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Draft EIA Report

of

M/s. Narayan Organics Pvt. Ltd. (Unit-II)


Block No. 164 to 170,
Village: Vedach, Taluka – Jambusar,
Dist. – Bharuch,
Gujarat.

Prepared by

San Envirotech Pvt.Ltd


424, Medicine Market
Opp. Shefali Centre
Paldi, Ahmedabad
Email: mahendra.sepl@gmail.com
Contents
Particulars Page No.
Contents 1-6
List of Tables 7
List of Figures 9

Executive Summary
E.1 Background E-1
E.2 Project Description E-1
E.3 Proposed Production Capacities of Plant E-2
E.4 Description of Environment E-3
E.5 Air Environment E-3
E.6 Water Environment E-4
E.7 Noise Environment E-5
E.8 Environmental Impacts and Mitigation Measures E-5
E.9 Environment Monitoring E-8
E.10 Qualitative Risk analysis E-8
E.11 Environment Management Plan E-8
E.12 Conclusion E-9
Chapter 1 Introduction
1.1 Background of the company 1-1
1.2 Purpose & needs of EIA 1-2
1.3 Statement of Principles 1-4
1.4 Statutory requirements 1-4
1.5 Terms of Reference Accepted/Issued By MoEF On Dated 1-4
09/09/2010
1.6 Objectives of EIA 1-9
1.7 Scope of EIA 1-9
1.8 Methodology of EIA 1-10
1.9 Justification for the project site 1-12
Chapter-2 Project Description
2.1 Introduction 2-1
2.2 Capital Investment 2-1
2.3 Type of Project 2-1

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2.4 Need of the Project 2-1
2.5 Land Requirement 2-2
2.6 Size of the project 2-6
2.7 Manufacturing Process 2-3
2.7.1 Copper Phthalocyanine Blue 2-3
2.7.2 Pigment Alpha Blue 2-5
2.7.3 Pigment Beta Blue 2-7
2.8 Input Requirements & Infrastructure facilities including 2-9
power sources
2.8.1 Water 2-9
2.8.2 Fuel 2-9
2.8.3 Power 2-9
2.8.4 Manpower 2-9
2.9 Generation of Pollutants 2-10
2.9.1 Details of pollutant generation 2-10
2.9.2 Pollution control strategy 2-11
2.9.3 Resource recovery 2-14
2.10 Resource conservation 2-16
2.10.1 Ground Water Recharging System 2-16
2.10.2 Green Belt Development 2-16
2.11 Health & Safety 2-16
Chapter-3 Baseline Environmental Status
3.1 Prelude 3-1
3.2 Air Environment 3-1
3.2.1 Design of Network for Ambient Air Quality Monitoring 3-2
Stations
3.2.2 Reconnaissance 3-2
3.2.3 Micrometeorology of the Area 3-3
3.2.4 Ambient Air Quality Survey 3-4
3.2.5 Baseline Status 3-4
3.2.6 Identification of Impacts 3-5
3.3 Water Environment 3-6
3.3.1 Water Quality 3-6
3.4 Noise Environment 3-7
3.4.1 Introduction 3-7

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3.4.2 Methodology 3-7
3.4.3 Ambient Air Quality Standards in Respect of Noise 3-7
3.4.4 Day-Time and Night-Time Noise Levels 3-8
3.4.5 Conclusions 3-8
3.5 Soil Environment 3-8
3.5.1 Introduction 3-8
3.5.2 Soil Characteristics 3-9
3.5.3 Corollaries 3-9
3.6 Terrestrial Ecology (Flora) 3-10
3.6.1 Common crop plants 3-10
3.6.2 Ecological Stresses 3-11
3.6.3 Terrestrial Wild Life 3-11
3.6.4 Fauna 3-11
3.7 Socio Economic & Land use 3-11
3.7.1 Land use pattern and infrastructure 3-11
3.7.2 Demographic and Socio-Economic Environment 3-12
3.7.3 Living Standard & Infrastructure 3-12
Chapter-4 Anticipated Environmental Impacts & Mitigation
Measures
4.1 General 4-1
4.2 Impact During Construction and Operation Phase 4-2
4.3 Impact on topography 4-2
4.4 Air Environment 4-2
4.4.1 Construction Phase 4-2
4.4.2 Operational phase 4-3
4.4.3 Source of Air pollution 4-3
4.4.4 Emissions 4-3
4.4.5 Micrometeorology 4-4
4.4.6 Air Quality Modeling and Predictions using the Gaussian 4-5
Model (ISCST3)
4.4.7 Predicted GLCs of proposed dyes Plant 4-7
4.5 Water Environment 4-7
4.5.1 Water demand 4-7
4.5.2 Wastewater Generation – Operational Phase 4-8
4.5.3 Effluent Treatment within Unit 4-8

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4.6 Noise level impact 4-9
4.6.1 Construction Phase 4-9
4.6.2 Operational Phase 4-10
4.7 Solid waste management 4-10
4.8 Socio-Economic Impacts: Construction & Operational Phase 4-11
Chapter-5 Environment Management Plan
5.1 Introduction 5-1
5.2 Objective of Environmental Management Plan 5-2
5.3 Components of EMP 5-2
5.4 Environmental, Health and management system 5-2
5.5 Air Environment 5-3
5.5.1 Measures for reducing stack emission 5-4
5.5.2 Measures for fugitive emissions 5-9
5.6 Water Environment 5-10
5.6.1 Segregation and collection philosophy 5-10
5.6.2 Wastewater Treatment 5-11
5.6.3 Artificial water recharge 5-11
5.7 Solid Waste Management 5-12
5.8 Noise Environment 5-13
5.9 Green Belt Development 5-14
5.10 Resource Conservation/ Waste Minimization 5-15
5.11 Health & Safety 5-15
5.11.1 Possibility of occupational health hazard & it control 5-17
5.11.2 Preventive Measures 5-18
5.12 Occupational Health Programme 5-18
5.12.1 Hazard Communication and chemical Safety 5-19
5.13 Post-Project Environmental Monitoring 5-20
Chapter-6 Quantitative Risk Assessment
6.1 Introduction 6-1
6.1.1 Scope of Study 6-1
6.1.2 Study objective 6-1
6.1.3 The Study Approach 6-1
6.1.4 System Description 6-2

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6.1.5 Identification of Hazards 6-2
6.1.6 Selection of Accident Scenarios 6-2
6.1.7 Effects & Consequence Estimation 6-2
6.1.8 Risk Reduction Measures 6-2
6.2 Hazardous Identification 6-2
6.2.1 Hazardous Substances to be handled at Narayan Organics 6-3
6.3 Quantities of Hazardous Materials 6-10
6.4 Hazards Due to leakage or Containment 6-10
6.5 Maximum Credible Accident Scenarios 6-11
6.5.1 Methodology for Selection of Accident Scenarios 6-11
6.5.2 Maximum Credible Accident Scenarios 6-12
6.5.3 Consequence Analysis 6-12
6.6 Probable hazards & risks 6-13
6.7 Methodology, approach and damage criteria for risk 6-13
assessment
6.7.1 Hazards evaluation: exposure to toxic dusts/ vapors 6-14
6.7.2 Liquid Pool Evaporation or Boiling 6-14
6.7.3 Plant leakage in confined space 6-14
6.7.4 Damage criteria 6-15
6.8 Risk Mitigation Measures 6-15
6.8.1 Personnel Protective Equipment (PPEs) 6-17
6.8.2 Handling of hazards 6-18
6.8.3 General working conditions 6-18
6.8.4 Safe operating procedures 6-19
6.8.5 Work permit system 6-19
6.8.6 Fire Protection 6-19
6.8.7 Emergency Preparedness 6-19
6.8.8 Static Electricity 6-19
6.8.9 Material handling 6-19
6.8.10 Communication System 6-20
6.8.11 Accident Reporting, Investigation And Analysis 6-20
6.8.12 Safety Inspections 6-20
6.8.13 Safe Operating Procedures 6-20
Chapter-7 Onsite Disaster Management Plan

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7.1 Introduction 7-1
7.2 Probable Hazards & Risk 7-2
7.3 Objectives of the plan 7-2
7.4 Identification of major hazards 7-3
7.5 Scope of plan 7-3
7.6 The utility, organization and utilization of resources and 7-4
facilities for emergencies
7.7 Response Organization Structure 7-5
7.8 Emergency Response Center 7-8
7.9 Post emergency – recovery 7-10

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List of Tables
Table No. Name Page No.
2.1 Raw Materials 2-17
2.2 Details of Water Consumption and waste water generation 2-18
2.3 Details of stacks 2-20
2.4 Estimated quality of Air emission 2-21
2.5 Details of ETP Units 2-22
2.6 Estimated quality of effluent 2-24
2.7 Details of Solid/Hazardous Waste 2-25
2.8 Estimated characteristics of Hazardous waste 2-26
3.1 Ambient Air Quality Monitoring Locations 3-14
3.2 Ambient Air Quality Status 3-14
3.3 Ambient Air Quality Status (PM10) 3-15
3.4 Ambient Air Quality Status (PM2.5) 3-16
3.5 Ambient Air Quality Status (SO2) 3-17
3.6 Ambient Air Quality Status (NOx) 3-18
3.7 Volatile Organic Compound (VOCs) in μg /m3 3-19
3.8 National Ambiant Air Quality Standards 3-20
3.9 Results of Groundwater Quality in the Study Area 3-22
3.10 Indian Standard Specification for Drinking Water 3-23
3.11 Ambient Noise Levels in the Study Area 3-24
3.12 Ambient Air Quality Standards with respect to Noise 3-24
3.13 Soil Analysis of Study area 3-25
3.14 List of Tree Species found in the study area 3-26
3.15 List of Amphibia, Reptilia and Birds in the study area 3-28
3.16 Land use statistics work out on the base of satellite 3-31
imaginary
3.17 Land Use Pattern 3-32
3.18 Summary of Socio-Economic Status 3-33
3.19 Basic amenities in the study area 3-35
4.1 Estimated quality of Air emission 4-12
4.2 The 24-hourly average GLC Concentration Values for SPM 4-13
4.3 The 24-hourly average GLC Concentration Values for SO2 4-14

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4.4 The 24-hourly average GLC Concentration Values for NOx 4-15
4.5 The 24-hourly average GLC Concentration Values for NH3 4-16
5.1 Design features for minimization of fugitive emissions 5-23
5.2 Environment Monitoring 5-23
6.1 Facilities for Storage of Chemicals 6-10

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List of Figures
Table No. Name Page No.
1.1 Location Map 1-13
2.1 Water balance diagram 2-19
2.2 ETP Flow Diagram 2-23
2.3A Location Map 2-27
2.3B Factory Layout 2-28
3.1 Graphical representation for PM10 3-15
3.2 Graphical representation for PM2.5 3-16
3.3 Graphical representation for SO2 3-17
3.4 Graphical representation for NOx 3-18
3.5 Ambient Air Quality Monitoring Station 3-38
3.6 Wind rose Diagram 3-39
3.7 Water sampling location 3-40
3.8 Location Noise monitoring station 3-41
3.9 Soil sampling station 3-42
3.10 Satellite image of Vedach Region 3-43
3.11 Forest Map of Gujarat 3-44
4.1 Isopleths for Ground Level Concentrations for SPM 4-17
4.2 Isopleths for Ground Level Concentrations for SO2 4-18
4.3 Isopleths for Ground Level Concentrations for NOx 4-19
4.4 Isopleths for Ground Level Concentrations for NH3 4-20
5.1 EHS Management 5-24
7.1 On Site Disaster Management Plan 7-12

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SAN Envirotech Pvt. Ltd, Ahmedabad

EXECUTIVE SUMMARY
E-1 BACKGROUND

The chemical industries have always played major role in the economic
development of the country. Gujarat, being an industrialized State,
has a significant contribution in industrial as well as economic
development of the country. Besides, necessary infrastructure;
availability of natural resources like water, mineral oil, natural gas;
market potential; and ease of export/import of raw materials and
finished products have also resulted in the substantial growth of
industries in the State. Many industries are of polluting nature hence,
it is essential to take adequate measures to maintain desirable
environmental quality in the area.

E-2 PROJECT DESCRIPTION

Location of Project
The unit will be located at Block No. 164 to 170, Village: Vedach,
Taluka: Jambusar, Dist: Bharuch, State: Gujarat. The location of the
project site is given here under in terms of longitude and latitude.
Longitude: 22009’21.04” N
Latitude: 72051’19.08” E
Elevation from sea level is 20 meter.
The proposed location will be set up at industrial state–Jambusar
which is about 80 km from Vadodara and 40 km from Bharuch. The
nearest airport is Vadodara.
Site Selection
The proposed project site will be located outside the notified area. The
selection of the project site at this location was considered on the
availability of the following amenities.
• Availability of all basic facilities like fuel, water, power, man
power, raw materials, etc.

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• The nearest town Bharuch is only 40 km away from the project


site which is very well connected with other parts of the country
by road & rail.
• Good communication and transportation facilities
• Effluent treatment and disposal facility is very near to project
site.
• Hazardous Waste disposal facility is also near to project site
• No R & R will be required
• No national park or wildlife Habitats falls within 10 km radial
distance from proposed project site.

Alternative Locations
The project location was determined by proximity to consumers and
suppliers; suitability of transportation facilities; proximity to an
existing effluent disposal facilities; and availability of existing
infrastructure such as power, roads, telecommunications and water.
Before finalizing the location, management has studied alternative
locations in Gujarat and concluded that the selected Industrial area is
most advantages because of its ready consumer access and availability
of infrastructure.

E-3 PROPOSED PRODUCTION CAPACITIES OF PLANT

M/s. Narayan Organics Pvt. Ltd. (Unit-II) will be involved in


manufacturing of various pigments. The details of products and by-
products along with its production capacity is summarized hereunder,
Detail of the Products
Sr. Products Items Qty Per Month (MT)
No.
1. Copper phthalocyanine blue 700

2. Pigment alpha blue 75

3. Pigment beta blue 200

Total 975
By product
1. Ammonium carbonate solution 600/1200
12-15% Conc./Ammonium Sulphate

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SAN Envirotech Pvt. Ltd, Ahmedabad

Investment of the project


The expected cost of the proposed project will be around Rs. 12.6
crores. Out of which @ 1.50 crore will be earmarked for development
of EMS (Environment Management Systems).

E-4 DESCRIPTION OF ENVIRONMENT

The base line data were monitored for December-10 to February-11,


with regard to environmental quality in the area e.g. ambient air
quality, noise levels, water quality, soil characteristics, flora & fauna
and parameters concerning human interest. The relevant impacts on
various environmental components were predicted using appropriate
mathematical models and impact assessment techniques. An
appropriate environmental management plan delineated to minimize
the adverse impacts.

E-5 AIR ENVIRONMENT

The ambient air quality monitoring was carried out at Six AAQM
locations, with a frequency of twice a week continuously for three
months, to assess the existing sub-regional air quality status in winter
season. The Respirable Dust Sampler and Fine particulate sampler
along with the analytical methods prescribed by CPCB were used for
carrying out air quality monitoring. At all these sampling locations;
PM10, PM2.5, SO2 and NOx were monitored on 24-hourly basis to enable
the comparison with ambient air quality standards prescribed by the
Central Pollution Control Board.

The data on concentrations of various pollutants were processed for


different statistical parameters like arithmetic mean, standard
deviation, minimum and maximum concentration and various
percentile values.

Respirable Suspended Particulate Matter (PM10)

An average and 98th percentile value of 24-hourly PM10 values at all


the locations ranged between 44-59 μg/m3 and 62-78 μg/m3 whereas
the stipulated standards of CPCB for industrial areas 100 μg/m3.

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SAN Envirotech Pvt. Ltd, Ahmedabad

Particulate Matter (PM2.5)

An average and 98th percentile value of 24-hourly concentrations of


SPM value at all the locations ranged between 25-34 μg/m3 and 36-47
μg/m3 respectively, which are meeting the stipulated standard of 60
μg/m3. The 24-hourly concentration values show that the values are
well within the prescribed limit.
Sulphur Dioxide (SO2)

An average and 98th percentile value of 24-hourly SO2 value of


arithmetic mean at all the locations ranged between 10-15 μg/m3 and
14-22 μg/m3 respectively, which are well within the stipulated
standards 80 μg/m3.
Oxides of Nitrogen (NOx)
An average and 98th percentile value of 24 hourly NOx value of
arithmetic mean at all the locations ranged between 09-17 μg/m3 and
14-23 μg/m3 respectively, which are much lower than the standards of
80 μg/m3.

E-6 WATER ENVIRONMENT

Ground water quality


Color: All the samples were color less meeting desirable norms.

pH: All the samples meet the desirable standards (pH ranges from 6.9
to 7.3).

Total Dissolved Solids (TDS): TDS in samples ranges from 996 mg/l
(Gajera) to 1196 mg/l (Nr. Industry). All the samples meet the
permissible limit of 2000 mg/l.

Calcium: Calcium contents in the water ranges from 43 mg/l (Vedach)


to 65 mg/l (Nr. Industry). All the samples meet the permissible limit of
200 mg/l, (If alternate sources of potable water is not available).

Magnesium: Magnesium content in the water ranges from 36 mg/l


(Piludara) to 55 mg/l (Dabha). All the samples meet even the

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permissible limit of 100 mg/l, (if alternate source of potable water in


not available).

Sulphate: Sulfate content in the water ranges from 39 mg/l (Gajera)


to 80 mg/l (Nr. Industry). All the samples meet the permissible limit of
400 mg/l for drinking water (if alternate source of potable water in not
available).

Total Alkalinity: Total alkalinity in the water samples ranges from


208 mg/l (Vedach) to 333 mg/l (Nr. Industry). All the samples are
within the permissible limit of 600 mg/l drinking water, (if alternate
source of portable water is not available).

Other Parameters: Potassium (ranges from 39 mg/l to 75 mg/l),


Sodium (ranges from 202 mg/l to 292 mg/l) and Chloride (ranges from
320 mg/l to 474 mg/l).

Conclusions: Ground water samples from villages generally meet the


permissible limit.

E-7 NOISE ENVIRONMENT

The Leq values of noise levels during daytime (Ld) varied between 53.1
to 61.9 dB (A). Highest Ld value was recorded near Bus stop Vavadi
(61.9 dB (A)) while the Leq values of noise levels during night time
(Ln) varied between40.0 to 53.2 dB (A). Highest Ln value was
recorded at Bus stop Vavadi (53.2 dB (A)).

E-8 ENVIRONMENTAL IMPACTS AND MITIGATION MEASURES

Air Environment

The main point sources will be flue gas emission from the stacks
attached to boilers, thermic fluid heater and hot air generators due to
combustion of bio fuel (Briquettes) and process gas emissions i.e.
ammonia gas, from the two reactor vessels.
Since Bio fuel will be used as fuel, comparatively less pollution will be
generated. However, the unit proposes to install dust collector to each
of the stacks.

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SAN Envirotech Pvt. Ltd, Ahmedabad

Chimney heights have been chosen such that the generated pollutants
disperse effectively and ensure that the ground level concentrations of
pollutants in the surrounding environment remain well within the
permissible limits. The unit proposes to provide adequate stack height
of 30.0 m and 15.0 m respectively to flue gas stacks and process gas
stacks.
To minimize fugitive emission, the unit has adopted the practice of
carrying out entire manufacturing process into closed vessel as well as
provided adequate scrubbing system for efficient absorption of process
gas.
Special care is also taken while material handling and storage. To
reduce the pollutant emission during transportation, the unit has
adopted the practice of regular check up and maintenance of vehicular
engines for complete combustion of the fuel.
In the present study, the mathematical model that has been used for
prediction on air quality includes steady state Gaussian Plume
Dispersion model designed for multiple point sources.

Air Quality Modelling and Predictions

It is predicted that the maximum contribution in GLCs, with units


operating at full capacity, is 3.469 μg/m3, 0.817 μg/m3 and 0.661
μg/m3 for SPM, SO2 and NOx respectively and for NH3 maximum GLC
will be 1.351 μg/m3. The point of maximum concentration by unit
would be 2.0 km from centre of industry in E direction for SPM, SO2
and NOx and 1.0 km from centre of industry in E direction for NH3.
With this marginal contribution due to the proposal of the project, the
levels of PM, SO2 and NOX well within the permissible limits as
prescribed by CPCB.
Water Environment
The main source of the water will be ground water. The unit will install
its own bore wells within premises to satisfy its fresh water demand.
Necessary permission will also be obtained from CGWA.

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The fresh water requirement for the proposed project will be


683.0 KLD, out of which 671.0 KLD will be utilized for industrial
purpose and remaining 12.0 KLD will be utilized for domestic and
gardening purpose.
The waste water generation will be from the process, washing, boiler
blow down, cooling bleed off, RO reject, etc. Entire quantity of
industrial effluent will be separated into three streams. Concentrated
acidic stream will be segregated and neutralized. Then neutralized
effluent will be collected and mixed with general stream and treated at
its own effluent treatment plant comprising of primary and secondary
treatment facilities followed by tertiary treatment units. Whereas the
third utility stream will be collected into treated effluent collection
sump. After confirmation of stipulated effluent discharged norms,
entire quantity of treated effluent will be discharged into Mahi River
through ECP channel.

Solid Waste Management

The entire quantity of hazardous waste will be handled and disposed


as per Hazardous Waste (Management, Handling and Trans boundary
Movement) Rules’2008. ETP sludge will be sold to cement
manufacturers or sent to approved TSDF site whereas discarded
barrels/bags will be properly cleaned & sold to approved end users and
if excess then reuse within premises. Spent/waste oil will also be sold
to CPCB approved recyclers.
The unit will provide isolated area for the storage of hazardous waste
having leachate collection system, impervious floor and roof cover.
Thus, hazardous waste management system provided by the unit will
be adequate.

Green Belt Development

The unit will do plantation in around 11220 sq. m, which will be around
33% of total land area.

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E-9 ENVIRONMENT MONITORING

Nature of Analysis Frequency of Number of Sample


Analysis
Stack Monitoring Monthly At all stack
Industrial Effluent for Ones in a Month One Sample
applicable parameters as
per the Consents
Conditions
Ambient Air Quality Monthly for 24 hours 3 Location
Monitoring or as per the
statutory conditions

E-10 QUALITATIVE RISK ANALYSIS

Proper handling and storage of hazardous chemicals and the risk


assessment studies have been conducted for identification of hazards,
to calculate damage distances and to spell out risk mitigation
measures. The study includes Identification of hazards, Selection of
credible scenarios, consequence Analysis of selected accidents
scenarios and Risk Mitigation Measures.

E-11 ENVIRONMENTAL MANAGEMENT PLAN

Overall objective of EMP


Prevention: Measures aimed at impeding the occurrence of negative
environmental impacts and/or preventing such an occurrence having
harmful environmental impacts.
Preservation: Preventing any future actions that might adversely
affect an environmental resource or attribute.
Minimization: Limiting or reducing the degree, extent, magnitude, or
duration of adverse impacts.
EMP for Narayan Organics Pvt. Ltd., Unit-II for proposed project covers
following aspects:
• Description of mitigation measures
• Description of monitoring program
• Institutional arrangements
• Implementation schedule and reporting procedures

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SAN Envirotech Pvt. Ltd, Ahmedabad

E-12 CONCLUSION

Based on the study


Water pollution potential of the project will be mitigated by treatment
of effluent in Effluent Treatment Plant comprising of primary and
secondary treatment facilities followed by tertiary treatment units.
Treated effluent will be discharged into effluent disposal pipeline for
final disposal into deep sea through ECP channel.
• Water use will be minimized to improve the process.
• The air pollution potential of the project will be mitigated by providing
dust collector to flue gas stacks and two stage water scrubber followed
by alkali scrubber as air pollution control system.
• For minimization/prevention of the fugitive emission, regular
maintenance of valves, pumps and other equipments will be done to
prevent leakage & entire process will be carried out in the closed
vessel as well as provided adequate scrubbing system for efficient
absorption of process gas.
• Adequate arrangement for handling and disposal of Hazardous solid
waste will be made.
• Fire protection and safety measures will be provided to take care of
fire and explosion hazard.
• Suggestions of qualitative risk analysis study will be followed to
minimize accidents and for safe operations.
• Recommendations suggested in Environmental Management Plan will
be followed to minimize the impact of proposed project.

Considering the above points and overall assessment, it can be concluded


that effects on various environment components will be improved by
Narayan Organics Pvt. Ltd., Unit-II.

• Overall, direct and indirect employment opportunities, improvement in


basic infrastructures by development of industry etc. will be observed
with negligible impact on environment.

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SAN Envirotech Pvt. Ltd, Ahmedabad

• It can be concluded that on positive implementation of mitigation


measures and environmental management plan during the construction
and operational phase, there will be negligible impact on the
environment.

REIA of Narayan Organics Pvt. Ltd., Unit-II E-10


San Envirotech Pvt. Ltd-Ahmedabad

CHAPTER-1
Introduction
1.1 BACKGROUND OF THE COMPANY
The Narayan Organics Pvt. Ltd., Unit-II is the proposed unit to be
located at Block No. 164 to 170, Village: Vedach, Taluka: Jambusar,
Dist: Bharuch, State: Gujarat. The unit proposes to manufacture various
pigments at the proposed premises. The unit proposes to manufacture
Copper Pthalocyanine Blue (CPC Blue), Pigment Alpha Blue and Pigment
Beta Blue of 700.0 TPM, 75.0 TPM and 200.0 TPM capacity respectively.
There will also be generation of Ammonium Carbonate Solution (12-
15%) as by-product up to 600.0 TPM or or Ammonium Sulphate as by-
product up to 1200.0 TPM.

The unit is directed by Mr. Dahyabhai Patel (Managing Director) who is


(B.Sc. Chemistry) and having total experience of 30 yrs. He is also
supported by Mr. Mehul Patel-Director, who is (B. E. Chemical-MBA) and
having total experience of 3 yrs. and other technical staff.

1.2 PURPOSE & NEED OF E.I.A

Environmental Impact Assessment (EIA) is a formal document provided


by the project proponent and preferably prepared by an independent
consultant, which summarizes the process and results of the
environmental analysis of a project having the potential for significant
and diverse impacts. Environmental analysis is the process of evaluating
the environmental impact of a project and identifying ways to improve
the project environmentally by preventing, minimizing, mitigating and
or compensating for adverse impacts.

M/s. Narayan Organics Pvt. Ltd., Unit-II falls under the category of 5(f)
of schedule of EIA Notification, 2006 “Synthetic Organic Chemicals
Industry” and categorized under “A” because unit is located outside of

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notified industrial area. Therefore, units require Environmental


Clearance of the proposed project.
In view of the above, monitoring work has been carried out for all the
environmental attributers by M/s. San Envirotech Pvt. Ltd-
Ahmedabad.

The Environmental (Protection) Act-1986 (Environmental Impact


Assessment Notification, 2006) established the requirements for
preparing Environmental Impact Assessment (EIA) in India. The EIAs
subsequently have been prepared, on an individual basis for
new/expansion of project. While the project specific EIAs have been
successful to varying extent in the incorporation of environmental
objectives in the project design, several experiments have been done to
address the issue of cumulative environmental impacts by carrying out
Regional Environmental Impact studies. This has given a basis for
evaluating total environmental impacts of the region and hence helped
in planning at the regional level. Other uses of EIA tool have been in the
Strategic Environmental Assessment (SEA), now mandatory in many
industrialized countries, to evaluate environmental impacts of policies
and programs. Hence, EIA tool has been improvised and used
innovatively for assisting decision-makers in assessment of
environmental impacts and considering alternative mitigation measures
in a variety of situations.

Environmental Impact Assessment (EIA) is required to be carried out


only for certain categories of projects and the criteria for screening have
been provided in the Act. Thus, EIA is essentially made applicable to
industrial and developmental projects, which are more likely to have
significant environmental impacts. Different criteria have been used for
screening. Indian regulation utilizes project category based on the Scale
of Impact, Sensitivity of Impact and Nature of locations as the primary
criteria for deciding on the requirement of EIA for approval.

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San Envirotech Pvt. Ltd-Ahmedabad

1.3 STATEMENT OF PRINCIPLES

The EIA is intended to provide for the protection, conservation and wise
management of environment through planning and informed decision
making.
Following are the guiding principles:
• To help decision-makers to protect, conserve and manage
environment according to the principles of sustainable development,
thereby achieving or monitoring human well being, a healthy
environment and a sound economy.
• To ensure that the industries consider the effect on the health,
economy and culture of the surrounding communities as well as its
impacts on the air, land and water.
• To ensure communication of information to Public.

1.4 STATUTORY REQUIREMENTS


As per the Environment Impact Assessment (EIA) notification of Ministry
of Environment and Forests (MoEF), dated 14th September 2006, setting
up a new projects or activities, or on the expansion or modernization of
existing projects or activities based on their potential environmental
impacts as indicated in the Schedule to the notification, being
undertaken in any part of India, unless prior environmental clearance
has been accorded, This EIA report for the proposed expansion of
formaldehyde production has been prepared for the perusal of MoEF for
judging the environmental compatibility of the project as discussed
during the presentation of Terms of Reference to Expert committee of
MoEF on dated 09/09/2010.

1.5 TERMS OF REFERENCE ACCEPTED/ISSUED BY MOEF ON DATED


09/09/10
Ministry of Environment & Forest as communicated following terms of
reference on the base of documents submitted by us and presentation
made by us on dated 05/05/2010.

