of mercury?
Mass spectrum of Mass spectrum of a
mercury vapor compound can give
Stream of positive ions information about the
with equal velocities structure of the compound.

Example
1. Two different nuclei have different
numbers of protons and a different
number of neutrons. Which of the 25.2 Radioactivity
following could be true?
They are different isotopes of the same
element.
They have the same electric charge.
Their nucleon density is the same.

Radioactivity Radioactivity
In 1896, Henri Becquerel discovered, Then Marie and Pierre Curie discovered more
radioactive elements including polonium and
almost by accident, that uranium can radium.
blacken a photographic plate, even in Scientists soon realised that there were three
the dark. different types of radiation.
These were called alpha ( ), beta ( ), and
Uranium emits very energetic gamma ( ) rays
radiation - it is radioactive. from the first three letters of the Greek
alphabet.

Alpha, Beta and Gamma Properties


Type of Alpha Beta Gamma
Penetrating effect radiation particles, particles, particles,
2 protons + 2 An electron EM-waves
neutrons as nucleus (similar to X-
(4He) decay ray)
Relative +2 -1 0
charges
Mass High low 0
(compare to )
Speed 0.1 the speed 0.9 the speed the speed of
of light of light light
Properties Properties
Type of Alpha Beta particles, Gamma
radiation particles, particles,
The diagram on the right
Ionizing effect Strong Weak Very weak
shows how the different
Penetrating Weak Penetrating, Strong, Never
types are affected by a
effect stopped by a Stopped by a Stopped. Leak magnetic field.
sheet of paper, few mm of Al and thick The alpha beam is a flow
skin or a few (or others concrete used
cm of air metal) to decrease of positively (+) charged
intensity particles, so it is
Effects on Deflected by Deflected by Not deflected equivalent to an electric
fields Magnetic and Magnetic and by Magnetic
Electric fields Electric fields and Electric
current.
fields

Properties Properties
The beta particles are much lighter than the
It is deflected in a alpha particles and have a negative (-) charge, so
direction given by they are deflected more, and in the opposite
Fleming's left-hand direction.
rule - the rule used for Being uncharged, the gamma rays are not
working out the deflected by the field.
direction of the force Alpha and beta particles are also affected by an
on a current-carrying electric field - in other words, there is a force on
wire in a magnetic them if they pass between oppositely charged
field. plates.

Ionising Properties
-particles, -particles and -ray photons are
all very energetic particles.
We often measure their energy in electron-volts
(eV) rather than joules.
Typically the kinetic energy of an -particle is
about 6 million eV (6 MeV).
We know that radiation ionises molecules by
`knocking' electrons off them.
As it does so, energy is transferred from the
radiation to the material.
The next diagrams show what happens to an
-particle

Alpha Decay
An alpha-particle is a helium nucleus and is
written 42He or 42 .
It consists of 2 protons and 2 neutrons.
Decay constant and half-life When an unstable nucleus decays by emitting
an -particle
it loses 4 nucleons and so its nucleon number
decreases by 4.
Also, since it loses 2 protons, its proton
number decreases by 2
Alpha Decay Beta Decay
The nuclear equation is Many radioactive nuclides (radio-nuclides)
decay by -emission.
A A 4 4 This is the emission of an electron from the
Z X Z 2Y 2 nucleus.
Note that the top numbers balance on each But there are no electrons in the nucleus!
side of the equation. So do the bottom
numbers.

Beta Decay Beta Decay


What happens is this: The nuclear equation is
one of the neutrons changes into a proton
(which stays in the nucleus) and an A A 0
electron (which is emitted as a -particle). Z X Z 1Y 1e
This means that the proton number
increases by 1, Notice again, the top numbers balance, as
do the bottom ones.
while the total nucleon number remains
the same.

