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  • Alcohol, Ether: Xercise

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    Krishan Lal
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    The document is a chemistry document that provides 30 multiple choice questions about alcohols, ethers, esters and reactions involving them. It covers topics like esterification, hydrolysis, acetylation, oxidation and reduction of alcohols. The questions test understanding of reaction mechanisms, reactivity patterns and molecular changes involved in different chemical transformations between alcohols, esters, acids and related functional groups.

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    Motion iit

    Original Title

    Ex-1

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    The document is a chemistry document that provides 30 multiple choice questions about alcohols, ethers, esters and reactions involving them. It covers topics like esterification, hydrolysis, acetylation, oxidation and reduction of alcohols. The questions test understanding of reaction mechanisms, reactivity patterns and molecular changes involved in different chemical transformations between alcohols, esters, acids and related functional groups.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    17 views9 pages

    Alcohol, Ether: Xercise

    Uploaded by

    Krishan Lal
    The document is a chemistry document that provides 30 multiple choice questions about alcohols, ethers, esters and reactions involving them. It covers topics like esterification, hydrolysis, acetylation, oxidation and reduction of alcohols. The questions test understanding of reaction mechanisms, reactivity patterns and molecular changes involved in different chemical transformations between alcohols, esters, acids and related functional groups.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 9

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    Solution Slot - 3 (Chemistry) Page # 123

    ALCOHOL , ETHER
    EXERCISE – I
    1 A
    D

    Value of x  5

    C
    A
    Total no. of HCHO in A = 1
    2. A

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Page # 124 Solution Slot - 3 (Chemistry)

    3. B

    4. B

    5 C

    6. C

    –H2O
    OH OH
    ••
    OH OH2 OH

    Ring Expans

    OH

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Solution Slot - 3 (Chemistry) Page # 125

    7 B

    8 A

    9 C

    10 B Me–CH Me–CH
    | |
    CH–OH CHO
    | 2 HIO4
    CH–OH O O + H–C–OH
    |
    CH–OH CHO O
    | |
    HC CH
    |
    CH2OH

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Page # 126 Solution Slot - 3 (Chemistry)

    11. B

    O CH2
    CH2–OH
    O | CH2
    CH2–OH
    O
    CH–COOEt H
    CH–COOEt
    | |
    CH3 CH
    (A) 3

    LiAlH4

    O CH2
    O
    CH2
    H3 O
    O
    CH–CH2–OH CH–CH2–OH
    | |
    CH3 CH
    (B) 3

    12 B

    13 B

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Solution Slot - 3 (Chemistry) Page # 127

    14 C

    KCN
    Ph–CH2–Cl Ph–CH 2–CN Ph–CH2–COOH

    18
    CH3–OH

    18
    Ph–CH2–C–OCH3
    O

    15 B

    Ph–C–CH2–C–OEt Ph–C–CH2–C–OH

    O O O O

    Ph–C–CH3

    16. D

    Order of alcohal towards esterification


    CH3–OH > 1°alcohal > 2°alcohal > 3°alchoal.

    17. B

    O O–C–CH 3

    CH3C–OH

    OH CH3 OH
    3° alcohal

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Page # 128 Solution Slot - 3 (Chemistry)

    18. B

    19. A

    O O
    H 3O
    R1–C–OH+R–OH R1–C–OR+H 2O

    CH3
    |
    –CH3 > –CH2–CH3 > –CH–CH3 > –C–CH3
    | |
    CH3 CH3

    20. B

    21. B

    H2O/OH 18
    Ph–C–OCH3 Ph–C–OH + CH3–OH
    Basic Medium
    O O

    Hydrolysis of ester in basic Medium is known as saponification.

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Solution Slot - 3 (Chemistry) Page # 129

    22. B

    23. C

    O O O O
    NaOEt
    CH3–C–CH2–C–OEt CH3–C–CH–C–OEt

    CH3–I

    O O

    CH3–C–CH–C–OEt

    CH3

    CH3–C–CH2–CH3 CH3–C–CH–C–OH

    O O CH3 O

    24. C

    R–C–Cl + R–O–H Pyridine

    O O

    HCl is formed in above reaction and react with pyridine and gives

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Page # 130 Solution Slot - 3 (Chemistry)

    25. B

    This is a esterfication reaction.

    26. B

    27. D

    28. D

    NaBH4 are weak reducing agent so only acid chloride are reduced in alcohal.

    29. D

    CHCH, CH2=CH2, Et–OH are not react with NaOH.

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com
    Solution Slot - 3 (Chemistry) Page # 131

    30. C

    in above reaction molecular weight of alcohal increase by C2H2O = 42.

    31. B

    32. B

    This is acetylation reaction.

    394 - Rajeev Gandhi Nagar Kota, Ph. No. 0744-2209671, 93141-87482, 93527-21564
    IVRS No. 0744-2439051, 0744-2439052, 0744-2439053, www.motioniitjee.com, email-info@motioniitjee.com

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