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-4


San Envirotech Pvt. Ltd-Ahmedabad

Sr. Conditions Compliance


No.
1. Executive Summary of the project Incorporated in the report as
separate chapter.
2. Justification of the project Refer Section: 2.4 of Chapter-
2 page No.: 2-1
3. Promoters and their background Refer Section: 1.1 of Chapter-
1 page No.: 1-1
4. Regulatory framework Refer Section: 1.2 of Chapter-
1 page No.: 1-1
5. Project location and plant layout Refer Figure: 2.3 of Chapter-
2 page no. 2.26 to 2.27.
6. Infrastructure facilities including power Refer Section: 2.8 of Chpater-
sources 2 Page No. 2-9.
7. Total cost of project along with total Refer Section:2.2 of Chpater-
capital cost and recurring cost/annum for 2 Page No. 2-1
environmental pollution control measures
8. Project site location along with site map of Refer figure 1.1 of Chapter-1
10 km area and site details providing Page No. 1-13.
various industries, surface water bodies,
forests, etc.
9. Present land use based on satellite Refer Figure-3.10 on page no-
imagery for the study area of 10 km 3-43 and table no-3.16 on
radius. Location of national park/ wild life page no-3-31.of chapter-3
sanctuary/reserve forest within 10 km
radius of project.
10. Permission from the State Forest Not applicable in our case
Department regarding the impact of the because there is no any
proposed plant on the surrounding reserve reserve or protected forest
forests, if any. wildlife sanctuary
11. Details of the total land and break-up of Refer Section:2.5 of chapter-
the land use for green belt and other uses. 2 Page No.2-2
12. List of raw materials, products along with Pl. refers point no-2.6 of
the production capacities and list of chapter-2 on page no-2-2 &
solvents and its recovery plan. table no-2-1 on page no- 2-
16 for RM.

There are no separate solvent


recovery systems, it’s a part
of manufacturing activities
and recovered solvent will be
recycled in the next batch.
13. Commitment for not using azo dyes in the Proposed project is for CPC
process should be given. based pigments and no use of
any azo based dyes.
14. Detailed list of raw material required and Refer table 2.1 of Chapter-2
source, mode of storage and Page No. 2-16.
transportation.
15. Manufacturing process details along with Refer Section:2.7 of Chapter-
the chemical reactions. 2 Page No. 2-3
16. Design details of ETP, incinerator, if any Refer table2.5 and figure-2.2
along with control of Dioxin & Furan, of Chpater-2 Page No.:2-21-

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-5


San Envirotech Pvt. Ltd-Ahmedabad

boiler, scrubbers/bag filters etc. 2-22. There will not be any


incinerator facilities. Technical
information of bag filter is
attached as annexure-IV.
17. Details of water and air pollution and its Refer Section: 2.9 of Chpater-
mitigation plan 2 Page No. 2-10
18. Site-specific micro-meteorological data Refer Section:3.2.3 of
using temperature, relative humidity, Chapter-3 Page No. 3-3
hourly wind speed and direction and
rainfall is necessary.
19. Ambient air quality monitoring for all the Refer table 3-1 to 3-7 of
parameters including VOCs within the chapter-3 on page No. 3-14.
study area of 5 km., aerial coverage from
project site. Location of one AAQMS in
downwind direction.
20. One season site-specific micro- Pl. refers point no-3.2.3 of
meteorological data using temperature, Chapter-3 Page No. 3-3 and
relative humidity, hourly wind speed and table 3-1 to 3-7 of chapter-3
direction and rainfall and AAQ data (except on page no-3-14.
monsoon) for PM10, SO2, NOx including HC
and VOCs. Should be collected. The
monitoring stations should take into
account the pre-dominant wind direction,
population zone and sensitive receptors
including reserved forests. Data for water
and noise monitoring should also be
included.
21. Action plan to control ambient air quality Following measures steps will
as per NAAQES Standards notified by the be taken by us to control the
Ministry on 16th September, 2009. air quality as per the NAAQES
standards notified by the
Ministry on 16th September,
2009.

- Effective implementation of
air pollution control measures
and monitoring.
- Ammonia recovery by
chilling systems to reduce
fugitive emission.
- Effective scrubbing systems
will be installed to control un-
recovered ammonia.
- Proper air pollution control
systems like dust collector will
be used.
- Bio fuel ((Briquettes) will be
used to reduce the contribute
of Sulfur dioxide in the
atmosphere.

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San Envirotech Pvt. Ltd-Ahmedabad

22. An action plan to control and monitor All liquid material will be
secondary fugitive emissions from all the transfer by pneumatically,
sources as per the latest permissible limits joint will be 100% leak proof
issued by the Ministry vide G.S.R. 414(E) and solid material will be
dated 30th May, 2008. transfer with care of zero
leakages.
23. Determination of atmospheric inversion Refer Section: 4.4.5 & 4.4.7
level at the project site and assessment of of Chapter-4 Page No. : 4-4
ground level concentration of pollutants
from the stack emission based on site-
specific meteorological features. Air quality
modelling for the proposed plant.
24. Permission for drawl of 612 m3/day ground Our proposed area fall in
water from the CGWA/SGWB. Water white zone however, we have
balance cycle data including quantity of applied to CGWA for water
effluent generated recycled and reused extraction and water
and discharged. Method to be used to recharging will be done as per
control ammonical nitrogen from industrial the guideline/conditions of
wastewater. CGWA.

Pl. refer point no-2.9.2 of


chapter-2 on page no-2-11
for control ammonical
nitrogen from industrial
wastewater
25. Ground water monitoring minimum at 6 Pl. refer table no-3.9 of
locations should be carried out. Geological chapter-3 on page no-3-22
features and Geo-hydrological status of
the study area and ecological status
(Terrestrial and Aquatic).
26. The details of solid and hazardous wastes Refer table-2-7 & 2-8 of
generation, storage, utilization and Chpater-2 Page No. :2-25 for
disposal particularly related to the quantity, disposal and
hazardous waste calorific value of characteristic of the
hazardous waste and detailed hazardous waste
characteristic of the hazardous waste.
27. Details of land fill along with design details We will not going to create
as per CPCB guidelines. Location of our landfill site hence not
secured land fill/TSDF. applicable. We will get
membership of any GPCB
approved and nearby TSDF
site before establishment of
our project.
28. Ground water monitoring around the land Not applicable in our case.
fill site
29. Membership of CETP for disposal to We will get membership of
effluent and TSDF for disposal of any GPCB approved and
hazardous waste/ solid waste. nearby TSDF site before
establishment of our project.
We will have our own ETP and
not planning to get CETP
membership.

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-7


San Envirotech Pvt. Ltd-Ahmedabad

30. Risk assessment for storage of Kindly refer Chapter:6


chemicals/solvents and phosgenes.
31. An action plan to develop green belt in 33 Refer Section: 5.4 of Chpater-
% area 5 Page No. :5-14
32. Action plan for rainwater harvesting Refer Section: 2.10.1 of
measures at plant site should be included Chpater-2 Page No. :2-16
to harvest rainwater from the roof tops
and storm water drains to recharge the
ground water.
33. Occupational health of the workers needs Refer Section: 5.11.1 of
elaboration including evaluation of noise, Chpater-5 Page No. : 5-17
heat, illumination, dust, any other
chemicals, metals being suspected in
environment and going into body of
workers either through inhalation,
ingestion or through skin absorption and
steps taken to avoid musculo-skeletal
disorders (MSD), backache, pain in minor
and major joints, fatigue etc. Occupational
hazards specific pre-placement and
periodical monitoring should be carried
out.
34. Socio economic development activities Refer Section: 4.8 of Chpater-
should be in place. 4 Page No.: 4-11
35. Note on compliance to the Pl. refers Annexure-II.
recommendations mentioned in the CREP
guidelines.
36. Detailed Environment management Plan Kindly refer Chapter-5
(EMP) with specific reference to details of
air pollution control system, water &
wastewater management, monitoring
frequency, responsibility and time bound
implementation plan for mitigation
measure should be provided.
37. EMP should include the concept of waste- Refer Section:5.10 of
minimization, recycle/reuse/recover Chpater-5 Page No.:5-15
techniques, Energy conservation, and
natural resource conservation.
38. Any litigation pending against the project Not Applicable
and/or any direction/order passed by any
Court of Law against the project, if so,
details thereof.
39. Public hearing issues raised and Yet to be attached.
commitments made by the project
proponent on the same should be included
separately in EIA/EMP Report in the form
of tabular chart with financial budget for
complying with the commitments made.
40. A tabular chart with index for point wise Done
compliance of above TORs.

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-8


San Envirotech Pvt. Ltd-Ahmedabad

1.6 OBJECTIVES OF EIA

EIA is a policy and management tool for both planning and decision
making. EIA assists in identification, prediction and evaluation of the
foreseeable environmental consequences of proposed developmental
and industrial projects.
The objectives of the present EIA Study is to assess the impacts on
various environmental components due to the proposed project and to
recommend appropriate environmental management plant for the unit
to ensure that the adverse impacts if any will be minimized. Moreover to
prepare an Environmental Statement to indicate conclusively if the
overall impacts are positive or negative.

1.7 Scope of EIA

The scope of present Environment Impact Assessment includes following


studies,
• Collection and evaluation of project details and related documents
• Analysis of the quality of gaseous emission, wastewater analysis,
hazardous waste generation based on the monitoring results for the
last one year
• Assessment of pollution potential due to proposed project
• Collection and evaluation of present environmental baseline status
within an impact zone of 5-km radial distance from the project site
on environmental parameters/attributes considering the proposed
activities like,
• Ambient Air quality
• Water quality and surrounding environmental water bodies.
• Soil quality
• Noise levels
• Meteorology and climates.
• Land use pattern and socio-economic status
• Identification, assessment and evaluation of the beneficial and
adverse impacts on surrounding environment due to proposed

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San Envirotech Pvt. Ltd-Ahmedabad

project activities considering the existing baseline status along with


compilation of other information
• Identify the sources and impact of hazards, if any
• Base on the same suggest and design risk assessment plant and
disaster management plant to prevent any hazard
• Preparation of final Environmental Impact Statement & EMP

1.8 Methodology for EIA

Environmental Assessment (EA), another term used in the


environmental studies, refers to an understanding of the present status
of environment and a study of how to manage them. Keeping in view
the nature and size of the proposed project and industrial area and
various guidelines available, it was decided to cover an area of 5-km
radius from the center of proposed plant site for the purpose of
environmental impact assessment study. The methodology is briefly
reported below and has been described in this section.

Project Components

The proposed project will be in the outside of notified industrial estate


located at Block No. 164 to 170, Village: Vedach, Taluka: Jambusar,
Dist: Bharuch, State: Gujarat. The company will appoint experts of
different fields like process, R & D, safety & Environment and moreover,
the company has a large experience in the respective field to take care
of the plant in all respect.
A useful way of identifying many of the potential impacts of a project is
to consider all the aspects of the projects and its receiving environment
and systematically identify the potential for interactions between them.
The first step is to draw up a list of all project components and activities
during each phase of its implementation. The possible components of
proposed project could lead to environmental impacts are described in
this section based on the understanding of Chemical industry.

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-10


San Envirotech Pvt. Ltd-Ahmedabad

Environmental Components

Defining all the possible aspects of the environment is essential for


identification of potential impacts. This may cover features of the
environment (e.g. habitats, settlements, and historic sites); aspects of
environmental quality (e.g. air quality, water quality, noise, physical
conditions, soil stability and hydrology) and uses of the environment
(e.g. agriculture, recreation and fishing). This will be done with
generation of base line data.
Baseline data Collection
The baseline data for the impact zone have been generated for the
following environmental parameters:
• Ambient Air Quality
• Micrometeorology
• Noise Levels
• Surface and ground water quality
• Soil Quality
• Flora and fauna
• Land use pattern
• Occupational structure and socio-economics
The baseline status of the above environmental parameters has been
worked out based on the rapid monitoring/analysis carried out during
the study period of one season i.e. Decemeber-10 to February-10,
supplemented by data collected from various government departments,
census publications etc.
Evaluation of Impact from Project Activities
The environmental Impact resulting from the various project activities,
have been identified, predicted and evaluated based on the study of
manufacturing process and other project related activities as well as
correlating the same with existing base line status.
Preparation of Environmental Management Plan
Environmental Management plan has been prepared covering pollution
prevention measures at source in terms of air and water pollution

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-11


San Envirotech Pvt. Ltd-Ahmedabad

control measures, solid waste/ hazardous waste management, safety


management, green belt development, environmental surveillance and
environmental management team.
Finally, the detailed assessment of the resultant environmental impacts
have been made based on the impacts identification and evaluated from
the activities over the baseline status of various environmental
components.

1.9 Justification for the project site

The unit is proposed to start at Block No. 164 to 170, Village: Vedach,
Taluka: Jambusar, Dist: Bharuch, State: Gujarat. The other supporting
factors are briefly summarized here under,
• Availability of all basic facilities like fuel, water, power, man
power, raw materials, etc.
• The nearest town Bharuch is only 40 km away from the project
site which is very well connected with other parts of the country
by road & rail.
• Good communication and transportation facilities
• Effluent treatment and disposal facility is very near to project site.
• Hazardous Waste disposal facility is also near to project site
• No R & R will be required
• No national park or wildlife Habitats falls within 10 km radial
distance from proposed project site.

REIA of Narayan Organics Pvt. Ltd., Unit-II 1-12


San Envirotech Pvt. Ltd-Ahmedabad

Figure 1.1
Location Map

Proposed location of NOPL, Unit-II

Transmental

Bodal Chemicals Ltd.

Kiri Dyes & Chemicals Pvt. Ltd.

Lonsen Kiri Chemical Industries Pvt. Ltd.


Asahi Songwon Ltd.

Mayur Dyechem

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San Envirotech Pvt. Ltd-Ahmedabad

Chapter 2
Project Description
2.1 INTRODUCTION
M/s. Narayan Organics Pvt. Ltd., Unit-II is the proposed unit to be
established at Block No. 164 to 170, Village: Vedach, Taluka: Jambusar,
Dist: Bharuch, State: Gujarat. The unit proposes to manufacture various
pigments at the proposed premises. The unit proposes to manufacture
Copper Pthalocyanine Blue (CPC Blue), Pigment Alpha Blue and Pigment
Beta Blue of 700.0 TPM, 75.0 TPM and 200.0 TPM capacity respectively.
There will also be generation of Ammonium Carbonate Solution (12-
15%) 600.0 TPM or Ammonium Sulphate as by-product up to 1200.0
TPM.

2.2 CAPITAL INVESTMENT


The expected cost of the proposed project will be around Rs. 12.6 crores.
Out of which @ 1.50 crore will be earmarked for development of EMS
(Environment Management Systems).

2.3 TYPE OF PROJECT


The proposed unit is Synthetic Organic Chemicals manufacturing unit
covered under the category of 5(f) “Synthetic organic chemicals industry
(dyes & dye intermediates; bulk drugs and intermediates excluding drug
formulations; synthetic rubbers; basic organic chemicals, other synthetic
organic chemicals and chemical intermediates)” of EIA Notification-2006.

2.4 NEED OF THE PROJECT


The products manufactured will be Crude pigments and finished
pigments. All the pigments are basically powders and insoluble in water.
However, due to their coloring properties they are used in paints,
plastics and inks.
Thus, looking to the application of products and increasing marketing
demand, the unit intends to set up the proposed project.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-1


San Envirotech Pvt. Ltd-Ahmedabad

2.5 LAND REQUIREMENT


The proposed unit of M/s. Narayan Organics Pvt. Ltd. will be located at
Block No. 164 to 170, Village: Vedach, Taluka: Jambusar, Dist.:
Bharuch, State: Gujarat. Total land area of the plant is apprx. 34,000.0
sqm. The land area break up is given hereunder,

Sr. Specification Area covered,


No. Sqm
1. Office Building 1250
2. Process plant 3650
3. Storage Tank Yard 3500
4. Utility 2100
5. Environmental Control Measures 3500
6. Road & parking 9180

7. Green Belt 11220


Total 34000

The Factory Layout of the unit is given in Figure: 2.3.

2.6 SIZE OF PROJECT

M/s. Narayan Organics Pvt. Ltd. (Unit-II) will be involved in


manufacturing of various pigments. The details of products and by-
products alongwith its production capacity is summarized hereunder,

Sr. Products Items Qty Per Month


No. (MT)
1. Copper phthalocyanine blue 700
2. Pigment alpha blue 75
3. Pigment beta blue 200
Total 975
By product
1. Ammonium carbonate solution 600/1200
12-15% Conc./Ammonium Sulphate

The details of Raw Material Consumption for the proposed project are
summarized in Table: 2.1.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-2


San Envirotech Pvt. Ltd-Ahmedabad

2.7 MANUFACTURING PROCESS

The detailed manufacturing process for various products is given


hereunder,
2.7.1 Copper Phthalocyanine Blue

¾ Charge required quantity of Phthalic Anhydride, Urea in a Glass Vessel,


which is already having a solvent at desire temperature.
¾ Heating the content to higher temperature and then, addition of catalyst
and Cuprous Chloride to it.
¾ Raise the temperature of the reaction mass at desire temperature and
maintain this temperature for 6/8 hours.
¾ After reaction is over, draw the sample and check for complete
conversion of Phthalic Anhydride to CPC Blue Crude.
¾ Discharge the batch into Horizontal Rotary Vacuum Dryer (HRVD) and
remove the solvent under vacuum. After complete removal of solvent
add water to the Horizontal Rotary Vacuum Dryer (HRVD) and transfer
the material to treatment tank.
¾ Give the requisite treatment to CPC Blue Crude and filter it through PP
Filter Press.
¾ Dry the material using Spin Flash Dryer (SFD) and collect the dried
powder in bags and send it to Godown.

BASIC CHEMICAL REACTIONS

4C8H4O3+2CO (NH2)2. 130°C ~ 140°C 4C8 NO2H5 + 2CO2 + 2H2O


Phthalamide Eq.-I
140°C~170°C
4C8 NO2H5+8CO(NH2)2. 4C8 H7NO2+2CO2+2H2O
Di-Amino Phthalamide
180°C~190°C Eq.–II
4C8H7N3+CuCl . C32H16N8Cu+NH4Cl+1/6N2+2/3 NH3
Ammonium Molybdate CPC Blue Equ - III

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-3


San Envirotech Pvt. Ltd-Ahmedabad

Material Balance Diagram:

CPC BLUE CRUDE

INPUT KGS OUTPUT KGS


Solvent 3250 Gas emission 1750
PA 1100 ( NH3, CO2,
Urea 1220 H2O, N2 etc)
CuCl 200 GLASS Vessel
Al. Moly. 3

Solvent recovery 3200

RVD

Spent Acid 2435


Water-recy 5000
Steam 1250
Acid Treatment

ETP 13308
Wastewater
Water 6000 Reused r 5000
DM Water 5000

Filter Press

Evoparation loss 1200

SFD
CPC CRUDE 1000
TOTAL 25458 25458

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2.7.2 Pigment Alpha Blue

There will not be any chemical reaction during manufacturing of pigment Alpha
Blue.

Manufacturing Process
¾ Copper phthalocyanine blue is ground in a ball mill
¾ Following this, ground copper phthalocyanine blue and 98% sulphuric
acid are charged and thoroughly mixed in a vessel to obtain a
homogenous paste.
¾ The temperature of the vessel is cooled to 100C
¾ The contents are dumped into another vessel containing water. This is
done to reduce sulphuric acid concentration to 10%-20%.
¾ The concentrate liquor obtained from the previous step is purified by
alkali wash (NaOH) followed by acid wash (98% Sulphuric acid)
¾ Each washing stage is followed by filter press drying.
¾ The dried finished product is finally sent down for SFD.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-5


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Material Mass Balance

Input Qty.(kg) Output Qty.(kg)

Copper Phthalocyanine 1010


Blue Reactor
Sulphuric Acid (98 %) 3500

Child Water Quenching


Chill Water 14000

Filtration Filtration 14000


(Sulphuric acid

Washing

Water 8700 Wash water 8700


used in CPC plant
Water from Beta Blue
Steaming 8000
Sodium Hydroxide 125 Alkali treatment
Oleic Acid 25
Caustic Soda 500
Filtration
Water 2500 Effluent 13490

Spin Flash Drying

Evp. Loss 1170

CPC Alpha Blue 1000


Total 38360 38360

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2.7.3 Pigment Beta Blue


There will not be any chemical reaction during manufacturing of pigment
Beta Blue.
Manufacturing Process
¾ Charge CPC crude into Ball mill for ball milling.
¾ Mix the material thoroughly and heat the contents till the reflux stars.
Continue the reflux of solvent for 5 hours and then, start recovery of the
same.
¾ Starts collecting recovered solvent in a separate tank
¾ Dump the material into dumping vessels with required surfactant and
additives. Stir for 4 to 5 hours.
¾ Filter the mass and wash the material to neutral Ph.
¾ Route the wet cake to SFD for drying purpose and collect the material in
the HDPE/ Jumbo bags.
¾ If necessary, blend the material in the blender and pack the material in
PP bags or Jumbo bags depending upon the requirement of the plant.

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Material Mass Balance of Beta Blue

CPC 1010
Ball Mill

Solvent 3000 Pigmentation Solvent Rec. 2950


water 5000 Vessel
Reflux

Surfectant Dumping vessel


Additives 25

Effluent 3785
Water 10000 Filter Press Recy. Alpha 6000
Scrubber to 4100
CPC Blue Plant

SF Evop loss 1200

Product 1000

Total 19035 19035

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2.8 INPUT REQUIREMENTS & INFRASTRUCTURE FACILITIES


INCLUDING POWER SOURCES
Being a proposed project, no existing infrastructure facilities are there.
We will create following infrastructure facilities at our proposed location.

The details of infrastructure facilities are given hereunder,


2.8.1Water
The main source of the water will be ground water. The unit will install
its own bore wells within premises to satisfy its fresh water demand.
Necessary permission will also be obtained from CGWA. The fresh water
requirement for the proposed project will be 683.0 KLD, out of which
671.0 KLD will be utilized for industrial purpose and remaining 12.0 KLD
will be utilized for domestic purpose. Recovered condensate water from
multi effect evaporator will be used for greenbelt development.
The detail break up of the water consumption is given in Table-2.2.
The water Balance diagram is also given in Figure-2.1.

2.8.2 Fuel
Biofuel i.e. briquettes will be used for proposed boilers, thermic fluid
heater and hot air generators after implementation of the proposed
project. In the absence of biofuel, we will use coal as fuel. The estimated
requirement of the same will be 45 TPD Biofuel/30 TPD Coal.

2.8.3 Power
M/s. Narayan Organic Pvt. Ltd. (Unit-II) fulfills the power requirement
through Daxin Gujarat Vij Company Limited. The total power
requirement will be 1500 KVA.

2.8.4Manpower
The unit proposes to provide employment to various skill an non skill
persons. The details of manpower requirement is given hereunder,
Type Nos. of persons
Skill 6

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San Envirotech Pvt. Ltd-Ahmedabad

Semi skill 10
Non skill 70
Administrative 4
Total 90

2.9 GENERATION OF POLLUTANTS


2.9.1 The details of pollutant generation is given hereunder,

A) Liquid Effluent
Effluent likely to be generated after proposed project will be divided
mainly into three streams, i.e.,
(i) concentrated stream (i.e. ML of acidic treatment of CPC Blue)
(ii) general/weak stream from manufacturing activities of other
product from Manufacturing stream
(iii) Effluent from the utility section i.e. DM plant regeneration, cooling
bleed off, boiler blow down etc.

The unit proposes to provide its own Effluent Treatment Plant consisting
of primary and secondary treatment facilities within premises and after
treatment entire quantity of treated effluent will be conveyed to estuary
of Mahi River. The details of industrial wastewater generation are
depicted in Table-2.2.

B) Gaseous Emissions
The main source of air pollution will be flue gas stacks and process gas
stacks. There will be three nos. of flue gas stacks which will be attached
to the boilers (2 nos.), Thermic Fluid Heaters (3 nos.) and Hot air
generators (3 nos.) where bio fuel (briquettes) will be used as fuel.
Whereas two nos. of reactors where ammonia gas will be liberated.
Adequate stack height of the 30.0 mt and 15.0 mt will be provided
respectively to each of the flue gas stacks and process gas stacks for
proper dispersion of gaseous emission.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-10


San Envirotech Pvt. Ltd-Ahmedabad

The details of the flue gas stacks and process gas stacks are given in
Table-2.3.
C) Fugitive Emission
There will also be chances of the fugitive emission due to handling of
process gas emission and hazardous chemicals as well as due to
liberation of the excess solvents from the reactors.
However, to prevent the same the unit will take all the precautionary
measures like adequate scrubbing system to absorb the process gas and
to carry out entire process in the closed reactors, etc.
D) Hazardous/ Solid waste
The main source of hazardous waste generation will be ETP sludge from
the Effluent Treatment facilities. The other sources will be discarded
barrels/bags/liners/drums and spent/waste oil from the material
handling and storage and plant & machinery.
The details of the hazardous waste are given Table-2.4.
E) Noise
Noise can be defined as an unwanted sound. It interferes with speech
and hearing and is intense enough to damage hearing or is otherwise
annoying. The definition of noise as unwanted sound implies that it has
an adverse effect on human beings and their environment. Noise can
also disturb natural wildlife and ecological system. Sound is mechanical
energy from a vibrating surface, transmitted by cyclic series of
compression and rarefaction of molecules of the materials through which
it passes.
Sound can be transmitted through gases, liquids and solids. The number
of compressions and rarefactions of the air molecules in the unit of time
is described as its frequency. Frequency is expressed in hertz (Hz),
which is the same as the number of cycles per second.

2.9.2 POLLUTION CONTROL STRATEGY


The unit proposes to provide adequate and efficient Environmental
Management System. The details are given hereunder,
A) Effluent Management

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-11


San Envirotech Pvt. Ltd-Ahmedabad

The unit proposes to provide its own Effluent Treatment Plant within
premises comprising of primary and secondary treatment facilities to
treat industrial effluent likely to be generated after proposed project.
After meeting effluent discharge norms, entire quantity of industrial
effluent will be discharged into ECP channel of Mahi River.
The stream wise brief description of effluent treatment scheme is given
hereunder,

(I) Concentrated Streams


The concentrated stream i.e. highly acidic ML will be segregated and
collected in acid proof brick lined tanks. Higher acidic effluent will be
reuse in the production of CPC crude and for production of by products
(Ammonium Sulphate). Dilute Acidic effluent will be taken into ETP
collection tank. The pH of acidic effluent will be raised to 9.5 using
hydrated lime, so as to precipitate out the copper salts in the form of
copper hydroxide and it will be pumped to plate and frame type of filter
press. The filtered from plate and frame filter press will be taken to the
filtered collection tank from there it will be conveyed to collection cum
equalization tank of general stream for further treatment. The sludge will
be removed from filter press at periodically and will store separately and
then will be either sent to the TSDF site or to cement manufacturing
units.

(II) General Stream:


The general stream consisting of wastewater other than concentrated ML
from process will be collected in equalization cum collection tank fitted
with stirring facilities. From where effluent will be pumped to flash mixer
after correcting to desired level of pH. In the flash mixer required
chemical will be added and then it will be taken to flocculation chamber
for effective formation of flocs. The overflow of flocculation will be taken
to primary settling tank for settlement of the flocs. The settled sludge
from the PST will be removed and sent to filter press for dewatering.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-12


San Envirotech Pvt. Ltd-Ahmedabad

The clear supernatant from PST will be sent to the aeration tank having
floating diffusion aeration system for secondary treatment.
The over flow of aeration tank with biomass will be go to the Secondary
Setting Tank where settled biomass is partly recycled back to the
aeration tank and partly wasted out in sludge sump. The over flow of the
Secondary Settling Tank is collected to final Treated Water Sump and
subjected to the tertiary treatment by passing through sand filter and
carbon filter prior to the final disposal.

After confirmation of effluent discharged norms, entire quantity of


treated effluent will be discharged in to ECP channel to Mahi River.

The details of Effluent Treatment Units are given in Table: 2.5. The
schematic flow diagram of Effluent Treatment Plant is given in Figure:
2.3.

Generated acidic water contains (NH4)2SO4 and some part of urea which
is responsible for Ammonical nitrogen in the effluent. We Will isolate
acidic effluent stream which contains ammonical nitrogen, and use to
scrub the gases (which contain ammonia and carbon dioxide). This acidic
filtrate will absorb ammonia and convert it to ammonium sulfate. As the
pH of this filtrate goes from 2 pH towards 7 pH, we will add more sulfuric
acid for faster reaction.
This will resulted in about 20% ammonium sulfate solution which we will
recover as by product by concentrating through multiple effect
evaporators. There by the effluent stream containing ammonical nitrogen
will be dealt separately and will not go to our effluent treatment plant.
Generated Ammonium Sulphate will be sold to actuak users.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-13


San Envirotech Pvt. Ltd-Ahmedabad

B) Air Pollution Control


The unit proposes to provide separate dust collector as air pollution
control measures to each of the flue gas stacks. Whereas the unit
proposes to provide adequate scrubbing system for process gases
pollutant comprising of two stages of water or Acidic scrubbers to absorb
the process gas generating from the process reactors for recovery of by-
products and controlling the emission levels as per GPCB norms.