Beta Decay Beta Decay


A radio-nuclide above the stability line
decays by -emission. N
Because it loses a neutron and gains a
proton, it moves diagonally towards the
stability line, as shown on this graph

Gamma Decay Decay chains


Gamma-emission does not change the A radio-nuclide often produces an unstable
structure of the nucleus, but it does make daughter nuclide.
the nucleus more stable The daughter will also decay, and the process
will continue until finally a stable nuclide is
because it reduces the energy of the
formed.
nucleus.
This is called a decay chain or a decay series.
Part of one decay chain is shown below
Decay chains Half Life
Suppose you have a sample of 100 identical
When determining the nuclei.
products of deacy All the nuclei are equally likely to decay, but you
series, the same rules can never predict which individual nucleus will
apply as in determining be the next to decay.
the products of alpha The decay process is completely random.
and beta, or artificial Also, there is nothing you can do to `persuade'
transmutation. one nucleus to decay at a certain time.
The only difference is The decay process is spontaneous.
several steps are
involved instead of just
one.

Half Life Half Life


Does this mean that we can never know the rate Iodine-131 is a radioactive isotope of iodine.
of decay?
The chart on the next slide illustrates the
No, because for any particular radio-nuclide
there is a certain probability that an individual decay of a sample of iodine-131.
nucleus will decay. On average, 1 nucleus disintegrates every
This means that if we start with a large number second for every 1000 000 nuclei present.
of identical nuclei we can predict how many will
decay in a certain time interval.

Half Life

Suppose there are 40 million nuclei.


8 days later, half of these have disintegrated.
With the number of undecayed nuclei now
halved, the number of disintegrations over the
next 8 days is also halved.
It halves again over the next 8 days... and so on.
Iodine-131 has a half-life of 8 days.

Definition 1 Activity and half-life


The half-life of a radioactive isotope is the In a radioactive sample, the average
time taken for half the nuclei present in number of disintegrations per second is
any given sample to decay. called the activity.
The SI unit of activity is the Becquerel
(Bq).
An activity of, say, 100 Bq means that 100
nuclei are disintegrating per second.
Activity, A = dN/dt (Bq)
Activity and half-life
The graph on the next slide of the next
page shows how, on average, the activity of
a sample of iodine-131 varies with time.
As the activity is always proportional to the
number of undecayed nuclei, it too halves
every 8 days.
So `half-life' has another meaning as well:

Definition 2
The half-life of a radioactive isotope is the
time taken for the activity of any given
sample to fall to half its original value.

Exponential Decay Rate of Decay


Any quantity that reduces by the same Rate of decay =
fraction in the same period of time is called N
an exponential decay curve. N=undecayed nuclei att time (an instant) t.
The half life can be calculated from decay Negative sign: no. of nuclei is decreasing
curves The rate of nuclear disintegration at a particular
Take several values and the take an average moment depends on the number of undecayed
nuclei at that moment,
Hence,
N
N
t

Rate of Decay Radioactive Decay Problems


decay constant, a positive
N
N constant used to describe the rate of
t exponential decay.
Let t 0,
N(t) = N0e- t
then N/ t dN/dt (the rate of decay)
No is the initial value of N
Hence, dN , = decay constant
N N(t) is the value of N at time t
dt
Activity, A = dN/dt (Bq) t is the time
= N ; dN/dt =- N Half-life : T1/2 = (ln 2)/
Rare Earth Elements Rare Earth Elements
Rare earth ore, shown with a United States
penny for size comparison

These rare-earth oxides are used as tracers to


determine which parts of a watershed are
eroding. Clockwise from top
center: praseodymium, cerium, lanthanum,neod
ymium, samarium, and gadolinium.[1]

Rare Earth Elements Rare Earth Elements


Despite their name, rare earth elements (with the exception of
As defined by IUPAC, rare earth the radioactive promethium) are relatively plentiful in
elements or rare earth metals are a set of the Earth's crust, with cerium being the 25th most abundant
element at 68 parts per million (similar to copper). However,
seventeen chemical elements in because of their geochemical properties, rare earth elements are
typically dispersed and not often found in concentrated and
the periodic table, specifically the economically exploitable forms known as rare earth
fifteenlanthanoids plus scandium and yttri minerals.[3] It was the very scarcity of these minerals (previously
called "earths") that led to the term "rare earth". The first such
um.[2] Scandium and yttrium are mineral discovered was gadolinite, a compound of
cerium, yttrium, iron, silicon and other elements. This mineral
considered rare earth elements since they was extracted from a mine in the village of Ytterby in Sweden;
tend to occur in the same ore deposits as many of the rare earth elements bear names derived from this
location.
thelanthanoids and exhibit similar
chemical properties.

