QUESTION FOR SHORT ANSWER

Q.1 How is the speed of sound related to the gas variables in the kinetic theory model?
Q.2 How can you best use a spoon to cool a cup of coffee? Stirring – which involves doing work– would
seem to heat the coffee rather than cool it.
Q.3 How does a layer of snow protect plants during cold weather? During freezing spells, citrus growers in
Florida often spray their fruit with water, hoping it will freeze. How does that help?
Q.4 Explain why the latent heat of vaporization of a substance might be expected to be considerably greater
than its latent heat of fusion.
Q.5 A thermos bottle contains coffee. The thermos bottle is vigorously shaken. Consider the coffee as the
system.
(a) Does its temperature rise? (b) Has heat been added to it?
(c) Has work been done on it? (d) Has its internal energy changed?
Q.6 Consider that heat can be transferred by convection and radiation, as well as by conduction, and explain
why a thermos bottle is doubled-walled, evacuated, and silvered.
Q.7 The outside surface of a metallic container of a gas is buffed vigorously by a polishing wheel. Is the
energy transferred to the gas inside the container called heat or work? Explain.
Q.8 Can you “heat up” a bowl of soup without adding heat? Must the temperature of a system change if heat
is added?
Q.9 An ice cube is placed in a well-insulated beaker of lukewarm water. Take the system to consist of the ice
cube and the water. The ice melts, and the final state of this system is liquid water at some final lower
temperatures. Is this process adiabatic? What provided the energy to melt the ice?
Q.10 In a cycle the final state of the system is the same as the initial state. Given the heat added in a cycle, can
you determine how much work is done by the system? Explain.
Q.11 In a pure gas, all molecules are identical and have the same mass. Is the average translational kinetic
energy still given by (3/2)kT for a mixture of gases such as air? Explain.
Q.12 The walls of a container of gas also consist of molecules. Thus a gas molecule colliding with a wall having
the same temperature as the gas actually collides with one or more molecules. How can we justify, in an
average sense, our assumption that the perpendicular component of velocity of a molecule merely reverses
on a collision with the wall?
Q.13 Can the gravitational potential energy of interaction of the molecules of a gas with the earth be neglected
in comparison with the kinetic energy of the molecules? What about the gravitational potential energy of
interaction of the molecules with each other? Explain.

Q.14 Consider the air in a basketball during a game. Is (the vector) ( v) = 0 for the air? Explain.
Q.15 How can the temperature of a gas change during an adiabatic process, since no heat is exchanged with
the surroundings? (Hint: Consider the change in velocity of a molecule colliding with a moving wall.)
Q.16 Suppose that an opposite pair of walls of a container of gas are maintained at different temperatures. By
what mechanism involving molecular collisions is heat conducted through this gas? Note that the gas is
not at a uniform temperature.
Q.17 Why is it improper to speak of the temperature of a molecule? Of a system of 100 molecules? How
many molecules must a system have before we can speak meaningfully of the temperature of that system?
Q.18 The speed of sound in He is greater than the speed of sound in air at the same temperature and pressure.
How, can this be understood at the molecular level?

Bansal Classes Question Bank on KTG & Thermodynamics [2]

 ONLY ONE OPTION IS CORRECT.
Take approx. 2 minutes for answering each question.

Q.1 PV curve for the process whose VT curve is

(A) (B) (C) (D)

Q.2 Find the approx. number of molecules contained in a vessel of volume 7 litres at 0°C at 1.3 × 105 pascal
(A) 2.4 × 1023 (B) 3 × 1023 (C) 6 × 1023 (D) 4.8 × 1023
Q.3 A cylindrical tube of cross-sectional area A has two air tight frictionless pistons at its two ends. The
pistons are tied with a straight two ends. The pistons are tied with a straight piece of metallic wire. The
tube contains a gas at atmospheric pressure P0 and temperature T0. If temperature of the gas is doubled
then the tension in the wire is
(A) 4 P0 A (B) P0A/2
(C) P0 A (D) 2 P0 A
Q.4 An ideal gas mixture filled inside a balloon expands according to the relation PV2/3 = constant. The
temperature inside the balloon is
(A) increasing (B) decreasing (C) constant (D) can’t be said
Q.5 An ideal gas undergoes a thermodynamics cycle as shown in figure.
Which of the following graphs represents the same cycle?

(A) (B) (C) (D)

Q.6 A rigid tank contains 35 kg of nitrogen at 6 atm. Sufficient quantity of oxygen is supplied to increase the
pressure to 9 atm, while the temperature remains constant. Amount of oxygen supplied to the tank is :
(A) 5 kg (B) 10 kg (C) 20 kg (D) 40 kg
Q.7 A perfect gas of a given mass is heated first in a small vessel and then in a large vessel, such that their
volumes remain unchanged. The P-T curves are
(A) parabolic with same curvature (B) parabolic with different curvature
(C) linear with same slopes (D) linear with different slopes
Q.8 At a temperature T K, the pressure of 4.0g argon in a bulb is p. The bulb is put in a bath having
temperature higher by 50K than the first one. 0.8g of argon gas had to be removed to maintained original
pressure. The temperature T is equal to
(A) 510 K (B) 200 K (C) 100 K (D) 73 K
Q.9 When 2 gms of a gas are introduced into an evacuated flask kept at 250C the pressure is found to be one
atmosphere. If 3 gms of another gas added to the same flask the pressure becomes 1.5 atmospheres.
The ratio of the molecular weights of these gases will be
(A) 1 : 3 (B) 3 : 1 (C) 2 : 3 (D) 3 : 2