Adequate stack height of 30.0 m to each of the flue gas stacks and 15.0
m to each of process gas will be provided for proper dispersion of the
gaseous emission and minimizing the impact of air pollution at ground
level.

C) Hazardous/Solid Waste Management


The entire quantity of hazardous waste will be handled and disposed as
per Hazardous Waste (Management, Handling and Trans boundary)
Rules’2008.
The unit proposes to provide adequate area for the storage of hazardous
waste having leachate collection system, roof cover and impervious floor.
Part of the ETP sludge will be sold to cement industries and remaining
will be disposed to secured landfill site approved by GPCB. Whereas
discarded/barrels/bags/drums/liners will be decontaminated and
reused/sold to approved vendors. The spent/waste oil will be sold to
CPCB approved recyclers.

2.9.3 RESOURCE RECOVERY


Ammonium carbonate solution12-15% Conc./Ammonium
Sulphate Recovery system

Main source of Ammonia is air emission from process. This will be


scrubbed by acidic effluent generated from process.

We will isolate acidic effluent stream which contains ammonical nitrogen


and use to scrub the gases (which contain ammonia and carbon dioxide).

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-14


San Envirotech Pvt. Ltd-Ahmedabad

This acidic filtrate will absorb ammonia as ammonium sulfate. As the pH


of this filtrate goes from 2 towards 7 we will go on adding more sulfuric
acid for faster reaction.

This will resulted in about 20% ammonium sulfate solution which we will
recover as by product by concentrating through multiple effect
evaporators.

Generated Ammonium Sulphate will be sold to actual users.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-15


San Envirotech Pvt. Ltd-Ahmedabad

2.10 RESOURCE CONSERVATION


2.10.1 GROUND WATER RECHARGING SYSTEM
In general the rain water from terraces/rooftop areas shall be collected
through rain water down-take pipes and collected to catch basins or
stored in rain water tanks. However, the rain water from plant area and
parking area may contaminate and not advise to collect directly to catch
basins. Rain water harvesting pits shall be provided wherever feasible so
that maximum rain water recharged into the ground before it reaches
the storm water mains.

The unit proposes ground water recharging sump at low lying area which
will be connected to the storm water drainage system. Thus, by
recharging the ground water during the rain, unit wills efforts to balance
ground water. Unit proposes to create 2 Nos of percolating well in law
lying green area of plant.

2.10.2 GREEN BELT DEVELOPMENT

The unit proposes to provide apprx. 11220 sq.m area for green belt
which will be 33 % of the total area of the premises.

2.11 HEALTH & SAFETY:

The unit will perform pre-employment medical checkup and periodical


medical examination for all employees. Adequate numbers of first aid
boxes will be kept at strategic locations in the plant. Workers will be
provided proper personal protective equipments as and when required.
The unit will also appoint panel doctor for medical assistance. There will
be probability of fire & explosion due to charging of chemicals. Sufficient
no. of fire extinguishers, sand bucket will be provided.

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-16


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.1
Raw Materials

Items Qty Per Source Mode of Transportation


Month Indigenous Imported storage
(MT/month)
Copper phthalocyanine blue
Phthalic Anhydride 770.0 Indigenous Imported Warehouse Road/Sea
Urea 900.0 Indigenous - Warehouse Road
Cuprous Chloride 140.0 Indigenous - Warehouse Road
Ammonium 2.0 Indigenous - Warehouse Road
Molybdate
Ortho Nitro Toluene 35.0 Indigenous - Warehouse Road
(ONT)
Caustic Soda Flakes 70.0 Indigenous - Warehouse Road
Spent Sulphuric Acid 1700.0 Indigenous - Warehouse Road
Pigment alpha blue
Copper 75.75 Captive - Warehouse -
phthalocyanine blue
Sulphuric acid 265.0 Indigenous - Warehouse Road
Caustic soda flakes 15.0 Indigenous - Warehouse Road
Pigment beta blue
Copper 202.0 Captive - Warehouse Road
phthalocyanine blue
Iso butyl alcohol 17.0 Indigenous - Warehouse Road
(make-up)

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-17


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.2
Details of Water Consumption & Wastewater Generation

Sr. Category Water Wastewater


No. Consumption, Generation,
KL/day KL/day
1. Domestic 12.0 10.0
2. Gardening 50.0* Nil
3. Process 594.0 391.0
4. Washing 27.0* 27.0
5. Boiler 50.0 05.0
6. Cooling (13*+ 17) 15.0
30.0**
7. Water Treatment 10.0*** 10.0
Plant
Total Industrial 683.0 448.0

Total 671.0 458.0


(Industrial + Domestic)

*Recycle water generated from condensation of multi effect evaporator.


**Partial recycles as mentioned in water balance diagram fig no-2.1
*** Quantity water disposed as reject water from raw water treatment
facilities

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-18


San Envirotech Pvt. Ltd-Ahmedabad

Figure 2.1
Water Balance Diagram

Raw water
683 kl/d

Domestic Process Washing Utilities Greenbelt


12 594 27* 77 50*

2.0
Loss Process Boiler Cooling Reject
594 50 Tower 10

Sock pit
Total Vol Steam
Ev. Loss 6618 30 Blow Blid off
Down 15
05
SFD
Scrubber Ev. Loss
185(20%) 42

ETP Collection Tank


MEE
391+27+ 30=448 kl/d
391
Ammonium
Sulphate
90* Kl Rec

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-19


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.3
Details of Stacks

Sr. Stack Fuel Stack APC Probable


No. attached Type Height measures emission
to
¾ Flue Gas Stacks

1 Boilers Bio Fuel 30.0 Dust Collector PM<150 mg/NM3


2 Nos. (Briquett SO2<100 mg/NM3
(3 TPH) es) NOx<150 mg/NM3
2 Thermic Bio Fuel 30.0 Dust Collector PM<150 mg/NM3
Fluid (Briquett SO2<100 mg/NM3
Heaters es) NOx<150 mg/NM3
3 Nos.
(10 Lacs
kcal/hr)
3 Hot Air Bio Fuel 30.0 Dust Collector PM<150 mg/NM3
Generator (Briquett SO2<100 mg/NM3
3 Nos. es) NOx<150 mg/NM3
(6 Lacs
kcal/hr)
¾ Process Gas stack

4. Process 15.0 Two stage NH3<150mg/NM3


Stack-1 -- water
Scrubber
followed Acid
scrubber
5. Process 15.0 Two stage NH3<150 mg/NM3
Stack-2 -- water
Scrubber
followed Acid
scrubber

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-20


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.4
Estimated Quality of Air Emission
FLUE GAS STACKS
Sr. Stack Flue gas Velocity of Pollutants
No. attached temp.0C stack gas,
to m/s PM SO2 NOX
mg/Nm3 mg/Nm3 mg/Nm3
1 Boilers 2 Nos 165 7.5 125 25 20
(3 TPH)
2 Thermic Fluid 180 10.0 120 30 25
Heaters 3 Nos
(10 Lacs
kcal/hr)
3 HAG-3Nos 180 10.0 120 30 25
(6 Lacs kcal/hr)

Process Stacks:

Sr. No. Stack attached to Pollutants, mg/Nm3


1. Process Stack-1 NH3 =50
2. Process Stack-2 NH3=50

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-21


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.5
Details of ETP units
Sr. Particulars Size in meter Capacity in m3 Qty.
No.
1. Oil & Grease Trap 4 x 2 x 1.5 9.6 4
(0.3 m FB)
2. Equalization Tank 14 x 14 x 3.5 588 2
(0.5 m FB)
3. Neutralization tank 10 x 10 x 3.5 350 1
(0.5 m FB)
4. Flash mixer 2.5 x 2.5 x 3.5 18.75 1
(0.5 m FB)
5. Chemical Dosing tanks - 2.0 4
6. Primary Clarifier 6.0 φ x 4.2 28 m2 surface 1
(2.2+2.0) area
7. Aeration Tank 15 x 15 x 4.5 1012.5 1
(0.5 m FB)
8. Secondary clarifier 4.5 φ x 4.0 16 m2 surface 1
(2.2+1.8) area
9. Intermediate Effluent 5 x 5 x 3.5 75 1
Collection Sump
10. Duel Media Filter 2.2 dia x 1.5 m - 1
11. Treated Effluent 5 x 5 x 3.5 75 1
Collection Sump
12. Filter press for @36 plates of - 1
dewatering size1.2x1.2

13. Air requirements 1000 m3/hr 20 hp 2 root


blower
14. Guard sump - 500 1

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-22


San Envirotech Pvt. Ltd-Ahmedabad

Figure 2.2
ETP Flow Diagram

5A 5B
Raw
Effluent 4

Equalization Neutralization
Tank Tank

Oil & Grease Primary


Trap Clarifier
Equalization
Tank

Aeration
Intermediate Tank
effluent Secondary
collection Clarifier
Sump

Sludge
Sump

Treated effluent
Dual media
collection Filter Press
filter
Sump

ECP Canal

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-23


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.6
Estimated Quality of Effluent

Sr. Parameters Unit Raw After After


No. Effluent Primary Secondary

1. pH pH Unit 2.5 8.0 7.5

2. Color Co-Pt 1810 142 89


Unit
3. SS mg/L 775 89 92

4. TDS mg/L 4610 4803 4542

5. COD mg/L 2195 1550 210

6. BOD mg/L 950 540 46

7. Oil & Grease mg/L 15.0 7.0 7.0

8. Copper mg/L 12.7 1.8 1.8

9. Ammonical mg/L 2510 292 45


Nitrogen

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-24


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.7
Details of Solid / Hazardous waste

Sr. Types of Sources Quantity Composition


No. Waste

1. Chemical ETP 600 Part of sludge will be sold


Sludge MT/Month to cement industries and
balance will be sent to
TSDF site as land filling
approved by GPCB
2. Spent Oil Spent Oil 0.2 Sold to approved recycler
MT/Yr

3. Discarded Raw Drums Sold to approved recycler


containers / material 120
barrels/liners Nos./Month
Liners
0.1 MT/Month

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-25


San Envirotech Pvt. Ltd-Ahmedabad

Table 2.8
Estimated characteristics hazardous waste

Sr. No. Parameters Unit Result


AS IS BASIS
1. Moisture (%) - 25.8
2. Ether Soluble gm/Kg 0.12
3. TIS at 5500 C gm/Kg 810
WATER LEACHATE (10% SOLUTION IN DISTILLED WATER)
1. pH pH Unit 8.2
2. Total Alkalinity gm/Kg 12.9
3. COD gm/Kg 5.0
4. Sulphate gm/Kg 50.3
5. Chloride gm/Kg 16.9
ACID LEACHATE
1. Iron gm/Kg 4.3
2. Total Chromium gm/Kg BDL
3. Copper gm/Kg 6.2

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-26


San Envirotech Pvt. Ltd-Ahmedabad

Figure 2.3A

Proposed
NOPL plant

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-27


San Envirotech Pvt. Ltd-Ahmedabad

Figure 2.3B
Factory Layout

ETP

REIA of Narayan Organics Pvt. Ltd., Unit-II 2-28


San Envirotech Pvt. Ltd - Ahmedabad

Chapter-3

Baseline Environmental Status


3.1 PRELUDE

Any developmental activities related to industrial sector are expected to


cause impacts on environmental quality in surrounding area of the
respective project locations. However, the intensity of environmental
impacts from a specific project depends on several factors such as type of
process (physical, chemical, fuel combustion etc.) involved in the project,
processing capacity (scale/size of the project), type and extent of pollution
control measures, project location, surrounding geomorphology,
demography, quality of life, etc. To assess environmental impacts from
proposed project at a specific location, it is essential to monitor the
environmental quality prevailing in the surrounding area prior to
implementation of the proposed project. The environmental status within
the impact zone could be used for identification of significant
environmental issues to be addressed in the impact assessment study.

The impacts from an existing industrial project on its surrounding


environment are mainly regulated by the nature of pollutants, their
quantities discharged to the environment, existing environmental quality,
assimilative capacity of the surrounding environment and topography and
terrain of the project site (its location) as well as the surrounding area.

In order to identify and establish the extent of likely impacts, it is essential


to gather information on existing environmental quality with regard to
various components of the environment.

3.2 AIR ENVIRONMENT

The impact on air environment would depend and has been identified on
the basis of identification of sources of air pollution from various process
operations; the nature of pollutants and their quantities likely to be

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-1


San Envirotech Pvt. Ltd - Ahmedabad

discharged to the atmosphere; and the baseline data on air quality. The
baseline data on air quality and micrometeorological conditions of the area
surrounding the project site have been generated through an
appropriately designed network for and monitoring of ambient air quality
(NAAQ) within the zone of likely impacts.

3.2.1 Design of Network for Ambient Air Quality Monitoring Stations

The following criteria were taken into account while designing the ambient
air quality-monitoring network:

Topography/Terrain of the study area

Populated areas within the region

Prediction of maximum concentrations and distances of their likely


Occurrence under prevailing meteorological conditions

Representation of regional background

Representation of valid cross sectional distribution in downwind Direction

3.2.2 Reconnaissance

Reconnaissance survey was undertaken to establish the baseline status of


air environment in the study region. The prime objective of the NAAQ
survey, within 05-km radial study area around the plant, was to establish
the existing ambient air quality levels. Six Ambient Air Quality Monitoring
(AAQM) stations were selected based on the criteria used for designing the
network. The locations (relative directions and distances) of these stations
with respect to project site are given in Figure 3.5 and details of these
stations are described in Table 3.1.

The Particulate Matter (PM10), Particulate Matter (PM2.5), Sulphur Dioxide


(SO2) and Oxides of Nitrogen (NOx), HC and VOCs were identified as
significant parameters for ambient air quality monitoring, particularly
because these are likely to be emitted from the industries and for which
ambient air quality standards are prescribed.

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-2


San Envirotech Pvt. Ltd - Ahmedabad

The micrometeorological data on wind speed; wind direction, temperature


and relative humidity were collected through a weather monitoring station
for the study period. The baseline status of air quality is monitored within
the study area i.e. 05-Km radial distance from project site as per the
latest regulatory guidelines.

3.2.3 Micrometeorology of the Area

The micrometeorological conditions at the project site will regulate the


transport and diffusion of air pollutants released into the atmosphere. The
principle meteorological variables are horizontal convective transport
(average wind speed and direction), vertical convective transport
(atmospheric stability, mixing height) and topography of the area.

The data on surface meteorological parameters (hourly average wind


speed and direction) in the study area were collected during 1st week of
December-2010 to February-2011 using automatic weather monitoring
station placed at Industry site. The sensors of this equipment were kept at
about 10 m above ground level with free exposure to the atmosphere all
through the study period in winter season.

Windrose

The 24 hourly wind rose was prepared using the data on wind direction
and speed collected for winter season in the study area. The same, as
depicted in Figure 3.6, shows the predominant wind directions are NNW,
NW, N, NNE, and ESE implying that winds come from these directions for
most of the time during the period. The wind speed class 1-5 kmph
occurred for 32.0 %, 6-10 kmph about 18.47 %, 11-15 kmph 13.89 %
and above 15 kmph and below 35 kmph occurred for 9.46 % of the study
duration and of the time. The calm condition (below 1 kmph) observed is
26.18 % of the time. The wind data generated at site were also compared
with the climatological data obtained from the closest Indian
Meteorological Department (IMD) station at Ahmedabad. The local
prevailing wind pattern during the study period is in conformity with the

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-3


San Envirotech Pvt. Ltd - Ahmedabad

climatological normal of the region. The average wind speed recorded is


6.1 kmph during the study period.

Temperature

During the study period, the maximum and minimum temperatures


recorded at project site were recorded as 33.8OC and 12.7OC respectively.

Relative Humidity
During study period at project site during study period, the maximum
relative humidity was recorded as 73.1% and minimum as 15.3%.

Rainfall
No rainfall during the study period at project site.

3.2.4 Ambient Air Quality Survey

The ambient air quality monitoring was carried out at Six AAQM locations,
with a frequency of twice a week continuously for three months, to assess
the existing sub-regional air quality status in winter season. The
Respirable Dust Sampler and Fine particulate sampler along with the
analytical methods prescribed by CPCB were used for carrying out air
quality monitoring. At all these sampling locations; PM10, PM2.5, SO2 and
NOx were monitored on 24-hourly basis to enable the comparison with
ambient air quality standards prescribed by the Central Pollution Control
Board.

The data on concentrations of various pollutants were processed for


different statistical parameters like arithmetic mean, standard deviation,
minimum and maximum concentration and various percentile values.

3.2.5 Baseline Status

The existing baseline levels with respect to PM10, PM2.5, SO2, NOx, HC and
VOCs are presented in Tables 3.2 to 3.7 along with statistical analysis;
represent the cross sectional distribution of baseline air quality status of
the study region.

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-4


San Envirotech Pvt. Ltd - Ahmedabad

Respirable Suspended Particulate Matter (PM10)


An average and 98th percentile value of 24-hourly PM10 values at all the
locations ranged between 44-59 μg/m3 and 62-78 μg/m3 whereas the
stipulated standards of CPCB for industrial areas 100 μg/m3.

Particulate Matter (PM2.5)


An average and 98th percentile value of 24-hourly concentrations of SPM
value at all the locations ranged between 25-34 μg/m3 and 36-47 μg/m3
respectively. The stipulated standard of PM2.5 for industrial area is 60
μg/m3 for residential area.
Sulphur Dioxide (SO2)
An average and 98th percentile value of 24-hourly SO2 value of arithmetic
mean at all the locations ranged between 10-15 μg/m3 and 14-22 μg/m3
respectively, which are well within the stipulated standards 80 μg/m3 for
industrial areas.
Oxides of Nitrogen (NOx)
An average and 98th percentile value of 24 hourly NOx value of arithmetic
mean at all the locations ranged between 09-17 μg/m3 and 14-23 μg/m3
respectively, which are much lower than the standards stipulated by CPCB
for industrial areas 80 μg/m3.

3.2.6 Identification of Impacts

The identification of impacts with regard to air environment involves a


careful consideration of all the major process operations, burning of fuel
required for generating the energy in terms of steam, hot air generator
and other activities that may lead to generation and discharge of air
pollutants to the atmosphere. The main source of air pollution will be flue
gas emission and process gas emission. The flue gas emission will from
the boilers, Thermic fluid heaters and hot air generators where biofuel
(Briquettes) will be used. Ammonia will be liberated as process gas.
However, adequate air pollution control measures will be provided to meet
gaseous emission norms recognized by GPCB.

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-5


San Envirotech Pvt. Ltd - Ahmedabad

3.3 Water Environment

Water Environment of an area is broadly classified into following


categories

1. Surface Water: Rivers, Drains, Canals, Ponds etc.

2. Ground water: Accumulation of water in deeper strata of ground.

The only source of recharging for both surface and groundwater source is
from precipitation (rainfall).

3.3.1 Water Quality

Collected water samples were analyzed for various desirable


characteristics of ground water. Sampling location is shown in Figure 3.7.
The results are shown in Table 3.9.

Color: All the samples were color less meeting desirable norms.

pH: All the samples meet the desirable standards (pH ranges from 6.9 to
7.3).

Total Dissolved Solids (TDS): TDS in samples ranges from 996 mg/l
(Gajera) to 1196 mg/l (Nr. Industry). All the samples meet the
permissible limit of 2000 mg/l.

Calcium: Calcium contents in the water ranges from 43 mg/l (Vedach) to


65 mg/l (Nr. Industry). All the samples meet the permissible limit of 200
mg/l.

Magnesium: Magnesium content in the water ranges from 36 mg/l


(Piludara) to 55 mg/l (Dabha). All the samples meet even the permissible
limit of 100 mg/l.

Sulphate: Sulfate content in the water ranges from 39 mg/l (Gajera) to


80 mg/l (Nr. Industry). All the samples meet the permissible limit of 400
mg/l for drinking water.

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-6


San Envirotech Pvt. Ltd - Ahmedabad

Total Alkalinity: Total alkalinity in the water samples ranges from 208
mg/l (Vedach) to 333 mg/l (Nr. Industry). All the samples are within the
permissible limit of drinking water (600 mg/l).

Other Parameters: Potassium (ranges from 39 mg/l to 75 mg/l), Sodium


(ranges from 202 mg/l to 292 mg/l) and Chloride (ranges from 320 mg/l
to 474 mg/l).
Conclusions: Ground water samples from villages meet the permissible
limit.

3.4 NOISE ENVIRONMENT


3.4.1 Introduction
Noise can be defined as an unwanted sound. It interferes with speech and
hearing and is intense enough to damage hearing or is otherwise
annoying. The definition of noise as unwanted sound implies that it has an
adverse effect on human beings and their environment. Noise can also
disturb natural wildlife and ecological system.
Sound is mechanical energy from a vibrating surface, transmitted by cyclic
series of compression and rarefaction of molecules of the materials
through which it passes. Sound can be transmitted through gases, liquids
and solids. The number of compressions and rarefaction’s of the air
molecules in the unit of time is described as its frequency. Frequency is
expressed in hertz (Hz), which is the same as the number of cycles per
second.
3.4.2 Methodology

To understand the noise environment in the study area, a survey was


conducted using Sound Level Meter at each of the Eight locations including
the plant site is shown in Figure 3.8.

3.4.3 Ambient Air Quality Standards in Respect of Noise

Ministry of Environment and Forest has notified the ambient standards in


respect of noise in Gazette of India on February 14, 2000. Table 3.12
depicts these standards in respect of noise.

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-7


San Envirotech Pvt. Ltd - Ahmedabad

3.4.4 Day-Time and Night-Time Noise Levels

The Leq values of noise levels during daytime (Ld) varied between 53.1 to
61.9 dB (A). Highest Ld value was recorded near Bus stop Vavadi (61.9 dB
(A)) while the Leq values of noise levels during night time (Ln) varied
between40.0 to 53.2 dB (A). Highest Ln value was recorded at Bus stop
Vavadi (53.2 dB (A)).

3.4.5 Conclusions

The hourly Leq noise levels recorded at various locations in the study area
show considerable fluctuations because of changes in traffic movement,
commercial and domestic activities in the study area. Generally noise
levels in public places like hospital, temples and community hall have
higher values in day time as per Residential area limit of 55 dB (A) but it
is less than Commercial area limit of 65 dB (A).
Ambient standards both for Ld and Ln with respect to noise applicable for
residential area during day - time {55 dB (A)} and night-time {45 dB (A)}
are not always met at all locations.

3.5 SOIL ENVIRONMENT

3.5.1 Introduction

Soils may be defined as a thin layer of earth’s crust that serves as a


natural medium for the growth of plants. It is the unconsolidated mineral
matter that has been subjected to and influenced by genetic and
environmental factors. Soils serve as a reservoir of nutrients for plants
and crops and also provide mechanical anchorage and favorable tilth.

The study area has primarily Grey Brown Aridisols type of soil. The soils of
this type basically originate from alluvium rocks. According to texture
classification, this belongs to Clay Loam category. This type of soil has
moderate permeability and water retention capacity. This soil has
moderate erosion potential.

The study area has following physical and chemical characteristics.

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3.5.2 Soil Characteristics

Samples of soils were done at 6 locations (Nr. Industry, Piludrara, Vedach,


Gajera, Dabha, Abhol). During the study period and these locations are
shown in Figure 3.9.
The values of important physical and chemical parameters of these soil
samples are depicted in Table 3.13. From the tabulated values, the
following conclusions can be made about the physical and chemical
characteristics of these soil samples.
3.5.3 Corollaries
Physical Parameters
Particle Size: A Particle size of the different constituents (clay, silt, sand
and gravel) controls the porosity and water holding characteristic of the
soil. Clay (size < 0.002 mm) amount in the soil samples ranges from 19%
to 25%; Silt (size 0.002 to 0.075 mm) in the soil samples is 25% to 37%
and Sand (size 0.075 to 0.475 mm) in the soil samples is 23% to 31%.
While Gravel (size > 4.75 mm) in the soil samples is 19% to 31%.
Analysis shows that the soil is sandy soil with less water holding capacity.
Porosity: Porosity is a measure of space in between soil particles caused
by structural conditions and determined under identical conditions.
Porosity of soil samples of the study area ranges from 40.3 to 42.1%.
Water Holding Capacity (WHC): Water holding capacity (WHC) of soil
samples of the study area ranges between 49.3 to 56.1 % and these being
sandy soils are not capable of retaining sufficient water during irrigation
for facilitating the plant growth.
Bulk Density: Bulk Density of soils in the study area is found to be in the
range from 1.43 to 1.49 g/cm3. Bulk density is of greater importance for
characterizing the physical behavior of soils. Generally, soils with low bulk
density have favorable physical conditions (porosity and permeability)
whereas those with high bulk density exhibit poor physical conditions.

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Chemical Parameters
pH: pH was determined by taking 1:5 ratio of soil and distilled water. pH
of soils in the study area is found to be in the range of 7.2 to 7.6 The soils
of the study area are neutral in nature.
Chloride: Chloride content in soils of the study area is found to be in the
range of 95 to137 mg/kg.
Calcium: The calcium as CaCO3 in soil samples is found to be in the range
of 41 to 119 mg/kg
Magnesium: Magnesium content in soil samples of the study area ranges
from46 to 55 mg/kg.
Available Phosphorus: Available Phosphorus content in soil samples of
the study area ranges from 139 to 161 mg/kg.
Available Nitrogen: Available nitrogen content in soil samples of the
study area is found to be in the range from 182 to 196mg/kg.
Potassium: Potassium content in soil samples of the study area is found
to be in the range from 52 to 95 mg/kg.
Sodium: Sodium content in soil samples of the study area is found to be
in the range from 98 to 105 mg/kg.
Total Organic Matter (TOM): Total organic matter content in soil
samples of the study area is found to be in the range of 1.31 to1.47
mg/kg.
Boron: Boron is found absent in the soil samples of the study area.
3.6 Terrestrial Ecology (Flora)
The structure and type of vegetation depends on climatic conditions and
physiography of an area. Climate of the study area is arid to semi arid and
suited for the growth of selected variety of vegetation.
The contents of this subsection are based secondary data obtain from local
forest department. List of floral diversity is presented in Table 3.14.
3.6.1 Common Crop Plants
Common cultivated crop plants in the study area include: Rabi season
(January to March) - wheat, mustard, jeera; April to June -juvar, bajra,

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gram and Kharif (July to October) - paddy; Sugar cane and vegetables are
also grown at some places.
3.6.2 Ecological Stresses
Human needs for settlement and commercial activities like farming,
industries, infrastructure (roads, canals, power lines, railways etc.) have
forced him to encroach on natural vegetation i.e. forests. Even the open
areas left for plantation/green cover at times have been occupied by
encroachers/slums resulting in stress on environment.
3.6.3 Terrestrial Wild Life
Because of being in arid / semi arid zone and lack of well developed forest
cover, the study area lacks in mammalian life and is the home of dry,
scrub jungle loving animals, best suited to the climate of arid and open
land. Avifauna and reptiles found in the study area and area around it.
This is compiled on the basis of sighting during field survey in the area
and also from the information collected from villagers and forest personnel
working in the area.
3.6.4 Fauna
Table 3.15 depicts the zoological name and abundance rating of wild
animals found in the study area and its adjoining area.

3.7 SOCIO ECONOMIC AND LAND USE

3.7.1 Land use pattern and infrastructure


The land use pattern indicates the manner in which different parts of land
in an area is being utilized or non-utilized. It is an important indicator of
environmental health human activity and a degree of inter play between
these two. Even though the soil quality, water availability and climate
have strong influence on agriculture and vegetation, the human activity
may alter the natural environment to a large extent to suit human needs.
Unnatural land use often triggers rapid environmental deterioration and
disturbs ecological balance.
In census records major land use classifications are; Forests, Culturable
land, Culturable waste land and area not available for cultivation.
Culturable land is further classified as: irrigated and unirrigated. Area not

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available for cultivation includes lands put to non-agriculture uses as well


as barren and uncultivable lands.
The main land use in area is for dwellings, infrastructure and related
activities. However the land use pattern for rural areas is discussed below.
The information is preliminary based on 2001 Census as depicting in Table
3.17.
3.7.2 Demographic and Socio-Economic Environment
The demographic and Socio-economic details of the study area are
discussed below. These are primarily based on census data of 2001. Data
on number of households, population as well as literacy and employment
pattern in the study area have been presented in Table-3.18. The
employment pattern in the area is indicator of number of persons
employed in various sectors. It also indicates the various categories of
employment flourishing in the area.
3.7.3 Living Standard and Infrastructure
In India it is not possible to setup a primary standard of living because of
wide variations in terms of income, economic conditions, social custom,
employment opportunity, pattern of spending etc. However, availability of
amenities like education, medical, water supply, communication, road
network, electricity etc. significantly reflects the level of development of
the area. Information on available amenities in the study area has been
extracted from census record of 2001. Total numbers of village in study
area are 32. On the basis of data presented in the Table-3.19, the status
of available amenities is discussed in following sub-sections:
Drinking Water Supply
All the villages in the study area have two or more sources of drinking
water. 30 villages in study area have tap water supply in addition to well
(almost all), tanks (almost all).

Communication and Transport


The main mode of public transport available in the study area is by bus
service. 5 villages have approach to railway station as western railway

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meter gauge line is passing nearby and also has stations. Majority of
villages in the study area is connected with pucca road.