Uranium
Additional knowledge: A Naturally Occurring
Radiation in Our Environment Radioactive Element in the

©Health Physics Society

Fiesta Ware Green Bathroom Tile

Some of these plates are


glazed with uranium certainly before 1943
The uranium has the Analysis showed it
chemical form U3O8 contains natural uranium
This form is called Dose rate in the
bathroom was about 10
is bright yellow in color times the normal
background (0.1 mR/h)
Firing the plate in a kiln
turns the color orange
Uranium Glass Vaseline Glass
Uranium was discovered
in 1792 by a German
chemist named Klaproth
It has been used in
making glass since the

Concentration of
uranium as well as
temperature and
annealing procedure can
determine the colors Under UV Light

A Uranium Glass Marble Cloisonné Jewelry


Fine jewelry formed on
metal frame with fine
glass powder poured
into frame
Glass is melted at about
850 C
Uranium oxide is used
to produce ivory, yellow
and gold colors
Under UV Light Typically about 7% UO2

Dentures Phosphate Fertilizer

Uranium is added to false teeth to provide a About 150 million tons of


shine to the material (about 10% of the teeth) phosphate are mined annually
Concentration of uranium is quite low about Ore contains uranium, thorium
300 parts per million and radium as well as K-40
Produces 12 to 15 million tons of
phosphate fertilizer
Total activity of Ra-226 in the
fertilizer tonnage is about 12 Ci

Cat Litter Penetrators


Armor-piercing bullets
Most cat litter made and shells
from clay (e.g.,
bentonite) uranium (DU)
Contains elevated levels DU is the U-238 left when
of naturally occurring most of the U-235 had
radionuclides been removed
Contains 4 pCi/g of Uranium metal is very
uranium series, 3 pCi/g dense and it burns
of thorium series, and 8 spontaneously upon
pCi/g of K-40 impact
The are higher
THORIUM concentrations of
thorium than uranium
A Naturally Occurring
This plate has been
Radioactive Element in the glazed with ThO2
It is used in a number of
applications

Thorium Lantern Mantles Welding Rods


Thorium oxide is also used
in tungsten welding rods
It increases the current
carrying capacity of the rod
Production is 1-5 million
rods per year
Concentration of ThO2 is
usually 1-2% (15-30 Ci)
Some welding rods have
concentrations up to 4%

Camera Lenses Other Uses of Thorium


Th-232 is added to the
lenses to increase the This tape dispenser
index of refraction has sand mixed with
Some lenses have up to epoxy resin in its base
12% thorium The sand is called
Use began around the Monazite (a black
sand)
Use ceased in the late Monazite sand
contains up to 10%
thorium
Military lenses may still
show radioactivity

Revigator
In the 1920-
believed that drinking
water containing radium
OTHER RADIONUCLIDES (Ra-226, Ra-228) was
good for your health

on demand, because it
had a radium-ore cone
inside
Smoke Detectors Smoke Detectors
Smoke detectors save
The radioactive
lives and are important
source used in
in commercial and
current detectors is
residential structures
Am-241
About 80% of U.S.
The total activity is
homes have at least one
low, about 1 Ci
detector
The detector and
The detector is really an
source are enclosed
ionization chamber
in the cover shown at
containing a small
the right
radioactive source

Static Eliminator
Many devices use
radioactive sources to
eliminate static RADIOACTIVITY IN
electricity
FOODSTUFFS
Copy machines and
other such machines
used static eliminators
The usual radioactive
source is Po-210, initial
activity 200 - 500 Ci

Bananas Salt Substitute


Bananas contain the Some individuals cannot
radionuclide K-40 or 40K use regular salt (NaCl) to
This is a naturally season their food
occurring isotope of the They use KCl instead
element potassium But the KCl is
Potassium is essential in radioactive because of
muscle function and the K-40 that is present
concentrates in the in the salt substitute
muscle Activity about 450 pCi/g
Who is more radioactive,
males or females?

