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log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
Fe(+2a) + H2O = FeOH(+a) + H(+a)
T deltaH
B' A' K kJ
-4666.72418 2.70993483 278.150 50.676
3.89515898 0.0121857 283.150 50.937
0.99998816 0.004524 288.150 51.135
1435403.14 17 293.150 51.286
29.3777284 0.00034793 298.150 51.400
303.150 51.488
308.150 51.557
∆�=𝐴+𝐵∗𝑇 313.150 51.613
318.150 51.658
B A 323.150 51.697
-0.05172984 89.2870716 328.150 51.729
0.00023368 0.07578418 333.150 51.754
0.99965322 0.02789509 338.150 51.775
49005.1258 17 343.150 51.795
38.1326628 0.01322832 348.150 51.816
353.150 51.838
358.150 51.861
363.150 51.887
368.150 51.916
Formula FM
g/mol
Fe(+2a) 55.847
H2O 18.015
g/mol
FeOH(+a) 72.854
H(+a) 1.008
Formula FM
g/mol
FeOH(+a) 72.854
g/mol
FeO(a) 71.846
H(+a) 1.008
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
= FeOH(+a) + H(+a)
deltaS deltaG K Log(K)
J/K kJ B' A'
-8.466 53.031 1.097E-010 -9.960 -2694.9961 -0.27546514
-7.536 53.071 1.618E-010 -9.791 1.68050824 0.00525734
-6.841 53.106 2.357E-010 -9.628 0.99999339 0.00195181
-6.322 53.139 3.393E-010 -9.469 2571786.98 17
-5.935 53.170 4.831E-010 -9.316 9.79738621 6.47626E-05
-5.642 53.199 6.804E-010 -9.167
-5.417 53.226 9.480E-010 -9.023
-5.239 53.253 1.307E-009 -8.884
-5.093 53.279 1.786E-009 -8.748
-4.973 53.304 2.416E-009 -8.617 B A
-4.875 53.329 3.240E-009 -8.490 0.00521413 51.6086964
-4.800 53.353 4.306E-009 -8.366 9.59808E-05 0.03112739
-4.737 53.377 5.677E-009 -8.246 0.99427256 0.01145755
-4.676 53.400 7.425E-009 -8.129 2951.16844 17
-4.617 53.423 9.637E-009 -8.016 0.38741626 0.00223168
-4.556 53.446 1.242E-008 -7.906
-4.490 53.469 1.589E-008 -7.799
-4.419 53.491 2.020E-008 -7.695
-4.339 53.513 2.551E-008 -7.593
O(a) + H(+a)
deltaS deltaG K Log(K)
J/K kJ B' A'
5.133 63.352 1.265E-012 -11.898 -3252.06784 -0.18811361
3.638 63.330 2.071E-012 -11.684 7.64053988 0.02390283
2.302 63.315 3.323E-012 -11.478 0.99990617 0.00887403
1.097 63.307 5.234E-012 -11.281 181163.666 17
0.000 63.304 8.100E-012 -11.092 14.2663587 0.00133872
-1.006 63.306 1.233E-011 -10.909
-1.937 63.314 1.848E-011 -10.733
-2.801 63.326 2.730E-011 -10.564
-3.607 63.342 3.977E-011 -10.400
-4.360 63.362 5.718E-011 -10.243 B A
-5.062 63.385 8.120E-011 -10.090 0.0038841 62.162436
-5.714 63.412 1.140E-010 -9.943 0.00044966 0.14582752
-6.325 63.442 1.582E-010 -9.801 0.81443801 0.05367707
-6.896 63.475 2.172E-010 -9.663 74.6135885 17
-7.428 63.511 2.953E-010 -9.530 0.21497871 0.04898087
-7.924 63.550 3.977E-010 -9.400
-8.383 63.590 5.307E-010 -9.275
-8.808 63.633 7.020E-010 -9.154
-9.197 63.678 9.211E-010 -9.036
= HFeO2(-a) + H(+a)
deltaS deltaG K Log(K)
J/K kJ B' A'
-93.225 48.541 7.650E-010 -9.116 -1208.58342 -4.77166314
-92.360 49.004 9.100E-010 -9.041 1.72838649 0.00540712
-91.701 49.464 1.078E-009 -8.967 0.99996523 0.00200742
-91.213 49.922 1.271E-009 -8.896 488957.977 17
-90.870 50.377 1.491E-009 -8.827 1.97036737 6.85054E-05
-90.649 50.831 1.741E-009 -8.759
-90.532 51.284 2.024E-009 -8.694
-90.508 51.736 2.341E-009 -8.631
-90.567 52.189 2.697E-009 -8.569
-90.703 52.642 3.091E-009 -8.510 B A
-90.913 53.096 3.528E-009 -8.452 0.09138899 23.1207713
-91.196 53.551 4.009E-009 -8.397 0.00011064 0.03588298
-91.537 54.008 4.535E-009 -8.343 0.99997508 0.01320802
-91.940 54.467 5.109E-009 -8.292 682224.276 17
-92.402 54.927 5.732E-009 -8.242 119.015264 0.00296568
-92.923 55.391 6.404E-009 -8.194
-93.501 55.857 7.126E-009 -8.147
-94.138 56.326 7.898E-009 -8.102
-94.833 56.798 8.721E-009 -8.059
= FeO(a) + 2H(+a)
deltaS deltaG K Log(K)
J/K kJ B' A'
-3.333 116.382 1.388E-022 -21.858 -5947.06394 -0.46357876
-3.898 116.400 3.350E-022 -21.475 6.00730797 0.01879339
-4.539 116.421 7.831E-022 -21.106 0.99998265 0.00697713
-5.225 116.446 1.776E-021 -20.751 980043.658 17
-5.935 116.474 3.914E-021 -20.407 47.7088734 0.00082757
-6.649 116.505 8.389E-021 -20.076
-7.354 116.540 1.752E-020 -19.756
-8.040 116.579 3.569E-020 -19.447
-8.701 116.621 7.101E-020 -19.149
-9.334 116.666 1.381E-019 -18.860 B A
-9.937 116.714 2.630E-019 -18.580 0.00909822 113.771132
-10.514 116.765 4.907E-019 -18.309 0.00035634 0.11556394
-11.062 116.819 8.979E-019 -18.047 0.97458537 0.04253746
-11.572 116.876 1.613E-018 -17.792 651.906034 17
-12.045 116.935 2.846E-018 -17.546 1.17958212 0.03076041
-12.479 116.996 4.939E-018 -17.306
-12.873 117.059 8.433E-018 -17.074
-13.226 117.125 1.418E-017 -16.848
-13.536 117.192 2.350E-017 -16.629
(-2)-H2O
278.15 298.15 368.15
5.84E-07 7.07E-06 5.18E-03
3.15E-05 1.45E-04 8.18E-03
1.21E-03 1.25E-02 6.05E+00
1.12E+07 2.59E+07 2.39E+08
1.11E+28 2.16E+27 2.84E+25
2a) = FeSO4
deltaS deltaG K Log(K)
J/K kJ B' A'
175.060 14.855 1.622E-003 -2.790 -4207.84819 12.2117133
184.828 13.955 2.664E-003 -2.575 55.868866 0.17478139
193.391 13.009 4.382E-003 -2.358 0.99701208 0.06488836
201.034 12.022 7.205E-003 -2.142 5672.57717 17
207.987 11.000 1.182E-002 -1.927 23.8843854 0.0715785
214.430 9.943 1.934E-002 -1.713
220.503 8.856 3.153E-002 -1.501
226.306 7.739 5.117E-002 -1.291
231.909 6.593 8.269E-002 -1.083
237.352 5.420 1.330E-001 -0.876 B A
242.652 4.220 2.129E-001 -0.672 -0.23585152 81.2213662
247.803 2.994 3.393E-001 -0.469 0.00331795 1.07603899
252.863 1.742 5.381E-001 -0.269 0.99664685 0.39607486
257.877 0.465 8.496E-001 -0.071 5052.86467 17
262.860 -0.837 1.335E+000 0.126 792.669621 2.66687996
267.824 -2.163 2.089E+000 0.320
272.783 -3.515 3.256E+000 0.513
277.751 -4.891 5.054E+000 0.704
282.741 -6.293 7.814E+000 0.893
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
CO2(a) + H2O = H2CO3(a)
T deltaH deltaS deltaG K
K kJ J/K kJ
278.150 5.568 17.837 0.606 7.694E-001
283.150 4.092 12.579 0.530 7.983E-001
288.150 2.662 7.572 0.480 8.184E-001
293.150 1.265 2.767 0.454 8.300E-001
298.150 -0.105 -1.867 0.452 8.333E-001
303.150 -1.454 -6.354 0.473 8.290E-001
308.150 -2.787 -10.718 0.515 8.178E-001
∆�=𝐴+𝐵∗𝑇 313.150 -4.108 -14.970 0.580 8.004E-001