Post and Telegraph


As per 2001 census record in study area 29 have post office facility at
doorstep. Most of villages have telephone facility in the village.

Power Supply
As per 2001 census record out all the villages are getting power supply for
all purposes.

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Table 3.1

Ambient Air Quality Monitoring Locations

Sr. Location Direction w.r. to center Distance in


No. of Industry (km)
1 Nr. Industry - -
2 Village Veduch (WNW) up wind direction 1.0
3 Village Piludra (NNE) Down wind direction 3.3
4 Village Gajera (NE) up wind direction 1.2
5 Village Dabha (SW) Down wind direction 5.9
6 Village Kanzat (SE) up wind direction 5.1

Table -3.2
Ambient Air Quality Status
(Period: - December-10 to Fabruary-11)

Average –24 Hours Unit - μg/m3


Sr. No Sampling Location PM10 PM2.5 SO2 NOx
Average (Min-Max)
1 Nr. Industry 71 40 18 19
(59-78) (31-47) (15-22) (17-23)
2 Village Veduch 65 35 14 16
(53-72) (29-41) (10-17) (12-22)
3 Village Piludra 67 38 15 16
(62-75) (34-42) (12-19) (13-22)
4 Village Gajera 62 34 16 15
(58-72) (32-40) (13-17) (12-18)
5 Village Dabha 61 37 15 16
(52-73) (30-43) (13-18) (12-19)
6 Village Kanzat 52 31 12 12
(44-62) (25-36) (10-14) (09-14)

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Table – 3.3
Ambient Air Quality Status (PM10)

(Period: - December-10 to Fabruary-11)

Average –24 Hours Unit - μg/m3


Station Name Max Min 98 75 50 25 Avg SD
Percentile Percentile Percentile percentile
Nr. Industry 78 59 77 75 71 68 71 5
Village Veduch 72 53 72 69 64 63 65 5
Village Piludra 75 62 74 68 66 65 67 4
Village Gajera 72 58 71 63 61 60 62 4
Village Dabha 73 52 71 66 62 55 61 6
Village Kanzat 62 44 60 56 53 47 52 5

Figure 3.1

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San Envirotech Pvt. Ltd - Ahmedabad

Table -3.4
Ambient Air Quality Status (PM2.5)
(Period: - December-10 to Fabruary-11)
Average –24 Hours Unit - μg/m3

Station Max Min 98 75 50 25 Avg SD


Name Percentile Percentile Percentile percentile
Nr. Industry 47 31 46 41 40 39 40 3
Village 41 29 40 37 35 33 35 3
Veduch
Village Piludra 42 34 42 39 38 36 38 2
Village Gajera 40 32 40 38 36 34 36 2
Village Dabha 43 30 42 39 37 35 37 4
Village Kanzat 36 25 36 33 31 30 31 3

Figure 3.2

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San Envirotech Pvt. Ltd - Ahmedabad

Table - 3.5
Ambient Air Quality Status (SO2)
(Period: - December-10 to Fabruary-11)

Average –24 Hours Unit - μg/m3


Station Max Min 98 75 50 25 Avg SD
Name Percentile Percentile Percentile percentile
Nr. Industry 22 15 22 18 18 16 18 2
Village 17 10 17 15 14 13 14 2
Veduch
Village Piludra 19 12 18 16 15 14 15 2
Village Gajera 17 13 17 17 16 15 16 1
Village Dabha 18 13 17 16 15 14 15 1
Village Kanzat 14 10 13 13 12 11 12 1

Figure 3.3

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San Envirotech Pvt. Ltd - Ahmedabad

Table -3.6
Ambient Air Quality Status (NOx)
(Period: - December-10 to Fabruary-11)
Average – 24 Hours Unit - μg/m3

Station Name Max Min 98 75 50 25 Avg SD


Percentile Percentile Percentile percentile
Nr. Industry 23 17 22 20 19 18 19 2
Village Veduch 22 12 21 18 16 14 16 3
Village Piludra 22 13 21 17 15 14 16 2
Village Gajera 18 12 18 16 16 14 15 2
Village Dabha 19 12 18 16 15 14 16 2
Village Kanzat 14 9 14 13 13 11 12 2

Figure 3.4

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San Envirotech Pvt. Ltd - Ahmedabad

Table -3.7: Volatile Organic Compound (VOCs) in μg /m3

Sr. No. Station Name VOCs HC

1 Nr. Industry 57 37
2 Village Veduch 36 24
3 Village Piludra 33 22
4 Village Gajera 22 15
5 Village Dabha 39 25
6 Village Kanzat 28 19

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Table -3.8: National Ambient Air Quality Standards


(EP, 7TH AMENDMENT RULES-2009)

Pollutants Time-weighted
Concentration in ambient air
average
Industrial, Ecologically Method of
Residential, Sensitive Measurement
Rural and area
others area (Notified by
Central
Government)
Sulphur Dioxide Annual Average* 50 20 ƒ Improved west and
(SO2) µg/m3 24 hours** 80 80 Gaeke
ƒ Ultraviolet
fluorescence
Oxides of Annual Average* 40 30 ƒ Modified Jacob
Nitrogen as 24 hours** 80 80 &Hochheiser
(NO2) µg/m3 (Na-Arsenate)
ƒ Chemiluminescence
Particulate Annual Average* 60 60 ƒ Gravimetric
Matter(Size less 24 hours** 100 100 ƒ TOEM
than 10 µm or ƒ Beta attenuation
PM10, µg/m3
Particulate Annual Average* 40 40 ƒ Gravimetric
Matter(Size less 24 hours** 60 60 ƒ TOEM
than 2.5 µm or ƒ Beta attenuation
PM2.5, µg/m3
Ozone (O3) 8 hours ** 100 100 ƒ UV photometric
µg/m3 1hours** 180 180 ƒ Chemiluminescence
ƒ Chemical Method
Lead (Pb) Annual Average* 0.50 0.50 ƒ AAS/ICP method
µg/m3 24 hours** 1.0 1.0 after sampling on
EPM 2000 or
equivalent filter
paper
ƒ ED-XRF using
Teflon filter
Carbon Monoxide 8 hours** 02 02 ƒ Non Dispersive
(CO) 1 hour** 04 04 Infra Red (NDIR)
µg/m3 spectroscopy
ƒ
Ammonia(NH3) Annual Average* 100 100 ƒ Chemiluminescence
µg/m3 24 hours** 400 400 ƒ Indophenol Blue
Method

Benzene (C6H6) Annual* 05 05 ƒ Gas


µg/m3 chromatography
based continuous
analyzer
ƒ Adsorption and
desorption followed
by GC analysis
Benzo(a)Pyrine Annual* 01 01 ƒ Solvent extraction
(BaP)-particulate followed by
phase only, HPLC/GC analysis
µg/m3

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Arsenic (As), Annual* 06 06 ƒ AAS/ICP method


µg/m3 after sampling on
EPM 2000 or
equivalent filter
paper
Nickel (Ni) Annual* 20 20 ƒ AAS/ICP method
µg/m3 after sampling on
EPM 2000 or
equivalent filter
paper
Annual Arithmetic mean of minimum 104 measurements in a year taken
* twice a week 24 hourly at uniform interval.
24 hourly/8 hourly or 01 hourly values, as applicable, shall be complied
** with 98% of the time in a year. 2% of the time the time, they may
exceed the limits but not two consecutive days of monitoring.

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Table -3.9: Results of Ground Water Quality in the Study Area


(Date of Sampling 02/02/2011)

Parameters Unit CONCENTRATION


Nr. Piludara Vedach Gajera Dabha Abhol
Industry
pH pH Unit 7.2 7.0 6.9 7.2 7.3 7.0
Color Co-Pt Color Color Color Color Color Color
Unit Less Less Less Less Less Less
0
Temperature C 26 25 26 26 25 25
Conductivity Micro
mhos/c
m 1710 1553 1470 1412 1903 1470
Turbidity NTU 3.8 5.8 3.8 5.7 4.9 4.5
TDS mg/L 1196 1119 1028 996 1343 1041
COD mg/L BDL BDL BDL BDL BDL BDL
Total Hardness mg/L
as CaCO3 325 300 264 272 357 292
Total Alkalinity mg/L 333 309 208 274 306 268
Sodium as Na+ mg/L 256 202 244 225 292 282
Potassium K+ mg/L 75 48 48 39 48 43
Calcium Ca+2 mg/L 65 62 43 48 52 46
Magnesium mg/L
Mg+2 39 36 38 37 55 43
Chlorides as Cl- mg/L 391 320 367 351 474 456
Sulfates as mg/L
SO4-2 80 63 50 39 70 52
Fluoride F- mg/L 0.55 0.58 0.54 0.53 0.50 0.57
Nitrates as mg/L
NO3-3 34 37 37 33 31 33
Phenol as mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
C6H5OH
Cynide as CN- mg/L <0.02 <0.02 <0.02 <0.02 <0.02 <0.02
Arsenic as As mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Cadmium as mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Cd
Copper as Cu mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Lead as Pb mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Manganese as mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Mn
Iron as Fe mg/L 0.12 0.16 0.13 0.17 0.14 0.19
Total mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Chromium
Zinc as Zn mg/L <0.01 <0.01 <0.01 <0.01 <0.01 <0.01

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Table -3.10: Indian Standard Specification for Drinking Water

S. Parameters Desirable Limit Permissible Limit


No. in the Absence of
Alternate Source
I Essential Characteristics
1. Colour, Hazen Units, Max. 5 25
2. Odour Unobjectionable -
3. Taste Agreeable -
4. Turbidity, NTU, Max. 5 10
5. pH value 6.5-8.5 No Relaxation
6. Total Hardness (as CaCO3) mg/l, 300 600
Max.
7. Iron (as Fe) mg/ l, Max. 0.3 1.0
8. Chlorides (as Cl) mg/l, Max. 250 1000
9. Residual Free Chlorine, mg/l, Min. 0.2* -
II Desirable Characteristics
10. Dissolved Solids, mg/l, Max. 500 2000
11. Alkalinity (as CaCO3), mg/l, Max. 200 600
12. Sulphate (as SO4) mg/l, Max. 200 400**
13. Nitrate (as NO3) 45 100
14. Fluoride (as F) mg/l, Max. 1.0 1.5
15. Calcium (as Ca) mg/l, Max. 75 200
16. Magnesium (as Mg) mg/l, Max. 30 100
17. Copper (as Cu) mg/l, Max. 0.05 1.5
18. Manganese (as Mn) mg/l, Max. 0.1 0.3
19. Mercury (as Hg) mg/l, Max. 0.001 No Relaxation
20. Cadmium (as Cd) mg/l, Max. 0.01 No Relaxation
21. Selenium (as Se) mg/l, Max. 0.01 No Relaxation
22. Arsenic (As As) mg/l, Max. 0.05 No Relaxation
23. Lead (as Pb) mg/l, Max. 0.05 No Relaxation
24. Zinc (as Zn) mg/l, Max. 5 15
25. Aluminium (as Al) mg/l, Max. 0.03 0.2
26. Boron (as B) mg/l, Max. 1 5
27. Chroumium (as Cr) mg/l, Max. 0.05 No Relaxation
28. Cyanide (as CN) mg/l, Max. 0.05 No Relaxation
29. Phenolic Compounds (as C6H5OH) 0.001 0.002
mg/l, Max.
30. Anionic Detergents (as MBAS) 0.2 1.0
mg/l, Max. mg/l, Max.
31. Mineral Oil mg/l, Max. 0.01 0.03
32. Pesticides Absent 0.001
33. Polynuclear Aromatic - -
Hydrocarbons (as PAH) g/l, Max.
34. Radioactive Materials
a. Alpha Emitters, Bq/I, Max. - 0.1
b. Beta Emitters, Bq/I, Max - 1
Note: * Applicable only when water is chlorinated
** Provided magnesium (as Mg) does not exceed 30 mg/l
Source: IS 10500: 1991, Fourth Reprint, July 1999

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Table -3.11: Ambient Noise Levels in the Study Area


Date of Monitoring: 02/02/2011 to 05/02/2011

Sr. No. Location Ld/Ln Noise Level


1 Project Site Ld 54.9
Ln 46.3
2 Primary School Piludara Ld 58.1
Ln 42.4
3 Primary School Vedach Ld 57.5
Ln 41.6
4 Temple Abhol Ld 55.3
Ln 40.0
5 Bus stop Vavadi Ld 61.9
Ln 53.2
6 Village Dabha Ld 55.7
Ln 40.7
7 Village Masar Ld 53.1
Ln 41.4
8 Bus stop Gajera Ld 59.6
Ln 42.0

Table -3.12: Ambient Air Quality Standards with respect to Noise

Category of Area Limits Leq, dB(A)


Day Time Night Time
Industrial 75 70
Commercial 65 55
Residential 55 45
Silence 50 40

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Table -3.13: Soil Analysis of Study area

(Date of Sampling 04/02/2011)

S. Parameters Unit Nr. Piludrara Vedach Gajera Dabha Abhol


No. Industry
1. pH (5%)Solution 7.4 7.2 7.3 7.3 7.5 7.6
2. Loss of Ignition % 6.5 6.3 6.1 6.2 5.9 6.1
3. Particle Size
Clay(< 0.002 mm) % 24 20 19 25 20 21
Silt(0.002 to % 28 30 37 26 27 25
0.075mm)
Sand(0.075- % 27 31 24 28 25 23
0.475mm
gravel (size > % 21 19 22 21 28 31
4.75mm)
4. Water Holding % 49.3 50.5 53.1 49.3 53.3 56.1
Capacity
5. Permeability cm/hr 3.39 3.30 3.19 3.30 3.40 3.23
6. Bulk Density g/cm3 1.43 1.45 1.46 1.47 1.45 1.49
7. Porosity % 42.1 41.3 40.9 40.5 40.3 40.3
8. Sodium Absorption Meq/ 2.04 1.98 2.1 2.12 2.2 2.6
Ratio 100gm
9. Sodium mg/kg 98 102 100 102 105 103
10. Potassium mg/kg 52 54 69 58 95 92
11 Calcium mg/kg 93 119 93 84 86 41
12. Magnesium mg/kg 49 49 47 55 52 46
13. Chlorides mg/kg 137 95 107 123 125 129
14. Sulphates mg/kg 87 71 85 71 98 78
15. Organic Matter mg/kg 1.47 1.38 1.43 1.42 1.36 1.31
16. Available Nitrogen mg/kg 183 189 187 192 196 182
17. Available mg/kg 140 154 156 161 145 139
Phosphorus
18. Iron mg/kg 1.49 1.38 1.34 1.26 1.29 1.32

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Table No-3.14: List of Tree Species found in the study area

List of Tree Species found in the study area

SR. NO. BOTANICAL NAME FAMILY VARNACULAR


NAME
1 Azadirachta indica Meliaceae Limdo
2 Acacia nilotica sub sp. Mimosaceae Baval
Indica
3 Achras sapota Sapotaceae Chiku
4 Ailanthus excelsa Simaroubacceae Rukhdo
5 Alangium salvifolium Alangiaceae Ankol
6 Albizia lebbeck Mimosaceae Kalo saras
7 Annona squamosa Annonaceae Sitaphal
8 Anogeissus seicea Combretaceae Dhao
9 Balanites aegyptiaca Balanitaceae Ingorio
10 Bauhinia racemosa Caesalpiniaceae Astori
11 Bombax ceiba Bombacaceae Shimlo
12 Borassus flabellifer Arecaceae Tad
13 Butea monosperma Fabeceae Kesudo
14 Cassia siamea Caesalpiniaceae ---
15 Ceiba pentandra Bombacaceae Dholo shimlo
16 Citrus limon Rutaceae Limbu
17 Dendrocalamus strictus Poaceae Vans
18 Eucalyptus globulus Myrtaceae Nilgiri
19 Feronia elephantum Rutaceae Kotha
20 Ficus benghalensis Moraceae Vad
21 Ficus religiosa Moraceae Papal
22 Ficus virens Moraceae Pipli
23 Fzizyphus mauritiana Rhamnaceae Bor
24 Holarrhena antidysenterica Apocynaceae Indrajav
25 Holoptelea integrifolia Ulmaceae Kanjo
26 Leucena latisiliqua Mimosaceae Pardesi baval
27 Madhuca indica Sapotaceae Mahudo
28 Mangifera indica Anacardiaceae Ambo
29 Manilkara hexandra Saptaceae Rayan
30 Morinda tomentosa Rubiaceae Aal
31 Moringa concan Moringaceae Jangli saragavo
32 Parkinsonia aculeata Caesalpiniaceae Ram baval
33 Phoenix sylvestris Arecaceae Khajuri
34 Pithecellobium dulce Mimosaceae Goras ambli
35 Pongamia pinnata Fabeceae Karanj
36 Prosopis juliflora Mimosaceae Gando baval
37 Prosopis spicigera Mimosaceae Khijado
38 Psidium guajava Myrtaceae Jamphal
39 Streblus asper Moraceae Harero
40 Tamarindus indica Caesalpiniaceae Amli
41 Teminalia catappa Combretaceae Deshi bardam

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List of Shrubs in the study area

SR. NO. BOTANICAL NAME FAMILY VARNACULAR


NAME
1 Euphorbia Nerifolia Euphorbiaceae Thor
2 Calotropis procera Asclepiafaceae Akado
3 Capparis decidua Capparidaceae Kerdo
4 Capparis sepiaria Capparidaceae Kanthar
5 Cassia auriculata Caesalpiniaceae Aval
6 Cobretum ovalifolium Combretaceae Mad velo
7 Cocculus cillosus meinspermaceae Vevdi
8 Euphorbia tirucalli Euphorbiaceae Thor
9 Impomoea fistulosa convolvulaceae Naphatio
10 Jatroha cureas Euphorbiaceae ---
11 Kriganelia reticulata Euphorbiaceae Kamboi
12 Lassonia inernis Lythraceae Mendhi
13 Mucuna pruriens Fabaceae Kavach
14 Opuntia elatori Cactaceae Phafda thor
15 Ricinus communis Euphorbiaceae Divel
16 Zizyphus mummularia Rhmnaceae Chani bor

List of Herbs in the study area

SR. NO. BOTANICAL NAME FAMILY VARNACULAR


NAME
1 Cynodon dactylon Poaceae Darbh
2 Apluda mutica Poaceae Pofli
3 Argemone mexicana Pepavraceae Darudi
4 Blumea membranacea Asteraceae -
5 Chloris barbata Poaceae Mindadin
6 Echinops echimatus Asteraceae Shulio
7 Eragrostic tinella Poaceae -
8 Hygrophila auriculata Acanthaceae Kantashulio
9 Sphaeranthus indicus Asteraceae Gorakh mundi
10 Tephrosia purpurea Fabaceae Sarphankho
11 Tridax procumbens Asteraceae Pardeshi bhangro
12 Typha angustata Typhaceae Ramban

List of Agriculture Crops in the study area

SR. NO. BOTANICAL NAME FAMILY VARNACULAR


NAME
1 Zea maize Poaceae Makai
2 Sorghum vulgare Poaceae Bajri
3 Triticum aestivum Poaceae Gehu
6 Gossypium herbaceum Malvaceae Kapas
7 Cajamus cajan Fabaceae Tuver
8 Oryaza sativa Poaceae Danger

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Table No-3.15
List of Amphibia, Reptilia and Birds in the study area

AMPHIBIA

SR. NO. COMMON NAME SCIENTIFIC NAME


1 Skipper frog Euphlyctic cyanophlytis
2 Common Indian Toad Bufo melanostictus

REPTILIA

SR. NO. COMMON NAME SCIENTIFIC NAME


1 Wall Lizard Hemidactylus flaviviridis
2 Garden lizard Calotes versicolor
3 Skink Mabuya carinata
4 Fan throated lizard Sitana ponticeriana
5 Cobra Naja naja
6 Rat Snake Ptyas mucous

BIRDS

SR. NO. COMMON NAME SCIENTIFIC NAME


1 Black drongo Dicrurus adsimilis
2 Ashy crowned finch lark Eremopterix grisea
3 Bank myna Acredotheres
ginginianus
4 Black winged kite Elanus caerulus
5 Blue rock pigeon Columba livia
6 Cattle egret Bulbucus ibis
7 Common babbler Turdoides caudatus
8 Common crow Corvus splendens
9 Common myna Acredotheres tristis
10 Common sandpiper Tringa hypoleucos
11 Coppersmith Megalaima
haemacephala
12 Crow- pheaasent Centropus sinensis
13 Fantail flycatcher Rhipidura aureola
14 Franklins wren warbler Prinia hodgsonii
15 Grey shrike Lanius excubitor
16 Grey tit Parus major
17 House sparrows Passer domesticus
18 House swift Apus affinus
19 Indian koel Eudynamysscolopaceae
20 Indian robin Saxicoloides fulicata
21 Indian roller Coracias benghalensis
22 Indian tree pie Dendrocitta vagabunda
23 Indian white backed vulture Gyps benghalensis
24 Jungle babbler Turdoides striatus
25 Jungle crow Corvus macrorhynchos
26 Lesser goldenbacked woodpeaker Dinopium benghalens

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San Envirotech Pvt. Ltd - Ahmedabad

SR. NO. COMMON NAME SCIENTIFIC NAME


27 Lotens sunbird Nectarinia lotenia
28 Magpie robin Copsychus saularis
29 Pariah kite Milvus migrans
30 Pond heron Ardeola grayii
31 Purple sunbird Nectarinia asiatica
32 Red vented bulbul Pycnonotus cafer
33 Red wattled lapwing Vanellus indicus
34 Rofous backed shrike Lanius schach
35 Rofous tailed finch lark Aammomanes deserti
36 Rose ringed parakeet Paittacula krameri
37 Shikra Accipter badius
38 Small green bee- eater Merops orientalis
39 Spotted owlet Ethane brama
40 Swallow Hirundo rustica
41 Tailor bird Orthotomus sutorius
42 White breasted kingfisher Halcyon smyrensis
43 White wagtail Motavilla alba
44 Yellow throated sparrows Patronia xanthocollis

List of Insects and others in the study area

SR. NO. COMMON NAME SCIENTIFIC NAME


1 Ant lion Myrmeleo sp.
2 Beetle Mylabris sp.
3 Black ant Camponotous compressus
4 Blue pancy Précis orithya
5 Common castor Ariadne merione merione
6 Common crow Euploea core core
7 Common evening brown Maelanitus leda leda
8 Common grass yellow Eurema hecabe simulate
9 Common mormon Papilio polyets romulus
10 Danaid eggfly Hypolimans misippus
11 Earthworm Megascolex sp
12 Field cricket Gryllus bimaculatus
13 German cockroach Blatta germanica
14 Grasshopper Orthetrum sp.
15 Grasshopper Conocephalus sp.
16 Honey bee Apis dorsata
17 Honey bee Apis indica
18 House cricket Gryllus domecticus
19 House fly Musca domestica (Linn.)
20 Indian cupid Everes lcturnus syntala
21 Lime butterfly Papilio demoles
22 Mole cricket Grylltaipa Africana
23 Mosquito Anopheles sp.
24 Mosquito Culex sp.
25 Pigmy locust Acridium sp.
26 Plain tiger Danus crysippus crysippus
27 Potter wasp Eumenes sp.
28 Red ant Oecophylla smargdina

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San Envirotech Pvt. Ltd - Ahmedabad

29 Red cotton bug Ddysdercus sp.


30 Striped tiger Danus genutia genutia
31 Termite Microtermes
32 Tree cricket Oecanthus indicus (Sauss)
33 wasp Icaria sp.
34 Water strider Geris spinole (Leth)
35 Yellow pancy Précis hierta hierta

SPIDERS

SR. NO. COMMON NAME SCIENTIFIC NAME


1 Banded four legged spider Argiope aemula
(Walckenaer)
2 Banded four legged spider Argiope sp.
3 House spider Crossopriza sp.
4 Jumping spider Plexippus sp.
5 Lynx spider Oxyopes sp.
6 Lynx spider Peucetia sp.
7 Orb web spider Cyclosa sp.
8 Orb web spider Larinia sp.
9 Orb web spider Neoscona sp.
10 See spider Clubiona sp.
11 Social spider Stegodyphus sp.
12 Two tailed spider Hersilia sp.
13 Wolf spider Hippasa sp.
14 Wolf spider Lycosa sp.
15 Wolf spider Pardosa sp.

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Table No-3.16
Land use statistics work out on the base of satellite imaginary

Sr. Category Sub Category Area In Sq Area in %


No. Meter
1 Agricultural Land Crop Land 232880233.53 74.13
Built Up Built Up area 2904982.32 0.92
2 (Rural)
3 Built Up Industrial 5338061.31 1.70
4 Vegetated Wetlands Sparse 27188576.38 8.66
5 Wastelands Dense scrub 6367736.94 2.03
6 Wastelands Mudflat 7861974.14 2.50
7 Wastelands Open scrub 557223.28 0.18
8 Wastelands Riverine 5708296.27 1.82
9 Wastelands Saline 14161465.25 4.51
10 Wastelands Saline/Sodic 4852107.38 1.54
11 Wastelands Shallow Ravinous 1028844.84 0.33
12 Water bodies Perennial 5285231.14 1.68
Total 314134732.79 100.00

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San Envirotech Pvt. Ltd - Ahmedabad

Table 3.17
Land Use Pattern
Sr. Name of Total Area of Irrigated Un Culturable Area not
No. Village the Village by irrigated waste available for
(ha) source (ha) (ha) cultivation
(ha)
1 Tithor 2462.04 25.29 549.29 9.72 1877.74
2 Karkhadi 1659.50 144.47 833.23 105.53 576.27
3 Kareli 2151.72 275.00 962.52 15.97 1098.23
4 Dadhwada 416.65 -- -- -- 258.21
5 Chitral 371.70 190.05 136.64 5.19 39.82
6 Kahanava 972.97 390.00 490.06 8.36 84.55
7 Piludara 720.62 40.00 596.75 8.04 75.83
8 Gametha 343.14 255.14 52.01 1.48 34.51
9 Gavasad 946.86 150.00 686.38 12.17 98.31
10 Maser 1361.44 620.11 593.18 26.06 122.09
11 Kural 561.66 92.14 404.68 5.49 59.35
12 Brahmanvasi 590.87 10.00 513.10 17.32 50.45
13 Vedach 3582.38 300.00 812.55 139.69 2330.14
14 Valipore 1690.75 -- 288.39 14.03 1388.33
15 Nondhana 589.60 5.00 517.93 14.26 52.41
16 Uber 4397.11 20.00 1699.60 -- 2699.51
17 Gajera 1505.76 300.00 1057.22 4.46 144.08
18 Pindapa 689.92 -- 587.40 32.30 70.22
19 Abhol 748.94 192.50 449.24 34.03 73.17
20 Nobar 968.81 7.00 848.45 15.79 97.57
21 Dabha 1465.04 100.00 1171.15 70.62 123.27
22 Kanzat 731.36 20.00 604.43 12.87 94.06
23 Sampla 871.20 -- 758.51 29.78 82.91
24 Bhanpur 314.60 -- 285.53 14.23 14.84
25 Uchchhad 726.66 12.00 631.32 21.63 61.71
26 Vahelam 567.44 -- 490.80 33.15 43.49
27 Vavli 331.67 20.00 257.45 18.08 36.14
28 Danoli 481.66 -- 402.22 20.85 58.59
29 Umra 688.59 10.00 598.73 24.45 55.41
30 Bhankhetar 162.99 -- 145.30 1.43 16.26
31 Anakhi 1490.07 40.80 1282.44 20.87 145.96
32 Jafarpara 305.09 31.00 225.63 20.92 27.54

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Table: 3.18 Summary of Socio-Economic Status

Name of No. of Total Population Literates Total main Cultivators Agricultura Marginal Non-Worker
the Occupied (Including Workers l Laborer Workers
Village/ Residential institutional and
Town/ House houseless population)
Ward P M F M F M F M F M F M F M F

Tithor 960 4495 2428 2067 1614 693 1345 406 232 33 637 209 119 91 964 1570

Karkhadi 983 4484 2436 2048 1726 1169 1385 68 255 03 671 47 04 03 1047 1977

Kareli 1144 5431 2832 2599 1972 1083 1648 577 658 84 683 282 68 270 1196 1752

Dadhwada 34 167 78 89 30 25 05 00 27 00 06 10 43 19 30 70

Chitral 342 1733 882 851 598 374 461 103 149 10 263 134 50 153 371 595

Kahanava 1636 7810 4202 3608 2815 1395 2475 494 941 100 1196 383 121 950 1606 2164

Piludara 902 4269 2255 2014 1740 1134 1319 527 499 40 309 81 05 12 931 1475

Gametha 483 2399 1269 1130 964 578 629 19 322 10 360 697 155 695 487 416

Gavasad 713 3448 1849 1599 1368 907 1118 578 215 12 393 247 00 111 731 1021

Maser 716 3429 1772 1657 1236 774 1019 407 256 200 497 343 66 373 687 877

Kural 567 2620 1393 1227 995 624 640 74 185 08 363 266 199 244 554 909

Brahmanva 395 1978 1070 908 695 368 603 211 197 11 352 240 43 145 424 552
si
Vedach 1369 6483 3429 3054 2327 1321 1833 329 474 39 780 442 272 495 1324 2230