Bansal Classes Question Bank on KTG & Thermodynamics [3]

Q.10 An ideal gas is trapped inside a test tube of cross-sectional area 20 × 10–6 m2 as shown in the figure. The
gas occupies a height L1 at the bottom of the tube and is separated from air at atmospheric pressure by
a mercury column of mass 0.002 kg. If the tube is quickly turned isothermally, upside down so that
L2
mercury column encloses the gas from below. The gas now occupies height L1 in the tube. The ratio L
1
is [Take atmospheric pressure = 105 Nm–2]
102 101 99 100
(A) (B) (C) (D)
101 99 100 99

Q.11 An open and wide glass tube is immersed vertically in mercury in such a way that length 0.05 m extends
above mercury level. The open end of the tube is closed and the tube is raised further by 0.43 m. The
length of air column above mercury level in the tube will be : Take Patm = 76 cm of mercury
(A) 0.215 m (B) 0.2 m (C) 0.1 m (D) 0.4 m
Q.12 A vessel of volume 0.02 m3 contains a mixture of hydrogen and helium at 20°C and 2 atmospheric
pressure. The mass of mixture is 5 gms. Find the ratio of mass of hydrogen to that of helium in the
mixture.
(A) 1 : 2 (B) 1 : 3 (C) 2 : 3 (D) 3 : 2
Q.13 An ideal gas follows a process PT = constant. The correct graph between pressure & volume is

(A) (B) (C) (D)

Q.14 The process AB is shown in the diagram. As the gas is taken from A to B,
its temperature
(A) initially increases then decreases (B) initially decreases then increases
(C) remains constant (D) variation depends on type of gas
Q.15 During an experiment an ideal gas oberys an addition equation of state P2V = constant. The initial
temperature and pressure of gas are T and V respectively. When it expands to volume 2V, then its
temperature will be :
(A) T (B) 2T (C) 2 T (D) 2 2 T
Q.16 A barometer tube, containing mercury, is lowered in a vessel containing mercury until only 50 cm of the
tube is above the level of mercury in the vessel. If the atmospheric pressure is 75 cm of mercury, what is
the pressure at the top of the tube?
(A) 33.3 kPa (B) 66.7 kPa (C) 3.33 MPa (D) 6.67 MPa
Q.17 One mole of a gas expands obeying the relation as shown in the P/V diagram.
The maximum temperature in this process is equal to
PV 3P0 V0 9P V
(A) 0 0 (B) (C) 0 0 (D) None of these
R R 8R

Q.18 A vessel with open mouth contains air at 60°C. When the vessel is heated upto temperature T, one fourth
of the air goes out. The value of T is
(A) 80°C (B) 171°C (C) 333°C (D) 444°C

Bansal Classes Question Bank on KTG & Thermodynamics [4]