Salmon Brazil Nuts


Salmon are born in fresh
These nuts concentrate
water but live their life in
Ra-226 from the soil
the ocean
These nuts are probably
Natural radioactivity from
the most radioactive
the rocks and soil is washed
foodstuff we consume
into the oceans
Yet the radioactivity is so
The salmon tend to
low that it is difficult to
concentrate this radioactive
measure it
material in their flesh
typical values are 20 pCi/g From 0.2 to 7 pCi/g
Nuclear Reactors

use fission of heavy


elements like uranium

25.3 Nuclear reaction

fusion reactor

PHY232 - Remco Zegers -


125
nuclear physics

Nuclear Reactions Nuclear Reactions


First nuclear reaction was a nitrogen target bombarded
A nuclear reaction takes place when a with alpha particles, which emitted protons. The
nucleus is struck by another nucleus reaction is written as:
or particle.
The first particle is the projectile and the second is the
nitrogen target. These two nuclei react to form proton
An example: projectiles and the residual oxygen target.
The reaction can be rewritten in shorthand as: 14N( ,
p)17O.
In general a reaction x + X y + Y can be rewritten
as X(x, y)Y

Reaction Energy Reaction Energy


x+X y+Y A proton strikes a tritium nucleus and the
Sum of masses of x + X> sum of masses of y + Y following nuclear reaction takes place
Decrease in mass due to some mass is converted 1H + 3H n + 3He
to energy
Thus Determine the energy released in MeV. (Masses:
3H = 3.016050 u, 1 H = 1.007276 u, 3He = 3.016030
x + X y + Y + Q (energy)
u, 1n = 1.008665 u, 1u = 931.5MeV)
Where Q = ( m)c2; m = mass (lost)
m = (3H + 1H) (3He + 1n) = -0.001369 u
If Q is positive exothermic, if Q is negative
endothermic Q = m (in MeV) = (-001369)(931.5) = -1.275MeV
endothermic

Important Technological Advances Important Technological Advances


The first cyclotron (at left) was built in 1932.
The high-voltage multiplier
circuit was developed in 1932 by It accelerated charged particles using large
J.D. Cockcroft and E.T.S. Walton. circular magnets.
This compact circuit produces
high-voltage, low-current pulses.
High voltage is required to
accelerate charged particles.
The Van de Graaff electrostatic
accelerator was developed in 1931.
It produces a high voltage from
the friction between two
different materials.
Types of Reactions Nuclear Fission
Nuclear photodisintegration is the initiation of a nuclear After absorbing a neutron, a
reaction by a photon.
Neutron or proton radioactive capture occurs when the uranium-235 nucleus will
nucleon is absorbed by the target nucleus, with energy and
momentum conserved by gamma ray emission. split into two roughly equal
The projectile and the target are said to be in the entrance parts.
channel of a nuclear reaction. The reaction products are in the
exit channel. One way to visualize this is
In elastic scattering, the entrance and exit channels are
identical and the particles in the exit channels are not in to view the nucleus as a kind
excited states.
of liquid drop.
In inelastic scattering, the entrance and exit channels are also
identical but one or more of the reaction products is left in an
excited state.
The reaction product need not always be in the exit channel.

Nuclear Fission Nuclear Fission; Nuclear Reactors


The energy release in a fission reaction is quite
In order to make a nuclear reactor, the
large. Also, since smaller nuclei are stable with chain reaction needs to be self-sustaining
fewer neutrons, several neutrons emerge from each it will continue indefinitely but
fission as well. controlled.
These neutrons can
be used to induce
fission in other
nuclei, causing a
chain reaction.

Nuclear Fission; Nuclear Reactors Nuclear Fission


Neutrons that Fission The splitting of heavy
nuclei into lighter, more-tightly
escape from the bound, pieces
uranium do not Spontaneous fission nuclei
splits without initiating event
contribute to fission. Neutron-induced fission nuclei
splits after being hit by a neutron
There is a critical
Fissionable Nuclei which can
mass below which a undergo neutron-induced fission
chain reaction will Fissile isotopes Nuclei in which

not occur because neutron. Examples: 233U, 235U,


239 Pt
too many neutrons
escape.

Fission of U-235 U-235 Chain Reaction


Nuclear Chain Reaction Nuclear Fusion
Neutrons can induce The lightest nuclei can fuse to form
fission, which can release heavier nuclei, releasing energy in the
additional neutrons
Chain reaction process process.
-
Subcritical one fission
Go to the other end of the scale
leads to less than one fission Put small nuclei together to form bigger
Critical one fission leads
to one fission ones and also releasing energy
Supercritical one fission
leads to more than one
fission
Enrichment For example,
increasing 235U relative to
238U