Valipore 72 280 144 136 115 80 85 10 45 04 30 08 00 05 59 121

Nondhana 449 1955 1039 916 668 383 548 45 81 12 251 83 21 147 470 724

Uber 753 3339 1764 1575 1317 754 993 175 508 49 354 293 132 401 639 999

Gajera 1052 4328 2334 1994 1687 1110 1426 390 311 22 488 196 46 75 862 1529

Pindapa 282 1473 782 691 603 313 447 66 195 87 148 128 16 156 319 469

Abhol 448 2141 1137 1004 743 444 693 159 192 05 351 144 18 45 426 800

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Name of No. of Total Population Literates Total main Cultivators Agricultura Marginal Non-Worker
the Occupied (Including Workers l Laborer Workers
Village/ Residential institutional and
Town/ House houseless population)
Ward P M F M F M F M F M F M F M F

Nobar 342 1696 871 825 648 426 521 28 275 07 184 195 19 342 331 455

Dabha 604 3095 1598 1497 1104 672 887 72 226 11 447 140 89 228 622 1197

Kanzat 910 4538 2329 2209 1705 1232 1173 164 126 18 392 115 104 186 1052 1859

Sampla 286 1473 780 693 601 420 478 74 159 14 153 42 03 23 299 596

Bhanpur 74 402 196 206 102 45 104 47 65 39 31 47 13 70 79 89

Uchchhad 614 2822 1464 1358 1122 800 828 172 196 146 169 151 63 325 573 861

Vahelam 170 774 377 397 263 165 139 61 85 01 94 102 94 102 144 234

Vavli 295 1278 687 591 543 344 372 87 69 05 175 99 22 101 293 403

Danoli 202 978 528 450 428 257 308 71 199 117 69 89 43 209 177 170

Umra 227 1011 498 513 371 232 274 72 88 24 103 109 26 175 198 266

Bhankhetar 99 470 254 216 211 125 153 69 69 28 21 37 15 27 86 120

Anakhi 609 2751 1445 1306 1140 764 859 81 192 17 267 181 10 156 576 1069

Jafarpara 126 579 319 260 210 126 191 58 50 02 123 59 13 07 115 195

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Table - 3.19
Basic Amenities in the Study Area
Name of Educational Medical Drinking Communication Transportation Approach Nearest Power
Village Facility Facility Water (Post Facility to town & Supply
Facility or Telegraph) (Bus etc.) Village Dist. (Kms)
Tithor P(2) RP,CHW T,W,TK,TW, PO, Phone BS PR Padra-18 EA
HP
Karkhadi P(2), H, PUC, MH,PHC,F T,W,TK,R PO, Phone BS PR Padra-24 EA
Ac PC,RP
Kareli P(7),H, Ac(6) CWC,PHS, T,W PO, Phone BS PR Jambusar-21 EA
FPC,RP(2)
CHW(4)
Dadhwada P -(-5 kms) HP,S -(-5 kms) -(-5 kms) KR Rajpipla-22 EA
Chitral P,H CHW T,W,TK,TW, PO BS PR,KR Padra-19 EA
Kahanava P(15),H, Ac(3) PHS,D, T,W,TW PO, Phone BS,RS PR,KR Jambusar-26 EA
FPC,RP,C
HW(2)
Piludara P(6),H, PUC, PHS,FPC, T,W,HP PO, Phone BS PR Jambusar-18 EA
Ac RP(2),
CHW
Gametha P,H CHW T,W,TK,TW PO BS PR Jambusar-18 EA
Gavasad P MH,PHS,D T,TW,TK,T PO, Phone BS PR Padra-18 EA
,FPC,CHW W
Maser P(2),H,PUC, MH,PHS,D T,W,TK,TW PO, Phone BS PR,KR Jambusar-12 EA
Ac ,FPC,RP,
CHW
Kural P,H,PUC MH,D,RP T,W,TK,N PO, Phone BS,RS PR Padra-20 EA
(2),CHW
Brahmanvasi P, Ac(2) CHW T,W,TK,TW PO BS PR Jambusar-18 EA
Vedach P(11), H, PHS,D,FP T,W,TK PO, Phone BS PR Jambusar-16 EA
Ac(3) C,RP(2),C
HW
Valipore P(2),H, Ac CWC,RP, T,W PO BS PR Jambusar-12 EA
CHW

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San Envirotech Pvt. Ltd - Ahmedabad

Name of Educational Medical Drinking Communication Transportation Approach Nearest Power


Village Facility Facility Water (Post Facility to town & Supply
Facility or Telegraph) (Bus etc.) Village Dist. (Kms)
Nondhana P(4),H, Ac(2), PHS,D,FP T,W,HP PO, Phone BS PR Jambusar-12 EA
O C,RP,CHW
Uber P(7), H, Ac(3) PHS,FPC, T,W,TK PO, Phone BS PR,KR Jambusar-11 ED,EAG
RP(2),
CHW
Gajera P(7),H, PUC, MH,PHC,D T,W,TW PTO, Phone BS PR,KR Jambusar-14 EA
Ac(3) FPC,RP(4)
,CHW
Pindapa P CHW T,W,TK PO BS PR,KR Padra-19 EA
Abhol P CHW T,W,TK PO BS,RS PR,KR Jambusar-12 EA
Nobar P(3),Ac(2),O PHS,FPC, T,W,HP PO BS PR,KR Jambusar-7 EA
RP,CHW
Dabha P(4),Ac(2) H,CHW T,W PO BS PR,KR Jambusar-8 EA
Kanzat P(3),H(2), MH,PHS, T,W,TK PTO, Phone BS,RS PR,KR Jambusar-15 EA
PUC, Ac RP,CHW
Sampla P CWC,CHW T,W,TK PO, Phone BS PR,KR Jambusar-12 EA
Bhanpur P CHW T,TW,TK -(-5 kms) BS PR Padra-26 EA
Uchchhad P(2),Ac(3) CHW W,TK PO BS PR,KR Jambusar-9 EA
Vahelam P(2),Ac(3) RP T,W PO BS PR Jambusar-12 EA
Vavli P(2),Ac(2) CHW T,W PO, Phone BS PR,KR Jambusar-8 EA
Danoli P CHW T,W,TK -(-5 kms) BS PR Padra-27 EA
Umra P(2),Ac CHW T,W PO, Phone BS PR,KR Jambusar-5 EA
Bhankhetar P(2),Ac CHW T,W PO BS PR,KR Jambusar-3 EA
Anakhi P(3),H, Ac(2) PHS, T,W PO, Phone BS,RS PR Jambusar-7 EA
FPC,RP,
CHW
Jafarpara P(2),Ac CHW T,W PO BS PR Jambusar-8 EA

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San Envirotech Pvt. Ltd - Ahmedabad

Abbreviations:
Educational
P - Primary School
H - Matriculation/High School
PUC - Higher Secondary/Pre P University/Junior College/Inter.
Ac - Adult Literacy Class/ Centre
O - Others

Medical Facility
MH - Maternity Home
CWC - Child Welfare Centre
PHC - Primary Health Centre
PHS - Primary Health Sub-Centre
D - Dispensary
FPC - Family Planning Centre
RP - Registered Private Practitioner
CHW - Common Health Worker

Drinking Water
T - Tap Water
W - Well Water
TK - Tank water
TW - Tube well Water
HP - Hand Pump
R - River water
S - Spring

Post and Telegraph


PO - Post Office
PTO - Post & Telegraph Office
P - Phone

Transportation
BS - Bus
RS - Railway Station

Approach to Village
PR - Pucca Road
KR - Kachcha Road

Power Supply
EA - Electricity for all Purposes

Land Use
R - River
TWE - Tube well
T - Total

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Figure: 3.5
Ambient Air Quality Monitoring Station

Industrial
Location

Indicating Air Quality monitoring location

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San Envirotech Pvt. Ltd - Ahmedabad

Figure: 3.6

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San Envirotech Pvt. Ltd - Ahmedabad

Figure: 3.7

Water sampling location

Industrial
Location

Indicating Water sampling location

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-40


San Envirotech Pvt. Ltd - Ahmedabad

Figure: 3.8

Location of Noise monitoring station

Industrial
Location

Indicating noise monitoring location

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-41


San Envirotech Pvt. Ltd - Ahmedabad

Figure-3.9

Soil sampling station

Industrial
Location

Indicating Soil sampling location

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-42


San Envirotech Pvt. Ltd - Ahmedabad

Figure-3.10: Satellite Image of Vedach Region

REIA of Narayan Organics Pvt. Ltd.-Unit-II 3-43


San Envirotech Pvt. Ltd - Ahmedabad

Figure-3.11: Forest Map of Gujarat

Narayan
Organics

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San Envirotech Pvt. Ltd-Ahmedabad

Chapter 4
Anticipated Environmental Impacts & Mitigation
Measures

4.1 GENERAL

Predicting the net contribution on overall qualitative environmental


indicators require environmental impact assessment study for the proposed
units. Prediction of impacts is an important component in environmental
impact assessment process. Several techniques and methodologies are in
vogue for predicting the impacts due to existing and proposed industrial
development on physical, chemical, biological and socio-economic
components of environment. Such predictions delineate contribution in
existing baseline condition for the proposed project. The additional impacts
due to proposed activities are analyzed keeping in mind the baseline
status. This helps assess the assimilative capacity of the environment and
in turn the gravity of the impacts. Depending on the nature of the impact,
suitable management plans are devised.

Proposed unit is for dyes and dyes intermediate manufacturing. As such it


becomes important to estimate the peak incremental concentrations of
pollutants caused due to the emissions from the proposed Narayan
Organics plant. Section 2.9 in Chapter 2 of this report discusses the
pollution sources from the proposed plant.

Mathematical models are the best tools to quantitatively describe the


cause- effect relationship between source of pollution and different
components of environment.

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4.2 IMPACT DURING CONSTRUCTION AND OPERATION PHASE

The impact assessment has been addressed for the following attributes,
which may get affected due to the proposed activities of the project.

Impact on topography;

Impact on Air Environment;

Impact on Water Environment;

Impact on Noise;

Impact due to solid waste generation;

Impact on terrestrial ecology;

Impact on aquatic ecology

4.3 IMPACT ON TOPOGRAPHY

The project activities include excavation of soil in the plant area and
construction of the plant and storage facilities. The area of the proposed
plant is flat. Very minor or no Leveling would be required for the
construction of the proposed plant. No tree plantation affected since plant
will be come in industrial area. During the construction, excavated soil will
be restored to its original shape. Thus the impact during the construction is
reversible, for short terms and insignificant.

During the operation phase of the project, no impact is envisaged on the


topography.

4.4 AIR ENVIRONMENT

4.4.1 Construction Phase

The source of air emission during the construction will include dust from
site cleaning and construction activity and dust from excavation of the
plant area. These emissions are expected to result in change in baseline air

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quality, primarily in the working area only. Dust and other emissions are
not likely to spread in wider area, which would affect homes and other
properties. Dust will generate within working areas and measures will need
to protect workers. To mitigate the impact due to Suspended Particulate
Matter (SPM), regular sprinkling of the water will be done along with the
construction activities.

4.4.2 Operational phase

In the present study, the mathematical model that has been used for
predictions on air quality includes steady state Gaussian Plume Dispersion
model designed for multiple point sources.

The impacts on air quality from any project depend on various factors like
design capacity, configuration, process technology, raw material, fuel to be
used, air pollution control measures, operation and maintenance. Apart
from the above, other activities associated with any project, viz.,
transportation of raw materials and finished products, storage facilities and
material handling within the plant premises may also contribute to air
pollution.

4.4.3 Sources of air pollution

In the proposed project of pigment manufacturing, point sources emitting


gaseous pollutants include three nos. of flue gas stacks and two nos. of
process gas stacks. The major air pollutants, identified from this industry,
are SPM, SO2 and NOx from flue gas stacks and ammonia (NH3) from
process gas stacks.

4.4.4 Emissions

In the operational unit Bio Fuel (Briquettes) will be used for Boiler, Thermic
fluid heater and Hot air generator. The rate of fuel consumption and other
details are shown in Table 4.1.

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Since the bio fuel will be used, the gaseous emission will be well within
GPCB norms and simultaneously, there will be less impact on the air
Environment due to fuel combustion. The unit also proposes to provide
adequate scrubbing system to the reactors so that ammonia emission will
also be well within the GPCB norms. However, similar types of stacks were
monitored to get the information about emission characteristics including
the emission rates of SPM, SO2 and NOx. The emission rates of SPM, SO2
and NOx and effluent gas characteristics as well as stack details for the
proposed units are presented in Table 4.1. A built-in scrubber will be
installed with spray dryer system. Fugitive emissions of organic gases may
occur through the leaks from pumps, valves etc. However, the industry
being of small scale the fugitive emissions and their impacts would be
negligible.

4.4.5 Micrometeorology

The hourly wind speed, solar insolation and total cloudiness during day
time and wind speed and total cloudiness during night time were used to
determine the hourly atmospheric stability classes (defined by Pasquill and
Gifford as A to F, A being most unstable and F being most stable). The
hourly stability classes were determined based on the technique suggested
by Turner.

Turner’s system used for determining the stability classes is as follows:

- For day or night: If total cloud cover (TC) = 10/10 and ceiling
<7000 ft (2134 m), NR=0

- For night-time (defined as period from one hour before sunset to


one hour after sunrise):

a) If TC<4/10, use NR = -2

b) If TC>4/10, use NR = -1

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- For daytime: determine isolation class number (IN)

a) If TC<5/10, use NR=IN

b) If TC>5/10, modify IN by the sum of the following applicable


criteria
If ceiling<7000 ft (2134m), modification = -2

If ceiling>7000 ft but <16000 ft (4877 m), modification = -1

If TC=10/10 and ceiling>7000 ft, modification = -1, and let modified value
of IN=NR, except for day-time NR cannot be <+1

During the study period stability calculated based on above-mentioned


Turner method gives average stability as B class during Day time and D
class during Night time. The mean mixing height considered for prediction
is 180 m as mean minimum and 1500 m as mean maximum. Average
micro meteorological data of December-2010 to February-2011 is
presented in Table 4.2.

4.4.6 Air Quality Modeling and Predictions using the Gaussian Model

The impact on air quality due to emissions from single source or group of
sources is evaluated by use of mathematical models. When air pollutants
are emitted into the atmosphere, they are immediately diffused into
surrounding atmosphere, transported and diluted due to winds. The air
quality models are designed to simulate these processes mathematically
and to relate emissions of primary pollutants to the resulting downwind air
quality. The inputs include emissions, meteorology and surrounding
topographic details to predict the impacts of conservative pollutants.

The impacts of air pollutants were predicted using Gaussian air dispersion
model, which is selected on the basis of existence of multiple point sources
within the industrial complex and the plain terrain at the project site.

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The Gaussian air dispersion model has been developed to simulate the
effect of emissions from point sources on air quality. Gaussian model
extensively used for predicting the Ground Level Concentrations (GLCs) of
conservative pollutants from point, area and volume sources. The impacts
of primary air pollutants are predicted using this air quality model keeping
in view the plain terrain at the project site. The micrometeorological data
monitored at project site during study period have been used in this model.

The Gaussian model provides estimates of pollutant concentrations at


various receptor locations. It is, an hour-by-hour steady state Gaussian
model which takes into account the following:

- Terrain adjustments

- Stack-tip downwash

- Gradual plume rise

- Buoyancy-induced dispersion, and

- Complex terrain treatment and consideration of partial reflection

- Plume reflection off elevated terrain

- Building down wash

- Partial penetration of elevated inversions is accounted for Hourly


source emission rates, exit velocity, and stack gas temperature

In the present case, prediction of impacts has been carried out December-
2010 to February-2011 on 24-hourly basis in the entire study area of 10
km radius using the Gaussian model.

Gaussian air dispersion models were used to estimate the ambient air
quality levels at different monitoring stations due to stack emissions. Only
two stability conditions based on the meteorology aspects were used to
calculate the theoretical maximum ground level concentration. Comparing
the actual data and data generated from mathematical modeling, it

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San Envirotech Pvt. Ltd-Ahmedabad

highlights that the stability condition E & A-B were predominant in the
region. The maximum ground level concentration of SPM, SO2, NOX & NH3
were away from the source. Using the estimated stack emission data and
wind speed directions, a mathematical model was prepared to establish the
ground level concentration in the region.

4.4.7 Predicted GLCs of proposed dyes plant

It is predicted that the maximum contribution in GLCs, with units operating


at full capacity, is 3.469 μg/m3, 0.817 μg/m3 and 0.661 μg/m3 for SPM, SO2
and NOx respectively and for NH3 maximum GLC will be 1.351 μg/m3. The
point of maximum concentration by unit would be 2.0 km from centre of
industry in E direction for SPM, SO2 and NOx and 1.0 km from centre of
industry in E direction for NH3.

4.5 WATER ENVIRONMENT

Impact on water environment due to the proposed dyes project will be

1. Due to demand for raw water and

2. Due to disposal of treated effluent from the plant.

These are discussed below:

4.5.1 Water Demand

Construction phase

During the construction activities there will be no adverse impact on the


quality of water. No disposal of construction waste outside the plant and no
leaching are anticipated.

Operational Phase

The main source of the water will be ground water. The unit will install its
own bore wells within premises to satisfy its fresh water demand.
Necessary permission will be obtained from CGWA.

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The fresh water demand will be for domestic, gardening and industrial
purpose. Industrial purpose includes water demand for boiler, cooling,
process, washing and RO reject, etc.

The estimated total quantity of the fresh water requirement will be 683.0
KLD. Figure-2.1 in Chapter 2 provides water balance of the proposed
project. However, efforts have to be made to conserve water as much as
possible. Also Chapter 5 proposes some additional mitigation measures to
minimise the raw water consumption. In view of these factors the impact
on water environment due to water use is assessed to be insignificant.

4.5.2 Wastewater Generation – Operational Phase

The industrial wastewater generation from the proposed project will be


about 448.0 KLD. The unit proposes to install its own Effluent Treatment
Plant comprising of primary and secondary treatment units followed by
tertiary treatment facilities. After meeting GPCB norms, the treated effluent
will be disposed to ECP channel to Mahi River.

4.5.3 Effluent Treatment within Unit

Narayan Organics proposes a well-designed Effluent Treatment Plant


providing three stages Physico-Chemical followed by aeration and pressure
sand filter and activated carbon filter treatment.

Wastewater stream is divided into two parts (i) concentrated stream and
(ii) General stream.

Concentrated stream will be neutralized and then treated at Effluent


Treatment Plant along with general stream. After meeting effluent
discharge norms, entire quantity of treated effluent will be discharge to
ECP channel to Mahi River. Whereas the utility stream will not contain any
kind of pollutant load and directly use for plantation and gardening or
mixed with treated effluent.

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The COD/BOD concentration in the influent of the plant ETP will be about
2000-2500 mg/L and 800-1000 mg/L respectively. After treatment COD/
BOD concentration in the effluent becomes COD: 150-250 mg/L and BOD:
40-50 mg/L whereas the TDS in the influent is reduced by approximately
10% in the effluent. Details of effluent quality are given in Table 2.6. The
ETP flow diagram is given in Fig. 2.2 of chapter-2.

Impact on Water Environment

The unit will make all efforts to minimize the quantity of wastewater
generation by adopting proper segregation, collection and treatment
philosophy to ensure that the effluent disposal shall have minimal impacts
on the receiving environment. Thus, considering the treatment facilities
proposes by the unit, it can be said that there would be chances of minor
impact on the water environment.

4.6 NOISE LEVEL IMPACT

4.6.1 Construction Phase

The noise produced during construction may have significant impact on the
existing ambient noise levels. The major work will be carried out during the
daytime. The construction equipment may generate high noise, which can
affect the personnel operating the machines. Use of proper personal
protective equipments will mitigate any adverse impact of noise generated
by such equipment.

The noise level in the working environment is compared with standards


prescribed by ISO 3746. The acceptable limit for each shift being of 8-hour
duration, the equivalent noise level exposure during the shift is 90 dB(A).
Hence noise generation due to excavation may affect workers, if equivalent
8 hours exposure is more then the safety limit. The noise level likely to be
generated during excavation, loading, transportation of construction

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materials will be in the range of 90-100 dB(A) and this will occur only when
all the equipment operate together and simultaneously. This will be a
remote possibility. The worker in general are likely to be exposed to an
equipment noise level of 80-90 dB(A) in an 8 hour shift for which all
statutory precautions as per laws will be taken into consideration.

4.6.2 Operational Phase

The main sources of noise within the plants are: boiler and spray dryer
blower. Suitable noise control system will be provided to ensure that noise
at the ventilation openings does not exceed 90 dB(A) at 1 m distance in
conformity with ISO 3746. The other sources of noise are the movement of
vehicles along the road. The typical industrial noise sources are given in
Table 4.4.

The results of monitoring carried out in the region have been presented in
Chapter-3. The permissible levels in the ambient environment as well as
industrial environment are also presented in Chapter 3. The results are
below the standards prescribed for Industrial environment. It can be
concluded that the impact on noise environment will be long term but
insignificant. The noise standards specified by regulations shall be met. The
mitigation measures being followed / proposed for minimising impacts on
noise quality are provided in chapter 5.

4.7 SOLID WASTE MANAGEMENT

The main source of hazardous waste generation will be ETP sludge. Other
sources will be discarded barrels/bags and spent/waste oil. As discussed in
Chapter-2, the unit proposes to provide adequate area i.e. 800 sqm. for
the storage of hazardous waste having roof cover, impervious floor and
leachate collection system. ETP sludge will be sold to cement
manufacturers or sent to approved TSDF site whereas discarded
barrels/bags will be properly cleaned and sold to approved end users and if

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San Envirotech Pvt. Ltd-Ahmedabad

excess then reuse within premises. Spent/waste oil will also be sold to
CPCB approved recyclers.

Thus, after taking adequate steps for the hazardous waste storage, there
will be minor impact on the environment due to proposed project activities.

4.8 SOCIO-ECONOMIC IMPACTS: CONSTRUCTION & OPERATIONAL


PHASE

Operational phase of the units covers the entire life span of the plant.
Hence the impacts of the operational phase extend over a long period of
time. These impacts include employment generation, effects on basic
infrastructure etc.

The development of industrial area will result in overall prosperity in the


area in terms of infrastructure development, employment generation,
indirect employment communications, medical facilities etc.

The unit will have direct employment of about 90 persons, which will
increase further. It will provide indirect employment as well as
development of well developed road network connecting nearby villages,
faster development of communication facilities and medical facilities.

Pigment manufacturing industry may impose some occupational health


effect on the workers. However, adequate preventive and protective
measures will be assured by the management to avoid the same.

In view of the above the overall impacts on socio-economic environment


due to the pigment manufacturing unit is long term and positive in nature.

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Table – 4.1
Estimated Quality of Air Emission
FLUE GAS STACKS
Sr. Stack attached Flue Velocity of Pollutants
No. to gas stack gas,
PM SO2 NOX
temp.0C m/s
mg/Nm3 mg/Nm3 mg/Nm3
1 Boilers 2 Nos 165 7.5 125 25 20
(3 TPH)
2 Thermic Fluid 180 10.0 120 30 25
Heaters 3 Nos
(10 Lacs
kcal/hr)
3 HAG-3Nos 180 10.0 120 30 25
(6 Lacs kcal/hr)

Process Stacks:

Sr. No. Stack attached to Pollutants, mg/Nm3

1. Process Stack-1 NH3 =50

2. Process Stack-2 NH3=50

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Table – 4.2
The 24-hourly average GLC Concentration Values for SPM
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 3.469 ( .00, 2000.00) GC 26 2.236 (-3000.00,3000.00) GC
2 3.122 ( .00, 3000.00) GC 27 2.205 ( .00, 4000.00) GC
3 2.828 ( .00, 2000.00) GC 28 2.204 ( .00, 5000.00) GC
4 2.737 (-2000.00, 2000.00) GC 29 2.180 ( .00, 2000.00) GC
5 2.716 ( .00, 2000.00) GC 30 2.173 ( .00, 4000.00) GC
6 2.695 ( .00, 1000.00) GC 31 2.171 ( .00, 4000.00) GC
7 2.690 ( .00, 2000.00) GC 32 2.156 ( .00, 3000.00) GC
8 2.678 ( .00, 2000.00) GC 33 2.121 ( .00, 1000.00) GC
9 2.675 ( .00, 2000.00) GC 34 2.104 (-1000.00,1000.00) GC
10 2.632 ( .00, 4000.00) GC 35 2.085 ( .00, 4000.00) GC
11 2.591 ( .00, 2000.00) GC 36 2.075 ( .00, 4000.00) GC
12 2.579 ( .00, 3000.00) GC 37 2.055 (1000.00, 1000.00) GC
13 2.552 ( .00, 3000.00) GC 38 2.034 (-2000.00,2000.00) GC
14 2.546 ( .00, 3000.00) GC 39 2.034 (-3000.00,3000.00) GC
15 2.529 (-2000.00, 2000.00) GC 40 2.029 ( .00, 3000.00) GC
16 2.463 ( .00, 3000.00) GC 41 2.024 ( .00, 3000.00) GC
17 2.438 ( .00, 3000.00) GC 42 2.001 ( .00, 4000.00) GC
18 2.390 ( .00, 2000.00) GC 43 1.991 (-2000.00,5000.00) GC
19 2.310 ( .00, 2000.00) GC 44 1.965 ( .00, 2000.00) GC
20 2.304 ( .00, 3000.00) GC 45 1.930 ( .00, 4000.00) GC
21 2.304 (-1000.00, 1000.00) GC 46 1.927 ( .00, 3000.00) GC
22 2.304 ( .00, 3000.00) GC 47 1.924 ( .00, 1000.00) GC
23 2.283 ( .00, 1000.00) GC 48 1.909 (2000.00, 2000.00) GC
24 2.259 ( .00, 2000.00) GC 49 1.904 ( .00, 1000.00) GC
25 2.253 ( .00, 2000.00) GC 50 1.879 ( .00, 4000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

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Table – 4.3
The 24-hourly average GLC Concentration Values for SO2
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 0.817 ( .00, 2000.00) GC 26 0.529 (-3000.00, 3000.00) GC
2 0.738 ( .00, 3000.00) GC 27 0.523 ( .00, 5000.00) GC
3 0.666 ( .00, 2000.00) GC 28 0.522 ( .00, 4000.00) GC
4 0.645 (-2000.00, 2000.00) GC 29 0.515 ( .00, 4000.00) GC
5 0.639 ( .00, 2000.00) GC 30 0.514 ( .00, 4000.00) GC
6 0.633 ( .00, 2000.00) GC 31 0.514 ( .00, 2000.00) GC
7 0.632 ( .00, 1000.00) GC 32 0.509 ( .00, 3000.00) GC
8 0.631 ( .00, 2000.00) GC 33 0.498 ( .00, 1000.00) GC
9 0.629 ( .00, 2000.00) GC 34 0.494 ( .00, 4000.00) GC
10 0.623 ( .00, 4000.00) GC 35 0.491 ( .00, 4000.00) GC
11 0.611 ( .00, 2000.00) GC 36 0.489 (-1000.00, 1000.00) GC
12 0.610 ( .00, 3000.00) GC 37 0.484 (1000.00, 1000.00) GC
13 0.603 ( .00, 3000.00) GC 38 0.481 (-3000.00, 3000.00) GC
14 0.602 ( .00, 3000.00) GC 39 0.480 ( .00, 3000.00) GC
15 0.596 (-2000.00, 2000.00) GC 40 0.479 (-2000.00, 2000.00) GC
16 0.582 ( .00, 3000.00) GC 41 0.479 ( .00, 3000.00) GC
17 0.576 ( .00, 3000.00) GC 42 0.474 ( .00, 4000.00) GC
18 0.562 ( .00, 2000.00) GC 43 0.473 (-2000.00, 5000.00) GC
19 0.545 ( .00, 3000.00) GC 44 0.462 ( .00, 2000.00) GC
20 0.545 ( .00, 2000.00) GC 45 0.457 ( .00, 4000.00) GC
21 0.544 ( .00, 3000.00) GC 46 0.456 ( .00, 3000.00) GC
22 0.537 ( .00, 1000.00) GC 47 0.452 ( .00, 1000.00) GC
23 0.536 (-1000.00, 1000.00) GC 48 0.451 (2000.00, 2000.00) GC
24 0.531 ( .00, 2000.00) GC 49 0.447 ( .00, 1000.00) GC
25 0.531 ( .00, 2000.00) GC 50 0.445 ( .00, 4000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

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San Envirotech Pvt. Ltd-Ahmedabad

