‘Name Period ___ Date For the following three reactions, ) write the Keg expression in terms of concentration, Ke, b) given the equilibrium concentrations, state Whether each equilibrium is produet-favored, reactant-favored, or fairly even ([produets] = [reactants)). ©) calculate the value of Ke, 1. Nog) +3 Ha(g) 5 2 NHs(g) [N:]=1.50M [Hh] = 2.00 M iH [NBs] 0.01 M Ke Cwd” (0% CNSICH,I” (150X206)? = B.33x 107% K.<4 80 veaclant favored 2, HF(aq) S H*(aq) + F-(aq) Atequilibrium: [HF] = 0.55 M tH] At equilibrium: 1.001 M Ke OFF] = © 001X0.00 Chel (0.55) pei Se Kéd So vesctant Saveve a 3. Fe™(aq) + SCN*(aq) 5 FeSCN™ (ag) Atequilibrium: ——_[Fe* [SCN [FeSCN*"]= 0.001 M Ke CFeSCn*] _ (0.901) Cre*IEsen] (0.520.001) Veeseeaccrd alee suiamarie®? PWVIY evens Fill in the blanks with product-favored, reactant- favored, and approximately equal Ke state of equilibrium Ke>>1 Product Favored KI Yeactenk Caveved Kal Aepronimate ly equal PROBLEM SET #4 4, Knowing that pure water has a density of 1g/ImL calculate the mass of 1.00 Liter of water. Nodk, come, 1g. ipo v t Calculate the number of moles in 1.00 L of H:0. 1004 x jg 2 56.56 mol What is the concentration (M) of water in water? Mz 2h. 55.5% mal L Be.piewal _/55. eM] At this temperature, can you get more moles of water oo this Liter of watese Geng S eee wl The [20]__ 1S 6s ABB case Gime. oa IS 7 ince The Orcefirations of solids and liquids are) Gg constant, they are incorporated into the py equilibrium constant, Key. That means, just leave € importa them out of the Ke or K, expression. Only include (g) and (aq)! 5. Write equilibrium expressions for each of the following reactions: a) CaCOxs) = CaO(s) + COx(g) Ke [o,1 b) Nils) + 4CO(@) ©) SCO(g) + 105(s) = h(g) + 5CO.Kg) Kes 3 £co,1$ [col * & Ca(HCOs):(aq) = CaCO;(s) + H20() + CO.(e) + COO, Beas COor7 [CatHco >>| €) AgCl(s) = Ag’(aq) + C'(aq) Ke,> CAg“IEci7]6. Write the equilibrium expression in terms of I pressures (K,) for each of the following reactions. Rate the reactions in order of their increasing (@) ANH3(£) + 302(2) = 2N2() + 6H2O(E) Kp= 1x 108 atm rot 3 Kee (ray ey Py Ey Prete Chan Pes” (6) N3@) + o2@) = 2NO(e) Kp=5x en <= most | K=O” (RMP, =) | (© 2F@= H®) + File) | Kya Tx 10" 2 modly veaclants tell (@) 2NOCIg) = Pa) + Chy(e) Kp=4.7x 104 aim g mostley reactants COGAN “CPrec)® 01 ‘A Question That You cons Be Able To Answer: ‘Why don't the K,’s in (b) and (c) have unis? The vnits unl Convel since ave Capel + of mmoles ton t eee roduc t 7. (@) Write the K. expression for 2 SOxg) + Ox(E) 2 SOX) K,> [S0y]* (301°T os] Calculate the value of Ke: ‘Atequilibrium: [SOx] = @ soy" (180)"(126) = 436 tendency to sd toward completion: CPrvela. rere eee eal by Feats (b) Ifwe reverse the equation, itis: 2 SOx(g) 5 2 SOXg) + Ox(g) ‘Write the Ke expression for this equation and calculate the new value of Ke: Ke [$,3"£0,2, C1S0Y"C 1.25) a How does the expression and the value of Kein 7(b) compare with those in 7(a)? K ae *horwurd)” “K crevase) (© Ifwe now multiply all of the coefficients by ¥6: SOx(g) 5 SOx(2) + % Ox(g) ‘Write the Ke expression for this equation and calculate the new value of Ke: Kes [So,100,1"* % Csoied” “TS 3.60 +0479 How do they compas um 7b)? (@® What would happen to the K. expression and its value if we doubled the coefficients? = (K.Y* ‘Summarize: ‘Equation K, expression & Value doubled Ki=(Ke\* Sivared reversed Ky fey inverse | halved: kKek* gy foot | 8. Consider an equilibrium that occurs in two steps: H,S(aq) H’(aq) + HSY{aq) (a + H.-S Bt ZH+4 SP- (a) Write the overall reaction. (©) How do the K-’s for the two steps (Ker & Ke) relate to the Ke of the overall reaction (K.)? kK, CHIcds a. = Lueaese7} ts] aie Ket Ku Kae Ke Ky. GATS LHL s*) < WEES! GST DAS]