Q.19 28 gm of N2 gas is contained in a flask at a pressure of 10 atm and at a temperature of 57°. It is found
that due to leakage in the flask, the pressure is reduced to half and the temperature reduced to 27°C.
The quantity of N2 gas that leaked out is
(A) 11/20 gm (B) 20/11 gm (C) 5/63 gm (D) 63/5 gm
Q.20 If a mixture of 28 g of Nitrogen, 4 g of Hydrogen and 8 gm of Helium is contained in a vessel at
temperature 400 K and pressure 8.3 × 105 Pa, the density of the mixture will be :
(A) 3 kg/m3 (B) 0.2 kg/m3 (C) 2 g/litre (D) 1.5 g/litre
Q.21 The temperature of a gas is doubled (i) on absolute scale (ii) on centigrade scale. The increase in root
mean square velocity of gas will be
(A) More in case (i) (B) More in case (ii) (C) Same in both case (D) Information not sufficient
Q.22 A cylinder containing gas at 27°C is divided into two parts of equal volume each 100cc and at equal
pressure by a piston of cross sectional area 10.85 cm2. The gas in one part is raised in temperature to
100°C while the other maintained at original temperature. The piston and wall are perfect insulators.
How far will the piston move during the change in temperature?
(A) 1 cm (B) 2 cm (C) 0.5 cm (D) 1.5 cm
Q.23 12gms of gas occupy a volume of 4×10–3 m3 ata temperature of 7oC. After the gas is heated at constant
pressure its density becomes 6×10–4gm/cc. What is the temperature to which the gas was heated.
(A) 1000K (B) 1400K (C) 1200K (D) 800K
Q.24 The expansion of an ideal gas of mass m at a constant pressure P is
given by the straight line B. Then the expansion of the same ideal gas of
mass 2 m at a pressure 2P is given by the straight line
(A) C (B) A (C) B (D) none
Q.25 A vessel contains 1 mole of O2 gas (molar mass 32) at a temperature T. The pressure of the gas is P. An
identical vessel containing one mole of He gas (molar mass 4) at a temperature 2T has a pressure of
(A) P/8 (B) P (C) 2P (D) 8P
Q.26 A container X has volume double that of contianer Y and both are connected by a thin tube. Both
contains same ideal gas. The temperature of X is 200K and that of Y is 400K. If mass of gas in X is m
then in Y it will be:
(A) m/8 (B) m/6 (C) m/4 (D) m/2
Q.27 An ideal gas of Molar mass M is contained in a vertical tube of height H, closed at both ends. The tube
is accelerating vertically upwards with acceleration g. Then, the ratio of pressure at the bottom and the
mid point of the tube will be
(A) exp[2MgH/RT] (B) exp[–2MgH/RT] (C) exp[MgH/RT] (D) MgH/RT
Q.28 The ratio of average translational kinetic energy to rotational kinetic energy of a diatomic molecule at
temperature T is
(A) 3 (B) 7/5 (C) 5/3 (D) 3/2
Q.29 One mole of an ideal gas at STP is heated in an insulated closed container until the average speed of its
molecules is doubled. Its pressure would therefore increase by factor.
(A) 1.5 (B) 2 (C) 2 (D) 4
Q.30 Three particles have speeds of 2u , 10u and 11u. Which of the following statements is correct?
(A) The r.m.s. speed exceeds the mean speed by about u.
(B) The mean speed exceeds the r.m.s. speed by about u.
(C) The r.m.s. speed equals the mean speed.
(D) The r.m.s. speed exceeds the mean speed by more than 2u.
Bansal Classes Question Bank on KTG & Thermodynamics [5]
 9
Q.31 The ratio of specific heats of a gas is , then the number of degrees of freedom of the gas molecules
7
for translational motion is :
(A) 7 (B) 3 (C) 6 (D) none
Q.32 A diatomic gas of molecules weight 30 gm/mole is filled in a container at 27°C. It is moving at a velocity
100 m/s. If it is suddenly stopped, the rise in temperature of gas is :
60 600 6  10 4 6 105
(A) (B) (C) (D)
R R R R
Q.33 One mole of an ideal diatomic gas is taken through the cycle as shown in the figure.
1  2 : isochoric process 2  3 : straight line on P-V diagram
3  1 : isobaric process
The average molecular speed of the gas in the states 1, 2 and 3 are in the ratio
(A) 1 : 2 : 2 (B) 1 : 2 : 2 (C) 1 : 1 : 1 (D) 1 : 2 : 4
Question No. 34 to 37 (4 questions)
Five moles of helium are mixed with two moles of hydrogen to form a mixture. Take molar mass of
helium M1 = 4g and that of hydrogen M2 = 2g
Q.34 The equivalent molar mass of the mixture is
13g 18g
(A) 6g (B) (C) (D) none
7 7
Q.35 The equivalent degree of freedom f of the mixture is
(A) 3.57 (B) 1.14 (C) 4.4 (D) none
Q.36 The equivalent value of  is
(A) 1.59 (B) 1.53 (C) 1.56 (D) none
Q.37 If the internal energy of He sample of 100J and that of the hydrogen sample is 200J, then the internal
energy of the mixture is
(A) 900 J (B) 128.5 J (C) 171.4 J (D) 300 J
Q.38 N( <100) molecules of a gas have velocities1, 2, 3........ N/km/s respectively. Then
(A) rms speed and average speed of molecules is same.
(B) ratio of rms speed to average speed is (2N+1)(N+1)/6N
(C) ratio of rms speed to average speed is (2N+1)(N+1)/6
(D) ratio of rms speed to average speed of a molecule is 2/6 x (2N+1)/(N+1)
Q.39 Two monoatomic ideal gas at temperature T1 and T2 are mixed. There is no loss of energy. If the masses
of molecules of the two gases are m1 and m2 and number of their molecules are n1 and n2 respectively.
The temperature of the mixture will be :
T1  T2 T1 T2 n 2 T1  n1T2 n1T1  n 2 T2
(A) n  n (B) n  n (C) n1  n 2 (D) n1  n 2
1 2 1 2

Q.40 At temperature T, N molecules of gas A each having mass m and at the same temperature 2N molecules
of gas B each having mass 2m are filled in a container. The mean sqaure velocity of molecules of gas B
is v2 and mean square of x component of velocity of molecules of gas A is w2. The ratio of w2/v2 is :
(A) 1 (B) 2 (C) 1/3 (D) 2/3
Q.41 Five particles have speeds 1, 2, 3, 4, 5 m/s. the average velocity of the particles is (in m/s)
(A) 3 (B) 0 (C) 2.5 (D) cannot be calculated.

Bansal Classes Question Bank on KTG & Thermodynamics [6]