Table – 4.4
The 24-hourly average GLC Concentration Values for NOx
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 0.661 ( .00, 2000.00) GC 26 0.428 (-3000.00,3000.00) GC
2 0.597 ( .00, 3000.00) GC 27 0.423 ( .00, 5000.00) GC
3 0.539 ( .00, 2000.00) GC 28 0.423 ( .00, 4000.00) GC
4 0.522 (-2000.00, 2000.00) GC 29 0.417 ( .00, 4000.00) GC
5 0.517 ( .00, 2000.00) GC 30 0.416 ( .00, 4000.00) GC
6 0.512 ( .00, 2000.00) GC 31 0.416 ( .00, 2000.00) GC
7 0.511 ( .00, 1000.00) GC 32 0.412 ( .00, 3000.00) GC
8 0.510 ( .00, 2000.00) GC 33 0.402 ( .00, 1000.00) GC
9 0.509 ( .00, 2000.00) GC 34 0.400 ( .00, 4000.00) GC
10 0.505 ( .00, 4000.00) GC 35 0.398 ( .00, 4000.00) GC
11 0.494 ( .00, 2000.00) GC 36 0.395 (-1000.00,1000.00) GC
12 0.493 ( .00, 3000.00) GC 37 0.391 (1000.00, 1000.00) GC
13 0.488 ( .00, 3000.00) GC 38 0.390 (-3000.00,3000.00) GC
14 0.487 ( .00, 3000.00) GC 39 0.388 ( .00, 3000.00) GC
15 0.482 (-2000.00, 2000.00) GC 40 0.388 (-2000.00,2000.00) GC
16 0.471 ( .00, 3000.00) GC 41 0.387 ( .00, 3000.00) GC
17 0.466 ( .00, 3000.00) GC 42 0.383 ( .00, 4000.00) GC
18 0.454 ( .00, 2000.00) GC 43 0.383 (-2000.00,5000.00) GC
19 0.441 ( .00, 3000.00) GC 44 0.374 ( .00, 2000.00) GC
20 0.440 ( .00, 2000.00) GC 45 0.370 ( .00, 4000.00) GC
21 0.440 ( .00, 3000.00) GC 46 0.369 ( .00, 3000.00) GC
22 0.434 ( .00, 1000.00) GC 47 0.365 ( .00, 1000.00) GC
23 0.433 (-1000.00, 1000.00) GC 48 0.365 (2000.00, 2000.00) GC
24 0.430 ( .00, 2000.00) GC 49 0.361 ( .00, 1000.00) GC
25 0.429 ( .00, 2000.00) GC 50 0.360 ( .00, 4000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

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San Envirotech Pvt. Ltd-Ahmedabad

Table – 4.5
The 24-hourly average GLC Concentration Values for NH3
RANK CONC RECEPTOR (XR,YR) TYPE RANK CONC RECEPTOR (XR,YR) TYPE
1 1.351 ( .00, 1000.00) GC 26 0.660 ( .00, 1000.00) GC
2 1.103 ( .00, 1000.00) GC 27 0.637 ( .00, 1000.00) GC
3 1.094 ( .00, 1000.00) GC 28 0.629 ( .00, 2000.00) GC
4 1.069 ( .00, 1000.00) GC 29 0.622 ( .00, 1000.00) GC
5 1.058 ( .00, 1000.00) GC 30 0.610 ( .00, 2000.00) GC
6 1.043 ( .00, 1000.00) GC 31 0.608 1000.00, 1000.00) GC
7 1.001 ( .00, 1000.00) GC 32 0.607 ( .00, 2000.00) GC
8 0.931 ( .00, 1000.00) GC 33 0.606 ( .00, 1000.00) GC
9 0.900 ( .00, 1000.00) GC 34 0.605 ( .00, 2000.00) GC
10 0.889 ( .00, 1000.00) GC 35 0.584 ( .00, 1000.00) GC
11 0.883 (-1000.00, 1000.00) GC 36 0.581 ( .00, 1000.00) GC
12 0.840 ( .00, 1000.00) GC 37 0.576 ( .00, 1000.00) GC
13 0.840 (-1000.00, 1000.00) GC 38 0.569 ( .00, 2000.00) GC
14 0.812 ( .00, 1000.00) GC 39 0.552 ( .00, 1000.00) GC
15 0.784 ( .00, 1000.00) GC 40 0.550 ( .00, 2000.00) GC
16 0.742 ( .00, 1000.00) GC 41 0.543 ( .00, 2000.00) GC
17 0.740 ( .00, 2000.00) GC 42 0.531 ( .00, 1000.00) GC
18 0.714 ( .00, 1000.00) GC 43 0.527 (-1000.00,1000.00) GC
19 0.713 ( .00, 1000.00) GC 44 0.519 (-1000.00,1000.00) GC
20 0.709 ( .00, 1000.00) GC 45 0.507 ( .00, 1000.00) GC
21 0.705 ( .00, 1000.00) GC 46 0.489 ( .00, 2000.00) GC
22 0.695 ( .00, 1000.00) GC 47 0.485 ( .00, 2000.00) GC
23 0.692 ( .00, 1000.00) GC 48 0.484 ( .00, 2000.00) GC
24 0.687 ( .00, 1000.00) GC 49 0.470 ( .00, 1000.00) GC
25 0.663 (-1000.00, 1000.00) GC 50 0.464 ( .00, 1000.00) GC
Note: Receptor Types: GC = Grid cart, Concentration in µg/m3

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Figure – 4.1
Isopleths for Ground Level Concentrations for SPM

10000

8000

6000

4000

2000

-2000

-4000

-6000

-8000

-10000
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

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Figure – 4.2
Isopleths for Ground Level Concentrations for SO2
10000

8000

6000

4000

2000

-2000

-4000

-6000

-8000

-10000
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

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Figure – 4.3
Isopleths for Ground Level Concentrations for NOx
10000

8000

6000

4000

2000

-2000

-4000

-6000

-8000

-10000
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

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Figure – 4.4
Isopleths for Ground Level Concentrations for NH3

10000

8000

6000

4000

2000

-2000

-4000

-6000

-8000

-10000
-10000 -8000 -6000 -4000 -2000 0 2000 4000 6000 8000 10000

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Chapter - 5
Environment Management Plan

5.1 INTRODUCTION

Assessment of environmental and social impacts arising due to


implementation of the proposed project activities is at the technical heart
of EIA process. An equally essential element of this process is to develop
measures to eliminate, off set or reduce impacts to acceptable levels
during implementation and operation of projects. The integration of such
measures in to project implementation and operation is supported by
clearly defining the environmental requirements within an Environmental
Management Plan (EMP).

From the previous chapter it can be said that there will be almost minor
impact on the surrounding environment due to proposed project.
However, for the abatement of environmental pollution, M/s. Narayan
Organics Pvt. Ltd., Unit-II would adopt several measures, which are
summarized in this chapter.

M/s. Narayan Organics Pvt. Ltd., Unit-II is equally concern for production
as well as pollution control. The unit has already done the homework to
develop the efficient Environmental Management Plan for its proposed
project. This will be put in to existence as per the requirement after the
execution of the proposal.

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5.2 OBJECTIVES OF EMP

The objectives of the Environmental Management Plan are summarized


here under,
• To limit/reduce the degree, extent, magnitude or duration of adverse
impacts
• To treat all the pollutants i.e. liquid effluent, air emissions and
hazardous waste with adoption of adequate and efficient technology
• To comply with all the norms and standards stipulated by Gujarat
Pollution Control Board / Central Pollution Control Board
• To create good working conditions
• To reduce any risk hazards and design the disaster management plan
• Continuous development and search for innovative technologies for a
cleaner and better environment

5.3 COMPONENTS OF EMP

EMP for the proposed project of M/s. Narayan Organics Pvt. Ltd. covers
following aspects:
• Description of proposed mitigation measures for proposed operation
phase only
• Description of monitoring program
• Institutional arrangements
• Implementation schedule and reporting procedures
All above aspects and objectives are kept in the view and considering the
same EMP is prepared for two major fields.

5.4 ENVIRONMENTAL, HEALTH AND SAFETY MANAGEMENT SYSTEM

Chemical Industries prefer an integrated approach and make


environmental management a part of overall Environment, Health and
Safety (EHS) Management system.

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This model EHS system as suggested addresses EMS issues such as:

- Management system expectation


- Management leadership, responsibilities and accountability
- Risk assessment and management
- Compliance and other requirements
- Personnel, training and contractor services
- Documentation and communications
- Facilities design and construction
- Operation, maintenance and management of change
- Community awareness and emergency response
- EHS performance monitoring and measurement
- Incident investigation reporting and analysis
- EHS management system audit
- Management review and audit

With this type of EHS management approach, proposed Narayan Organics


would be able to integrate the requirements of ISO-14001 into the overall
management system.

5.5 AIR ENVIRONMENT

Environmental management plan for an industrial activity is an integral


part of EIA and has been proved to be an effective tool to mitigate the
adverse environmental impacts arising due to the establishment and
operational phase of the industry. This gives a sequential approach with
feasible options to ensure that the mitigation/control measures overcome
the adverse impacts of the industrial activity and thus achieve the
sustainable operation.

In order to mitigate the adverse environmental impact due to the


operation of the proposed unit following measures are recommended.

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5.5.1Measures for reducing stack emissions

Narayan Organics proposes to establish five stacks to meet the emission


requirement due to various operations. Out of the same three will be flue
gas stacks attached individually to boilers, thermic fluid heaters and hot
air generators. Whereas process gas stacks are attached to process
reactors from where ammonia gas will be liberated. Adequate stack height
of 30.0 m and 15.0 m will be provided to flue gas stacks and process
stacks respectively.

Since biofuel/Coal proposed to be used, less pollution will be generated.


However, on the precautionary bases the unit proposes to install dust
collector as air pollution control measures.

The unit also proposes to install two stage water scrubber followed by acid
scrubber as air pollution control measures to absorb ammonia gas likely to
be generated as process gas.

Thus, air pollution control measures proposed by the unit will be adequate
to obtain gaseous emission norms recognized by GPCB.

Moreover, Narayan Organic’s maximum contribution in ambient air quality


will be 3.469 μg/m3, 0.817 μg/m3 and 0.661 μg/m3 for SPM, SO2 and NOx
respectively and for NH3 maximum GLC will be 1.351 μg/m3. The point of
maximum concentration by unit would be 2.0 km from centre of industry
in E direction for SPM, SO2 and NOx and 1.0 km from centre of industry in
E direction for NH3. As per the analysis of similar type facilities, emissions
coming out from the stack of boilers, heaters and also on the basis of
characteristics of the fuel, it is observed that SO2, NOx and PM emissions
are well within the permissible limits (as prescribed by CPCB). However, in
order to achieve further reduction, it is suggested that regular
maintenance and periodic tuning of the burner system should be done to

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San Envirotech Pvt. Ltd-Ahmedabad

ensure proper atomization and subsequent minimization of any unburned


combustibles. Besides reduction in particulate emissions, it would also
result in better operating efficiency. For this, combustion process may be
further improved by adopting following measures:

Optimization of combustion aerodynamics should be done using a flame


retention device.

Primary flame zone O2 level should be decreased by decreasing overall O2


level, controlling (delaying) mixing of fuel and air, and use of fuel-rich
primary flame zone.

Flue gas volume should be checked for amount of air needed for the
complete combustion of the fuel.

The unit may also implement energy conservation measures through


installation of heat recovery systems. This would reduce the fuel
consumption and in turn the emissions.

Injury Symptoms and Pollutant Dose Thresholds of Tolerance by


Sensitive Species of Plants

Pollutant Threshold Dose Plant Injury Symptoms


3
Sulphur Dioxide 0.70 ppm (1820 μg/m ) for Interveinal necrotic blotches
(SO2) 1 hr.; Red brown dieback or
0.18 ppm (468 μg/m3) for banding in pines
8 hr.;
0.008 – 0.017 ppm (21/44
μg/m3) for growing season
Nitrogen Oxides 20 ppm (38 x 103 μg/m3) Interveinal necrotic blotches
(NOX) for 1 hr.; similar to those by SO2
1.6 – 2.6 ppm (3000-5000
μg/m3) for 48 hr.;
1 ppm (1900 μg/m3) for
100 hr.

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-5


San Envirotech Pvt. Ltd-Ahmedabad

What type of plants should be planted?

There are certain plants that are sensitive to certain air pollutants, e.g.
gladiolus is sensitive to HF. However, it is difficult to identify species that
are selectively tolerant to certain air pollutants. Moreover, an industrial
area invariably emits several pollutants rather than a single one. Green
belts as a pollution sink hence, should aim at cultivating plants that are
tolerant to air pollutants in general, rather than tolerant to SO2, to HF or
to O3, etc. Scattering of a few known sensitive plants (including selectively
sensitive species for SPM, SO2, and NOX) within a green belt however, do
carry out an important function of indicating the presence of pollutants,
which the tolerant would not indicate.

Characters of plant including shapes of crowns considered necessary for


effective absorption of pollutant gases and removal of dust particles are as
follows:

For absorption of gases

1. Tolerance towards pollutants in question, at concentrations, that are


not too high to be instantaneously lethal;
2. Longer duration of foliage;
3. Freely exposed foliage, through
a. adequate height of crown,
b. openness of foliage in canopy,
c. big leaves (long and broad laminar surfaces, with larger leaf area
index),
d. large number of stomatal apertures,
e. Stomata well exposed (in level with the general epidermal surface).

For removal of suspended particulate matter

1. Height and spread of crown;

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San Envirotech Pvt. Ltd-Ahmedabad

2. Leaves supported on firm petioles;


3. Abundance of surfaces on bark and foliage, through
a. roughness of bark,
b. epidermal outgrowths on petioles,
c. abundance of auxiliary hairs,
d. hairs or scales on laminar surfaces,
e. Stomata protected (by wax, arches / rings, hairs, etc.).

Note: All tolerant plants are not necessarily good for green belts, e.g.
Xerophytes with sunken stomata can withstand pollution by avoidance but
are poor absorbers of pollutants due to low gaseous exchange capacity.

While making choice of plant species for cultivation in green belts,


weightage has to be given to the natural factor of bio-climate. Moreover,
the species should be indigenous to that area and most of them should be
quick growing. Attention should also be focused to their economic or
aesthetic value. A good green belt should have a well-proportioned mix of
trees and shrubs of different heights, and evergreen and deciduous.
Hence, considering the bio-climatic characteristics of the project region,
the following plants might be used for green belt development:

Scientific Name Common Tree/ Evergreen/ Height Canopy


Name Shrub Deciduous (in m) Shape
Abutilon indicum Khapat Shrub Deciduous 5 Oblong
Acacia nilotica Baval Tree Evergreen 8 Spreading
Adenanthera pavonina Badigumehi Tree Deciduous 20 Spreading
Aegle marmelos Bili Tree Evergreen 12 Oblong

Albizia lebbeck Pilosarasio Tree Deciduous 20 Round/


Spreading
Azadirachta indica Limbado Tree Deciduous 20 Spreading
Balanites roxburghii Ingoriyo Tree Evergreen 9 Spreading
Bauhinia racemosa Asundro Small Deciduous 5 Oblong
tree
Cassia fistula Garmala Tree Deciduous 12 Round
Casurina equisetifolia Jangli saru Tree Evergreen 10 Oblong
Derris indica Karanja Tree Evergreen 10 Round
Emblica officinalis Amali Tree Deciduous 5 Oblong

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-7


San Envirotech Pvt. Ltd-Ahmedabad

Erythrina variegata Bangaro Tree Deciduous 10 Oblong


Ficus benghalensis Vad Tree Evergreen 20 Spreading
Grewia subinequalis Phalsa Shrub Evergreen 7 Round
Heterophragma Warras Tree Evergreen 18 Round/
roxburghii Oblong
Lawsonia inermis Medi Shrub Evergreen 5 Round
Madhuca longifolia Mahuda Tree Deciduous 15 Round/
Oblong
Murrya paniculata Chulajuti Shrub Evergreen 5 Round
Nyctanthus arbor- Harsingara Shrub Deciduous 5 Oblong/
tristis Round
Phyllanthus acidus HarparawariTree Deciduous 8 Oblong
Poinciana pulcherrima Sandheshar Shrub Evergreen 3 Oblong
Prosopis cineraria Sami Tree Evergreen 12 Spreading
Psidium guajava Perala Tree Evergreen 5 Oblong
Ricinus communis Diveligo Shrub Evergreen 6 Oblong
Sesbania sesban Jayati Shrub Evergreen 6 Oblong
Soymida febrifuga Rohina Tree Deciduous 15 Round/
Oblong
Syzygium cumini Jambu Tree Evergreen 20 Oblong/
Spreading
Tamarindus indica Amli Tree Evergreen 20 Spreading
Tectona grandis Saga Tree Deciduous 20 Oblong/
Round
Terminalia arjuna Sadado Tree Deciduous 15 Oblong/
Round
Trema orientalis Gol Tree Evergreen 6 Round/
Oblong
Zizyphus mauritiana Bordi Tree Evergreen 10 Round
Var. Fructicosa
Green belt developed with the above plant species should include the
following plants also as those are sensitive to air pollutants. These plants
should be scattered among the above plants.

Scientific Common Tree / Evergreen/ Height Canopy Sensitive


Name Name Shrub Deciduous (in m) Shape to
Dalbergia Sisam Tree Evergreen 10 Round SO2/SPM
sisoo
Delonix Gulmohur Tree Deciduous 15 Spreading/ SO2/Flyash
regia Flat topped
Magnifera Amri Tree Evergreen 15 Round/ SO2/Coal
indica Oblong dust

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-8


San Envirotech Pvt. Ltd-Ahmedabad

How and Where to be planted: The standard practice for green belt
development involves planting of saplings in pits of substantial dimensions
i.e. 1m x 1m x 1m for big trees and almost half of these dimensions for
smaller trees and shrubs. The pits should then be filled with earth, sand,
silt and manure in the pre-determined proportions. Saplings planted in
such pits are to be watered liberally. The growing plants should be
nurtured for three years and should be cared and protected against any
damage caused by domestic elements.

For effective removal of pollutants, it is necessary that


1. Plants grow under conditions of adequate nutritional supply (for
health and vigour of growth);
2. Absence of water stress (to maintain openness of stomatal apertures
and form of epidermal structures); and
3. Plants are well-exposed to atmospheric conditions of light and
breeze (i.e. away from engineering structures hindering free flow of
air) to maintain free interaction with gases.

Industry has sufficient space to systemically develop green belt, the above
mentioned plant species should be planted wherever the space and
conditions permit. In order to increase efficiency of the green belt, shrubs
should be inserted between big trees. If space permits for more than one
row, smaller trees should be planted inside while taller trees on the
outside with respect to emission sources.

5.5.2 Measures for fugitive emissions

The fugitive emissions of organic chemicals and VOCs come from leakage
through valves, fittings, pumps, etc. Though this is not expected to be
significant, adopting the following measures may reduce it further:

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San Envirotech Pvt. Ltd-Ahmedabad

Regular maintenance of valves, pumps and other equipment should be


undertaken to prevent leakage and thus minimize the fugitive emissions of
VOCs.

In case the units undertake modernization, design features as suggested


in Table 5.1 for new equipment may be considered.

5.6 WATER ENVIRONMENT

The mitigative measures for minimizing the impacts on water environment


in general includes following:

- Minimization of water use


- Segregation and collection philosophy for effluent to minimize waste
generation and facilitate treatment as well as recycle
- Treatment philosophy to achieve mandated standards
- Reuse/recycle and disposal

Some of the measures, which are to be implemented, include:

- Use equipment wash down waters as makeup solutions for subsequent


batches.
- Use high-pressure air-water jet for equipment cleaning to reduce the
amount of wastewater generated.
- Reducing the actual process water consumption by way of improvement
in operation of processing units
- Ensuring proper operation and maintenance schedule for the ETP.
- Artificial recharge of water.

5.6.1 Segregation and Collection Philosophy

A segregated drainage system is suggested wherever feasible to achieve


following objectives:

- Optimise the treatment process

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San Envirotech Pvt. Ltd-Ahmedabad

- Minimise generation of secondary wastes such as sludge


- Facilitate reuse/ recycle of process effluents and consequently minimise
impacts associated with disposal

The segregation of effluents in small units is not always practical and


feasible. It has to be implemented after careful study of effluents at each
unit. The emphasis has to be on resource recovery potential. The units
shall utilize the concept of waste minimization circles. The suggestions
provided in Comprehensive Industry Document by CPCB should also be
applied depending on technical feasibility.

5.6.2 Wastewater Treatment

Entire effluent will be divided into three streams (i) Concentrated stream
and (ii) General stream. The unit proposes to provide its own Effluent
Treatment Plant comprising of primary and secondary treatment units
followed by tertiary treatment units.

Concentrated stream will be separated and then neutralized. After


neutralization, it will be mixed with general stream and treated at Effluent
Treatment Plant. Whereas third stream i.e. utility stream which will not
contain any kind of pollution load, will be used for gardening or plantation
within premises and/or stored in treated effluent collection sump. Entire
effluent after confirming effluent discharge norms will be discharged to
ECP channel to Mahi River.

5.6.3 Artificial water recharge

The average long-term rainfall, out of which 20% of the rainfall is


considered to go to the ground as a natural recharge and remaining
rainfall runoff and this is available for the artificial recharge after
accounting for soil moisture storage and evaporation.

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San Envirotech Pvt. Ltd-Ahmedabad

Thus approximately 100% of the water use for the factory is available for
artificial recharge from rainfall which can be put into the ground water
reservoir directly by construction of “Injection tube well”. The opener
must be fitted with filter pit.

The location of such injection bore well must be decided considering the
slope of the ground in the factory premises so that the accumulated
flowing rain water can be injected in to bore well.

Surface Geology and Geohydrolocal condition is prime importance in


successful implementation of artificial recharge scheme. The regional
hydro geological map provide details of ground water aquifer system,
ground water potential, ground water flow and chemical analysis of water
in different aquifers. It is suggested to do above survey before deciding
the location of such inject bore well. It will helpful for selection of location
and proper designing of artificial injection bore wells.

5.7 SOLID WASTE MANAGEMENT

Solid Waste management includes following:

- Measures to minimize waste generation


- Operation of waste handling, treatment and disposal facilities

As discussed in Chapter-2, adequate area for the storage of hazardous


waste will be provided having roof covered impervious floor and leachate
collection system. The ETP sludge will be sent to cement manufacturers or
sent to approved TSDF site for the disposal whereas discarded
bags/drums/liners will be sold to approved reusers or reused within
premises for the storage of sludge and spent/waste oil will be sold to CPCB
approved recyclers. Thus, hazardous waste management plan proposed by
the unit will be adequate.

However, the Waste Management plan should also include:

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San Envirotech Pvt. Ltd-Ahmedabad

- Waste Inventory
- Classification of waste
- Packaging, Storing and Transporting Wastes to Disposal site
- Selecting a Hazardous Waste Management Facility – Final Disposal
- Data Management and Reporting
- Contingency Plan
- Personnel Training
- Waste Minimization

The condition specified in the Authorization from GPCB shall be followed.


The manifest system shall be implemented for control and record keeping.

5.8 NOISE ENVIRONMENT

The main sources of noise within the plant are: boiler, manufacturing
activities, transferring pumps and material handling systems. Additional
noise will be generated due to installation of new machineries and
equipments however, these impacts will be very minor and temporary in
nature. The impact on the environment during the operational phase will
be long term but, of insignificant quantity.
To minimize the noise pollution, the unit proposes the following noise
control measures:
• Noise suppression measures such as enclosures, buffers and/or
protective measures should be provided (wherever noise level is more
than 90 dB (A)).
• Employees should be provided with ear protection measures like
earplugs or earmuffs. Earplug should be provided to all workers where
exposure is 85 dB (A) or more.
• The transportation contractor shall be informed to avoid unnecessary
speeding of the vehicles inside the premises.

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San Envirotech Pvt. Ltd-Ahmedabad

• Extensive oiling, lubrication and preventive maintenance will be


carried out for the machineries and equipments to reduce noise
generation.
• The selection of any new plant equipment will be made with
specification of low noise levels.
• Areas with high noise levels will be identified and segregated where
possible and will include prominently displayed caution boards.
• The green belt area will be developed within industrial premises and
around the periphery to prevent the noise pollution in surrounding
area.
Monitoring of noise levels is essential to assess the efficacy of
maintenance schedules undertaken to reduce noise levels and noise
protection measures. A good quality digital sound pressure level meter is
essential for this purpose.

5.9 GREEN BELT DEVELOPMENT

Tree plantation is one of the effective remedial measures to control the air
pollution and noise pollution. It also causes aesthetics improvement of the
area as well as sustains and supports the biosphere.
Plantation around the pollution sources control the air pollution by filtering
the air particulate and interacting with gaseous pollutant before it reaches
the ground.
Each plant shows different air pollution tolerance level depending upon
number of factors. In green belt area about 1000 trees per acre of land as
prescribed by Gujarat Pollution Control Board shall be planted. The
selection of tree species suitable for plantation at the industry shall be
governed by following factors,
• The trees should be tolerant to air pollutants present in the area
• The trees should be able to grow and thrive on soil of the area, be
evergreen, inhabitant and having minimum of leaf fall.

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San Envirotech Pvt. Ltd-Ahmedabad

• The trees should be tall in peripheral curtain plantation and with large
and spreading canopy in primary and secondary attenuation zone
• It is also recommended to plant few trees, which are sensitive to air
pollution as air pollution indicator.
The unit have extensive greenbelt plantation in 11220 sqm, which is
around 33% of total land area. Local spices are planted and survival rate
is more than 65%.

5.10 RESOURCE CONSERVATION / WASTE MINIMIZATION

The units shall also implement the concept of waste minimization circle.
Good Housekeeping or proper housekeeping practice makes the system
easier and less costly. Some of these are as follows:
• Rain water harvesting system shall be adopted to reduce the fresh
water requirement.
• Cleaner production technology shall be adopted for the resource
conservation and pollution control.
The process emission containing Ammonia mainly. The Ammonia gas gets
absorbed in the water and results in Liq. Ammonia solution (12–15%) or
reaction with spent sulfuric acid and convent to Ammonium Sulphate as by
products. This Ammonia solution will be recovered as By- Product and sold
to actual end users. Thus, this is the step towards waste minimization and
resource conservation.

5.11 HEALTH & SAFETY

M/s. Narayan Organics Pvt. Ltd., Unit-II will follow occupational health
program right from the start of production. Health hazards associated with
occupation are called occupational hazards. The following check-ups shall
be carried out regularly to avoid occupational hazards:
• Pre-employment medical check-up at the time of employment
• Provision of periodic medical check up for all the employees

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San Envirotech Pvt. Ltd-Ahmedabad

• To provide necessary first aid facilities, the first aid training shall also
be given to the employees
• Monitoring of occupational hazards like noise, ventilation, chemical
exposure shall be carried out at frequent intervals.
• The unit will appoint the medical officer for the regular medical
examination and treatment of the employee.

The following precautions shall be taken to avoid foreseeable accident like


spillage, fire and explosion hazards and to minimize the effect of any such
accident and to combat the emergency at site level in case of emergency.
• Various emergency spots in plant area will be identified and kept in
sharp and alert watch
• Use of protective equipments will be regularly checked and will be kept
easily accessible and easily workable during emergency
• Safety installations like available quantity of running water will be
regularly watched
• Fire bucket and hose reels will be provided to withstand the fire or
explosion conditions
• Various types of fire extinguishers such as (Foam type, water type,
CO2 type) will be provide inside the factory premises
• Every pressure vessel will be provided with minimum one or more
pressure relief devices. The design of the valve is made in such a way
that the breakage of any part will not obstruct force discharge of the
liquid under pressure. Moreover, relief valves are tested and a periodic
schedule for their testing shall be maintained. The defective valves will
be removed if found unsafe for the operation.

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San Envirotech Pvt. Ltd-Ahmedabad

5.11.1Possibility of occupational health hazard & its control

Following are major health hazards involve in our proposed activities


mainly
Chemical agents: There are possibility to generate gases, vapours,
liquids and aerosols (dusts, fumes, mists). We will take care to reduce it
at optimum minimum level and advice to workers to use PPE who work
in such identify area.

Noise & Heat: Noise is considered as any unwanted sound that may
adversely affect the health and well-being of individuals or populations.
Aspects of noise hazards include total energy of the sound, frequency
distribution, duration of exposure and impulsive noise. Hearing acuity is
generally affected first with a loss or dip at 4000 Hz followed by losses in
the frequency range from 2000 to 6000 Hz. Noise might result in acute
effects like communication problems, decreased concentration,
sleepiness and as a consequence interference with job performance.
Exposure to high levels of noise (usually above 85 dB(A)) over a
significant period of time may cause both temporary and chronic hearing
loss. Permanent hearing loss is the most common occupational disease in
compensation claims.
In our case there will be no high noise level issue or heat or radiation.
However we will identify such are like D.G. Sets, utilities area and advice
to workers to not enter without PPE.

Occupational surveillance involves active programmes to anticipate,


observe, measure, evaluate and control exposures to potential health
hazards in the workplace. Depending upon the occupational environment
and problem, two surveillance methods can be employed: medical and
environmental. Medical surveillance is used to detect the presence or

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-17


San Envirotech Pvt. Ltd-Ahmedabad

absence of adverse health effects for an individual from occupational


exposure to contaminants, by performing medical examinations and
appropriate tests. Environmental surveillance is used to document
potential exposure to contaminants for a group of employees, by
measuring the concentration of contaminants in the air, in bulk samples
of materials, and on surfaces.
Medical surveillance is performed because diseases can be caused or
exacerbated by exposure to hazardous substances. We will appoint part
time doctor who are knowledgeable about occupational diseases,
diagnoses and treatment.

5.11.2Preventive Measures

The methods of protecting the work force from exposure to toxic agents in
the workplace apply to the use of solvents:—

• Segregation of processes using solvents;


• Enclosures or special ventilator control of processes;
• Good general ventilation — particularly important if the solvent is
used in a confined space;
• Personal protection — Protective clothing should be worn, including
gloves, where there is a possibility of absorption through the skin.
Suitable respiratory protection is necessary like Panorama gas mask
with cartridge suitable for the chemicals we will be handling,
Breathing Air Apparatus and Air Hood with instrument air connection.
• Gas detector with emergency alarm systems in confined area.
• Emergency preparedness plan.

