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Algebra
1. Let x be a real number with 0<x<. Prove that, for all natural numbers n,
the sum sinx + sin3x/3 + sin5x/5 + ... + sin(2n-1)x/(2n-1) is positive.
2. Use combinatorial argument to prove the identity:
n-r+1
Cd . r-1Cd-1 = nCr
d=1
2. The gas liberated on heating a mix of 2 salts with NaOH gives a reddish brown
ppt with an alk soln K2HgI4. The soln (aq) of the mix on treatment with BaCl2
gives a white pt which is sparingly solution in conc HCl. On heating the mix with
K2Cr2O7 and conc H2SO4 red vap of A are produced. The aq soln of the mix gives
a deep blue coloration B with pot ferricyanide soln. Identify the radicals and write
balanced eqns for formation of A and B?
3. A black colored compd A on reaction with dil H2SO4 gives a gas B which on
passing in a soln of an acid C gives a white turbidity D. Gas B when passed thro
acidified soln of E gives a ppt F solution in dil HNO3. After boiling this soln when
an excess of ammonium hydroxide is added a blue colored compd G is formed. To
this soln on addn of acetic acid and aq pot ferrocyanide a chocolate ppt H is
obtained. On addn of an aq soln of E a white ppt insol in HNO3 is obtained.
Identify A to H.
4. A mix of 2 salts were treated as follows:
i. The mix was heated with manganese dioxide and conc H2SO4 when
yellowish green gas was obtained.
ii. The mix on heating with sod hydroxide soln gave a gas, which turned red
litmus blue.
iii. Its soln in water gave blue ppt with pot ferricyanide and red coloration
with amm thiocyanate.
iv. The mix was boiled with pot hydroxide and the liberated gas was bubbled
thro an alk soln of K2HgI4 to give brown pt.
Identify the 2 salts. Give ionic reactions for the tests (i) to (iii).
8. The
shown arrangement
is in a horizontal
plane. The particle with
mass m is restricted to
move in an elliptical
orbit with shown
dimension. The particle has velocity v at the shown position towards right. Length
of rod is 2l. The coefficient of restitution between the particle and the rod is 1/3.
The moment of inertia of rod is I, about O.
i. Find the locus of mid-point of spring of force constant K3.
ii. Find the frequency of the rod.
iii. What would be the maximum angular displacement of the oscillating
system.