Nuclear Fusion Nuclear Fusion


Fusion The
combining of light
nuclei into a heavier,
more-tightly bound,
pieces
What is the challenge
in inducing fusion?
Energy mechanism of
Sun Sun converts
H He Li Be
B Fe

Nuclear Fusion Nuclear Fusion


Powers the sun and stars with various The sequence of fusion processes that
cycles leading to iron Counting change hydrogen into helium in the
positron-electron Sun. They are listed here :
p p d e annihilation the
3 net energy
p d 2 He
output is 26.7
3 3 4
2 He 2 He 2 He p p MeV. Not as
much as fission,
4 p 42 He 2e 2 2 but per kg of fuel
a much bigger
yield.

Fusion: endless supply of energy.


Fusion Just not quite available yet.
In a nuclear fusion reaction, two lesser nuclei Fusion energy comes from very mundane everyday stuff. Like
combine to make a heavier one. The nuclei again go water. Typical fusion reaction: 2D + 2D 4 He

from loose binding to tight. The slope is much higher (here 2D is deuterium, heavy isotope of hydrogen. It is found
so the energy released is much greater!
Note the scale: However, controlled fusion is still an elusive goal. The
0 to 9 MeV. uncontrolled version of fusion exists in the form of hydrogen
Mass of a nucleon is bomb.
about 932 MeV, so
even in a fusion
reaction only a fraction
of one percent of the
total mass is converted
to energy
Annihilation: all mass goes into energy Energy-momentum diagram for annihilation
Annihilation is an interaction between a particle Before annihilation: two particles of mass
and its own antiparticle. Result of annihilation is m each, at rest, so: p = 0, E = 2m
electromagnetic radiation photons.
After: photon(s) of mass 0, equal energy
Simple example: an electron and a positron,
both at rest (nearly), annihilate. How many
and momentum.
photons come out? Photon positron 2m
electron photon positron
One big photon? Or many small ones?
photon m photon
Conservation of energy-momentum helps us v = -1v = 0
vv==01
p = -2m
answer this question... p =0 pp==02m electron
E = 2m
EE==m
2m
E=m momentum
2m 2m

Annihilation: all mass goes into


Mass production of antimatter
energy - 2
Antihydrogen can be made by combining antiprotons (the
Annihilation is a very simple, but by no means -elements
the only possible outcome of a particle- are much harder to make: first, the anti-nucleus must be
formed our of antiprotons and antineutrons, a very difficult
antiparticle collision. More exciting, and more process.
Two experiments at CERN are trying to make antihydrogen in
interesting from the point of view of physics, large quantities (thousands to millions of anti-atoms).
are collisions that produce new massive
particles.
Annihilation may be a source of energy (even
more efficient than fusion 100% of mass goes
into energy), but we first need a source of
antimatter.

Uses of antimatter Special Applications


Antihydrogen is of interest to physicists who look for A specific isotope of a radioactive element is called a
violation of certain symmetries. Hydrogen atom has radioisotope.
been measured to an unbelievable precision; if we can
now do spectroscopy on antihydrogen to a precision Radioisotopes are produced for useful purposes by different
that is anywhere near that, small deviations can be methods:
discovered that lead to new understanding of laws of 1) By particle accelerators as reaction products
Nature. To make such high-precision measurements,
many antihydrogen atoms are needed, millions or 2) In nuclear reactors as fission fragments or decay
more. products
Curious fact: when NASA learned about antihydrogen 3) In nuclear reactors using neutron activation
production experiments, they immediately asked if
An important area of applications is the search for a very small
CERN could send them 1 mg of antihydrogen in a
bottle. Well, magnetic bottle. Still how many atoms is concentration of a particular element, called a trace element.
that? 1 gram of hydrogen (or antihydrogen) is about 6 Trace elements are used in detecting minute quantities of trace
x 1023 atoms, so 1 milligram is about 6 x 1020 atoms elements for forensic science and environmental purposes.
a far cry from what is possible.