5.12 OCCUPATIONAL HEALTH PROGRAMME


Some of the philosophies underlining the occupational health programme
are discussed below.

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-18


San Envirotech Pvt. Ltd-Ahmedabad

M/s. Narayan Organics Pvt. Ltd. will employ well qualified and experienced
safety Manager and make arrangement for part time doctor for regular
checking of health of the employees. Also, plans to become member of
any local hospital for emergency need. Annual health check for employees
will be carried out and record will be maintained. Regular training to plant
personnel in safety fire fighting and first aid will be provided.

Unit will maintain a healthy work environment. This will be accomplished


through the identification, evaluation and control of workplace
environmental factors which may cause sickness, impaired health or
significant discomfort and inefficiency among workers. Environmental
factors such as noise, physical hazards toxicity/ chemical hazard and
ergonomic hazards will be monitored on a periodic basis to assist in
maintaining a healthy work environment. Workers exposed to noise and
toxic materials will be evaluated against applicable recognised exposure
levels in the Factories Act. Hearing protection aid will be provided to
workers who work in the high noise areas, during construction of the
proposed facilities and also to those who will continue through the life of
the facility.

5.12.1Hazard Communication and Chemical Safety


The information on the hazards of the materials to be used will be
provided to the workers for the proposed project of M/s. Narayan Organics
Pvt. Ltd. A hazardous chemical directory is being developed to maintain
information on the hazards associated with each chemical used. Copies of
Material Safety Data Sheets for all hazardous materials at the proposed
facility will be kept at the unit and will be available for employee review.
Specific programs and procedures for the control of health hazards
associated with potentially harmful materials such as Acids, Alkali and

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San Envirotech Pvt. Ltd-Ahmedabad

volatile chemicals etc. will follow the guiding principles established for
Occupational Health. The hazard communication program will serve as the
basis for selection of personal protective equipment such as gloves,
goggles, face shields, etc. A selected group of employees at the proposed
facility will receive first aid training to provide an immediate response and
medical care for injuries.

5.13 POST-PROJECT ENVIRONMENTAL MONITORING

The post – project environmental monitoring suggested herewith should


be as per the following guideline. The highlights of the integrated
environmental monitoring plan are:
• The stack monitoring facilities like ladder, platform and port – hole of
all the stacks maintained in good condition.
• Regular monitoring of all gaseous emissions from stacks / vents and all
fugitive emissions in the process areas.
• The performance of air pollution control equipment evaluated based on
these monitoring results.
• Water consumption in the complex recorded daily.
• Analysis of untreated and treated effluent, before discharge into the
final disposal pipeline carried out regularly.
• Performance of effluent treatment plant units evaluated based on
these analysis results.
• As far as possible, noise curbed at its source, with the help of acoustic
hood and other such noise reducing equipments.
• Regular noise level monitoring to be carried out.
• Green belt properly maintained and new plantation programmes
undertaken frequently.
• Continued environmental awareness programmes carried out within
the employees and also in the surrounding villages.

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San Envirotech Pvt. Ltd-Ahmedabad

• Rain water harvesting ponds will be developed within the industrial


premises and encouraged in the surrounding villages too. All possible
back–up and support provided to them.
Ambient Air Quality monitoring
Schemes for monitoring ambient air quality stack emissions and fugitive
emissions are proposed. The ambient air quality monitoring systems are
recommended for monitoring the ground level concentrations and fugitive
emissions around the plant. M/s. Narayan Organics Pvt. Ltd. should install
three monitoring stations around its battery limit (at 1200 as per
guideline) for monitoring SPM, SO2 and NOX. The combined data will
provide overall characteristic and emission from the industry.
For this, the following equipment is recommended to be procured or can
higher the services from Environmental consultant by the project
proponent for implementing the above mentioned monitoring schemes:

• Respirable dust sampler


• Blower -1.0-1.5 m3/min capacity with adapter for uniform suction
through filter and a properly calibrated manometer assembly for the
determination of flow rate through filter paper.
• Rota meter- For gaseous sampling, calibrated Rota meter (0-5 LPM)
for maintaining flow rate should be provided
• Main housing-The main housing should be rectangular with a stand of
about 1.25 m height.
• Besides this, stack emissions monitoring as per GPCB guidelines shall
be carried out.
• Noise Environment
• Monitoring of noise levels is essential to assess the efficacy of
maintenance schedules undertaken to reduce noise levels and noise
protection measures. A good quality digital sound pressure level meter
is essential for this purpose.

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-21


San Envirotech Pvt. Ltd-Ahmedabad

• Water Environment
• Wastewater should be analyzed at the ETP discharge regularly.

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-22


San Envirotech Pvt. Ltd-Ahmedabad
Deleted: 1
Table 5-1111: Design features for minimization of fugitive emissions

Equipment Design Features Control


Efficiency, %
Pumps Sealless design 100
Dual Mechanical Seal 100
Valves Sealless Design 100
Compressor Dual Mechanical Seal 100
Connectors Weld together 100
Pressure Relief Rupture Disc 100
Devices
Sampling Connection Closed loop sampling 100

Table – 5.2:- Environment Monitoring


Nature of Analysis Frequency of Number of Sample
Analysis
Stack Monitoring Monthly At all stack
Industrial Effluent for Ones in a Month One Sample
applicable parameters as
per the Consents
Conditions
Ambient Air Quality Monthly for 24 hours 3 Location
Monitoring or as per the
statutory conditions

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-23


San Envirotech Pvt. Ltd-Ahmedabad

Figure – 5.1:- EHS Management

Technical Director

Director

Environment Management Cell

Officer - Officer-
Safety
Environment

Chemist-
Environmental

Supervisor

REIA of Narayan Organics Pvt. Ltd., Unit-II 5-24


SAN Envirotech Pvt. Ltd, Ahmedabad

Chapter - 6
QUANTITATIVE RISK ASSESSMENT
6.1 INTRODUCTION
M/s. Narayan Organics Pvt. Ltd. is the proposed unit for Pigment
manufacturing to be located at Block No. 164 to 170, Village: Vedach,
Taluka: Jambusar, Dist: Bharuch, State: Gujarat.
The risk assessment studies have been conducted for identification of
hazards, to calculate damage distances and to spell out risk mitigation
measures.

6.1.1 SCOPE OF STUDY

The scope of work is to carry out risk analysis for the proposed project
of the production facility covering all the hazardous chemicals to be
handled and stored at the plant.

6.1.2 STUDY OBJECTIVE

The objective of the risk analysis includes the following:


• Identification of hazards
• Selection of credible scenarios
• Consequences Analysis of selected accidents scenarios
• Risk Mitigation Measures

6.1.3 THE STUDY APPROACH

The risk assessment study broadly comprises the following steps:


• System Description
• Identification of Hazards
• Selection of Credible Accident Scenarios
• Consequence Analysis
• Risk Mitigation Measures

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SAN Envirotech Pvt. Ltd, Ahmedabad

6.1.4 SYSTEM DESCRIPTION

This step comprises the compilation of the location, design and


operational information needed for the risk analysis.

6.1.5 IDENTIFICATION OF HAZARDS

Hazards associated with the plant are identified and summary of


relevant accident cases are reviewed.

6.1.6 SELECTION of ACCIDENT SCENARIOS

The release sources and potential accidents scenarios in the plant are
listed. For each selected release source several scenarios are developed
depending upon the failure mode causing loss of containment.

6.1.7 EFFECTS & CONSEQUENCE ESTIMATION

Effects & consequence estimation are done to determine the potential


for damage or injury from the selected scenarios. The incident outcomes
are analyzed using release rate, dispersion, combustion, and heat
radiation and explosion models from fires.

6.1.8 RISK REDUCTION MEASURES

Based on hazard identification and consequence analysis, risk reduction


measures are suggested to reduce risk and enhance safety at the plant.

6.2 HAZARDOUS IDENTIFICATION

Hazard is defined as those chemical or physical conditions that have the


potential for causing damage to people, property or the environment.
This chapter describes hazards associated with the plant due to handling
and storage of hazardous chemicals. Maximum credible accidents
scenarios involved in release of hazardous materials are selected and
vulnerable zones are computed.
Hazard identification is the first step in the risk analysis and entails the
process of collecting information on the types and quantities of
hazardous substances stored and handled, the location of storage tanks

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SAN Envirotech Pvt. Ltd, Ahmedabad

& other facilities, potential hazards associated with the spillage and
release of hazardous chemicals.
The assessment of vulnerable zones resulting from an accidental release
of hazardous substance into the environment is one of the key elements
of risk analysis. Quantification of the effects of such releases requires,
data of the chemicals stored or handled in the area, quantities stored,
operating parameters, quantity that would be released in case of an
accident, meteorological conditions and physical attributes of the area.
The starting point of risk analysis study is the identification of hazards
and selection of scenarios that are then addressed for further
consequence analysis.
The proposed plant will be engaged in handling and storage of various
flammable and toxic hazardous materials. Important characteristic of
these hazardous materials are described in details.

6.2.1 HAZARDOUS SUBSTANCES To BE HANDLED at NARAYAN


ORGANICS

M/s. Narayan Organics will be engaged in the production of pigment


manufacturing plant. During operation phase various hazardous
chemicals will be required to be handled. Important characteristics of
these hazardous materials are described in details,

I) Ortho Nitro Toluene


MSDS: 2-Nitrobenzyl Chloride, 98 %

CAS: 612-23-7

Synonyms: o-Nitrobenzyl chloride, Toluene, alpha-chloro-o-nitro

Physical and chemical properties:

Color: Yellow color

Odor: None reported.

Vapor Density: Not available.


Evaporation Rate: Not available.

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Viscosity: Not available.


Boiling Point: 127.0 - 133.0 deg C @ 10.00mm
Freezing/Melting Point: 46.00 - 48.00 deg C
Decomposition Temperature: Not available.
Solubility: Insoluble.
Specific Gravity/Density: Not available.
Molecular Formula: C7H6ClNO2
Molecular Weight: 171.58

Stability and reactivity:

Chemical Stability: Stable, however, may violently decompose at


temperatures above 125 oC.

Conditions to Avoid: Incompatible materials, metals, oxidizers, amines.

Incompatibilities with Other Materials: Bases, alcohols, amines, steel,


oxidizing agents (strong, e.g. bromine, hydrogen peroxide, nitrogen
dioxide, potassium nitrate), moisture.

Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides,


carbon monoxide, carbon dioxide, chloride fumes.

Hazardous Polymerization: Has not been reported.

Potential Health Effects

Eye: Lachrymator (substance which increases the flow of tears). Causes


severe eye irritation and possible burns.

Skin: Causes severe skin irritation and possible burns.

Ingestion: Causes gastrointestinal irritation with nausea, vomiting and


diarrhea.

Inhalation: May cause burning sensation, coughing, wheezing,


laryngitis, shortness of breath, headache, nausea and vomiting.

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Causes severe respiratory tract irritation with possible burns.

Chronic: Effects may be delayed.

First Aid Measures

Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or
keep eyes closed. Gently lift eyelids and flush continuously with water.
Ex tensive irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing and
shoes. Wash clothing before reuse. Destroy contaminated shoes.

Ingestion: Never give anything by mouth to an unconscious person. Get


medical aid immediately. Do NOT induce vomiting. If conscious and
alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Get medical aid immediately. Remove from exposure and
move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

II) Iso Butyl Alcohol

CAS: 78-83-1

Synonyms: 2-Methyl-1-propanol

Formula: (CH“)’CHCH’OH

Physical and chemical properties:

Melting Point: -162.4 oF

Boiling Point: 225.86 oF

Vapour Pressure: 8.8

Specific Gravity: 0.802

Vapour Density: 2.55

Solubility in water: 8.5%

Appearance and odor: Colorless liquid, mild alcohol

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Flash Point: 81.86 oF

Evaporation rate: 0.8

Hazard Identification

Keep away from heat and ignition sources. Harmful if swallowed. Avoid
breathing vapors. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothes. Wash thoroughly after handling. Keep container
closed.

First Aid Measures

Keep away from heat and ignition sources. Harmful if swallowed.

Avoid breathing vapors. Use with adequate ventilation.

Avoid contact with eyes, skin, and clothes.

Wash thoroughly after handling. Keep container closed.


FIRST AID: CALL A PHYSICIAN.

SKIN: Remove contaminated clothing. Wash exposed area with soap


and water.

EYES: Wash eyes with plenty of water for at least 15 minutes, lifting lids
occasionally. Seek Medical Aid. INHALATION: Remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen

INGESTION: If swallowed, induce vomiting immediately after giving two


glasses of water. Never give anything by mouth to an unconscious
person.

Fire Fighting Measures


Fire Extinguisher Carbon Dioxide, dry chemical powder or
Type: appropriate foam

Fire/Explosion Heat will build pressure and may rupture closed


Hazards: storage containers

Wear self-contained breathing apparatus and


Fire Fighting
protective clothing to prevent contact with skin
Procedure:
and clothing.

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Accidental Release Measures

Evacuate area. Wear self-contained breathing apparatus and protective


clothing. Eliminate all sources of ignition.

Handling and Storage

Store in a cool dry well ventilated area. Keep away from heat and flame.
Do not get in eyes, on skin, or on clothing.

Stability and Reactivity Information

Stability: Stable

Conditions to Avoid: Avoid contact with heat, sparks, flames, or other


sources of ignition

Materials to Avoid: Oxidizing materials

Hazardous Decomposition: Carbon monoxide and other toxic vapor

III) Sulphuric Acid (60 -70 %)


Sulphuric acid is colorless and odorless liquid and identified as a
corrosive hazard of class 8. As a result of spillage on the ground, it
evaporates and forms a toxic vapor cloud.
Physical & Chemical Properties
Appearance: Clear oily liquid.
Odor: Odorless.
Solubility: Miscible with water, liberates much heat.
Specific Gravity: 1.84 (98%), 1.40 (50%), 1.07 (10%)
Boiling Point: ca. 290C (ca. 554F) (decomposes at 340C)
Melting Point: 3C (100%), -32C (93%), -38C (78%), -64C (65%).
Vapor Density (Air=1): 3.4
Vapor Pressure (mm Hg): 1 @ 145.8C (295F)
Potential Hazards Effects
Inhalation: Inhalation produces damaging effects on the mucous
membranes and upper respiratory tract. Symptoms may include
irritation of the nose and throat, and labored breathing. May cause lung
edema, a medical emergency.

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Ingestion: Corrosive. Swallowing can cause severe burns of the mouth,


throat, and stomach, leading to death. Can cause sore throat, vomiting,
diarrhea. Circulatory collapse with clammy skin, weak and rapid pulse,
shallow respirations, and scanty urine may follow ingestion or skin
contact. Circulatory shock is often the immediate cause of death.

Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn


can occur. Circulatory collapse with clammy skin, weak and rapid pulse,
shallow respirations, and scanty urine may follow skin contact or
ingestion. Circulatory shock is often the immediate cause of death.

Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain
and severe tissue burns. Can cause blindness.

Chronic Exposure: Long-term exposure to mist or vapors may cause


damage to teeth. Chronic exposure to mists containing sulfuric acid is a
cancer hazard.

Aggravation of Pre-existing Conditions: Persons with pre-existing skin


disorders or eye problems or impaired respiratory function may be more
susceptible to the effects of the substance.

First Aid Measures:

Inhalation: Remove to fresh air. If not breathing, give artificial


respiration. If breathing is difficult, give oxygen. Call a physician
immediately.
Ingestion: DO NOT INDUCE VOMITING. Give large quantities of water.
Never give anything by mouth to an unconscious person. Call a
physician immediately.

Skin Contact: In case of contact, immediately flush skin with plenty of


water for at least 15 minutes while removing contaminated clothing and
shoes. Wash clothing before reuse. Excess acid on skin can be
neutralized with a 2% solution of bicarbonate of soda. Call a physician
immediately.

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Eye Contact: Immediately flush eyes with gentle but large stream of
water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Call a physician immediately.

Fire Fighting Measures


Fire: Concentrated material is a strong dehydrating agent. Reacts with
organic materials and may cause ignition of finely divided materials on
contact.

Explosion: Contact with most metals causes formation of flammable and


explosive hydrogen gas.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Do not
use water on material. However, water spray may be used to keep fire
exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing
and NIOSH-approved self-contained breathing apparatus with full face
piece operated in the pressure demand or other positive pressure mode.
Structural firefighter's protective clothing is ineffective for fires involving
this material. Stay away from sealed containers.

IV) Caustic Soda


Sodium hydroxide is white flaked and odourless. It is identified as a
corrosive hazard of ‘Class 8’. On spillage on the ground, it evaporates
and some toxic vapour may be formed but this alkali vapour cloud is
generally vary small and of no consequence.
It is harmful if swallowed or inhaled and causes burns to any area of
contact. It is not considered to be fire hazard. Do not handle without
PPEs. Use safety goggles, Gumboots, PVC hand gloves and rubber apron
if required.

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Main Physical properties are as follows:

Molecular formula NaOH


Appearance Clear Soapy Liquid or white flakes
Odour Odourless
Boiling point 1480C
Vapour pressure at 400C 3.6 mm Hg
Bulk density 1.5 g/ml
pH Highly alkaline
Specific gravity 2.12

6.3 QUANTITIES OF HAZARDOUS MATERIALS


As mentioned in Section-6.2, various hazardous chemicals will be stored
at the plant in small to large quantities as per requirement. As per
Manufacture, storage and Import of Hazardous Chemicals rules 1989
and amendment subsequently, there will be only few hazardous
chemicals, which have potential for creating risk to life and property in
an unlikely event of leakage or spillage followed by fire.

The hazardous chemicals are stored at the plant in tank with adequate
dyke. Other chemicals will be stored in cylindrical tanks, barrels and
carboys. Details of storage of hazardous materials are given in Table -
6.1.
Table - 6.1: Facilities for Storage of Chemicals
Name of Chemical Quantity, MT/month Storage Facility
Sulphuric Acid (98%) 30 MSRL
Spent Acid (20-22%) 25 MSRL

6.4 HAZARDS DUE TO LEAKAGE OR CONTAINMENT


Since the proposed project is for the manufacturing of dyes and dyes
intermediates, various hazardous chemicals will be required to be
handled.

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Hazardous chemical to be handled and stored at the plant is in liquid


form. In the event of leakage or accidental release of these chemicals, it
will create only localized effects within the short distances from fixed or
spread pool in case of fire. There is possibility that release of some
hazardous chemicals may form vapour cloud which can move towards
wind direction and may explode in the event of fire if mass and
concentration of air and vapour mixture is within the LEL and UEL limits.
However, mass of vapour and air mixture may not be adequate to
generate explosive mass.

Storage and handling of hazardous chemical will not pose any hazardous
situation if these are handled or stored correctly with adequate safety
provisions and fire fighting facilities. Therefore, suitable safety measures
including fire fighting facilities will be provided at the plant to attend any
emergency due to accidental release of these hazardous chemicals.
Among the hazardous inventories, there are few potential toxic
materials that can form toxic vapour cloud in unlikely event of release.

6.5 MAXIMUM CREDIBLE ACCIDENT SCENARIOS

The plant will be dealing with some hazardous substances i.e. Sulphuric
Acid, Ortho Nitro Benzene, Iso butyl alcohol described in details. This is
in the form of liquid and considered as odorous. Subsequently, their
consequence due to thermal radiation will be confined within short
distances. If released quantities are not ignited, therefore, vapour
formation can result in vapour and air mixture and may generate
explosive mass which can explode if it gets the source of ignition. Toxic
cloud of hazardous chemicals may also be formed and moved towards
wind direction.

6.5.1 Methodology For Selection of Accident Scenarios

In this study, following steps are followed for scenario selection for risk
analysis study:

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• The hazardous materials to be handled at the plant and the


associated hazards have been identified and assessed.
• Operating and storage conditions of handling and storage of
hazardous materials are studied.
• An assessment is made of what inventories can get released
accidentally.
• Release rates are calculated considering different cases. For further
analysis of selected release sources, representative failure modes
and failure sizes are identified.

6.5.2 Maximum Credible Accident Scenarios


Following maximum credible scenarios have been selected for
consequence analysis as a result of accidental releases:

Sr. Type of Release Outcome Cases Considered


No.
Formation of pool and thermal
radiation due to fire
1. Release of Solvent Vapour cloud explosion
Dispersion of toxic cloud of
vapours
Vapour cloud explosion
2 Acid leakages Dispersion of toxic cloud of
vapours

6.5.3 Consequence Analysis


Consequence analysis for the selected accident scenarios has been
carried to estimate the vulnerable zones. Thermal radiation distances
have been computed based on various heat flux values vulnerable to
men and materials at the plant, while modelling of dispersion cloud is
based on IDLH (Immediately Dangerous for Life and Health) values. On
identification of vulnerable zones for failure cases, measures can be
taken for risk mitigation and to eliminate or minimize damage to the
plant and injury to personal.

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6.6 PROBABLE HAZARDS & RISK

From the preliminary risk assessment study carried out for Narayan
Organics Pvt. Ltd. Some of the possible hazards have been identified.
The likely accident scenarios considered are given below:

Sr. Scenario Vulnerability Remarks


No. Zone
1. Toxic Confined Area Spillage to be mopped up,
Liquid decontaminated (if required) and
Leakage/ disposed of as per norms.
Spillage in Fresh Air inlet / Ventilation
Confined System to be fully opened.
Space Ventilation Exhaust will carry
harmful vapors. Personnel to
avoid contact with exhaust
vapors. Exhaust to be released at
safe elevation.
2. Flammable Area adjoining Deluge all adjoining tanks till fire
liquid tank to tank stops and heat is dissipated.
in tank periphery/ Transfer/neutralize the spillage
farm on other tanks in (if any).
fire tank farm

The above-mentioned hazards scenarios can further aggravate into


much more serious incidents if not intercepted in time. The fire in one
tank of tank farm can spread to adjoining tanks and may result in
explosions. The vulnerability zone will be considerably enlarged. The
vapors of toxic fluids/dust if carried away by wind above TLV
concentrations may further enlarge the vulnerability zone. Similarly,
toxic fluid spillage and all wastes leaving the live processing zone if not
decontaminated properly can cause serious health hazard to plant
personnel and persons in nearby area.

6.7 METHODOLOGY, APPROACH AND DAMAGE CRITERIA FOR RISK


ASSESSMENT
Consequence analysis is that part of risk analysis, which considers
individual failure cases and the damage, caused by each failure case. It
is done to predict the outcome of potentially serious hazardous

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accidents to man and material in and around the plant boundary limits.
The advantages of carrying out consequence analysis are given below:
• To improve plant layout (for new projects and for expansion of
existing one)
• To meet statutory requirements
• Protection of public in the nearby areas (no residential/ inhabited
near by)
• Disaster management planning
• Training tool
The findings of a consequence analysis provide information about
hazardous effects resulting from an accident scenario. In addition,
Methods for dealing with possible catastrophic events are also provided.
6.7.1 HAZARDS EVALUATION: EXPOSURE To TOXIC DUSTS / VAPORS
Leakage in process plant from failure of nozzles, joints (flange joint),
welding failures or dripping from non-holding valves/glands or dusts
generation during charging of solids at times goes unnoticed. If the
leaky dust or fluids being toxic and odorless it is a potential source of
risk, which may cause fatal/serious hazards.
Liquids with high saturation vapor pressures evaporate faster because
the evaporation rate (mass/time) is essentially proportional to the
saturation vapor pressure. In the case of vaporization into stagnant air,
the vaporization rate is proportional to the difference between the
saturation vapor pressure and the partial pressure in the stagnant air.
6.7.2 LIQUID POOL EVAPORATION OR BOILING
The pool boiling cases may be encountered during heavy leakage in
enclosed area (dyke wall of tanks) and with heat source nearby
(ambient or fire) the vapor can explode or catch fire (in case the
material is flammable and sparks/flame contact is made).

6.7.3 PLANT LEAKAGE IN CONFINED SPACE

A chemical fluid spill is a common type of process incident and can lead
to potentially serious accident. If the spilled material gives rise to

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hazardous vapor or aerosol these may interact with plant environment


resulting in explosion or harm to plant’s personnel/ damage to plant
equipment/machinery (if vapors are toxic/ corrosive/inflammable). Most
chemical spills do not have such dramatic sequences but they must all
be handled carefully and correctly. Plant of Narayan Organics Pvt. Ltd.
will open with natural ventilation.
6.7.4 DAMAGE CRITERIA
In order to appreciate the extent of damage produced by various
accident scenarios, it is appropriate to discuss the physiological/
physical effects of toxic fluid exposure/thermal radiation intensities due
to spillage causing subsequent fire. The thermal radiation usually results
in burn on the human body and damage to plantation. Furthermore,
inanimate objects like equipment, piping, cables, etc. may be affected
and may aggravate the situation further.

Consequence analysis has been carried out for selected failure cases.
Consequence analysis quantifies vulnerable zones for a likely incident
and once the vulnerable zone is identified for an incident, measures are
proposed to eliminate damage to plant and potential injury to personnel.

6.8 RISK MITIGATION MEASURES

For risk mitigation/reduction, attempts should be made either to reduce


inventories that could get released in the event of loss of containment
or failure likelihoods or both as feasible. Risk analysis identifies the
major risk contributors, which enables prioritization of the plant that
deserve special attention in terms of inspection and maintenance in
particular and over all safety management as a whole.
For the risk reduction at the plant, the following salient suggestions and
recommendations are made:
• On site and off site emergency response plan should be prepared
and circulated to concern persons.

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• Personnel at the proposed plant and public in surrounding area


should be made aware about the hazardous substance stored at the
plant and risk associated with them.
• A written process safety information document should be compiled
for general use.
• The document compilation should include an assessment of the
hazards presented including (i) toxicity information (ii) permissible
exposure limits. (iii) Physical data (iv) thermal and chemical stability
data (v) reactivity data (vi) corrosivity data (vii) information on
process and mechanical design.
• The process design information in the process safety information
compilation must include P & IDs/PFDs; process chemistry;
maximum intended inventory; acceptable upper and lower limits,
pressures, flows and compositions and process design and energy
balances.
• The adequate numbers of heat and smoke detectors should be
provided at strategic locations in the plant and indication of
detectors/sensors should be provided in main control room.
• Predictive and preventive maintenance schedule should be prepared
for equipment, piping, etc. and thickness survey should be done
periodically as per standard practices.
• A written procedure (Management of Change) must be developed to
manage changes to process chemicals, technology, equipment and
procedures that affect a covered process.
• Safe work practices should be developed to provide for the control of
hazards during operation and maintenance such as: (i) lockout/tag
out (ii) Confined space entry (iii) Opening process equipment or
piping (iv) Control over entrance into a facility by maintenance,
contractor, laboratory, or other support personnel.
• Personnel engaged in handling of hazardous chemicals should be
trained to respond in an unlikely event of emergencies.

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• The plant should check and ensure that all instruments provided in
the plant are in good condition and documented.
• Safety measures in the form of “DO” and “Don’t do” should be
displayed at strategic locations especially in local language and
English.
• Regular mock drills should be carried out once in every 3 months
and shortcomings should be recorded and rectified. Records should
be maintained for the response of Mock Drills and corrective actions
should listed and taken accordingly.

6.8.1 PERSONAL PROTECTIVE EQUIPMENT


Personal protective equipments are devices that are fitted and issued to
each worker personally for his or her exclusive use. They are intended
for temporary use and emergency response action only. If a worker has
to enter in a contaminated area, he must wear adequate protective
equipment. Employees should be taught when and how to use
respiratory apparatus provided, and how to recognize defects in the
equipment. Full dress escape drills should be conducted at least once a
year. If such safety equipment is not available, entry into the
contaminated area should not be attempted.
• Personal protective equipment should be easily accessible outside
the hazardous material storage area and away from areas of likely
contamination.
• Employees who work near RM storage Tank must be issued a
properly fitting cartridge type or canister type escape respirator.
• Facial hair should not be permitted for those who are issued
escape-type or self-contained respirators because it prevents a
proper seal.
• Each employee should maintain his/her personal protective
equipment clean and in working condition at all times.
• All equipments should be used and maintained in accordance with
the manufacturer’s instructions.

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6.8.2 HANDLING OF HAZARDS


• Personal protective equipment used by the person during handling
of hazardous chemicals, should be replaced after certain time.
• Any spillage of hazardous chemicals should be cleaned and disposed
off as per standard practice.
• Empty drums of hazardous chemicals should be neutralized
immediately.
• Personnel engaged in handling of hazardous chemicals should be
made aware of properties of hazardous chemicals.

6.8.3 GENERAL WORKING CONDITIONS

(a) House Keeping


• All the passages, floors and stairways should be maintained in
good condition. The system should be available to deal with any
spillage of dry or liquid chemical at the plant.
• Sufficient disposable bins should be clearly marked and these
should be suitably located in the plant.
• Walkways should be clearly marked and free from obstructions.
• In the plant, precaution and instructions should be displayed at
strategic locations.
• All pits, sumps should be properly covered or securely fenced.
• Roads/walkway within the plant should be maintained neat and
clean.

(b) Ventilation
• Adequate ventilation should be provided in the work floor
environment.
• The work environment should be assessed and monitored
regularly.
• Local ventilation is most effective method for controlling dust and
gaseous emissions at work floor.