Q.42 A given mass of a gas expands from a state A to the state B by three paths 1, 2 T 1 B
and 3 as shown in T-V indicator diagram. If W1, W2 and W3 respectively be
2
the work done by the gas along the three paths, then A 3
(A) W1 > W2 > W3 (B) W1 < W2 < W3 O V
(C) W1 = W2 = W3 (D) W1 < W2, W1 > W3
Q.43 An ideal gas undergoes the process 1  2 as shown in the figure, the heat supplied and work done in the
process is Q and W respectively. The ratio Q : W is
(A)  :  – 1 (B) 
(C)  – 1 (D)  – 1 
Q.44 In the above thermodynamic process, the correct statement is
(A) Heat given in the complete cycle ABCA is zero
(B) Work done in the complete cycle ABCA is zero
(C) Work done in the complete cycle ABCA is (1/2 P0V0)
(D) None
Q.45 Pressure versus temperature graph of an ideal gas is shown in figure
(A) During the process AB work done by the gas in positive
(B) during the process CD work done by the gas is negative
(C) during the process BC internal energy of the gas is increasing
(D) None
Q.46 A reversible adiabatic path on a P-V diagram for an ideal gas passes through state A where P=0.7×105 N/
m–2 and v = 0.0049 m3. The ratio of specific heat of the gas is 1.4. The slope of path at A is :
(A) 2.0 × 107 Nm–5 (B) 1.0 × 107 Nm–5 (C) – 2.0 × 107 Nm–5 (D) –1.0 × 107 Nm–5
Q.47 An ideal gas at pressure P and volume V is expanded to volume 2V. Column I represents the
thermodynamic processes used during expansion. Column II represents the work during these processes
in the random order.
Column I Column II
PV (1  21  )
(p) isobaric (x)
 1
(q) isothermal (y) PV
(r) adiabatic (z) PV ln 2
The correct matching of column I and column II is given by :
(A) p-y, q-z, r-x (B) p-y, q-x, r-z (C) p-x, q-y, r-z (D) p-z, q-y, r-x
Q.48 An ideal gas is taken from point A to point C on P-V diagram through
two process AOC and ABC as shown in the figure. Process AOC is
isothermal
(A) Process AOC requires more heat than process ABC.
(B) Process ABC requires more heat than process AOC.
(C) Both process AOC & ABC require same amount of heat.
(D) Data is insufficient for comparison of heat requirement for the two processes.
Q.49 One mole of an ideal gas is contained with in a cylinder by a frictionless piston and is initially at
temperature T. The pressure of the gas is kept constant while it is heated and its volume doubles. If R is
molar gas constant, the work done by the gas in increasing its volume is
(A) RT ln2 (B) 1/2 RT (C) RT (D) 3/2 RT

Bansal Classes Question Bank on KTG & Thermodynamics [7]

Q.50 The figure, shows the graph of logarithmic reading of pressure and volume for two
ideal gases A and B undergoing adiabatic process. From figure it can be concluded
that
(A) gas B is diatomic (B) gas A and B both are diatomic
(C) gas A is monoatomic (D) gas B is monoatomic & gas A is diatomic
Q.51 A thermodynamic cycle takes in heat energy at a high temperature and rejects energy at a lower
temperature. If the amount of energy rejected at the low temperature is 3 times the amount of work done
by the cycle, the efficiency of the cycle is
(A) 0.25 (B) 0.33 (C) 0.67 (D) 0.9
Q.52 Monoatomic, diatomic and triatomic gases whose initial volume and pressure are same, are compressed
till their volume becomes half the initial volume.
(A) If the compression is adiabatic then monoatomic gas will have maximum final pressure.
(B) If the compression is adiabatic then triatomic gas will have maximum final pressure.
(C) If the compression is adiabatic then their final pressure will be same.
(D) If the compression is isothermal then their final pressure will be different.
Q.53 If heat is added at constant volume, 6300J of heat are required to raise the temperature of an ideal gas
by 150K. If instead, heat is added at constant pressure, 8800 joules are required for the same temperature
change. When the temperature of the gas changes by 300K, the internal energy of the gas changes by
(A) 5000J (B) 12600J (C) 17600J (D) 22600J
Q.54 Three processes form a thermodynamic cycle as shown on P-V diagram for an
ideal gas. Process 1  2 takes place at constant temperature (300K). Process
2  3 takes place at constant volume. During this process 40J of heat leaves
the system. Process 3  1 is adiabatic and temperature T3 is 275K. Work
done by the gas during the process 3 1 is
(A) -40J (B) -20J
(C) +40J (D) +20J
Q.55 When unit mass of water boils to become steam at 1000C, it absorbs Q amount of heat. The densities of
water and steam at 1000C are 1 and 2 respectively and the atmospheric pressure is p0. The increase in
internal energy of the water is

1 1   1 1 1 1 
(A) Q (B) Q + p0    (C) Q + p0      (D) Q - p0     
    2 1  1 2
 1 2

Q.56 A polyatomic gas with six degrees of freedom does 25J of work when it is expanded at constant pressure.
The heat given to the gas is
(A) 100J (B) 150J (C) 200J (D) 250J
Q.57 An ideal gas expands from volume V1 to V2. This may be achieved by either of the three processes:
isobaric, isothermal and adiabatic. Let U be the change in internal energy of the gas, Q be the quantity
of heat added to the system and W be the work done by the system on the gas. Identify which of the
following statements is false for U?
(A) U is least under adiabatic process.
(B) U is greatest under adiabatic process.
(C) U is greatest under the isobaric process.
(D) U in isothermal process lies in-between the values obtained under isobaric and adiabatic processes.