318.150 -5.419 -19.122 0.665 7.777E-001
323.150 -6.722 -23.185 0.771 7.506E-001
328.150 -8.018 -27.166 0.897 7.199E-001
333.150 -9.309 -31.071 1.042 6.864E-001
338.150 -10.596 -34.907 1.207 6.509E-001
343.150 -11.881 -38.677 1.391 6.141E-001
348.150 -13.163 -42.387 1.594 5.766E-001
353.150 -14.444 -46.040 1.815 5.389E-001
358.150 -15.725 -49.640 2.054 5.016E-001
363.150 -17.005 -53.191 2.311 4.651E-001
368.150 -18.286 -56.696 2.586 4.296E-001
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
∆�=𝐴+𝐵∗𝑇
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
∆�=𝐴+𝐵∗𝑇
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
∆�=𝐴+𝐵∗𝑇
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
∆�=𝐴+𝐵∗𝑇
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
∆�=𝐴+𝐵∗𝑇
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
∆�=𝐴+𝐵∗𝑇
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
Log(K)
B' A'
-0.114 296.688542 -1.09159287
-0.098 40.4767274 0.12662828
-0.087 0.75963841 0.04701131
-0.081 53.7267741 17
-0.079 0.11873958 0.03757108
-0.081
-0.087
-0.097 ∆�=𝐴+𝐵∗𝑇
-0.109
-0.125 B A
-0.143 0.02240939 -6.16668877
-0.163 0.00241064 0.78179093
-0.186 0.83561574 0.28776627
-0.212 86.4162276 17
-0.239 7.15607844 1.40776029
-0.268
-0.300
-0.332
-0.367
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
Log(K)
B' A'
-10.551 -517.204954 -8.61179679
-10.486 35.3808151 0.11068612
-10.428 0.92630889 0.04109271
-10.376 213.692699 17
-10.330 0.36084384 0.02870639
-10.289
-10.253
-10.222
∆�=𝐴+𝐵∗𝑇
-10.194
-10.170 B A
-10.150 0.16617401 9.47566876
-10.132 0.00210017 0.68110428
-10.118 0.99729195 0.25070493
-10.106 6260.59076 17
-10.098 393.496673 1.06850036
-10.091
-10.088
-10.086
-10.087
SO4(-2a)-H2O Ligando
k\T 278.15 298.15 368.15
LogK k1' 1.85E-02 4.88E-02 6.33E-01
k2' 2.60E-02 1.15E-02 1.35E-03
𝐴′ + 𝐵′ * (1⁄𝑇)
SO3(a) + H2O = HSO4(-a) + H(+a)
T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
278.150 35.697 94.834 9.319 1.777E-002 -1.750
283.150 35.370 93.667 8.848 2.331E-002 -1.632
288.150 35.070 92.617 8.382 3.022E-002 -1.520
293.150 34.789 91.651 7.922 3.876E-002 -1.412
298.150 34.521 90.745 7.466 4.919E-002 -1.308
303.150 34.261 89.880 7.014 6.184E-002 -1.209
308.150 34.005 89.040 6.567 7.704E-002 -1.113
313.150 33.748 88.214 6.124 9.516E-002 -1.022
318.150 33.490 87.396 5.685 1.166E-001 -0.933
323.150 33.228 86.580 5.250 1.417E-001 -0.849
328.150 32.963 85.767 4.819 1.709E-001 -0.767
333.150 32.695 84.955 4.392 2.048E-001 -0.689
338.150 32.422 84.141 3.969 2.437E-001 -0.613
343.150 32.142 83.318 3.551 2.880E-001 -0.541
348.150 31.853 82.484 3.136 3.384E-001 -0.471
353.150 31.556 81.638 2.726 3.951E-001 -0.403
358.150 31.250 80.777 2.320 4.588E-001 -0.338
363.150 30.933 79.898 1.918 5.297E-001 -0.276
368.150 30.605 79.001 1.521 6.084E-001 -0.216
𝐴′ + 𝐵′ * (1⁄𝑇)
HSO4(-a) = SO4(-2a) + H(+a)
T deltaH deltaS deltaG K Log(K)
K kJ J/K kJ
278.150 -15.835 -88.979 8.914 2.117E-002 -1.674
283.150 -17.823 -96.064 9.377 1.862E-002 -1.730
288.150 -19.600 -102.285 9.874 1.622E-002 -1.790
293.150 -21.213 -107.836 10.399 1.402E-002 -1.853
298.150 -22.702 -112.872 10.951 1.206E-002 -1.919
303.150 -24.098 -117.516 11.527 1.032E-002 -1.986
308.150 -25.426 -121.863 12.126 8.798E-003 -2.056
313.150 -26.706 -125.983 12.746 7.479E-003 -2.126
318.150 -27.950 -129.923 13.385 6.341E-003 -2.198
323.150 -29.165 -133.713 14.045 5.366E-003 -2.270
328.150 -30.354 -137.364 14.722 4.532E-003 -2.344
333.150 -31.515 -140.876 15.418 3.823E-003 -2.418
338.150 -32.661 -144.290 16.131 3.221E-003 -2.492
343.150 -33.800 -147.634 16.861 2.712E-003 -2.567
348.150 -34.935 -150.918 17.607 2.281E-003 -2.642
353.150 -36.069 -154.152 18.370 1.917E-003 -2.717
358.150 -37.204 -157.345 19.149 1.611E-003 -2.793
363.150 -38.344 -160.506 19.943 1.353E-003 -2.869
368.150 -39.491 -163.643 20.754 1.135E-003 -2.945
𝐴′ + 𝐵′ * (1⁄𝑇)
S(-2a)-H2O Ligando
k\T 278.15
LogK k1' 5.50E-08
k2' 3.31E-14
log𝐾 = 𝐴′ + 𝐵′ * (1⁄𝑇)
H2S(a) = HS(-a) + H(+a)
T deltaH deltaS
B' A' K kJ J/K
-1744.90933 4.54101269 278.150 28.984 -36.413
8.29983978 0.0259654 283.150 27.131 -43.019
0.99961552 0.00963977 288.150 25.458 -48.876
44198.3758 17 293.150 23.922 -54.160
4.10714157 0.00157973 298.150 22.492 -59.000
303.150 21.141 -63.494
308.150 19.849 -67.719
∆�=𝐴+𝐵∗𝑇 313.150 18.603 -71.731
318.150 17.391 -75.572
B A 323.150 16.205 -79.269
-0.08661694 33.3023904 328.150 15.042 -82.841
0.00049599 0.16085276 333.150 13.899 -86.298
0.99944289 0.05920765 338.150 12.770 -89.663
30497.5541 17 343.150 11.647 -92.958
106.910556 0.05959427 348.150 10.529 -96.194
353.150 9.412 -99.380
358.150 8.293 -102.525
363.150 7.171 -105.636
368.150 6.043 -108.723
deltaG K Log(K)
kJ B' A'
39.113 4.511E-008 -7.346 -906.306208 -4.00105156
39.312 5.589E-008 -7.253 37.8670111 0.11846399
39.542 6.784E-008 -7.169 0.97117827 0.04398028
39.799 8.087E-008 -7.092 572.832771 17
40.082 9.487E-008 -7.023 1.10801045 0.03288251
40.389 1.097E-007 -6.960
40.717 1.252E-007 -6.903
41.066 1.411E-007 -6.850
41.434 1.573E-007 -6.803
41.821 1.735E-007 -6.761 B A
42.226 1.896E-007 -6.722 0.07800319 16.8946244
42.649 2.053E-007 -6.688 0.00224519 0.72813355
43.089 2.205E-007 -6.657 0.98611148 0.26801574
43.546 2.349E-007 -6.629 1207.03259 17
44.019 2.484E-007 -6.605 86.7040954 1.22115147
44.508 2.608E-007 -6.584
45.012 2.720E-007 -6.565
45.533 2.819E-007 -6.550
46.069 2.904E-007 -6.537
deltaG K Log(K)
kJ B' A'
71.910 3.124E-014 -13.505 -2462.0669 -4.62828699
72.318 4.549E-014 -13.342 14.8828026 0.04655969
72.722 6.547E-014 -13.184 0.9993792 0.01728549
73.127 9.308E-014 -13.031 27367.1931 17
73.534 1.307E-013 -12.884 8.17699334 0.0050794
73.944 1.811E-013 -12.742
74.359 2.480E-013 -12.606
74.780 3.353E-013 -12.475
75.208 4.478E-013 -12.349
75.644 5.911E-013 -12.228 B A
76.089 7.714E-013 -12.113 0.08915251 46.9523888
76.542 9.954E-013 -12.002 0.00090918 0.29485316
77.005 1.270E-012 -11.896 0.99823514 0.10853131
77.477 1.605E-012 -11.795 9615.49984 17
