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Skim the air conditioner problem statement individually, and then in your group respond to the
following questions:
(a) What quantities needed for this calculation are given in the process specifications? (Two
quantities on the list would be the temperature and relative humidity of the outside air; what are
the others?)
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Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
What we’re going to do now you should have learned in high school or last year. Some of you know it,
most don’t. Learn it and save hours of calculation time and avoid costly (in grades here, in dollars later)
and easily avoidable mistakes. (The Mars probe was lost because of a unit conversion error.)
Measured and counted quantities have dimensions (length, time, mass, length/time,…) and
units (s, ft, kg, miles/h, ft/s2, kg/m3, artichokes, moose/mile2,…)
In arithmetic operations, treat units like algebraic variables:
12 ft 7 ft 5 ft (12 x 7 x 5 x)
12 ft 7 cm ??? (12 x 7 y ???)
5 ft 3 lb m = 15 ft lb m (5 x 3y = 15xy )
(3 sec) 2 9 sec 2 (3x)2 9 x 2
9.0 kg
3 (dimensionless quantity )
3.0 kg
miles x
55 3 h 165 miles 55 3 y 165 x
h y
Conversion factor: Ratio of a quantity to its equivalent in different units (= 1). Find ones
you don’t know in the conversion factor table on the inside front cover of the text.
Dimensional equations. To convert a quantity from one set of units to another, use a
dimensional equation. Start with the quantity you’re given & multiply by conversion factors
to replace old units with new ones.
Convert 0.02562 g in/min 2 to ton miles/wk 2
0.02562 g in _________ ton ____ ft _____ mile ______ min 2 ___________ _________
2 2
min _________ g ____ in _______ ft ______ h __________ _____ wk 2
Why four significant figures? In multiplication & division, sig. figs. in result = lowest number of sig.
figs. in any of the terms being multiplied & divided. Read Sect. 2.5a, & obey the rules—lose points if
you don’t.
Mass and weight. Go through Sect. 2.4 carefully. Make sure you can do the Test Yourself on p. 13
without looking up the answers.
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Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
o Note the difference between lbm (a mass unit) and lbf (a force unit). When you use the
word “pounds” be sure to know which you are talking about.
o gc is a conversion factor between natural and derived force units. Don’t confuse it with
the gravitational constant, g. If you are having trouble getting your units to come out
right, you may have forgotten to use gc.
The operation of a chemical plant is based on the measurement of process variables – temperatures,
pressures, flowrates, concentrations, etc. To a process engineer, a process is defined as the set of all
those variables.
Sometimes possible to measure directly, but more often we must relate one variable to another that is
easier to measure. We might do some kind of calibration experiment from which we can develop an
equation relating one variable to another.
(μS/cm)
CA κ
4.62 10.0
12.4 28.5
Conductivity ... …
meter
Solution: Known ... ...
amounts of A and H2O ... ...
CA (mg A/L)
Plot CA vs. κ (calibration plot). Then, measure κ for solutions with unknown salt concentration, use
calibration plot to determine CA.
Possibilities:
CA CA CA
κ κ κ
1-3
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
If (a) or (b), our life is easy and we have a straightforward linear relationship.
CA = aκ + b
(Equation is much more convenient than curve for converting κ to CA—calculator, spreadsheet, computer
program,....)
If it’s (c) but we straight-line it anyway, when do we run into trouble? When we get outside the range of
our data. Interpolation versus extrapolation. Better—find a nonlinear function that fits the curvature of
the data. (Extrapolation still risky.)
(μS/cm)
CA κ
4.62 10.0
17.4 28.5
Conductivity 63.8 92
meter
Solution: Known 95.1 147
amounts of A and H2O 213 316
CA (mg A/L)
200
CA
100
(κ1 = 10.0, CA1 = 5.00)
Aqueous solutions are drawn from two process vessels and analyzed. Their electrical conductivities
are found to be κa = 200 μS/cm and κb = 550 μS/cm. Estimate the salt concentrations in both vessels.
1-4
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Which of your two estimates would you have least confidence in, and why? Speculate on whether
your value is an underestimate or an overestimate, and explain your reasoning.
Suppose the salt concentration of the first solution is determined by chemical analysis, and it is found
to be significantly different from the value you determined. Think of at least five possible
explanations for the discrepancy.