Bansal Classes Question Bank on KTG & Thermodynamics [8]

Q.58 In an isobaric expansion of an ideal gas, which of the following is zero?
(A) work done (B) Q (C) U (D) d 2 V dT 2
Q.59 A perfect gas is found to obey the relation PV3/2 = constant, during an adiabatic process. If such a gas, initially
at a temperature T, is compressed adiabatically to half its initial volume, then its final temperature will be
(A) 2T (B) 4T (C) 2T (D) 22T
Q.60 A ideal monoatomic gas is carried around the cycle ABCDA as shown
in the fig. The efficiency of the gas cycle is
4 2
(A) (B)
21 21
4 2
(C) (D)
31 31
Q.61 A gas takes part in two processes in which it is heated from the same
initial state 1 to the same final temperature. The processes are shown on
the P-V diagram by the straight line 1-2 and 1-3. 2 and 3 are the points
on the same isothermal curve. Q1 and Q2 are the heat transfer along the
two processes. Then
(A) Q1 = Q2 (B) Q1 < Q2 (C) Q1 > Q2 (D) insufficient data
Q.62 In thermodynamic process pressure of a fixed mass of gas is changed in such a manner that the gas
releases 30 joule of heat and 18 joule of work was done on the gas. If the initial internal energy of the
gas was 60 joule, then, the final internal energy will be :
(A) 32 joule (B) 48 joule (C) 72 joule (D) 96 joule
Q.63 A cylinder made of perfectly non conducting material closed at both ends is divided into two equal parts
by a heat proof piston. Both parts of the cylinder contain the same masses of a gas at a temperature
t0 = 27° and pressure P0 = 1 atm. Now if the gas in one of the parts is slowly heated to t = 57°C while
the temperature of first part is maintained at t0 the distance moved by the piston from the middle of the
cylinder will be (length of the cylinder = 84 cm)
(A) 3 cm (B) 5 cm (C) 2 cm (D) 1 cm
Q.64 1 gm water at 100°C and 105Pa pressure converts into 1841cm3 of steam at constant temperature and
pressure. If latent heat of vapourization of water is 2250 J/gm. The change in internal energy of water in
this process is
(A) zero (B) 2250 J (C) 2066 J (D) none
Q.65 Two identical vessels A & B contain equal amount of ideal monoatomic
gas. The piston of A is fixed but that of B is free. Same amount of heat is
absorbed by A & B. If B's internal energy increases by 100 J the change
in internal energy of A is
500
(A) 100 J (B) J (C) 250 J (D) none of these
3
Q.66 Three processes compose a thermodynamics cycle shown in the PV
diagram. Process 12 takes place at constant temperature. Process 23
takes place at constant volume, and process 31 is adiabatic. During the
complete cycle, the total amount of work done is 10 J. During process
23, the internal energy decrease by 20J and during process 31, 20 J
of work is done on the system. How much heat is added to the system
during process 12?
(A) 0 (B) 10 J
(C) 20 J (D) 30 J
Bansal Classes Question Bank on KTG & Thermodynamics [9]
Q.67 An ideal gas undergoes an adiabatic process obeying the relation PV4/3 = constant. If its initial temperature
is 300 K and then its pressure is increased upto four times its initial value, then the final temperature is
(in Kelvin):
(A) 300 2 (B) 300 3 2 (C) 600 (D) 1200
Q.68 The adiabatic Bulk modulus of a diatomic gas at atmospheric pressure is
(A) 0 Nm–2 (B) 1 Nm–2 (C) 1.4 ×104 Nm–2 (D) 1.4  105 Nm–2
Q.69 A closed container is fully insulated from outside. One half of it is filled with an
ideal gas X separated by a plate P from the other half Y which contains a vacuum
as shown in figure. When P is removed, X moves into Y. Which of the following
statements is correct?
(A) No work is done by X (B) X decreases in temperature
(C) X increases in internal energy (D) X doubles in pressure
Q.70 An ideal gas undergoes a thermodynamics cycle as shown in figure.
Which of the following graphs represents the same cycle?

(A) (B) (C) (D)

Q.71 A cyclic process ABCA is shown in PT diagram. When presented on PV, it would

(A) (B) (C) (D)

Q.72 Considere the thermodynamics cycle shown on PV diagram. The process

A  B is isobaric, B  C is isochoric and C  A is a straight line
process. The following internal energy and heat are given :
UA  B = + 400 kJ and QB  C = – 500 kJ
The heat flow in the process QC  A is :
(A) – 20 kJ (B) + 25 kJ (C) – 25 kJ (D) Data are insufficient
Q.73 1 kg of a gas does 20 kJ of work and receives 16 kJ of heat when it is expanded between two states. A
second kind of expansion can be found between the initial and final state which requires a heat input of
9 kJ. The work done by the gas in the second expansion is :
(A) 32 kJ (B) 5 kJ (C) – 4 kJ (D) 13 kJ
Q.74 A vessel contains an ideal monoatomic gas which expands at constant pressure, when heat Q is given to
it. Then the work done in expansion is :
3 2 2
(A) Q (B) Q (C) Q (D) Q
5 5 3
Q.75 One mole of an ideal monoatomic gas at temperature T0 expands slowly according to the law
P/V = constant. If the final temperature is 2 T0, heat supplied to the gas is :
3 1
(A) 2 R T0 (B) R T 0 (C) R T0 (D) R T0
2 2
Q.76 m
A diatomic gas follows equation PV = constant, during a process. What should be the value of m such
that its molar heat capacity during process = R
(A) 2/3 (B) 1 (C) 1.5 (D) 5/3

Bansal Classes Question Bank on KTG & Thermodynamics [10]

