Identification and Contirmatory Tests for Group Ill cations 1. Residue (trom part 1, step 6) Separate the mixture immediately Add 10 draps of aM HCl and stir the mixture Add 3 drops of 12M Hel Wash the residue with 4 drops of 1M HCl Heat the mixture Ina water bath Add sufficient 4M aqueous ammonia to make the mixture basic until it becomes litmus Add 1 drop of 14M. Mh Binoy tothe recdue from step + Dilute the the solution mixtureto: JP MPU cine mL eatery bd aliol Taeeer) Add distilled water to the residue to make amb Add 1 mL of 4M HNO3 and evaporate to a moist residue Transfer the mixture ina test tube Heat it in a hot Add io drops of 396 H202 water bath for =f Centrifuge to the mixture minutes Combine the ‘Wash the residue with 10 drops of water to which centrifuge and pe added 1 drop of 4 washings, for step & M NaOH To treat the residue with 1 mL of 4M. HING3 and 2 drops oft M NaNo2 Stir the mixture Heat the solutian to boiling Remove any residue that remains Heat ina hot water bath ‘Add a small amount of TEST FOR solid Na3BIQ3 and few Pasi drops of 4M HNO3 to the solution Dilute the TESTFOR solution with add 2 to 3 crystals ro distilled up to 4 of NH4sCN mL‘Add 4M CH3COOH to the centrifuge from step 3 until it changes to acid, red to litmus, add 2 oF 3 drops in excess add 4M aqueaus NH3 Until the solution changes from distinctly alkaline to Separate the mixture and reserve the solution Tar step 6 Centrifuge Dissolve the residue in 44 " Preseiae Trae CH3COGH and add 2 aluminurn hydroxide might drops of aluminon (dye) $f, _ | Theiotmation of red lake bbe present precipitate confirms the reagent and enaugh iM presence of aluminum (NH4}2C03 to make the solution basic The formation of pracipitata eonlirms zine The formation pracipitate confirms the presence ol zine