Medicine Archaeology
Over 1100 radioisotopes are available for Investigators can now measure a large number of trace elements in
clinical use. many ancient specimens and then compare the results with the
Radioisotopes are used in tomography, concentrations of components having the same origin.
a technique for displaying images of Radioactive dating indicates that humans had a settlement near Clovis,
practically any part of the body to look New Mexico 12,000 years ago. Several claims have surfaced in the past
for abnormal physical shapes or for few years, especially from South America, that dispute this earliest
testing functional characteristics of finding, but no conclusive proof has been confirmed.
organs. By using detectors (either The Chauvet Cave, discovered in France in 1995, is one of the most
surrounding the body or rotating important archaeological finds in decades. More than 300 paintings
around the body) together with
and engravings and many traces of human activity, including hearths,
fiintstones, and footprints, were found. These works are believed, from
computers, three-dimensional images of 14C radioactive dating, to be from the Paleolithic era, some 32,000 years
the body can be obtained. ago.
They use single-photon emission
computed tomography, positron
emission tomography, and magnetic
resonance imaging.
Art Crime Detection
Neutron activation is a nondestructive technique that is
becoming more widely used to examine oil paintings. A The examination of gunshots by measuring
thermal neutron beam from a nuclear reactor is spread trace amounts of barium and antimony from
broadly and evenly over the painting. Several elements
within the painting become radioactive. X-ray films the gunpowder has proven to be 100 to 1000
sensitive to beta emissions from the radioactive nuclei are times more sensitive than looking for the
subsequently placed next to the painting for varying lengths
of time. This method is called an autoradiograph. residue itself.
Saint Rosalie Interceding
for the Plague-Stricken of Palermo, from the New York Scientists are also able to detect toxic
Metropolitan Museum of Art collection and revealed an
over-painted self-portrait of Van Dyck himself. elements in hair by neutron activation
analysis.

Mining and Oil Mining and Oil


Geologists and petroleum The neutrons activate nuclei in the
engineers use radioactive sources material surrounding the borehole, and
routinely to search for oil and gas. these nuclei produce gamma decays
A source and detector are characteristic of the particular element.
inserted down an exploratory drill
hole to examine the material at
different depths.
Neutron sources called PuBe
(plutonium and beryllium) or
AmBe (americium and beryllium)
are particularly useful.

Small Power Systems New Elements


Alpha-emitting radioactive sources have been
used as power sources in heart pacemakers. No transuranic elements those with atomic
number greater than Z = 92 (uranium) are
Smoke detectors use 241Am sources of alpha
found in nature because of their short half-
particles as current generators. The scattering of
lives.
the alpha particles by the smoke particles
reduces the current flowing to a sensitive solid-
state device, which results in an alarm.
Spacecraft have been powered by radioisotope
generators (RTGs) since the early 1960s.

New Elements Summary


Reactors and especially accelerators have been Nuclues:
able to produce 22 of these new elements up to Z Atomic number & Mass number: Z AX
= 116. Mass defect
Over 150 new isotopes heavier than uranium mp + (A - Z)mn] - MN

have been discovered. Binding Energy


EB = (mass defect) X c2
Physicists have reasons to suspect from shell Discovery of Neutrons
model calculations that superheavy elements
Isotopes
with atomic numbers of 110 120 and 184 Mass Spectrometry
neutrons may be particularly long-lived. Selected velocity, v = E/B
In magnetic field, qvB = mv2/r
Summary Summary
RADIOACTIVITY NUCLEAR REACTION

Radioactive Nuclear Nuclear


Radioactive Decay Constant Uses
Decay and Half-Lite Decay Fission Fusion
n+X X+Y
Radioactive tracer
dN/dt = - N N(t) = N0e- t -Medicine Y + Z + kn Z + energy
-Agriculture + energy
= ln2 / T1/2 Bombardment
-Industry
Carbon-14 dating With Chain Reaction Thermonuclear
-particles Reaction
protons Nuclear Reaction

End of Chapter

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