77.959 2.006E-012 -11.698 113.261414 0.20024378
78.452 2.484E-012 -11.605
78.954 3.047E-012 -11.516
79.467 3.705E-012 -11.431
79.990 4.465E-012 -11.350
LogK
278.15 298.15 368.15 A
H2CO3(a) = HCO3(-a) + H(+a) -6.495 -6.366 -6.069 -4.74879241
HCO3(-a) = CO3(-2a) + H(+a) -10.551 -10.330 -10.087 -8.61179679
Puntos de intersección
)
Log(K) 1/T DG=A+BT
K^-1 A B r2
-6.495 0.004 9.19029431 0.09106653 0.99986507
-6.460 0.004
-6.427 0.003 0.0910665321 9.190294312
-6.395 0.003 0.0002565788 0.083210669
-6.366 0.003 0.9998650682 0.03062868
-6.338 0.003 125972.545414 17
-6.311 0.003 118.1768641 0.015947972
-6.285 0.003
-6.261 0.003 logk=A+B(1/T)
-6.238 0.003 A B r2
-6.216 0.003 -4.74879241 -482.806364 0.99862442
-6.194 0.003
-6.174 0.003 -482.80636438 -4.748792411
-6.154 0.003 4.3460104109 0.013596154
-6.136 0.003 0.9986244175 0.005047633
-6.118 0.003 12341.4005534 17
-6.101 0.003 0.3144415421 0.000433136
-6.084 0.003
-6.069 0.003
A= 0.49472
I= 0.1
carga Log(ϒi) ϒi
H2CO3 0 0.01 1.023292992
HCO3(-a -1 -0.1089636004 0.778101763
H(+a) 1 -0.1089636004 0.778101763
CO3(-2a) -2 -0.4358544018 0.366560444
Constantes reales
H2CO3(a) = HCO3(-a) + H(+a) K1 = 1.892685E-07
HCO3(-a) = CO3(-2a) + H(+a) K2 = 1.029928E-11
A= 0.49472
I= 0.01
carga Log(ϒi) ϒi
H2CO3 0 0.001 1.002305238
HCO3(-a -1 -0.1089636004 0.778101763
H(+a) 1 -0.1089636004 0.778101763
CO3(-2a) -2 -0.4358544018 0.366560444
Constantes reales
H2CO3(a) = HCO3(-a) + H(+a) K1 = 1.932317E-07
HCO3(-a) = CO3(-2a) + H(+a) K2 = 1.0299E-11
A= 0.49472
I= 0.001
carga Log(ϒi) ϒi
H2CO3 0 0.0001 1.000230285
HCO3(-a -1 -0.1089636004 0.778101763
H(+a) 1 -0.1089636004 0.778101763
CO3(-2a) -2 -0.4358544018 0.366560444
Constantes reales
H2CO3(a) = HCO3(-a) + H(+a) K1 = 1.936326E-07
HCO3(-a) = CO3(-2a) + H(+a) K2 = 1.029928E-11
5°C 25°C
PORCENTAJES
∑[CO32-] =
5°C
PORCENTAJES
Ph [H+] [H2CO3]% [HCO3-]% [CO3-2]
0 1 100% 0% 0%
0.5 0.316227766 100% 0% 0%
1 0.1 100% 0% 0%
1.5 0.031622777 100% 0% 0%
2 0.01 100% 0% 0%
2.5 0.003162278 100% 0% 0%
3 0.001 100% 0% 0%
3.5 0.000316228 100% 0% 0%
4 0.0001 100% 0% 0%
4.5 3.162278E-05 99% 1% 0%
5 0.00001 98% 2% 0%
5.5 3.162278E-06 94% 6% 0%
6 0.000001 84% 16% 0%
6.5 3.162278E-07 63% 37% 0%
7 0.0000001 35% 65% 0%
7.5 3.162278E-08 14% 86% 0%
8 0.00000001 5% 95% 0%
8.5 3.162278E-09 2% 98% 0%
9 0.000000001 1% 98% 1%
9.5 3.162278E-10 0% 97% 3%
10 1E-10 0% 91% 9%
10.5 3.162278E-11 0% 75% 25%
11 1E-11 0% 49% 51%
11.5 3.162278E-12 0% 23% 77%
12 1E-12 0% 9% 91%
12.5 3.162278E-13 0% 3% 97%
13 1E-13 0% 1% 99%
13.5 3.162278E-14 0% 0% 100%
14 1E-14 0% 0% 100%
5°C
PORCENTAJES
Ph [H+] [H2CO3]% [HCO3-]% [CO3-2]%
0 1 100% 0% 0%
0.5 0.316227766 100% 0% 0%
1 0.1 100% 0% 0%
1.5 0.031622777 100% 0% 0%
2 0.01 100% 0% 0%
2.5 0.003162278 100% 0% 0%
3 0.001 100% 0% 0%
3.5 0.000316228 100% 0% 0%
4 0.0001 100% 0% 0%
4.5 3.162278E-05 99% 1% 0%
5 0.00001 98% 2% 0%
5.5 3.162278E-06 94% 6% 0%
6 0.000001 84% 16% 0%
6.5 3.162278E-07 63% 38% 0%
7 0.0000001 35% 67% 0%
7.5 3.162278E-08 14% 87% 0%
8 0.00000001 5% 97% 0%
8.5 3.162278E-09 2% 100% 0%
9 0.000000001 1% 101% 1%
9.5 3.162278E-10 0% 99% 3%
10 1E-10 0% 93% 10%
10.5 3.162278E-11 0% 77% 25%
11 1E-11 0% 50% 52%
11.5 3.162278E-12 0% 24% 78%
12 1E-12 0% 9% 93%
12.5 3.162278E-13 0% 3% 99%
13 1E-13 0% 1% 101%
13.5 3.162278E-14 0% 0% 102%
14 1E-14 0% 0% 102%
5°C
PORCENTAJES
Ph [H+] [H2CO3]% [HCO3-]% [CO3-2]
0 1 100% 0% 0%
0.5 0.316227766 100% 0% 0%
1 0.1 100% 0% 0%
1.5 0.031622777 100% 0% 0%
2 0.01 100% 0% 0%
2.5 0.003162278 100% 0% 0%
3 0.001 100% 0% 0%
3.5 0.000316228 100% 0% 0%
4 0.0001 100% 0% 0%
4.5 3.162278E-05 99% 1% 0%
5 0.00001 98% 2% 0%
5.5 3.162278E-06 94% 6% 0%
6 0.000001 84% 16% 0%
6.5 3.162278E-07 62% 37% 0%
7 0.0000001 34% 64% 0%
7.5 3.162278E-08 14% 84% 0%
8 0.00000001 5% 93% 0%
8.5 3.162278E-09 2% 96% 0%
9 0.000000001 1% 96% 1%
9.5 3.162278E-10 0% 95% 3%
10 1E-10 0% 89% 9%
10.5 3.162278E-11 0% 74% 24%
11 1E-11 0% 48% 50%
11.5 3.162278E-12 0% 23% 75%
12 1E-12 0% 9% 89%
12.5 3.162278E-13 0% 3% 95%
13 1E-13 0% 1% 97%
13.5 3.162278E-14 0% 0% 97%
14 1E-14 0% 0% 98%
25°C 95°C
PORCENTAJES
0.001
-5
-10
Diagrama de Bjerrum (5°C)
0
-5.2837938 -3.0067153 -4.9939083676 0 2 4 6 8 10
-5.7916998 -3.0146213 -4.5018143605
-5
-6.3198591 -3.0427807 -4.029973709
-6.8995758 -3.1224973 -3.6096903738 -10
-7.5845704 -3.307492 -3.2946850253
-8.4061755 -3.6290971 -3.1162901326 -15
-9.3301295 -4.0530511 -3.0402441001
-10.303019 -4.5259409 -3.0131339259 -20
-11.294082 -5.0170034 -3.0041964078
-12.291217 -5.5141384 -3.0013314092 -25
-13.290307 -6.0132284 -3.00042147 l og[H2CO3] l og[HCO3-] l og[CO
-20
-5
-10
-25
l og[H2CO3] l og[HCO3-] l og[CO
-25
l og[H2CO3] l og[HCO3-] l og[CO3
∑[CO32-] = 0.001
95°C
PORCENTAJES 25°C
-5
-10
-15
4 6 8 10 12 14 -20
[H2CO3]% [HCO3-]% [CO3-2] l og[H2CO3] l og[HCO3-] l og[CO32-]
-25
MA DE PREDOMINANCIA(5°C
H2CO3(a) = HCO3(-a) + H(+a)
HCO3(-a) = CO3(-2a) + H(+a)
A=
I=
H2CO3
6 8 10 12 14 16 HCO3(-a)
CO3]% [HCO3-]% [CO3-2] H(+a)
CO3(-2a)
A=
I=
H2CO3
HCO3(-a)
MA DE PREDOMINANCIA(5°C) H(+a)
CO3(-2a)
6 8 10 12 14 16
CO3]% [HCO3-]% [CO3-2]
H2CO3
HCO3(-a)
H(+a)
MA DE PREDOMINANCIA(5°C CO3(-2a)
6 8 10 12 14 16
CO3]% [HCO3-]% [CO3-2]
-5
-10
-15
-20
og[HCO3-] l og[CO32-]
l og[H2CO3] l og[HCO3-] l og[CO32-]
-25
25°C
Constantes ideales T=25°C
Ph [H+]
2CO3(a) = HCO3(-a) + H(+a) K1 = 4.307034E-07
CO3(-a) = CO3(-2a) + H(+a) K2 = 4.67625E-11 0 1
0.5 0.31622777
1 0.1
1.5 0.03162278
2 0.01
2.5 0.00316228
3 0.001
0.5092 3.5 0.00031623
0.1 4 0.0001
4.5 3.1623E-05
carga Log(ϒi) ϒi 5 0.00001
0 0.01 1.02329299 5.5 3.1623E-06
-1 -0.1121529 0.77240866 6 0.000001
1 -0.1121529 0.77240866 6.5 3.1623E-07
-2 -0.4486115 0.35594963 7 0.0000001
7.5 3.1623E-08
Constantes reales 8 0.00000001
2CO3(a) = HCO3(-a) + H(+a) K1 = 2.51115E-07 8.5 3.1623E-09
CO3(-a) = CO3(-2a) + H(+a) K2 = 1.664509E-11 9 1E-09
9.5 3.1623E-10
10 1E-10
10.5 3.1623E-11
11 1E-11
11.5 3.1623E-12
12 1E-12
12.5 3.1623E-13
13 1E-13
13.5 3.1623E-14