Q.77 One mole of an ideal gas at temperature T1 expends according to the law P = a (constant). The work
done by the gas till temperature of gas becomes T2 is : V2
1 1 1 1
(A) R(T2 – T1) (B) R(T2 – T1) (C) R(T2 – T1) (D) R(T2 – T1)
2 3 4 5
Q.78 2 moles of a diatomic gas undergoes the process : PT2/V = constant. Then, the molar heat capacity of
the gas during the process will be equal to
(A) 5R/2 (B) 9R/2 (C) 3R (D) 4R
Q.79 A resistance coil connected to an external battery is placed inside an adiabatic
cylinder fitted with a frictionless pistn and containing an ideal gas. A current
i flows through the coil which has a resistance R. At what speed must the piston
move upward in order that the temperature of the gas remains uchanged? Neglect
atmospheric pressure.
i2m Rmg mg i2R
(A) (B) (C) (D)
Rg i2 i2 mg

ONE OR MORE THAN ONE OPTION MAY BE CORRECT

Take approx. 3 minutes for answering each question.
Q.1 A process is shown in the diagram. Which of the following curves
may represent the same process ?

(A) (B) (C) (D)

Q.2 An ideal gas expands in such a way that PV2 = constant throughout the process.
(A) The graph of the process of T-V diagram is a parabola.
(B) The graph of the process of T-V diagram is a straight line.
(C) Such an expansion is possible only with heating.
(D) Such an expansion is possible only with cooling.
Q.3 A gas expands such that its initial and final temperature are equal. Also, the process followed by the gas
traces a straight line on the P-V diagram :
(A) The temperature of the gas remains constant throughout.
(B) The temperature of the gas first increases and then decreases
(C) The temperature of the gas first decreases and then increases
(D) The stright line has a negative slope.
Q.4 Figure shows the pressure P versus volume V graphs for two different gas sample
at a given temperature. MA and MB are masses of two samples, nA and nB are
numbers of moles. Which of the following must be incorect.
(A) MA > MB (B) MA < MB
(C) nA > nB (D) nA < nB

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 Question No. 5 to 7 (3 questions)
A very tall vertical cylinder is filled with a gas of molar mass M under isothermal conditions at temperature
T. The density and pressure of the gas at the base of the container is 0 and p0, respectively
Q.5 Choose the correct statement(s)
(A) Pressure decreases with height
(B) The rate of decreases of pressure with height is a constant.
dp
(C) = – g where  is density of the gas at a height h.
dh
RT
(D) p = 
M
Q.6 Choose the correct statement(s) if gravity is assumed to be constant throughout the container
(A) Both pressure and density decreases exponentially with height.
Mgh

(B) The variation of pressure is p = p0 e RT

Mgh

(C) The variation of density  = 0 e RT
(D) The molecular density decreases as one moves upwards.
Q.7 Choose the correct statement(s)
(A) The density of gas cannot be uniform throughout the cylinder.
(B) The density of gas cannot be uniform throughout the cylinder under isothermal conditions.
dT R
(C) The density of gas is constant if | |=
dh Mg
dT Mg
(D) The density of gas is uniform if | |=
dh R
Q.8 During an experiment, an ideal gas is found to obey a condition VP2 = constant. The gas is initially at a
temperature T, pressure P and volume V. The gas expands to volume 4V.
P
(A) The pressure of gas changes to
2
(B) The temperature of gas changes to 4T
(C) The graph of above process on the P-T diagram is parabola
(D) The graph of above process on the P-T diagram is hyperbola.
P2
Q.9 During an experiment, an ideal gas is found to obey a condition = constant [ = density of the gas]. The

gas is initially at temperature T, pressure P and density . The gas expands such that density changes to  2 .
(A) The pressure of the gas changes to 2 P
(B) The temperature of the gas changes to 2 T
(C) The graph of above process on the P–T diagram is parabola
(D) The graph of the above process on the P–T diagram is hyperbola.
Q.10 According to kinetic theory of gases, which of following statement will be true.
(A) Ideal gases can not be liquified
(B) The molecules of ideal gas do not obey newtons laws of motion.
(C) Pressure of gas is always inversely proportional to its volume
(D) molecules of gas never move in straight line.

Bansal Classes Question Bank on KTG & Thermodynamics [12]