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6.8.4 SAFE OPERATING PROCEDURES

• Safe operating procedures should be available for almost all


operations and equipments.
• Workers should be informed of the consequences of failure to
observe the safe operating procedures.

6.8.5 WORK PERMIT SYSTEM

Work permit system should be followed at the plant. Hazardous work


permit should be used for hot work, electrical works, etc.
6.8.6 FIRE PROTECTION
• Adequate fire fighting facilities should be available at the plant,
including, dry chemical powder type, water CO2 type, mechanical
foam type, CO2 type and sand buckets.
• The fire fighting system and equipment should be tested and
maintained as per relevant standards.
• The fire drills should be conducted once in six months.

6.8.7 EMERGENCY PREPAREDNESS

• On-site emergency plan should be prepared and readily available for


an unlikely event of emergency.
• Emergency telephone numbers should be available and displayed
properly at strategic locations.

6.8.8 STATIC ELECTRICITY

• All equipments and storage tanks/containers of flammable chemicals


should be bounded and earthed.
• Electrical resistance for earthing circuits should be maintained.
Periodic inspections should be done for earth pit and record should
be maintained.

6.8.9 MATERIAL HANDLING


• Material handling areas should be clearly defined.
• The workers should be made aware about the hazards associated
with manual material handling.

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6.8.10 COMMUNICATION SYSTEM

• Adequate communication facilities should be available at the plant


and supported with uninterrupted power supply.
• Communication facilities should be checked periodically for its proper
functioning.

6.8.11 ACCIDENT REPORTING, INVESTIGATION AND ANALYSIS

A system should be initiated for accident reporting, investigation and


analysis. To motivate and to increase awareness among the personnel
at the plant about safety, total accident (lost time injury) free days can
be displayed on the board prominently at strategic location.

6.8.12 SAFETY INSPECTIONS

The system should be initiated for checklist based routine safety


inspection and internal audit of the plant periodically. Safety inspection
team should be formed from various disciplines and departments.

6.8.13 SAFE OPERATING PROCEDURES

Safe operating procedures should be formulated and updated, specific


to process & equipment and distributed to concerned plant personnel.

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Chapter 7
ONSITE DISASTER MANAGEMENT PLAN
7.1 INTRODUCTION
An emergency is said to have arisen when operators in the plant are not
able to cope with a potential hazardous situation i.e. loss of control of an
incident, causes the plant to go beyond its normal operating conditions,
thus creating danger. When such an emergency evolves, chain of events
which affect the normal working within the factory area and/or which, may
cause injuries, loss of life, substantial damage to property and environment
both inside and around the factory take place, then the DISASTER is said
to have occurred.

M/s. Narayan Organics Pvt. Ltd., Unit-II is the proposed unit for pigment
manufacturing. The unit proposes to manufacture Copper Pthalocyanine
Blue (CPC Blue), Pigment Alpha Blue and Pigment Beta Blue of 700.0 TPM,
75.0 TPM and 200.0 TPM capacity respectively. There will also be
generation of Ammonium Carbonate Solution (12-15%) as by-product up
to 600.0 TPM. Thus, total production capacity of the unit including by-
product will be 1575.0 TPM.

As described in chapter-6, the risk assessment studies have been


conducted for identification of hazards, to calculate damage distances and
to spell out risk mitigation measures.

Despite of best efforts to manage an emergency situation in the prevention


of any risk hazards from the manufacturing process or material handling,
things can go wrong. Therefore, it is essential to plan and develop the
support system, which will be required in case an emergency arises.

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7.2 PROBABLE HAZARDS AND RISK


From the preliminary risk assessment study presented in Chapter 6 of this
report, some of the possible hazards have been identified.

7.3 OBJECTIVES OF THE PLAN


Following are the Objectives of the disaster management plan:
• To define and assess emergencies, including risk and environment
impact assessment.
• To reduce possibilities of an accident
• To safeguard employees, visitors and other people in the vicinity.
• To minimize damage to property and/or the environment.
• To inform employees, general public and the authorities on the
hazards/risk assessed, safeguards provided, residual risks, if any, and
the role to be played by them in the event of an emergency.
• To be ready for the mutual aid if need rises to help the neighbouring
unit. Normal jurisdiction of an On-site Emergency Plan is the own
premises only, but looking to the time factor in the arriving the
external help of off-site plan agency, the jurisdiction must be
extended outside to the extent possible in case of an emergency
occurring outside.
• To inform authorities and mutual aid centres to come for help.
• To affect rescue and treatment of casualties to count injured.
• To identify and list any dead.
• To inform and help relatives.
• To secure the safe rehabilitation of affected area and to restore
normality.
• To provide authoritative information to the news media.
• To preserve records, equipment, etc., and to organize investigation
into the cause of the emergency and preventive measures to stop its
reoccurrence.

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• To ensure safety of the work force before they re-enter and resume
work.
• To work out a plan with all provisions to handle emergencies and to
provide for emergency preparedness and the periodical rehearsal of
the plan.
The structure of the plan may vary depending on number of employees,
materials and processes, availability of resources, location of site, size and
complexity of work.
The plan should not be complicated. Instructions should not overlap or
create any confusion. Responsibilities should be clearly assigned and
should be workable smoothly. For clear understanding and quick action,
the action (role) by each individual (his emergency duty) should be
prepared in a booklet or card size and given to him.
7.4 IDENTIFICATION OF MAJOR HAZARDS
The major hazardous field where disaster management plan is required are
as under:
• Bursting of high-pressure steam pipe, vessels, etc. due to
abnormal pressure rise
• Fire hazard due to ignition of fuel
• Inhalation of any hazardous chemical
7.5 SCOPE OF THE PLAN
• The plan will set into action immediately after a fire or other hazard
occurs in and/or around the plant
• Fuel storage facility will be situated away from the manufacturing plant
and will follow all rules and regulation
• All the electrical fittings will be of explosion proof fitting
• All necessary fire-fighting arrangements will be provided near the
storage area

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-3


SAN Envirotech Pvt. Ltd, Ahmedabad

7.6 THE UTILITY, ORGANIZATION AND UTILIZATION OF RESOURCES


AND FACILITIES FOR EMERGENCIES
In order to maintain an emergency response capability, certain facilities
must be kept in a state of readiness and sufficient supplies and equipment
must be available. In some cases, it may be impossible to maintain all of
the equipment necessary for all possible emergencies. In these cases,
agreements have to be made with neighbouring facilities to provide
additional support as and when necessary.
Where the local police or private agencies may be called upon, such as
volunteer fire companies and ambulance associations, agreements have to
be developed ahead of time. Emergency hardware can be classified
according to its use during the response operations. Typical examples are:
• Emergency operation centres
• Communication equipment
• Alarm system
• Personal protection equipment
• Fire fighting facilities, equipment and supplies
• Spill and vapour release control equipment and supplies
• Medical facilities, equipment and supplies
• Monitoring systems
• A media Centre
• Transportation system
• Security and access control equipment
Some of these resources will also be available in the local municipalities. It
is the responsibility of the plant management to ensure that the
appropriate equipments and materials are available to respond to their
very hazard-specific emergencies at the facilities, independently from
external resources. These resources can be extremely valuable, but should

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-4


SAN Envirotech Pvt. Ltd, Ahmedabad

be used mainly in support of the main response actions that the facility
personnel will have to implement in case of a serious emergency.
In any case, the availability of resources within the community must be
determined before hand, so that these resources can be mobilized, if the
time comes to do so.

7.7 RESPONSE ORGANISATION STRUCTURE


To set up a response organization structure necessary for chain of
commands during emergency situation, which may arise in the premises, is
one of the most important objectives of emergency plan, which is briefly
described hereunder:
Functions and Responsibilities
The main key person of the emergency plan is Chief Emergency
co-ordinator (Factory Manager / Plant Head). He shall be assisted by,
• Emergency Plant Coordinator, Chief (Production)
• Material Management Coordinator, Chief (Commercial)
• Special Job Coordinator, Chief (Administration Finance)
Chief Emergency Coordinator

He shall be responsible for

• Essential communications
• Public relation
• Transportation
• Investigation and reports
• Alert the hospital authorities
Emergency Plant Coordinator (Chief – Production)

• Rush to the site of emergency on receipt of information.


• Direct plant operation/shut-down operations as needed to control
situation.

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-5


SAN Envirotech Pvt. Ltd, Ahmedabad

• Guide the Shift Production Officer and members of the Emergency


Squad in fire fighting/rescue operations.
• Arrange for any additional fire fighting/safety equipment, which may
be required at the site.
• Keep in constant touch with the Chief Emergency Coordinator and pass
on all relevant and necessary information to him so as to enable him
keep in touch with concerned authorities.
• Keep in touch with the other coordinators for requirement of any
services like external help, communication, transportation, etc.
• Arrange for replacement/refilling of used up fire fighting equipments or
gas masks/canisters so as to make these available at the site at the
earliest.
• Carry out investigation of the accident and assist in filling of statutory
reports as required.
• Carry out preliminary investigation into the accident with the help of
concerned personnel.
• Preserve records/evidence that may be required for investigation.
Material Management Coordinator (Chief-Commercial)

• Rush to the site of emergency.


• Keep the stores open for emergency issue of any items that may be
required for control of emergency.
• In case some material is not available, arrange for its emergency
purchase.
• Keep contact with other coordinators to assess any requirements in
terms of material.
• Arrange for any trucks/trolleys, which may be required for
transportation of materials.
• Keep in constant touch with the Chief Emergency Coordinator.

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-6


SAN Envirotech Pvt. Ltd, Ahmedabad

• Assess the situation in consultation with the Chief Emergency


Coordinator and other coordinators.
• Arrange to get maintenance mechanics along with their toolboxes to
provide help in any isolation/repair work as may be required.
• Arrange for requisite number of contractor workmen in case any
additional help is required.
• Arrange for the Shift Electrician and get power supply to the affected
area, if required.
• Make arrangements for temporary lighting/emergency lighting at the
affected area, as required.
• In case of a power failure, ensure the running of the DG sets and
uninterrupted power supply to emergency facilities.

Special Job Coordinator (Chief – Administration/Finance)

• Rush to the site of emergency


• Assess the situation in consultation with Emergency Plant Coordinator
to provide help as may be required.
• Keep in constant touch with the Chief Emergency Coordinator.
• Assess the situation in consultation with Chief Emergency Coordinator.
• Attend to all emergencies related communications at the Security
Gate.
• Arrange for all Security Guards at their respective post and in case of
the availability of some spare Security Guards, they may be sent to
site of emergency to assist emergency Squad in fire fighting/rescue
operations.
• Closely monitor all movements at the gate, keeping passage clear for
movement of emergency vehicles.
• No visitors should be allowed to come inside the premises during the
period of emergency.

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-7


SAN Envirotech Pvt. Ltd, Ahmedabad

• Assess the law and order situation inside/outside the premises and
take necessary action accordingly. Proper vigilance to be maintained to
avoid any attempts from inside/outside saboteurs.
• Arrange to keep the emergency vehicles and ambulance ready with
their drivers for any movement of personnel/material.
• Arrange for canteen services for the personnel on duty and in the
affected area.
• In case of any injuries, provide necessary first aid and arrange for
shifting of the injured personnel to the ESI or other hospitals as the
case may be.
• Attend to any external calls/telephones relating to information about
emergency.
• In case of need from other emergency coordinators at site, arrange to
inform external agencies like Fire Brigade, Police Station, Ambulance
and other Medical Services.
• Arrange for filling of statutory report that may be required.

7.8 EMERGENCY RESPONSE CENTRE


The place identified as Emergency Response Centre will be considered
as the Security Gate Office.
The location of Emergency Response Centre may change in future as per
convenience. The facilities available at the Emergency Response Centre
shall include:
• Internal Telephone
• External Telephone
• Manual Fire/Emergency Siren
• Siren Actuation Switch
• Important Address and Telephone Numbers
• Emergency Vehicles
• Confined Space Entry Procedure

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-8


SAN Envirotech Pvt. Ltd, Ahmedabad

• List of antidote/actions to be taken in case of exposure to


hazardous Chemicals/materials.
• Material Safety Data Sheets of chemicals
• A copy of On-Site Disaster Management Plan
All communications after General Shift working hours and on
Sundays/Holidays are to be routed through the Security Gate Office.
General Rules

• Follow sense of discipline and do not panic.


• Do not rush and endanger your personal safety.
• Use personnel protective equipment according to the situation.
• Do not block any passages which may hinder the movement of
emergency Vehicles.
• In case you have to shut down your plant operations, do it in an
orderly manner as per standard operating procedures.
• In situation when you have to leave your work and evacuate to
identify places out of operating areas, do it in an orderly manner.
• Follow instructions of the Emergency Co-ordinators.
• Understand the disaster management plan well and take interest
in practice drills
Emergency Squad

There is a group of personnel (5-10 in number) who will be identified to


handle any emergency situation. These personnel including officers shall be
taken from various operating areas and will be imparted extensive training
in fire fighting, material safety data for hazardous chemicals, rescue
operations, decontamination procedures, confined space entry procedures,
first aid and other related functions. The members will be so chosen that at
any given time, at least 2–3 members of Emergency Squad will be
available in the premises.

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-9


SAN Envirotech Pvt. Ltd, Ahmedabad

Communication System

Intercom telephone points shall be provided at all critical areas of


operations. An Emergency Telephone shall be available at the Emergency
Response Centre. In addition, telephone connections shall be provided at
the residence of all critical personnel to ensure immediate contact.

7.9 POST EMERGENCY – RECOVERY


When an emergency is over, it is desirable to carry out a detailed analysis
of the causes of accidents to evaluate the influence of various factors
involved and to propose methods to eliminate or minimize them in future.
Simultaneously, the adequacy of the disaster preparedness plan will be
evaluated and any shortcomings will be rectified.
Accident Investigation

After the emergency is over and plant operation has


a. become normal, the investigation shall be carried out as
soon as possible to determine the cause of the event.
Representatives from various disciplines should take
b.
part and report in the investigating team.
The area of the event shall be sealed off so that
c. tampering or alteration of the physical evidence will not
occur.
Key components shall be photographed and logged with
d.
time, place, direction, etc.
Statements shall be taken from those who were involved
e.
with the operation or who witnessed the event.

Damage Assessment

This phase of recovery establishes the quantum of replacement of


machinery considered necessary for bringing back the plant to normal
operation, property and personnel losses, and culminates in a list of
necessary repair, replacement and reconstruction work.

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-10


SAN Envirotech Pvt. Ltd, Ahmedabad

Insurance companies will be informed of the damage and requested to pay


the compensation as per claim.
Cleanup and Restoration

• This phase will only begin after the investigation is complete.


• Reporting documentation will be prepared and forwarded to
appropriate authorities.
• Repairs, restoration and cleanup will begin.
Insurance claims will be prepared and submitted.

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-11


SAN Envirotech Pvt. Ltd, Ahmedabad

Figure – 7.1:- On Site Disaster Management Plan

Chief Emergency Coordinator


Factory manager /
Plant head

Emergency Special Job Material


Plant Coordinator Coordinator management
(Chief Production) (Chief Coordinator
Administration (Chief Commercial)
Finance)

REIA of Narayan Organics Pvt. Ltd.,Unit-II 7-12


F. No. J-11011126112010- IA ll (I)
Government of India
Ministry o f Environment and Forests
(I.A. Division)
Paryavaran Bhawan
CGO Complex, Lodhi Road
New Delhi - 110 003

E-mail : pb.rastoai@.nic.in
Telefax : 011 : 2436 7668
Dated 9Ih September, 2010

To' d i r i Dahyabhai N Patel


Managing Director
MIS Narayan Organics Pvt. Ltd.
Plot N o . 130516 /A+B, Phase IV GlDC Naroda,
Ahmadabad - 382330 (Gujarat)

E-mail : ; Fax No. : 79-22823572

Subject:Copper Phthalocyanine Blue (700 MTPM), Pigment Alpha Blue (75 MTPM),
and Pigment Beta Blue (200 MTPM) Manufacturing Unit at Block No. 164,
165, 166, 167, 168, 169 and 170, Village Vedach, Tehsil Jambusar, District
Bharuch, Gujarat by MIS Narayan Organics Pvt. Ltd. - reg.
Ref. : Your letter no. nil dated 5thMay, 2010.

Sir,
Kindly refer your letter no, nil dated 5Ih May, 2010 alongwith project documents
including Form-I, Pre-feasibility Report and draft 'Terms of Reference' as per the EIA
., Notification, 2006. It is noted that proposal is for Copper Phthalocyanine Blue (700
MTPM), Pigment Alpha Blue (75 MTPM), and Pigment Beta Blue (200 MTPM)
Manufacturing Unit at Block No. 164, 165, 166, 167, 168, 169 and 170, Village Vedach,
Tehsil Jambusar, District Bharuch, Gujarat by MIS Narayan Organics Pvt.

Draft Terms of Reference (TOR) have been discussed and finalized during the
- 13" Expert Appraisal Committee (Industry-2) meeting held during lgth-2dh ~ u g u s t 2010
for preparation of EINEMP. Following are the 'TORS':
,

1. Executive summary of the project


2. Justification of the project.
3. Promoters and their back ground
4. Regulatory framework
5. Project location and plant layout.
6. Infrastructure facilities including power sources.
7. Total cost of the project alongwith total capital cost and recurring costlannum for
environmental pollution control measures.
8. Project site location along with site map of 10 km area and site details providing
various industries, surface water bodies, forests etc.
Iv
9. Present land use based on satellite imagery for the study area of 10 km radius.
Location of National P a r m i l d life sanctuarylReserve Forest within 10 km radius
of the project.
10. Permission from the State Forest Department regarding the impact of the
proposed plant on the surrounding reserve forests, if any.
11. Details of the total land and break-up of the land use for green belt and other
uses.
12. List of raw materials, products alongwith the production capacities and list of
solvents and its recoveryplan.
13. Commitment for not using azodyes in the process should be given.
-
14. Detailed list of raw material required and source, mode of storage and
transporiation.
15. Manufacturing process details alongwith the chemical reactions.
16. Design details of ETP, incinerator, if any alngwith control of Dioxin B Furan,
boiler, scrubberslbag filters etc.
17. Details of water and air pollution and its mitigation plan
18. Site-specific micro-meteorological data using temperature, relative humidity,
hourly wind speed and direction and rainfall is necessary.
19. Ambient air quality monitoring for all the parameters including VOCs within the
study area of 5 km., aerial coverage from project site. Location of one AAQMS in
downwind direction.
20. One season site-specific micro-meteorological data using temperature, relative
humidity, hourly wind speed and direction and rainfall and AAQ data (except
monsoon) for PM,o, SO,, NOx including HC and VOCs.should be collected. The
. monitoring stations should take into account the pre-dominant wind direction,
population zone and sensitive receptors including reserved forests. Data for
water and noise monitoring should also be included.
21. Action pLa,n_to control ambed airquality a s per NAAQES Standards notified b y
the Ministry on 16Ih september. 2009.
22. An action plan to control and monitor secondary fugitive emissions from all the
sources as per the latest permissible limits issued by the Ministry vide G.S.R.
414(E) dated 3 0 ' ~May, 2008.
23. Determination of atmospheric inversion level at the project site and assessment
of ground level concentration of pollutants from the stack emission based on site-
specific meteorological features. Air quality modelling for the proposed plant.
24. Permission for drawl of 612 m31dayground water from the CGWNSGWB. Water
balance cycle data including quantity of effluent generated recycled and reused
and discharged. Method to be used to control ammonical nitrogen from industrial
wastewater.
25. Ground water monitoring minimum at 6 locations should be carried out.
Geological features and Geo-hydrological status of the study area and ecological
status (Terrestrial and Aquatic).
26. The details of solid and hazardous wastes generation, storage, utilization and
disposal particularly related to the hazardous waste calorific value of hazardous
waste and detailed characteristic of the hazardous waste.
27. Details of land fill alongwith design details as per CPCB guidelines. Location of
secured land filllTSDF.
28. Ground water monitoring around the land fill site
29. Membership of CETP for disposal to effluent and TSDF for disposal of hazardous
water1 solid waste.
30. Risk assessment for storage for chemicals/solvents and phosgenes. (J
31. An action plan to develop green belt in 33 % area
32. Action plan for rainwater harvesting measures at plant site should be included to
harvest rainwater from the roof tops and storm water drains to recharge the
ground water.
33..Occupational health of the workers needs elaboration including evaluation of
noise, heat, illumination, dust, any other chemicals, metals being suspected in
environment and going into body of workers either through inhalation, ingestion
or through skin absorption and steps taken to avoid musculo-skeletal disorders
(MSD), backache, pain in minor and major joints, fatigue etc. Occupational
hazards specific pre-placement and periodical monitoring should be carried out.
34. Socio economic development activities should be in place.
35. Note on compliance to the recommendations mentioned in the CREP guidelines.
36. Detailed Environment management Plan (EMP) with specific reference to details
of air poiiution control system, water & wastewater management, monitoring
frequency, responsibility and time bound implementation plan for mitigation
measure should be provided.
37. EMP should include the concept of wa$e-minimization, recyclelreuselrecover
techniques, Energy conservation, and natural resource conservation.
-.
38. Any litigation pending against the project andlor any directionlorder passed by
any Court of Law against the project, if so, details thereof.
39. Public hearing issues raised and commitments made by the project proponent on
the same should be included separately in EINEMP Report in the form of tabular
chart with financial budget for complying with the commitments made.
40. A tabular chart with index for point wise compliance of above TORS.

The following general points should be noted:

(i) All documents should be properly indexed, page numbered.


(ii) Periodldate of data collection should be clearly indicated.
(iii) Authenticated English translation of all material provided in Regional
languages.
(iv) The letterlapplication for EC should quote the MOEF file No. and also attach a
copy of the ietter.
(v) The copy of the letter received from the Ministry should be also attached as an
annexure to the final EIA-EMP Report.
(vi) The final EIA-EMP report submitted to the Ministry must incorporate the issues
,-
in this letter. The index of the final. EIA-EMP report must indicate the specific
chapter and page no. of the EIA-EMP Report.
(vii) While preparing the EIA report, the instructions for the proponents and
instructions for the consultants issued by MoEF vide O.M. No. J-
1101314112006-lA.ll (I) dated 4th August, 2009, which are available on the
website of this Ministry should also be followed.
(viii) The consultants involved in the preparation of EINEMP report after
accreditation with Quality Council of India (0CI)INational Accreditation Board of
Education and Training (NABET) would need to include a certificate in this
regard in the EINEMP reports prepared by them and data provided by other
organization1Laboratories including their status of approvals etc. In this regard
circular no F. No. J -1101317712004-lA Il(1) dated 2nd December, 2009 posted
on the Ministry's website http://w.moef.nic.in may be referred.
(ix)
should be included, ,/
'Certificate of Accreditation' issued by the QCI to the environmental consultant
' These 'TORS' should be considered for the preparation of EIA IEMP report of
Copper Phthalocyanine Blue (700 MTPM), Pigment Alpha Blue (75 MTPM), and
Pigment Beta Blue (200 MTPM) Manufacturing Unit at Block No. 164, 165, 166, 167,
168, 169 and 170, Village Vedach, Tehsil Jambusar, District Bharuch, Gujarat in addition
to all the relevant information as per the 'General Structure of EIA' given in Appendix Ill
and lllA in the EIA Notification, 2006. The EINEMP as per TORS should be submitted to
the Ministry for considering the proposal for environmental clearance within 2 years as
per the MoEF O.M. No. J-11013/41/2006-Ill (I) dated 2Pd March, 2010. The drafi
EINEMP report should be submitted to the Gujarat Pollution Control Board for public
hearing. The issues emerged and response to the issues raised during public hearing
should be incorporated in the EIA report. The7inal EINEMP alongwith 'Certificate of
Accreditation' issued by the QCl should be submitted to the Ministry for obtaining
environmental clearance.

The consultants involved in the preparation of EINEMP report afler accreditation


with Quality Council of India INational Accreditation Board of Education and Training
(QCIINABET) would need to include a certificate in this regard in the EINEMP reporls
prepared by them and data provided by other Organization(s)lLaboratories including
their status of approvals etc. In this regard circular no F. No. J -1101317712004-lA Il(1)
dated 2"d December, 2009 available on the Ministry's website http.Nwww.moef.nic.in
may be referred. ,-.
ih &
[Dr. P.B. Rastogi)S l s l l L '
Scientist 'F;

Copy to: The Chairman. Gujarat State Pollut~onControl Board, Paryavaran Bhawan,
Sector 10 A, Gandhi Nagar-382 043, Gujarat.

(Dr. P.B. Rastogi)


Scientist 'F'
Charter on Corporate Responsibility for Environmental Protection (CREP) for dyestuff Industry
Name of the Industry (Unit):For M/s. Narayan Organics Pvt. Ltd. Unit-II.
Name of Products:- Copper phthalocyanine blue-700 TPM
Pigment alpha blue-75 TPM
Pigment beta blue-200TPM
Scale of operation:- SSI/MSI

Sr. No Points for Action Implementation Schedule


1 Do you have any programme for Yes, we will recover dilute sulfuric acid from Alpha Blue
recovery and purification of bye- plant and Ammonia from air Pollution Control System
products and convert it to by product Ammonium Sulphate. Action
will be start from commissioning of plant.
2 Do you have incinerator? No we have no incinerator
3 Is there any waste exchange We will utilize weak acid for producing Ammonium
programme with other Industry for Sulphate in our own plant
proper use of
weak acid
4 Do you have any programme for Pl. refer poijt no-1
recovery and purification of bye-
products?
5 Do you have regular monitoring We will develop monitoring programme start from
programme for ground water at the commissioning of plant.
vicinity?
6 Whether Waste generated from one Yes, we will recover dilute sulfuric acid from Alpha Blue
Industry is used by other? plant and Ammonia from air Pollution Control System
and convert it to by product Ammonium Sulphate. Action
will be start from commissioning of plant.
7 Do you have any waste minimization By product recovery is a part of waste minimization
programme on practice activities.
8 Is there any possibility for No, there will be no possibility to install spray dryer and
introduction of spray drying instead we are not doing salting to recover product because
of salting product itself water insoluble.
9 Is the scrubbing system up- gradation From the beginning, we will install proper design
programme initiated? scrubber to control of hazardous air pollutants (such as
Ammonia and it will converted as by product. Action plan
to be submitted to GPCB immediately after plant
commission.
10 Do you have any programme for All liquid material will be transfer by pneumatically, joint
volatile organics loss minimization will be 100% leak proof and solid material will be transfer
programme with care of zero leakages.
11 Better management practice Environment Management Cell will be created for better
practice to control the relevant pollutant.
12 Solid waste management programme Chemical Sludge-600 MT/Month

Part of sludge will be sold to cement industries and


balance will be sent to TSDF site as land filling approved
by GPCB
Oyanies !Pert. ~ t dUnit
. II
REGD. OFFICE : 1305/6/A+B, PHASE - IIP,
G.I.D.C. ESTATE. NARODA.
AHMEDABAD-382330. INDIA.
PH. : ++91-79-22821099, 22816038,
22814789,22815098
FAX : ++91-79-22823572, 25631830
E-mail : lnfo@narayanorganlcs.com
Website : www.narayanorganlcs.com

To,
The regional Director
CGWB, West Central Region,
S.N. College Building,
Shah Alam Toll naka,
Ahmedabad

Subject: Permission for Bore well

Respected Sir,

With reference t o above subject matter and GPCB (Gujarat Pollution


., Control Board) demand for obtaining permission of water sources. You
are requested t o kindly issue us letter for tapping t h e bore well at our
above referred address.

Thanks & regards,

Yours Faithfully.

For, Narayan Organics Pvt Ltd (Unit 11)

Director

FACTORY ADDRESS : ON ECP CHANNEL ROAD. NEAR TRANSMETAL. VILLAGE : VEDACH. TALUKA : JAMBUSAR. DIST. : BHARUCH.
Details of Bag House

A] PULSE JET BAG FILTER

1. Operating parameters

a) Gas volume : 750 Am3/hour (Approx.)

b) Temperature : 1400 C

c) Type of dust : Gas loaded with fines

d) Inlet dust loading : 10-15 mg/Nm3

e) Outlet emission : 50 mg/ Nm3

2. Bag filter data

a) Type of bag filter : Pulse jet type, on line cleaning

b) Quantity required : 1 No.

c) Filter area : 16 m2

d) Air to cloth ratio : 0.78 m3/min/m2

e) Pressure drop maximum : 150 mm WC

f) Location : Outdoor

3. Bags

a) Material : Woven fiber glass with acid resistant finish

b) Size : 152 mm diameter x 2743 mm length

c) Number of bags : 12 No.


4. Composed Air

a) Type : By purchaser

b) Quantity : 10-15 m3/hour

c) Pressure : 6 kg/cm2

d) Contents of compressed air should be free from moisture & oil.

5. Material of construction

a) Casing : Carbon steel

b) Hopper : Carbon steel

B] I.D. FAN

Technical Data

1. Purpose : Induced draft the air from pulse jet bag filter

2. Type : Centrifugal air blower

3. Capacity : 1100 m3/hr

4. Pressure : 300 mm WC

5. Temperature : 1400 C

6. Quantity : 1 No.

7. Drive : Indirect driven by “V” belt

8. Motor rating : 7.5 H.P., 1440 rpm, Foot mounted, TEFC, 3 phases, Sq.

Cage indicator motor

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