14 1E-14
0.5092
0.01 25°C
0.5092 25°C
0.001
Ph [H+]
carga Log(ϒi) ϒi
0 0.0001 1.00023029 0 1
-1 -0.0155069 0.96492401 0.5 0.31622777
1 -0.0155069 0.96492401 1 0.1
-2 -0.0620275 0.86690689 1.5 0.03162278
2 0.01
Constantes reales 2.5 0.00316228
2CO3(a) = HCO3(-a) + H(+a) K1 = 4.009263E-07 3 0.001
CO3(-a) = CO3(-2a) + H(+a) K2 = 4.053873E-11 3.5 0.00031623
4 0.0001
4.5 3.1623E-05
5 0.00001
5.5 3.1623E-06
6 0.000001
6.5 3.1623E-07
7 0.0000001
7.5 3.1623E-08
8 0.00000001
8.5 3.1623E-09
9 1E-09
9.5 3.1623E-10
10 1E-10
10.5 3.1623E-11
11 1E-11
11.5 3.1623E-12
12 1E-12
12.5 3.1623E-13
13 1E-13
13.5 3.1623E-14
14 1E-14
95°C
-5
-10
-15
-20
-25
l og[H2CO3] l og[HCO3-] l og[CO32-]
l og[CO32-]
25°C
PORCENTAJES
[H2CO3]% [HCO3-]% [CO3-2] log[H2CO3] log[HCO3-] log[CO32-]
25°C
PORCENTAJES
[H2CO3]% [HCO3-]% [CO3-2] log[H2CO3] log[HCO3-] log[CO32-]
25°C
PORCENTAJES
[H2CO3]% [HCO3-]% [CO3-2] log[H2CO3] log[HCO3-] log[CO32-]
l og[CO32-]
Constantes ideales
A= 0.5926
I= 0.1
carga Log(ϒi)
H2CO3 0 0.01
HCO3(-a) -1 -0.130522
H(+a) 1 -0.130522
CO3(-2a) -2 -0.5220879
Constantes reales
H2CO3(a) = HCO3(-a) + H(+a)
HCO3(-a) = CO3(-2a) + H(+a)
A= 0.5926
I= 0.01
carga Log(ϒi)
H2CO3 0 0.001
HCO3(-a) -1 -0.0526875
H(+a) 1 -0.0526875
CO3(-2a) -2 -0.2107501
Constantes reales
H2CO3(a) = HCO3(-a) + H(+a)
HCO3(-a) = CO3(-2a) + H(+a)
A= 0.5926
I= 0.001
carga Log(ϒi)
H2CO3 0 0.0001
HCO3(-a) -1 -0.0180467
H(+a) 1 -0.0180467
CO3(-2a) -2 -0.0721868
Constantes reales
H2CO3(a) = HCO3(-a) + H(+a)
HCO3(-a) = CO3(-2a) + H(+a)
T=95°C
K1 = 8.537E-007
K2 = 8.194E-011
ϒi
1.0232929923
0.7404198081
0.7404198081
0.3005468046
K1 = 4.573827E-07
K2 = 2.462563E-11
ϒi
1.0023052381
0.8857526753
0.8857526753
0.6155309443
K1 = 6.682648E-07
K2 = 5.043419E-11
ϒi
1.000230285
0.9592974662
0.9592974662
0.84686306
K1 = 7.854711E-07
K2 = 6.938864E-11
% de predominancia y bejerrum para S(-2) - H2O
1.5
1.0
0.5
0.0
-1.0
-1.5
H2O Limits
-2.0
-4 -2 0 2 4 6 8 10 12 14 16 18 20
C:\HSC6\EpH\S25.IEP pH
Reacciones
5°C
Porcentajes
PH [H+] [H2S]%
0 1
0.5 0.316227766
1 0.1
DG = A + B*T 1.5 0.031622777
A B r2 2 0.01
16.8946244 0.07800319 0.98611148 2.5 0.003162278
3 0.001
0.07800319 16.8946244 3.5 0.000316228
0.00224519 0.72813355 4 0.0001
0.98611148 0.26801574 4.5 3.162278E-05
1207.03259 17 5 0.00001
86.7040954 1.22115147 5.5 3.162278E-06
6 0.000001
6.5 3.162278E-07
Log(K) = A' + B'/T 7 0.0000001
A' B' r2 7.5 3.162278E-08
-4.0010516 -906.30621 0.97117827 8 0.00000001
8.5 3.162278E-09
-906.30621 -4.0010516 9 0.000000001
37.8670111 0.11846399 9.5 3.162278E-10
0.97117827 0.04398028 10 1E-10
572.832771 17 10.5 3.162278E-11
1.10801045 0.03288251 11 1E-11
11.5 3.162278E-12
12 1E-12
12.5 3.162278E-13
13 1E-13
13.5 3.162278E-14
14 1E-14
DG = A + B*T 14.5 3.162278E-15
A B r2 15 1E-15
46.9523888 0.08915251 15.5 3.162278E-16
16 1E-16
0.08915251 46.9523888 16.5 3.162278E-17
0.00090918 0.29485316 17 1E-17
0.99823514 0.10853131 17.5 3.162278E-18
9615.49984 17 18 1E-18
113.261414 0.20024378 18.5 3.162278E-19
19 1E-19
Log(K) = A' + B'/T 19.5 3.162278E-20
A' B' r2 20 1E-20
-4.628287 -2462.0669 0.9993792
-2462.0669 -4.628287
14.8828026 0.04655969
0.9993792 0.01728549
27367.1931 17
8.17699334 0.0050794
5°C
Porcentajes
[HS-]% [S2-]%
Reacciones
Fe(+2a) + 2H2O = Fe(OH)2 + 2H(+a) k1 = [H(+a)]2/ [Fe(+2a)]
FeOH(+a) + H2O = Fe(OH)2 + H(+a) k2 = [H(+a)] / [FeOH(+a)]
FeO(a) + H2O = Fe(OH)2 k3 = 1 / [FeO(a)]
HFeO2(-a) + H(+a) = Fe(OH)2 k4 = 1 / [HFeO2(-a)][H(+a)]
[𝐻𝐹𝑒𝑂2(−𝑎)]= 1/(𝑘4∗[𝐻])
Log [Fe+2]
-4
1.43E-14 1.09E-19 -3.00E+00 -8.96E+00 -1.68E+01 -2.20E+01
1.43E-13 3.46E-18 -3.00E+00 -8.46E+00 -1.58E+01 -2.05E+01 -5
1.43E-12 1.09E-16 -3.00E+00 -7.96E+00 -1.48E+01 -1.90E+01 -6
1.43E-11 3.46E-15 -3.00E+00 -7.46E+00 -1.38E+01 -1.75E+01
-7
1.43E-10 1.09E-13 -3.00E+00 -6.96E+00 -1.28E+01 -1.60E+01
1.43E-09 3.46E-12 -3.00E+00 -6.46E+00 -1.18E+01 -1.45E+01 -8
1.43E-08 1.09E-10 -3.00E+00 -5.96E+00 -1.08E+01 -1.30E+01 -9
1.43E-07 3.45E-09 -3.00E+00 -5.47E+00 -9.85E+00 -1.15E+01
-10
1.42E-06 1.08E-07 -3.00E+00 -4.97E+00 -8.85E+00 -9.97E+00
1.38E-05 3.34E-06 -3.01E+00 -4.48E+00 -7.86E+00 -8.48E+00
1.29E-04 9.86E-05 -3.04E+00 -4.01E+00 -6.89E+00 -7.01E+00
1.06E-03 2.57E-03 -3.13E+00 -3.59E+00 -5.97E+00 -5.59E+00
6.48E-03 4.95E-02 -3.34E+00 -3.31E+00 -5.19E+00 -4.31E+00
1.78E-02 4.31E-01 -3.90E+00 -3.37E+00 -4.75E+00 -3.37E+00
1.17E-02 8.92E-01 -5.09E+00 -4.05E+00 -4.93E+00 -3.05E+00
4.08E-03 9.86E-01 -6.55E+00 -5.01E+00 -5.39E+00 -3.01E+00
1.31E-03 9.98E-01 -8.04E+00 -6.00E+00 -5.88E+00 -3.00E+00
4.14E-04 9.99E-01 -9.54E+00 -7.00E+00 -6.38E+00 -3.00E+00
1.31E-04 1.00E+00 -1.10E+01 -8.00E+00 -6.88E+00 -3.00E+00
4.14E-05 1.00E+00 -1.25E+01 -9.00E+00 -7.38E+00 -3.00E+00
1.31E-05 1.00E+00 -1.40E+01 -1.00E+01 -7.88E+00 -3.00E+00
4.14E-06 1.00E+00 -1.55E+01 -1.10E+01 -8.38E+00 -3.00E+00
1.31E-06 1.00E+00 -1.70E+01 -1.20E+01 -8.88E+00 -3.00E+00
4.14E-07 1.00E+00 -1.85E+01 -1.30E+01 -9.38E+00 -3.00E+00
1.31E-07 1.00E+00 -2.00E+01 -1.40E+01 -9.88E+00 -3.00E+00
4.14E-08 1.00E+00 -2.15E+01 -1.50E+01 -1.04E+01 -3.00E+00
1.31E-08 1.00E+00 -2.30E+01 -1.60E+01 -1.09E+01 -3.00E+00
4.14E-09 1.00E+00 -2.45E+01 -1.70E+01 -1.14E+01 -3.00E+00
1.31E-09 1.00E+00 -2.60E+01 -1.80E+01 -1.19E+01 -3.00E+00
Log [Fe+2]
-4
3.89E-13 5.82E-18 -3.00E+00 -8.31E+00 -1.54E+01 -2.02E+01
3.89E-12 1.84E-16 -3.00E+00 -7.81E+00 -1.44E+01 -1.87E+01 -5
3.89E-11 5.82E-15 -3.00E+00 -7.31E+00 -1.34E+01 -1.72E+01 -6
3.89E-10 1.84E-13 -3.00E+00 -6.81E+00 -1.24E+01 -1.57E+01
-7
3.89E-09 5.81E-12 -3.00E+00 -6.31E+00 -1.14E+01 -1.42E+01
3.88E-08 1.84E-10 -3.00E+00 -5.82E+00 -1.04E+01 -1.27E+01 -8
3.87E-07 5.79E-09 -3.00E+00 -5.32E+00 -9.41E+00 -1.12E+01 -9
3.83E-06 1.81E-07 -3.01E+00 -4.82E+00 -8.42E+00 -9.74E+00
-10
3.71E-05 5.55E-06 -3.02E+00 -4.34E+00 -7.43E+00 -8.26E+00
3.37E-04 1.59E-04 -3.06E+00 -3.88E+00 -6.47E+00 -6.80E+00
2.60E-03 3.89E-03 -3.17E+00 -3.49E+00 -5.58E+00 -5.41E+00
1.41E-02 6.67E-02 -3.44E+00 -3.25E+00 -4.85E+00 -4.18E+00