Q.11 According to kinetic theory of gases,
(A) The velocity of molecules decreases for each collision
(B) The pressure exerted by a diatomic gas is proportional to the mean velocity of the molecule.
(C) The K.E. of the gas decreases on expansion at constant temperature.
(D) The mean translational K.E. of a diatomic gas increases with increase in absolute temperature.
Q.12 Two vessels of the same volume contain the same gas at same temperature. If the pressure in the vessels
be in the ratio of 1 : 2, then
(A) the ratio of the average kinetic energy is 1 : 2
(B) the ratio of the root mean square velocity is 1 : 1
(C) the ratio of the average velocity is 1 : 2
(D) the ratio of number of molecules is 1 : 2
Q.13 The total kinetic energy of translatory motion of all the molecules of 5 litres of nitrogen exerting a pressure
P is 3000 J.
(A) the total k.e. of 10 litres of N2 at a pressure of 2P is 3000 J
(B) the total k.e. of 10 litres of He at a pressure of 2P is 3000 J
(C) the total k.e. of 10 litres of O2 at a pressure of 2P is 20000 J
(D) the total k.e. of 10 litres of Ne at a pressure of 2P is 12000 J
Q.14 A vertical cylinder with heat-conducting walls is closed at the bottom and is fitted with a smooth light
piston. It contains one mole of an ideal gas. The temperature of the gas is always equal to the surrounding’s
temperature, T0. The piston is moved up slowly to increase the volume of the gas to  times. Which of
the following is incorrect?
(A) Work done by the gas is RT0 ln .
(B) Work done against the atmosphere is RT0( 1).
(C) There is no change in the internal energy of the gas.
1
(D) The final pressure of the gas is times its initial pressure.
(  1)
Q.15 A closed vessel contains a mixture of two diatomic gases A and B. Molar mass of A is 16 times that of B
and mass of gas A contained in the vessel is 2 times that of B. The following statements are given
(i) Average kinetic energy per molecule of A is equal to that of B.
(ii) Root mean square value of translational velocity of B is four times that of A.
(iii) Pressure exerted by B is eight times of that exerted by A.
(iv) Number of molecules of B in the cylinder is eight time that of A.
(A) (i), (ii) and (iii) are true (B) (ii), (iii) and (iv) are true
(C) (i), (ii) and (iv) are true (D) All are true
Q.16 A mixture of ideal gases 7 kg of nitrogen and 11 kg of CO2. Then
(A) equivalent molecular weight of the mixture is 36.
(B) equivalent molecular weight of the mixture is 18.
(C)  for the mixture is 5/2
(D)  for the mixture is 47/35.
(Take  for nitrogen and CO2 as 1.4 and 1.3 respectively)
Q.17 What is/are the same for O2 and NH3 in gaseous state
(A) ratio of specific heats
(B) average velocity
(C) maximum no. of vibrational degree of freedom
(D) None of these

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Q.18 A piston is slowly pushed into a metal cylinder containing an ideal gas. Which of the following statements
is/are incorrect?
(A) The pressure of the gas increases
(B) The number of the molecules per unit volume increases
(C) The average speed of gas molecules increases
(D) The frequency of collision of the gas molecules with the piston increases.
Q.19 Which of the following statements is/are not an assumption of the kinetic theory for an ideal gas?
(A) The duration of a collision is negligible as compared to the time between successive collisions
(B) The molecules have negligible attraction for each other
(C) The molecules have negligible momentum change on collision with the container walls
(D) There is no total kinetic energy change of the molecules on colliding with each other or with the walls
of the container.
Q.20 Select the incorrect statement about ideal gas.
(A) Molecules of a gas are in incessant random motion colliding against one another and with the walls
of the container.
(B) The gas is not isotropic and the constant (1/3) in equation P = (1/3) v 2rms is result of this property
(C) The time during which a collision lasts is negligible compared to the time of free path between collisions.
(D) There is no force of interaction between molecules among themselves or between molecules and the
wall except during collision.
Q.21 Select the incorrect statement(s)
(A) RMS speed of 8 gm oxygen gas in container at 27° C is approximately 484 m/s
(B) RMS speed of 8 gm oxygen in container at 27° C is approximately 968 m/s
(C) For number of molecules greater than one, RMS speed is greater than average speed
(D) A gas behaves more closely as an ideal gas at low pressures and high temperatures
Q.22 Hydrogen gas and oxygen gas have volume 1 cm3 each at N.T.P.
(A) Number of molecules is same in both the gases.
(B) The rms velocity of molecules of both the gases is the same.
(C) The internal energy of each gases is the same
(D) The average velocity of molecules of each gas is the same.
Q.23 A gas is enclosed in a vessel at a constant temperature at a pressure of 5 atmosphere and volume 4 litre.
Due to a leakage in the vessel, after some time, the pressure is reduced to 4 atmosphere. As a result, the
(A) volume of the gas decreased by 20% (B) average K.E. of gas molecule decreases by 20%
(C) 20% of the gas escaped due to the leakage (D) 25% of the gas escaped due to the leakage
Q.24 In case of hydrogen and oxygen at N.T.P., which of the following quantities is / are the same?
(A) average momentum per molecule (B) average kinetic energy per molecule
(C) kinetic energy per unit volume (D) kinetic energy per unit mass
Q.25 A container holds 1026 molecules/m3, each of mass 3 × 10–27 kg. Assume that 1/6 of the molecules
move with velocity 2000 m/s directly towards one wall of the container while the remaining 5/6 of the
molecules move either away from the wall or in perpendicular direction, and all collisions of the molecules
with the wall are elastic
(A) number of molecules hitting 1 m2 of the wall every second is 3.33 × 1028.
(B) number of molecules hitting 1 m2 of the wall every second is 2 × 1029.
(C) pressure exerted on the wall by molecules is 24 × 105Pa.
(D) pressure exerted on the wall by molecules is 4 × 105Pa.

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Q.26 An ideal gas is taken from state 1 to state 2 through optional path A, B, C & D
as shown in P-V diagram. Let Q, W and U represent the heat supplied, work
done & internal energy of the gas respectively. Then
(A) QB – WB > QC – WC (B) QA – QD = WA – WD
(C) WA < WB < WC < WD (D) QA > QB > QC > QD

Q.27 A student records Q, U & W for a thermodynamic cycle A  B  C  A.

Certain entries are missing. Find correct entry in following options.
(A) WBC = – 70 J (B) QCA = 130 J
(C) UAB = 190 J (D) UCA = – 160 J
Q.28 Two moles of monoatomic gas is expanded from (P0, V0) to (P0 , 2V0) under isobaric condition. Let
Q1, be the heat given to the gas, W1 the work done by the gas and U1 the change in internal energy.
Now the monoatomic gas is replaced by a diatomic gas. Other conditions remaining the same. The
corresponding values in this case are Q2 , W2 , U2 respectively, then
(A) Q1 – Q2 = U1 – U2 (B) U2 + W2 > U1 + W1
(C) U2 > U1 (D) All of these
Q.29 For an ideal gas
(A) The change in internal energy in a constant pressure process from temperature T1 to T2 is equal to
n C ( T2 – T1) where C is the molar specific heat at constant volume and n is the number of the moles of the gas.
(B) The change in internal energy of the gas and the work done by the gas are equal in magnitude in an
adiabatic proces.
(C) The internal energy does not change in an isothermal process.
(D) A, B and C
Q.30 An enclosed ideal gas is taken through a cycle as shown in the figure. Then
(A) Along AB, temperature decreases while along BC temperature increases
(B) Along AB, temperature increases while along BC the temperature decreases.
(C) Along CA work is done by the gas and the internal energy remains constant.
(D) Along CA work is done on the gas and internal energy of the gas increases.
Q.31 Two gases have the same initial pressure, volume and temperatue. They expand to the same final volume,
one adiabatically and the other isothermally
(A) The final temperature is greater for the isothermal process
(B) The final pressure is greater for the isothermal process
(C) The work done by the gas is greater for the isothermal process
(D) All the above options are incorrect
Q.32 In the previous question, if the two gases are compressed to the same final volume
(A) the final temperature is greater for the adiabatic process
(B) the final pressure is greater for the adiabatic process
(C) the work done on the gas is greater for the adiabatic process
(D) all the above options are incorrect
Q.33 The first law of thermodynamics can be written as U = Q + W for an ideal gas. Which of the
following statements is correct?
(A) U is always zero when no heat enters or leaves the gas
(B) W is the work done by the gas in this written law.
(C) U is zero when heat is supplied and the temperature stays constant
(D) Q = –W when the temperature increases very slowly.

Bansal Classes Question Bank on KTG & Thermodynamics [15]

Q.34 A cyclic process ABCD is shown in the p-V diagram. Which of the
following curves represents the same process if BC & DA are isothermal
processes

(A) (B) (C) (D)

Q.35 For two different gases X and Y, having degrees of freedom f1 and f2 and molar heat capacities at
constant volume CV1 and CV2 respectively, the ln P versus ln V graph is plotted for adiabatic process,
as shown
(A) f1 > f2 (B) f2 > f1
(C) CV2 > C V1 (D) C V1 > C V2
Q.36 2 moles of a monoatomic gas are expanded to double its initial volume, through a process P/V = constant.
If its initial temperature is 300 K, then which of the following is not true.
(A) T = 900 K (B) Q = 3200 R (C) Q = 3600 R (D) W = 900 R

Answer Key
ONLY ONE OPTION IS CORRECT.

Q.1 A Q.2 A Q.3 C Q.4 A Q.5 A Q.6 C Q.7 D

Q.8 B Q.9 A Q.10 B Q.11 C Q.12 A Q.13 C Q.14 A
Q.15 B Q.16 A Q.17 C Q.18 B Q.19 D Q.20 C Q.21 A
Q.22 A Q.23 B Q.24 C Q.25 C Q.26 C Q.27 C Q.28 D
Q.29 D Q.30 A Q.31 B Q.32 A Q.33 A Q.34 D Q.35 A
Q.36 C Q.37 D Q.38 D Q.39 D Q.40 D Q.41 D Q.42 A
Q.43 A Q.44 C Q.45 C Q.46 C Q.47 A Q.48 A Q.49 C
Q.50 D Q.51 A Q.52 A Q.53 B Q.54 A Q.55 B Q.56 A
Q.57 B Q.58 D Q.59 C Q.60 A Q.61 B Q.62 B Q.63 C
Q.64 C Q.65 B Q.66 D Q.67 A Q.68 D Q.69 A Q.70 A
Q.71 C Q.72 C Q.73 D Q.74 C Q.75 A Q.76 D Q.77 B
Q.78 D Q.79 D

ONE OR MORE THAN ONE OPTION MAY BE CORRECT

Q.1 C Q.2 D Q.3 B,D Q.4 C

Q.5 A,C,D Q.6 A,B,C,D Q.7 A,B,D Q.8 A,D
Q.9 B,D Q.10 A Q.11 D Q.12 B,D
Q.13 C,D Q.14 D Q.15 D Q.16 A,D
Q.17 B Q.18 C Q.19 C Q.20 B
Q.21 B Q.22 A,C,D Q.23 C Q.24 A,B,C
Q.25 A,D Q.26 B,D Q.27 D Q.28 D
Q.29 D Q.30 A Q.31 A,B,C Q.32 A,B,C
Q.33 C Q.34 A,B Q.35 B,C Q.36 B

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