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R(x) = dB dA
- = -- = kx with a 9570 conversion of compound A . Limiting Case of the Tubular Reactor
at dt The inlet and outlet concentrations are
All holding times are assumed equal
Therefore R,'(z) = 12 and the quantity compound A and r = no is the tubular-reactor holding
OR,' = Ok is constant for all reactors. All 20= 1.00 mole/liter, X, = 0.05 mole/liter time. Therefore
the matrices M , are therefore the same, and product B
Formula (5) may be written as v n = M-"vO yo = 0.00 mole/liter, yn = 0.95 mole/liter
nr
"1
1
constant
1 + jwe lc = 19.0 hr.-'
Ari
1 The holding time, 0, for a reactor of the -RZi', jw
-1 + elc + j w e y
- (I
0 chain is found from a mass balance over
the system, given by Neglecting second-order terms in AT;
gives
CONVERSION. I- +e CONVERSION, I- %
Fig. 6. Fractional control quality against Fig. 7. Fractional control quality against
conversion for proportional control of a first- conversion for derivative control of a first-
order reaction in a C.S.T.R. order reaction in a C.S.T.R.
I 1
-m
dwe'"'Y(jw) (17) stream. Reactor operation is assumed to
be isothermal and data of Illustration 4 The integrals expressed above are
are used. Thus the frequency-response calculated by integration in the complex
Therefore function for a chain of n equal-sized plane or use of tables in the appendix of
reactors is given by Expression (9) : reference 9. The results have been
I ='S,- 1 W ( t ) l a dt cl(jw)= --
Y, = ek C
X=n-1
(1 + ek
expressed here in terms of the system with
no control in fractional form:
X0 X-0
= /m Y ( j w ) Y ( - j w ) du (18)
a G O
p -001 -0.01
X . MOLE/LITER TIME , MINUTES
for derivative control
TIME , MINUTES
T,lc 1 2 , *K 0 10 20
AD =
2 + + rF2%
elc
.K 1.0 0 7
:.
-0.01
decreases, which is evident a priori, X . MOLE/LITER TIME ,MINUTES
Integral control
d -aoi
X, MOLElLlTER TIME, MINUTES
TIME, MINWES
*K 1.0 , r\ 2 , .K O
0r 10 20
Proportional control
1
E = --p 0.5 I/ \
K
Differential control " \- g-2.01
TIME, MINUTES
10 20
H, .K / MINUTE