3.23E-02 4.83E-01 -4.08E+00 -3.40E+00 -4.49E+00 -3.32E+00
1.91E-02 9.01E-01 -5.31E+00 -4.12E+00 -4.72E+00 -3.05E+00
6.59E-03 9.85E-01 -6.77E+00 -5.09E+00 -5.18E+00 -3.01E+00
2.11E-03 9.97E-01 -8.27E+00 -6.08E+00 -5.68E+00 -3.00E+00
6.68E-04 9.99E-01 -9.76E+00 -7.08E+00 -6.18E+00 -3.00E+00
2.11E-04 1.00E+00 -1.13E+01 -8.08E+00 -6.67E+00 -3.00E+00
6.69E-05 1.00E+00 -1.28E+01 -9.08E+00 -7.17E+00 -3.00E+00
2.11E-05 1.00E+00 -1.43E+01 -1.01E+01 -7.67E+00 -3.00E+00
6.69E-06 1.00E+00 -1.58E+01 -1.11E+01 -8.17E+00 -3.00E+00
2.11E-06 1.00E+00 -1.73E+01 -1.21E+01 -8.67E+00 -3.00E+00
6.69E-07 1.00E+00 -1.88E+01 -1.31E+01 -9.17E+00 -3.00E+00
2.11E-07 1.00E+00 -2.03E+01 -1.41E+01 -9.67E+00 -3.00E+00
6.69E-08 1.00E+00 -2.18E+01 -1.51E+01 -1.02E+01 -3.00E+00
2.11E-08 1.00E+00 -2.33E+01 -1.61E+01 -1.07E+01 -3.00E+00
6.69E-09 1.00E+00 -2.48E+01 -1.71E+01 -1.12E+01 -3.00E+00
2.11E-09 1.00E+00 -2.63E+01 -1.81E+01 -1.17E+01 -3.00E+00
6.69E-10 1.00E+00 -2.78E+01 -1.91E+01 -1.22E+01 -3.00E+00
Log [Fe+2]
-4
2.41E-09 2.13E-13 -3.00E+00 -6.60E+00 -1.16E+01 -1.57E+01
2.41E-08 6.72E-12 -3.00E+00 -6.10E+00 -1.06E+01 -1.42E+01 -5
2.41E-07 2.12E-10 -3.00E+00 -5.60E+00 -9.62E+00 -1.27E+01 -6
2.39E-06 6.68E-09 -3.00E+00 -5.10E+00 -8.62E+00 -1.12E+01
-7
2.35E-05 2.08E-07 -3.01E+00 -4.61E+00 -7.63E+00 -9.68E+00
2.23E-04 6.23E-06 -3.03E+00 -4.13E+00 -6.65E+00 -8.21E+00 -8
1.92E-03 1.69E-04 -3.10E+00 -3.69E+00 -5.72E+00 -6.77E+00 -9
1.32E-02 3.67E-03 -3.26E+00 -3.36E+00 -4.88E+00 -5.44E+00
-10
6.05E-02 5.33E-02 -3.60E+00 -3.20E+00 -4.22E+00 -4.27E+00
1.33E-01 3.71E-01 -4.26E+00 -3.36E+00 -3.88E+00 -3.43E+00
9.16E-02 8.08E-01 -5.42E+00 -4.02E+00 -4.04E+00 -3.09E+00
3.42E-02 9.54E-01 -6.85E+00 -4.94E+00 -4.47E+00 -3.02E+00
1.12E-02 9.88E-01 -8.33E+00 -5.93E+00 -4.95E+00 -3.01E+00
3.57E-03 9.96E-01 -9.83E+00 -6.93E+00 -5.45E+00 -3.00E+00
1.13E-03 9.99E-01 -1.13E+01 -7.92E+00 -5.95E+00 -3.00E+00
3.58E-04 1.00E+00 -1.28E+01 -8.92E+00 -6.45E+00 -3.00E+00
1.13E-04 1.00E+00 -1.43E+01 -9.92E+00 -6.95E+00 -3.00E+00
3.59E-05 1.00E+00 -1.58E+01 -1.09E+01 -7.45E+00 -3.00E+00
1.13E-05 1.00E+00 -1.73E+01 -1.19E+01 -7.95E+00 -3.00E+00
3.59E-06 1.00E+00 -1.88E+01 -1.29E+01 -8.45E+00 -3.00E+00
1.13E-06 1.00E+00 -2.03E+01 -1.39E+01 -8.95E+00 -3.00E+00
3.59E-07 1.00E+00 -2.18E+01 -1.49E+01 -9.45E+00 -3.00E+00
1.13E-07 1.00E+00 -2.33E+01 -1.59E+01 -9.95E+00 -3.00E+00
3.59E-08 1.00E+00 -2.48E+01 -1.69E+01 -1.04E+01 -3.00E+00
1.13E-08 1.00E+00 -2.63E+01 -1.79E+01 -1.09E+01 -3.00E+00
3.59E-09 1.00E+00 -2.78E+01 -1.89E+01 -1.14E+01 -3.00E+00
1.13E-09 1.00E+00 -2.93E+01 -1.99E+01 -1.19E+01 -3.00E+00
3.59E-10 1.00E+00 -3.08E+01 -2.09E+01 -1.24E+01 -3.00E+00
1.13E-10 1.00E+00 -3.23E+01 -2.19E+01 -1.29E+01 -3.00E+00
Solubilidad 5C
2 4 6 8 10 12 14 16 18
0
-1
-2
Fe(OH)2
-3
Log [Fe+2]
-4
-5
-6
-7
-8
Fe(+2a) FeOH(+a) HFeO2(-a)
-9
-10
pH
-1
-2
Fe(OH)2
-3
Log [Fe+2]
-4
-5
-6
-7
-10
pH
-1
-2
Fe(OH)2
-3
Log [Fe+2]
-4
-5
-6
-7
-10
pH
80%
70%
60%
% Fe+2
50%
40%
30%
20%
10%
0%
2 4 6 8 10 12 14 16
pH
70%
60%
% Fe+2
50%
40%
30%
20%
10%
0%
2 4 6 8 10 12 14 16
pH
70%
60%
% Fe+2
50%
40%
30%
20%
10%
0%
2 4 6 8 10 12 14 16
pH
-4
-5
Log [Fe+2]
-6
-7
-8
-9
14 16 18 -10
pH
-4
-5
Log [Fe+2]
-6
-7
-8
-9
14 16 18 -10
pH
-4
-5
Log [Fe+2]
-6
-7
-8
-9
14 16 18 -10
pH
HFeO2(-a)
g%FeO(a ) Log%HFeO2(-a)
12 14 16 18
HFeO2(-a)
gFeO(a) LogHFeO2(-a )
12 14 16 18
HFeO2(-a)
gFeO(a) LogHFeO2(-a )
Reacciones
Fe(+2a) + CO2(a) + H2O = FeCO3 + 2H(+a) k1 = [H(+a)]2/ [Fe(+2a)]*[CO2(a)]
Fe(+2a) + HCO3(-a) = FeCO3 + H(+a) k2 = [H(+a)] / [Fe(+2a)]*[HCO3(-a)]
FeOH(+a) + HCO3(-a) = FeCO3 + H2O k3 = 1 / [FeOH(+a)]*[HCO3(-a)]
HFeO2(-a) + HCO3(-a) + 2H(+a) = FeCO3 + 2H2O k4 = 1 / [HFeO2(-a)]*[H(+a)]2*[HCO3(-a)]
HFeO2(-a) + CO3(-2a) + 3H(+a) = FeCO3 + 2H2O k5 = 1 / [HFeO2(-a)]*[H(+a)]3*[CO3(-2a)]
CO2(a)
0.001
Log [Fe+2]
-3
-5.51E+00 -1.15E+01 -2.45E+01 -3.09E+01
-5.01E+00 -1.05E+01 -2.25E+01 -2.84E+01 -5
-4.52E+00 -9.49E+00 -2.05E+01 -2.60E+01 -7
-4.05E+00 -8.51E+00 -1.85E+01 -2.35E+01
-9
-3.63E+00 -7.59E+00 -1.66E+01 -2.11E+01
-3.31E+00 -6.77E+00 -1.48E+01 -1.87E+01 -11
CO2(a)
-3.12E+00 -6.09E+00 -1.31E+01 -1.66E+01 -13
-3.04E+00 -5.51E+00 -1.15E+01 -1.45E+01
-15
-3.02E+00 -4.98E+00 -9.98E+00 -1.25E+01
-3.02E+00 -4.48E+00 -8.48E+00 -1.05E+01
-3.05E+00 -4.01E+00 -7.01E+00 -8.48E+00
Log[Fe
-3.13E+00 -3.59E+00 -5.59E+00 -6.56E+00
Log[H
-3.35E+00 -3.31E+00 -4.31E+00 -4.78E+00
-4.06E+00 -3.53E+00 -3.53E+00 -3.50E+00
-5.69E+00 -4.66E+00 -3.65E+00 -3.12E+00
-7.61E+00 -6.07E+00 -4.07E+00 -3.04E+00
-9.58E+00 -7.54E+00 -4.54E+00 -3.01E+00
-1.16E+01 -9.04E+00 -5.03E+00 -3.00E+00
-1.36E+01 -1.05E+01 -5.53E+00 -3.00E+00
-1.56E+01 -1.20E+01 -6.03E+00 -3.00E+00
-1.76E+01 -1.35E+01 -6.53E+00 -3.00E+00
-1.96E+01 -1.50E+01 -7.03E+00 -3.00E+00
-2.16E+01 -1.65E+01 -7.53E+00 -3.00E+00
-2.36E+01 -1.80E+01 -8.03E+00 -3.00E+00
-2.56E+01 -1.95E+01 -8.53E+00 -3.00E+00
-2.76E+01 -2.10E+01 -9.03E+00 -3.00E+00
-2.96E+01 -2.25E+01 -9.53E+00 -3.00E+00
-3.16E+01 -2.40E+01 -1.00E+01 -3.00E+00
-3.36E+01 -2.55E+01 -1.05E+01 -3.00E+00
Log [Fe+2]
-3
-5.47E+00 -1.08E+01 -2.27E+01 -1.87E+01
-4.97E+00 -9.78E+00 -2.07E+01 -1.62E+01 -5
-4.48E+00 -8.79E+00 -1.87E+01 -1.37E+01 -7
-4.01E+00 -7.82E+00 -1.67E+01 -1.12E+01
-9
-3.59E+00 -6.91E+00 -1.48E+01 -8.83E+00
-3.28E+00 -6.10E+00 -1.30E+01 -6.52E+00 -11
-3.13E+00 -5.45E+00 -1.14E+01 -4.37E+00 -13 CO2(a)
-3.84E+00 -5.65E+00 -1.06E+01 -3.08E+00
-15
-5.77E+00 -7.08E+00 -1.10E+01 -3.00E+00
-7.76E+00 -8.58E+00 -1.15E+01 -3.00E+00
-9.76E+00 -1.01E+01 -1.20E+01 -3.00E+00
Log[F
-1.18E+01 -1.16E+01 -1.25E+01 -3.00E+00
Log[H
-1.38E+01 -1.31E+01 -1.30E+01 -3.00E+00
-1.58E+01 -1.46E+01 -1.35E+01 -3.00E+00
-1.78E+01 -1.61E+01 -1.40E+01 -3.00E+00
-1.98E+01 -1.76E+01 -1.45E+01 -3.00E+00
-2.18E+01 -1.91E+01 -1.50E+01 -3.00E+00
-2.38E+01 -2.06E+01 -1.55E+01 -3.00E+00
-2.58E+01 -2.21E+01 -1.60E+01 -3.00E+00
-2.78E+01 -2.36E+01 -1.65E+01 -3.00E+00
-2.98E+01 -2.51E+01 -1.70E+01 -3.00E+00
