Professional Documents
Culture Documents
♦ Study about Thomson Mass Spectrograph which is used to measure atomic masses of various
isotopes in a gas♦
Some of the positive ions pass through the fine hole in the cathode. This fine ray of positive ions
is subject to electric field E and magnetic field B and then allowed to strike a fluorescent screen
or photographic plate placed just before the screen
(not shown in figure). The positive ions produced near
the anode are accelerated through a greater distance
and thus have more kinetic energy and velocity. The
different positive ions have different speeds. It can be
shown that all positive ions having the same q/m, fall
on the screen or photographic plate forming a
parabolic trace. By changing the direction of B the other side of the parabola can be obtained.
It is found that separate isotopes forms separate parabola. Thus the number of parabolas (figure)
given the number of isotopes in the gas taken in the bulb. Some ions after coming out of the
cathode get neutralize and continue to move in a straight line. The impinge at the vertex of the
parabola, forming a dark spot on the photographic plate.
The electric field and magnetic field are parallel to each other. However, the electric force and
the magnetic force are perpendicular to each other. The deflection (upwards) due to the electric
field alone as observed on the screen is:
𝑞𝐸𝐿𝐷
𝑌 =
𝑚𝑢2
While the deflection (side ways) due to the magnetic field alone is
𝒒𝑩𝑳𝑫
𝑿 =
𝒎𝒖
Eliminating u, we notice that when both E and B are present, then X – Y coordinates of the
deflection are related by
For a given spectrograph B , L , D
, E are constants , then
Note :
(1) Thus all positive ions having charge to mass ratio (q/m)
lie on a parabola. Higher is the velocity, lower is the value of
Y and X. In principle only those positive ions for which velocity
is infinite can reach the origin O.
(2) Thus, infact, the trace does not extend upto origin O
(vertex of the parabola). Since the highest velocity positive
ions are those which originate near anode, the parabola’s
lower end is due to high velocity ions, low velocity ions are far
away from the vertex on the parabolic trace.
where AB = 2X2 and CD = 2X1 in the figure. The heavier isotope lie on the inner parabolic trace
while the lighter isotope is on the outer parabolic trace. The q/m is large for the outer parabola
(m small) while q/m is small for the inner parabola. Thomson, using this spectrograph, discovered
the isotopes of the neon.
Drawbacks: