Professional Documents
Culture Documents
ON
UNIT OPERATION
In partial fulfilment of the requirements for Bachelor of
Technology Degree in Chemical Engineering (2017-18)
Submitted by:
SHIVAM DWIVEDI
Chemical (3rd Year)
Roll.no-1516651038
SHIVAM DWIVEDI
B.TECH 3rd Year
CHEMICAL ENGG.
Dr.AITH, Kanpur
UNIT OPERATION
FLUID TRANSPORTATION
Pipeline transport is the transportation of goods or material
through a pipe. The latest data from 2014 gives a total of
slightly less than 2,175,000 miles (3,500,000 km) of pipeline in
120 countries of the world. The United States had 65%, Russia
had 8%, and Canada had 3%, thus 75% of all pipeline were in
these three countries.
Pipeline and Gas Journal's worldwide survey figures indicate
that 118,623 miles (190,905 km) of pipelines are planned and
under construction. Of these, 88,976 miles (143,193 km)
represent projects in the planning and design phase; 29,647
miles (47,712 km) reflect pipelines in various stages of
construction. Liquids and gases are transported in pipelines
and any chemically stable substance can be sent through a
pipeline. Pipelines exist for the transport of crude and refined
petroleum, fuels – such as oil, natural gas and biofuels – and
other fluids including sewage, slurry, water, and beer. Pipelines
are useful for transporting water for drinking or irrigationover
long distances when it needs to move over hills, or
where canals or channels are poor choices due to
considerations of evaporation, pollution, or environmental
impact. Pneumatic tubes using compressed air can be used to
transport solid capsules.
Oil pipelines are made from steel or plastic tubes which are
usually buried. The oil is moved through the pipelines
by pump stations along the pipeline. Natural gas (and similar
gaseous fuels) are lightly pressurised into liquids known as
Natural Gas Liquids (NGLs). Natural gas pipelines are
constructed of carbon steel. Hydrogen pipeline transport is the
transportation of hydrogen through a pipe. District
heating or teleheatingsystems use a network of insulated pipes
which transport heated water, pressurized hot water, or
sometimes steam to the customer.
Pipelines conveying flammable or explosive material, such as
natural gas or oil, pose special safety concerns and there have
been various accidents. Pipelines can be the target
of theft, vandalism, sabotage, or even terrorist attacks. In war,
pipelines are often the target of military attacks.
2.COLD FILTRRATION
3. VACCUM FILTRATION
FILTER MEDIA
Two main types of filter media are employed in laboratories:
a surface filter, a solid sieve which traps the solid particles,
with or without the aid of filter paper (e.g. Büchner funnel, Belt
filter, Rotary vacuum-drum filter, Cross-flow filters, Screen
filter); and a depth filter, a bed of granular material which
retains the solid particles as it passes (e.g. sand filter). The first
type allows the solid particles, i.e. the residue, to be collected
intact; the second type does not permit this. However, the
second type is less prone to clogging due to the greater surface
area where the particles can be trapped. Also, when the solid
particles are very fine, it is often cheaper and easier to discard
the contaminated granules than to clean the solid sieve.
FILTER AID
Certain filter aids may be used to aid filtration. These are often
incompressible diatomaceous earth, or kieselguhr, which is
composed primarily of silica. Also used are wood cellulose and
other inert porous solids such as the cheaper and safer perlite.
These filter aids can be used in two different ways. They can be
used as a precoat before the slurry is filtered. This will prevent
gelatinous-type solids from plugging the filter medium and also
give a clearer filtrate. They can also be added to the slurry
before filtration. This increases the porosity of the cake and
reduces resistance of the cake during filtration. In a rotary filter,
the filter aid may be applied as a precoat; subsequently, thin
slices of this layer are sliced off with the cake.
The use of filter aids is usually limited to cases where the cake
is discarded or where the precipitate can be chemically
separated from the filter.
FLUIDIZATION
Fluidization is a process similar to liquefaction whereby
a granular material is converted from a static solid-like state to
a dynamic fluid-like state. This process occurs when a fluid
(liquid or gas) is passed up through the granular material.
When a gas flow is introduced through the bottom of a bed of
solid particles, it will move upwards through the bed via the
empty spaces between the particles. At low gas velocities,
aerodynamic drag on each particle is also low, and thus the
bed remains in a fixed state. Increasing the velocity, the
aerodynamic drag forces will begin to counteract the
gravitational forces, causing the bed to expand in volume as
the particles move away from each other. Further increasing
the velocity, it will reach a critical value at which the upward
drag forces will exactly equal the downward gravitational
forces, causing the particles to become suspended within the
fluid. At this critical value, the bed is said to be fluidized and will
exhibit fluidic behavior. By further increasing gas velocity, the
bulk density of the bed will continue to decrease, and its
fluidization becomes more violent, until the particles no longer
form a bed and are "conveyed" upwards by the gas flow.