-3.18E+01 -2.66E+01 -1.75E+01 -3.00E+00
-3.38E+01 -2.81E+01 -1.80E+01 -3.00E+00
-3.58E+01 -2.96E+01 -1.85E+01 -3.00E+00
-3.78E+01 -3.11E+01 -1.90E+01 -3.00E+00
-3.98E+01 -3.26E+01 -1.95E+01 -3.00E+00
-4.18E+01 -3.41E+01 -2.00E+01 -3.00E+00
-4.38E+01 -3.56E+01 -2.05E+01 -3.00E+00
-4.58E+01 -3.71E+01 -2.10E+01 -3.00E+00
Log [Fe+2]
-3
-5.35E+00 -8.94E+00 -2.11E+01 -1.40E+01
-4.85E+00 -7.95E+00 -1.91E+01 -1.15E+01 -5
-4.37E+00 -6.96E+00 -1.71E+01 -9.04E+00 -7
-3.90E+00 -6.00E+00 -1.52E+01 -6.58E+00
-9
-3.54E+00 -5.13E+00 -1.33E+01 -4.21E+00
-4.36E+00 -5.46E+00 -1.26E+01 -3.03E+00 -11
-6.33E+00 -6.92E+00 -1.31E+01 -3.00E+00 -13
-8.33E+00 -8.42E+00 -1.36E+01 -3.00E+00 CO2(a)
-15
-1.03E+01 -9.92E+00 -1.41E+01 -3.00E+00
-1.23E+01 -1.14E+01 -1.46E+01 -3.00E+00
-1.43E+01 -1.29E+01 -1.51E+01 -3.00E+00
Log[F
-1.63E+01 -1.44E+01 -1.56E+01 -3.00E+00
Log[H
-1.83E+01 -1.59E+01 -1.61E+01 -3.00E+00
-2.03E+01 -1.74E+01 -1.66E+01 -3.00E+00
-2.23E+01 -1.89E+01 -1.71E+01 -3.00E+00
-2.43E+01 -2.04E+01 -1.76E+01 -3.00E+00
-2.63E+01 -2.19E+01 -1.81E+01 -3.00E+00
-2.83E+01 -2.34E+01 -1.86E+01 -3.00E+00
-3.03E+01 -2.49E+01 -1.91E+01 -3.00E+00
-3.23E+01 -2.64E+01 -1.96E+01 -3.00E+00
-3.43E+01 -2.79E+01 -2.01E+01 -3.00E+00
-3.63E+01 -2.94E+01 -2.06E+01 -3.00E+00
-3.83E+01 -3.09E+01 -2.11E+01 -3.00E+00
-4.03E+01 -3.24E+01 -2.16E+01 -3.00E+00
-4.23E+01 -3.39E+01 -2.21E+01 -3.00E+00
-4.43E+01 -3.54E+01 -2.26E+01 -3.00E+00
-4.63E+01 -3.69E+01 -2.31E+01 -3.00E+00
-4.83E+01 -3.84E+01 -2.36E+01 -3.00E+00
-5.03E+01 -3.99E+01 -2.41E+01 -3.00E+00
Solubilidad 5C
0 2 4 6 8 10 12 14
5
3
FeCO3
1
-1
Log [Fe+2]
-3
-5
-7
-9
-11
CO2(a) HCO3(-a) CO3(-2a)
-13
-15
pH
-3
% Fe+2
-5 50%
-7 40%
-9 30%
-11 20%
-3
% Fe+2
-5 50%
-7 40%
-9 30%
-11 20%
CO3(-2a)
-13 10%
CO2(a) HCO3(-a)
-15 0%
pH 2
60%
% Fe+2
50%
40%
30%
20%
10%
0%
2 4 6 8 10 12 14 16 18
pH
80%
70%
60%
% Fe+2
50%
40%
30%
20%
10%
0%
2 4 6 8 10 12 14 16 18
pH
70%
60%
% Fe+2
50%
40%
30%
20%
10%
0%
2 4 6 8 10 12 14 16 18
pH
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
16 18 -18
-20
pH
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
16 18 -20
pH
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
16 18 -20
pH
CO3(-2a)
O2(-a)I Log%HFeO2(-a)II
10 12 14
CO3(-2a)
O2(-a)I Log%HFeO2(-a)II
10 12 14
CO3(-2a)
O2(-a)I Log%HFeO2(-a)II
Reacciones
Fe(+2a) + SO3(a) + H2O = FeSO4 + 2H(+a) k1 = [H(+a)]2/ [Fe(+2a)]*[SO3(a)]
Fe(+2a) + HSO4(-a) = FeSO4 + H(+a) k2 = [H(+a)] / [Fe(+2a)]*[HSO4(-a)]
Fe(+2a) + SO4(-2a) = FeSO4 k3 = 1 / [Fe(+2a)]*[SO4(-a)]
FeOH(+a) + SO4(-2a) + H(+a) = FeSO4 + H2O k4 = 1 / [FeOH(+a)]*[H(+a)]*[SO4(-2a)]
HFeO2(-a) + SO4(-2a) + 3H(+a) = FeSO4 + 2H2O k5 = 1 / [HFeO2(-a)]*[H(+a)]3*[SO4(-2a)]
SO4(-2a)
0.01
5
-3.00E+00 -8.97E+00 -2.20E+01
-3.00E+00 -8.46E+00 -2.05E+01
-3.00E+00 -7.96E+00 -1.90E+01 0
-3.00E+00 -7.46E+00 -1.75E+01
-3.00E+00 -6.96E+00 -1.60E+01
-3.00E+00 -6.46E+00 -1.45E+01 -5
-3.00E+00 -5.96E+00 -1.30E+01
-3.00E+00 -5.47E+00 -1.15E+01 SO3(a)
-10
-3.00E+00 -4.97E+00 -9.97E+00
-3.01E+00 -4.48E+00 -8.48E+00
-3.04E+00 -4.01E+00 -7.01E+00
Log[Fe(+2a )] I L
-3.13E+00 -3.59E+00 -5.59E+00
Log[FeOH(+a )] L
-3.34E+00 -3.31E+00 -4.30E+00
-3.90E+00 -3.36E+00 -3.36E+00
-5.08E+00 -4.05E+00 -3.04E+00
-6.54E+00 -5.01E+00 -3.00E+00
-8.04E+00 -6.00E+00 -3.00E+00
-9.54E+00 -7.00E+00 -3.00E+00
-1.10E+01 -8.00E+00 -3.00E+00
-1.25E+01 -9.00E+00 -3.00E+00
-1.40E+01 -1.00E+01 -3.00E+00
-1.55E+01 -1.10E+01 -3.00E+00
-1.70E+01 -1.20E+01 -3.00E+00
-1.85E+01 -1.30E+01 -3.00E+00
-2.00E+01 -1.40E+01 -3.00E+00
-2.15E+01 -1.50E+01 -3.00E+00
-2.30E+01 -1.60E+01 -3.00E+00
-2.45E+01 -1.70E+01 -3.00E+00
-2.60E+01 -1.80E+01 -3.00E+00
Log [Fe+2]
5
-3.00E+00 -8.32E+00 -2.02E+01
-3.00E+00 -7.82E+00 -1.87E+01
-3.00E+00 -7.31E+00 -1.72E+01 0
-3.00E+00 -6.81E+00 -1.57E+01
-3.00E+00 -6.31E+00 -1.42E+01
-3.00E+00 -5.82E+00 -1.27E+01 -5
-3.00E+00 -5.32E+00 -1.12E+01 SO3(a)
-3.01E+00 -4.82E+00 -9.74E+00 HSO4(-a)
-10
-3.02E+00 -4.34E+00 -8.26E+00
-3.06E+00 -3.88E+00 -6.80E+00
-3.17E+00 -3.49E+00 -5.41E+00
Log[Fe(+2a )] I
-3.43E+00 -3.25E+00 -4.17E+00
Log[FeOH(+a )]
-4.07E+00 -3.38E+00 -3.30E+00
-5.30E+00 -4.12E+00 -3.04E+00
-6.77E+00 -5.08E+00 -3.00E+00
-8.26E+00 -6.08E+00 -3.00E+00
-9.76E+00 -7.08E+00 -3.00E+00
-1.13E+01 -8.08E+00 -3.00E+00
-1.28E+01 -9.08E+00 -3.00E+00
-1.43E+01 -1.01E+01 -3.00E+00
-1.58E+01 -1.11E+01 -3.00E+00
-1.73E+01 -1.21E+01 -3.00E+00
-1.88E+01 -1.31E+01 -3.00E+00
-2.03E+01 -1.41E+01 -3.00E+00
-2.18E+01 -1.51E+01 -3.00E+00
-2.33E+01 -1.61E+01 -3.00E+00
-2.48E+01 -1.71E+01 -3.00E+00
-2.63E+01 -1.81E+01 -3.00E+00
-2.78E+01 -1.91E+01 -3.00E+00
Log [Fe+2]
5
-3.03E+00 -6.63E+00 -1.57E+01
-3.01E+00 -6.11E+00 -1.42E+01
-3.00E+00 -5.60E+00 -1.27E+01 0
-3.00E+00 -5.10E+00 -1.12E+01
-3.01E+00 -4.61E+00 -9.68E+00
-3.03E+00 -4.13E+00 -8.21E+00 -5
-3.10E+00 -3.69E+00 -6.77E+00
-3.26E+00 -3.35E+00 -5.43E+00 SO3(a) HSO4(-a)
-10
-3.57E+00 -3.17E+00 -4.25E+00
-4.20E+00 -3.29E+00 -3.37E+00
-5.38E+00 -3.97E+00 -3.05E+00
Log[Fe(+2a)] I
-6.83E+00 -4.93E+00 -3.01E+00
Log[FeOH(+a)]
-8.33E+00 -5.92E+00 -3.00E+00
-9.83E+00 -6.92E+00 -3.00E+00
-1.13E+01 -7.92E+00 -3.00E+00
-1.28E+01 -8.92E+00 -3.00E+00
-1.43E+01 -9.92E+00 -3.00E+00
-1.58E+01 -1.09E+01 -3.00E+00
-1.73E+01 -1.19E+01 -3.00E+00
-1.88E+01 -1.29E+01 -3.00E+00
-2.03E+01 -1.39E+01 -3.00E+00
-2.18E+01 -1.49E+01 -3.00E+00
-2.33E+01 -1.59E+01 -3.00E+00
-2.48E+01 -1.69E+01 -3.00E+00
-2.63E+01 -1.79E+01 -3.00E+00
-2.78E+01 -1.89E+01 -3.00E+00
-2.93E+01 -1.99E+01 -3.00E+00
-3.08E+01 -2.09E+01 -3.00E+00
-3.23E+01 -2.19E+01 -3.00E+00
Solubilidad 5C
4 6 8 10 12 14 100%
90% SO3(a)
FeSO4
80%
70%
60%
% Fe+2
50%
40%
30%
20%
10%
SO4(-2a)
0%
0 2 4
pH
90%
HSO4(-a)
FeSO4
80%
70%
11 60% SO3(a)
% Fe+2
50%
40%
30%
20%
10%
SO4(-2a)
0%
0 2 4
pH
90%
SO3(a)
FeSO4
80% HSO4(-a)
70%
60%
% Fe+2
50%
40%
30%
20%
10%
SO4(-2a)
0%
pH 0 2 4
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
2 4 6 8 10 12 14 -20
pH
-4
-6
O3(a)
-8
Log [Fe+2]
-10
-12
-14
-16
-18
2 4 6 8 10 12 14 -20
