CORRIGES DES EXERCICES (Initiation)

Exercice 1
(1) 5.87 T
(2) 62.86 MHz
(3) 5.67 T

Exercice 2
(1)
(2)
noyau H D T
M(g.mol-1) 1 2 3
γ (107 rad.s-1.T-2) 26.7519 4.1064 28.5336
I ½ 1 ½
ν (MHz) 90 13.81 95.99
(3) 5.22 ppm
(4) 5.22 ppm 72 Hz
(5) 5.22 ppm 501 Hz

Exercice 3

CH3
(a) (b)
Cl
Cl
H3C CH3

(c) (d)
O CH3
H3C O

O
(e) (f)

H3C CH3
O H3C CH3
(g) (h)
H3C Cl

O H3C CH3

(i)

Exercice 5
Jab < Jac
Exercice 6
Jab = 5Hz et Jac = 16.7Hz

1
Exercice 8 Exercice 13
CH3 1)
CH3
H3C

CH3 CH3

Exercice 9 H3C

O O
2)
H3C
O
O

H3C CH3
CH3

Exercice 10
H3C
Exercice 14
O CH3

NH2
H3C
Exercice 11
H3C
O CH3

O Exercice 15
+
N H3C O

-
O
Exercice 12

Cl H3C O
CH3

CH3

ϕCH3 ϕCH2Cl
C(ϕCH2Cl)/C(ϕCH3)=3/2

Exercice 16

Cl

Cl Cl
Cl

A B C

Cl

Cl