When fluidized, a bed of solid particles will behave as a fluid,
like a liquid or gas. Like water in a bucket: the bed will conform
to the volume of the chamber, its surface remaining
perpendicular to gravity; objects with a lower density than the
bed density will float on its surface, bobbing up and down if
pushed downwards, while objects with a higher density sink to
the bottom of the bed. The fluidic behavior allows the particles
to be transported like a fluid, channeled through pipes, not
requiring mechanical transport (e.g. conveyor belt).
APPLICATIONS
Most of the fluidization applications use one or more of three
important characteristics of fluidized beds:
CONVECTION
Convective heat transfer, or convection, is the transfer of heat
from one place to another by the movement of fluids, a process
that is essentially the transfer of heat via mass transfer. Bulk
motion of fluid enhances heat transfer in many physical
situations, such as (for example) between a solid surface and
the fluid.[10]Convection is usually the dominant form of heat
transfer in liquids and gases. Although sometimes discussed as
a third method of heat transfer, convection is usually used to
describe the combined effects of heat conduction within the
fluid (diffusion) and heat transference by bulk fluid flow
streaming.
RADIATION
Thermal radiation occurs through a vacuum or any
transparent medium (solid or fluid). It is the transfer of energy
by means of photons in electromagnetic waves governed by
the same laws.
Thermal radiation is energy emitted by matter as
electromagnetic waves, due to the pool of thermal energy in all
matter with a temperature above absolute zero. Thermal
radiation propagates without the presence of matter through
the vacuum of space.
Thermal radiation is a direct result of the random movements of
atoms and molecules in matter. Since these atoms and
molecules are composed of charged particles
(protons and electrons), their movement results in the emission
of electromagnetic radiation, which carries energy away from
the surface.
Evaporation
Evaporation is a type of vaporization, that occurs on
the surface of a liquid as it changes into the gaseous
phase.[1] The surrounding gas must not be saturated with the
evaporating substance. When the molecules of the liquid
collide, they transfer energy to each other based on how they
collide. When a molecule near the surface absorbs enough
energy to overcome the vapor pressure, it will "escape" and
enter the surrounding air as a gas.[2] When evaporation occurs,
the energy removed from the vaporized liquid will reduce the
temperature of the liquid, resulting in evaporative cooling.[3]
On average, only a fraction of the molecules in a liquid have
enough heat energy to escape from the liquid. The evaporation
will continue until an equilibrium is reached when the
evaporation of the liquid is the equal to its condensation. In an
enclosed environment, a liquid will evaporate until the
surrounding air is saturated.
Evaporation is an essential part of the water cycle. The sun
(solar energy) drives evaporation of water from oceans,
lakes, moisture in the soil, and other sources of water.
In hydrology, evaporation and transpiration (which involves
evaporation within plant stomata) are collectively
termed evapotranspiration. Evaporation of water occurs when
the surface of the liquid is exposed, allowing molecules to
escape and form water vapor; this vapor can then rise up and
form clouds. With sufficient energy, the liquid will turn into
vapor.
Heat exchanger
A heat exchanger is a device used to transfer heat between a
solid object and a fluid, or between two or more fluids. The
fluids may be separated by a solid wall to prevent mixing or
they may be in direct contact.[1] They are widely used in space
heating, refrigeration, air conditioning, power stations, chemical
plants, petrochemical plants, petroleum refineries, natural-gas
processing, and sewage treatment.
FLOW ARRANGEMENT
There are three primary classifications of heat exchangers
according to their flow arrangement. In parallel-flow heat
exchangers, the two fluids enter the exchanger at the same
end, and travel in parallel to one another to the other side.
In counter-flow heat exchangers the fluids enter the exchanger
from opposite ends. The counter current design is the most
efficient, in that it can transfer the most heat from the heat
(transfer) medium per unit mass due to the fact that the
average temperature difference along any unit length is higher.
See countercurrent exchange. In a cross-flow heat exchanger,
the fluids travel roughly perpendicular to one another through
the exchanger.
TYPES
1. SHELL AND TUBE HEAT EXCHANGER
2.PLATE HEAT EXCHANGER
3.PLATE AND SHELL HEAT EXCHANGER
4.PLATE FIN HEAT EXCHANGER
5.FLUID HEAT EXCHANGER
6.PILLOW PLATE HEAT EXCHANGER
MASS TRANSFER
Mass transfer is the net movement of mass from one location,
usually meaning stream, phase, fraction or component, to
another. Mass transfer occurs in many processes, such
as absorption, evaporation, drying, precipitation, membrane
filtration, and distillation. Mass transfer is used by different
scientific disciplines for different processes and mechanisms.
The phrase is commonly used in engineering for physical
processes that involve diffusive and convective transport
of chemical species within physical systems.
SORPTION
Sorption is a physical and chemical process by which
one substancebecomes attached to another. Specific cases of
sorption are treated in the following articles:
DRYING
Drying is a mass transfer process consisting of the removal of
water or another solvent[1] by evaporation from a solid, semi-
solid or liquid. This process is often used as a final production
step before selling or packaging products. To be considered
"dried", the final product must be solid, in the form of a
continuous sheet, long pieces, particles or powder . A source
of heatand an agent to remove the vapor produced by the
process are often involved. In bioproducts like food, grains,
and pharmaceuticals like vaccines, the solvent to be removed
is almost invariably water. Desiccation may
be synonymous with drying or considered an extreme form of
drying.