pH
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
2 4 6 8 10 12 14 -20
pH
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
-20
pH
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
-20
pH
-4
-6
-8
Log [Fe+2]
-10
-12
-14
-16
-18
-20
pH
Eh
Eh(Volts)
(Volts) Cd
Cd--H2O
H2O--System
Systemat
at5.00
5.00 CC
2.0
2.0
1.5
1.5
1.0
1.0
95
95
0.5
0.5
0.0
0.0 9595
9595 95
95 95
95
CdO(a)
CdO(a) Cd(OH)4(-2a)
Cd(OH)4(-2a)
Cd(+2a)
Cd(+2a)
-0.5
-0.5 95
HCdO2(-a)
HCdO2(-a)
95
CdOH(+a)
CdOH(+a)
-1.0
-1.0
-1.5
-1.5
H
H22O
O lim
limits
its
-2.0
-2.0
00 22 44 66 88 10
10 12
12 14
14 16
16 18
18 20
20
C:\HSC6\EpH\CEpHSD0.EPT
C:\HSC6\EpH\CEpHSD0.EPT pH
pH
ELEMENTS
ELEMENTS Molality
Molality Pressure
Pressure
Cd
Cd 1.000E-05
1.000E-05 1.000E+00
1.000E+00
1.5
1.5
1.0
1.0
0.5
0.5
0.0
0.0
H2S(a)
H2S(a) HS(-a)
HS(-a) S(-2a)
S(-2a)
-0.5
-0.5
-1.0
-1.0
-1.5
-1.5
H
H22O
O lim
limits
its
H
H22O
O lim
limits
its
-2.0
-2.0
00 22 44 66 88 10
10 12
12 14
14 16
16 18
18 20
20
20
20
C:\HSC6\EpH\S5.iep
C:\HSC6\EpH\S5.iep pH
pH
pH
pH
ELEMENTS
ELEMENTS Molality
Molality Pressure
Pressure
SS 1.000E-02
1.000E-02 1.000E+00
1.000E+00
1/T
0.00359518
0.0035317
G=H+S*T 0.00347041
A B R^2 0.00341122
-37.305744 -0.0108166 0.88475444 0.00335402
-0.0108166 -37.305744 0.0032987
0.0009468 0.30706062 0.00324517
0.8847544 0.11302471 0.00319336
130.51111 17 0.00314317
1.6672252 0.21716793 0.00309454
0.00304739
LogK = A + B(1/T) 0.00300165
A' B' R^2 0.00295727
0.59617382 1938.79213 0.9988417 0.00291418
1938.79213 0.59617382 0.00287233
16.0128968 0.0500951 0.00283166
0.9988417 0.01859803 0.00279213
14659.6192 17 0.00275368
5.07056604 0.00588007 0.00271628
ml
ml
ml
ml
1/T
0.00359518
G=H+S*T 0.0035317
A B R^2 0.00347041
-54.200368 -0.0888198 0.99637851 0.00341122
-0.0888198 -54.200368 0.00335402
0.0012987 0.42118712 0.0032987
0.9963785 0.15503307 0.00324517
4677.1943 17 0.00319336
112.41755 0.40859929 0.00314317
0.00309454
LogK = A + B(1/T) 0.00304739
A' B' R^2 0.00300165
4.5972254 2845.09834 0.99899747 0.00295727
2845.09834 4.59722538 0.00291418
21.8594424 0.06838556 0.00287233
0.99899747 0.02538844 0.00283166
16940.117 17 0.00279213
10.9191419 0.01095774 0.00275368
0.00271628
ml
ml
ml
ml
1/T
0.00359518
0.0035317
G=H+S*T 0.00347041
A B R^2 0.00341122
-108.44168 -0.0993819 0.99643435 0.00335402
-0.0993819 -108.44168 0.0032987
0.0014419 0.46761232 0.00324517
0.9964343 0.17212154 0.00319336
4750.714 17 0.00314317
140.74381 0.50363899 0.00309454
0.00304739
LogK = A + B(1/T) 0.00300165
A' B' R^2 0.00295727
5.1443217 5680.10938 0.99969106 0.00291418
5680.10938 5.1443217 0.00287233
24.2180234 0.0757642 0.00283166
0.99969106 0.02812779 0.00279213
55009.2859 17 0.00275368
43.5218494 0.01344994 0.00271628
ml
ml
ml
ml
ml
De los graficos de Cd-H2O Y S-H2O obtenemos las ecuaciones:
H
H22O
O lim
limits
its 5 HCdO2(-a) + S(-2a) + 3H(+a) = CdS + 2H2O
20
20
pH
pH
6 Cd(OH)4(-2a) + S(-2a) + 4H(+a) = CdS + 4H2O
LogK = A + B(1/T)
A' B' R^2
19.002328 16482.8091 0.9992361
16482.8091 19.0023278
110.533098 0.34579417
0.9992361 0.12837762
22237.0806 17
366.485168 0.28017382
Log K K(HSC) K (Es
5° C 5° C A'
𝑆][𝐻2𝑂]4/( 𝐾6[𝑆][𝐻]4)
liminamos los solidos:
remos que para cada ecuación el azufre que se usara es: ∑S = 1.00E-02
S]) [Cd]
2.71340556502808E-06
Log [Cd]
-5.5664852886
[Cd]
1.49323090842861E-13
Log [Cd]
-12.8258730292
[Cd]
2.72049990842955E-24
2.71340556502808E-07 -6.5664852886 4.72201074319673E-14 -13.3258730292 2.72049990842955E-24
2.71340556502808E-08 -7.5664852886 1.49323090842861E-14 -13.8258730292 2.72049990842955E-24
2.71340556502808E-09 -8.5664852886 4.72201074319673E-15 -14.3258730292 2.72049990842955E-24
2.71340556502808E-10 -9.5664852886 1.49323090842861E-15 -14.8258730292 2.72049990842955E-24
2.71340556502808E-11 -10.5664852886 4.72201074319673E-16 -15.3258730292 2.72049990842955E-24
2.71340556502808E-12 -11.5664852886 1.49323090842861E-16 -15.8258730292 2.72049990842955E-24
2.71340556502808E-13 -12.5664852886 4.72201074319673E-17 -16.3258730292 2.72049990842955E-24
2.71340556502808E-14 -13.5664852886 1.49323090842861E-17 -16.8258730292 2.72049990842955E-24
2.71340556502808E-15 -14.5664852886 4.72201074319673E-18 -17.3258730292 2.72049990842955E-24
2.71340556502808E-16 -15.5664852886 1.49323090842861E-18 -17.8258730292 2.72049990842955E-24
2.71340556502808E-17 -16.5664852886 4.72201074319673E-19 -18.3258730292 2.72049990842955E-24
2.71340556502808E-18 -17.5664852886 1.49323090842861E-19 -18.8258730292 2.72049990842955E-24
2.71340556502808E-19 -18.5664852886 4.72201074319673E-20 -19.3258730292 2.72049990842955E-24
2.71340556502808E-20 -19.5664852886 1.49323090842861E-20 -19.8258730292 2.72049990842955E-24
2.71340556502808E-21 -20.5664852886 4.72201074319673E-21 -20.3258730292 2.72049990842955E-24
2.71340556502808E-22 -21.5664852886 1.49323090842861E-21 -20.8258730292 2.72049990842955E-24
2.71340556502808E-23 -22.5664852886 4.72201074319673E-22 -21.3258730292 2.72049990842955E-24
2.71340556502808E-24 -23.5664852886 1.49323090842861E-22 -21.8258730292 2.72049990842955E-24
2.71340556502808E-25 -24.5664852886 4.72201074319673E-23 -22.3258730292 2.72049990842955E-24
2.71340556502808E-26 -25.5664852886 1.49323090842861E-23 -22.8258730292 2.72049990842955E-24
2.71340556502808E-27 -26.5664852886 4.72201074319673E-24 -23.3258730292 2.72049990842955E-24
2.71340556502808E-28 -27.5664852886 1.49323090842861E-24 -23.8258730292 2.72049990842955E-24
2.71340556502808E-29 -28.5664852886 4.72201074319673E-25 -24.3258730292 2.72049990842955E-24
2.71340556502808E-30 -29.5664852886 1.49323090842861E-25 -24.8258730292 2.72049990842955E-24
2.71340556502808E-31 -30.5664852886 4.72201074319673E-26 -25.3258730292 2.72049990842955E-24
2.71340556502808E-32 -31.5664852886 1.49323090842861E-26 -25.8258730292 2.72049990842955E-24
2.71340556502808E-33 -32.5664852886 4.72201074319673E-27 -26.3258730292 2.72049990842955E-24
2.71340556502808E-34 -33.5664852886 1.49323090842861E-27 -26.8258730292 2.72049990842955E-24
2.71340556502808E-35 -34.5664852886 4.72201074319673E-28 -27.3258730292 2.72049990842955E-24
2.71340556502808E-36 -35.5664852886 1.49323090842861E-28 -27.8258730292 2.72049990842955E-24
2.71340556502808E-37 -36.5664852886 4.72201074319673E-29 -28.3258730292 2.72049990842955E-24
2.71340556502808E-38 -37.5664852886 1.49323090842861E-29 -28.8258730292 2.72049990842955E-24
2.71340556502808E-39 -38.5664852886 4.72201074319673E-30 -29.3258730292 2.72049990842955E-24
2.71340556502808E-40 -39.5664852886 1.49323090842861E-30 -29.8258730292 2.72049990842955E-24
2.71340556502808E-41 -40.5664852886 4.72201074319673E-31 -30.3258730292 2.72049990842955E-24
2.71340556502808E-42 -41.5664852886 1.49323090842861E-31 -30.8258730292 2.72049990842955E-24
2.71340556502808E-43 -42.5664852886 4.72201074319673E-32 -31.3258730292 2.72049990842955E-24
2.71340556502808E-44 -43.5664852886 1.49323090842861E-32 -31.8258730292 2.72049990842955E-24
2.71340556502808E-45 -44.5664852886 4.72201074319673E-33 -32.3258730292 2.72049990842955E-24
2.71340556502808E-46 -45.5664852886 1.49323090842861E-33 -32.8258730292 2.72049990842955E-24
10
0
0 5
10
0
0 5
-10
-20
-30
-40
-50
-60
-70
-80
-90
K (Estimación lineal)
B' Log K K
𝑑𝑆][𝐻2𝑂]/
/(
𝐾5[𝑆][𝐻]3) +
5 10 15 20 25
5 10 15 20 25
Cd (+2a) + H2S(a) = Cd
Cd (+2a) + HS (-a) = Cd
CdOH(+a) + HS (-a) = C
CdO(a) + HS(-a) + H(+a
HCdO2(-a) + S(-2a) + 3
Cd(OH)4(-2a) + S(-2a)
Log[∑Cd]
[Cd]= 1/(K_5 [Cd]= 1/(K_6
[S] 〖 [H] 〗 [S] 〖 [H] 〗
^3 )+ S(-2a) + 3H(+a) = CdS + 2H2O
HCdO2(-a) ^4 ) + S(-2a) + 4H(+a) = CdS + 4H2O
Cd(OH)4(-2a)
[Cd] Log [Cd] [Cd] Log [Cd]
.95362043242224E-62 -61.5296453163 5.48234158142025E-77 -76.2610339089
.34016791006571E-61 -60.0296453163 5.48234158142025E-75 -74.2610339089
.95362043242224E-59 -58.5296453163 5.48234158142025E-73 -72.2610339089
.34016791006572E-58 -57.0296453163 5.48234158142025E-71 -70.2610339089
.95362043242224E-56 -55.5296453163 5.48234158142025E-69 -68.2610339089
.34016791006572E-55 -54.0296453163 5.48234158142025E-67 -66.2610339089
.95362043242224E-53 -52.5296453163 5.48234158142025E-65 -64.2610339089
.34016791006572E-52 -51.0296453163 5.48234158142025E-63 -62.2610339089
.95362043242224E-50 -49.5296453163 5.48234158142025E-61 -60.2610339089
.34016791006571E-49 -48.0296453163 5.48234158142025E-59 -58.2610339089
.95362043242224E-47 -46.5296453163 5.48234158142025E-57 -56.2610339089
.34016791006572E-46 -45.0296453163 5.48234158142025E-55 -54.2610339089
.95362043242224E-44 -43.5296453163 5.48234158142025E-53 -52.2610339089
.34016791006572E-43 -42.0296453163 5.48234158142025E-51 -50.2610339089
.95362043242224E-41 -40.5296453163 5.48234158142025E-49 -48.2610339089
.34016791006572E-40 -39.0296453163 5.48234158142025E-47 -46.2610339089
.95362043242224E-38 -37.5296453163 5.48234158142025E-45 -44.2610339089
.34016791006572E-37 -36.0296453163 5.48234158142025E-43 -42.2610339089
.95362043242224E-35 -34.5296453163 5.48234158142025E-41 -40.2610339089
.34016791006572E-34 -33.0296453163 5.48234158142025E-39 -38.2610339089
.95362043242224E-32 -31.5296453163 5.48234158142025E-37 -36.2610339089
.34016791006571E-31 -30.0296453163 5.48234158142025E-35 -34.2610339089
.95362043242224E-29 -28.5296453163 5.48234158142025E-33 -32.2610339089
.34016791006571E-28 -27.0296453163 5.48234158142025E-31 -30.2610339089
.95362043242224E-26 -25.5296453163 5.48234158142025E-29 -28.2610339089
.34016791006572E-25 -24.0296453163 5.48234158142025E-27 -26.2610339089
.95362043242224E-23 -22.5296453163 5.48234158142025E-25 -24.2610339089
.34016791006571E-22 -21.0296453163 5.48234158142025E-23 -22.2610339089
.95362043242224E-20 -19.5296453163 5.48234158142025E-21 -20.2610339089
.34016791006572E-19 -18.0296453163 5.48234158142025E-19 -18.2610339089
.95362043242224E-17 -16.5296453163 5.48234158142025E-17 -16.2610339089
.34016791006572E-16 -15.0296453163 5.48234158142025E-15 -14.2610339089
.95362043242224E-14 -13.5296453163 5.48234158142025E-13 -12.2610339089
.34016791006571E-13 -12.0296453163 5.48234158142025E-11 -10.2610339089
.95362043242224E-11 -10.5296453163 5.48234158142025E-09 -8.2610339089
.34016791006571E-10 -9.0296453163 5.48234158142025E-07 -6.2610339089
.95362043242224E-08 -7.5296453163 5.48234158142025E-05 -4.2610339089
0.000000934 -6.0296453163 0.0054823416 -2.2610339089
.95362043242224E-05 -4.5296453163 0.5482341581 -0.2610339089
0.0009340168 -3.0296453163 54.8234158142 1.7389660911
0.0295362043 -1.5296453163 5482.3415814203 3.7389660911
Cd (+2a) + H2S(a) = CdS + 2H(+a)
Cd (+2a) + HS (-a) = CdS + H(+a)
CdOH(+a) + HS (-a) = CdS + H2O
CdO(a) + HS(-a) + H(+a) = CdS + H2O
HCdO2(-a) + S(-2a) + 3H(+a) = CdS + 2H2O
Cd(OH)4(-2a) + S(-2a) + 4H(+a) = CdS + 4H2O
Log[∑Cd]
∑[Cd] Log[∑Cd]
1.4932309E-13 -12.8258730292
2.713406E-07 -6.566485213
2.7134071E-08 -7.5664850496
2.7134103E-09 -8.5664845328
2.7134205E-10 -9.5664828986
2.7134528E-11 -10.5664777309
2.7135549E-12 -11.5664613894
2.7138778E-13 -12.566409717
2.7148988E-14 -13.5662463551
2.7181276E-15 -14.565730163
2.7283379E-16 -15.5641018438
2.7606259E-17 -16.5589924348
2.8627314E-18 -17.543219402
3.1856338E-19 -18.4968041432
4.2069086E-20 -19.3760369285
7.4381377E-21 -20.1285357873
1.7672947E-21 -20.7526910216
5.0206432E-22 -21.2992406396
1.5478448E-22 -21.8102725787
5.0298869E-23 -22.2984417813
1.7954811E-23 -22.7458191537
8.3144348E-24 -23.0801672691
6.9627144E-24 -23.1572214192
1.1885761E-23 -22.9249730233
3.0386244E-23 -22.5173229842
9.0628198E-23 -22.0427366548
3.0768814E-22 -21.5118892439
1.8607752E-21 -20.7303060872
3.7769951E-20 -19.4228535833
1.4909458E-18 -17.8265381534
8.438711E-17 -16.0737238877
6.4164453E-15 -14.192705504
5.7777064E-13 -12.238244533
5.5757433E-11 -10.2536972251
5.5118778E-09 -8.2587004203
5.4916817E-07 -6.2602946387
0.000054853 -4.2607999951
0.0054832756 -2.2609599252
0.5482636943 -0.2610105119
54.824349831 1.73897349
5482.3711176 3.7389684309