ADSORPTION
Adsorption is the adhesion of atoms, ions or molecules from a
gas, liquid or dissolved solid to a surface.[1] This process
creates a film of the adsorbate on the surface of the adsorbent.
This process differs from absorption, in which
a fluid (the absorbate) is dissolved by or permeates a liquid or
solid (the absorbent), respectively.[2] Adsorption is a surface-
based process, while absorption involves the whole volume of
the material. The term sorption encompasses both processes,
while desorption is the reverse of it. Adsorption is a surface
phenomenon.
THERMODYNAMIC PROCESS
Thermodynamic process is a passage of a thermodynamic
system from an initial to a final state of thermodynamic
equilibrium. The initial and final states are the defining elements
of the process. The actual course of the process is not the
primary concern, and thus often is ignored. This is the
customary default meaning of the term 'thermodynamic
process'. In general, during the actual course of a
thermodynamic process, the system passes through physical
states which are not describable as thermodynamic states,
because they are far from internal thermodynamic equilibrium.
Such processes are useful for thermodynamic theory.Defined
by change in a system, a thermodynamic process is a passage
of a thermodynamic system from an initial to a
final state of thermodynamic equilibrium. The initial and final
states are the defining elements of the process. The actual
course of the process is not the primary concern, and often is
ignored. A state of thermodynamic equilibrium endures
unchangingly unless it is interrupted by a thermodynamic
operation that initiates a thermodynamic process. The
equilibrium states are each respectively fully specified by a
suitable set of thermodynamic state variables, that depend only
on the current state of the system, not the path taken by the
processes that produce that state. In general, during the actual
course of a thermodynamic process, the system passes
through physical states which are not describable as
thermodynamic states, because they are far from internal
thermodynamic equilibrium.
LIQUIFICATION PROCESS
Liquefaction of gases is physical conversion of a gas into
a liquid state (condensation).
The processes are used for scientific, industrial and commercial
purposes. Many gases can be put into a liquid state at
normal atmospheric pressure by simple cooling; a few, such
as carbon dioxide, require pressurization as
well. Liquefaction is used for analyzing the fundamental
properties of gas molecules (intermolecular forces), for storage
of gases, for example: LPG, and in refrigeration and air
conditioning. There the gas is liquefied in the condenser, where
the heat of vaporization is released, and evaporated in
the evaporator, where the heat of vaporization is
absorbed. Ammonia was the first such refrigerant, and is still in
widespread use in industrial refrigeration, but it has largely
been replaced by compounds derived.
liquefaction is a process that generates a liquid from a solid or
a gas or that generates a non-liquid phase which behaves in
accordance with fluid dynamics. It occurs
both naturally and artificially. As an example of the latter, a
"major commercial application of liquefaction is the liquefaction
of air to allow separation of the constituents, such as oxygen,
nitrogen, and the noble gases." Another is the conversion of
solid coal into a liquid form usable as a substitute for liquid
fuels.
REFRIGERATION
CYCLIC REFRIGERATION
This consists of a refrigeration cycle, where heat is removed
from a low-temperature space or source and rejected to a high-
temperature sink with the help of external work, and its inverse,
the thermodynamic power cycle. In the power cycle, heat is
supplied from a high-temperature source to the engine, part of
the heat being used to produce work and the rest being
rejected to a low-temperature sink. This satisfies the second
law of thermodynamics.
SCREENING
A pulverizer or grinder is a mechanical device for the grinding
of many different types of materials. For example, a pulverizer
mill is used to pulverize coal for combustion in the steam-
generating furnaces of fossil fuel power plants.This practice
occurs in a variety of industries such as mining and mineral
processing, agriculture, pharmaceutical, food, plastics, and
recycling.
A screening machine consist of a drive that induces vibration, a
screen media that causes particle separation, and a deck which
holds the screen media and the drive and is the mode of
transport for the vibration.
CONCLUSION
In one or another concrete economic situation very successful
use can be made of the positive side of small-scale industry —
the greater gross and net output per unit of capital investment
as compared with the factory industry. At the same time it
should be remembered that large-scale factory production, first
of all the production of the means of production, must remain
the basis for the industrial development of the countries
investigated. Only the development of modern forms of industry
can guarantee these countries the most rapid and steady
movement along the road of progress. In our view, the present
role of small-scale industry is that it makes it possible not to
hurry with the development of certain branches and
enterprises, i.e., small-scale industry can supply the basic
branches with auxiliary output during the entire period of
transition to a developed economy. In addition to the fact that
such "auxiliary" use of forms with a low level of mechanization
will ensure the production of a number of deficit products, it will
also considerably increase general employment, and,
accordingly, the size of national income. In these forms of
production there will be a continuous growth of technical cadres
familiar with the principles of a given production unit, able to
use at least the most elementary work tools, and possessing
certain work skills.