Suppose we have data for y (dependent variable) vs. x (independent variable) & wish to derive an
expression for y(x). First step is to plot y vs. x.
x x
Strategy: Guess a function for y(x), figure out what would yield a straight-line plot if the guess is correct,
plot it, and see if it works.
Example (TAPPS):
x y
0 1
1 2 y
What kinds of functions might you try?
2 9
3 28
x
Let’s try y = ax3 + b (in this class you would be given a potential function to evaluate – you would not
have come up with the function). If this is a good fit, then a plot of y vs. x3 should be a straight line with
slope ___ & intercept _____.
x y x3 Slope =
0 1 0
1 2 1
2 9 8 y Intercept =
3 28 27
x3
Equation:
1-5
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
General procedure: Given (x,y) data & a curved plot of y vs. x, try to find f(x,y) and g(x,y) such that a plot
of f (y in the example) vs. g (x3 in the example) is a straight line. If it is, then f = ag + b.
Example:
x y y
... ...
... ...
... ...
... ...
x
Suppose there is reason to expect that y = a x + b so that [f (x,y) = y, g(x,y) = x]
Then
x y x
... ... ... y Function is correct, slope = a, intercept = b
... ... ...
... ... ...
... ... ...
x
Question: What if the plot were distinctly curved? ___________________________________________
Example
Sometimes we have to rearrange an equation to get it in a linear form. Suppose we have nonlinear (x,y)
data, and we have reason to believe that they are related through the equation
sin y nx my
where n and m are constants (adjustable parameters). Questions: (1) Does that relationship fit our data?
(2) If it does, what are the best values of n and m?
Task: Rearrange the equation into a form f(x,y) = ag(x,y) + b, plot f vs. g. If linear, original equation is
valid. Determine a and b from plot, use to calculate m and n.
How about (sin y – my) = nx, plot (sin y – my) vs. x, if linear then slope = n?
Won’t work, because _____________________________________________
Solution:
sin y x
sin y x x y sin y
sin y nx my n m y y
y y ... ... ... ... y
... ... ... ...
f(x,y) g(x,y) ... ... ... ...
... ... ... ... x/ y
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Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Work through Test Yourself on p. 27. For additional practice, work through Problem 2.31 in the
Student Workbook and check your solutions in the back.
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Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Y
3.0
2 1.4 2.0 Non-linear!
3 2.6 1.0
0.0
4 4.0
0 1 2 3 4 5
5 5.6 X
1.0 0.00
-1.00 -0.50 -0.500.00 0.50 1.00 1.50 2.00
Y
-1.00
-1.50
0.1 -2.00
0.1 1 10 ln X
X
1-8
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Example. A toxic waste product from a chemical process, A, is treated in a holding tank with a bacterial
agent that causes it to decompose.
The initial concentration of A in the tank is CA0 = 10.0 mol A/liter. Samples are frequently drawn from
the reactor and analyzed for A, leading to the following data:
t(min) mol A
CA
L 10
0 10.0
CA(mol/L)
8
1 6.1
6
2 3.7
3 2.2 4
4 1.3 2
5 0.8
6 0.5 0 2 4 6 8
t (min)
We want to determine an expression for CA(t) so we can determine the holding time required for the A to
fall below its safe value of 0.001 mol/L.
Curve looks like an exponential decay, so let’s try C A aebt (expect b to be negative).
C A aebt ln(C A ) ln a bt
Plot ln C A vs. t. If plot is linear, assumption is correct, slope = b, intercept = ln a
Rectangular plot Semilog plot
0 10.0 2.303
CA
1 6.1 1.808
2 3.7 1.308
1.0
or
3
2
3 2.2 0.788
4 1.3 0.262 0 1
5 0.80 –0.223 2 4 6 2 4 6
t 0.5 t
6 0.50 –0.693 –1.0
logarithmic axis
1-9
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Rectangular:
What would you plot versus what?
How do you calculate the slope and intercept?
Semilog:
What would you plot versus what?
How do you calculate the slope and intercept?
1-10
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
10
CA(mol/L)
(R1=2.7, CA1=0.75)
(R2=38, CA2=4.7)
1 10 R 100
o a = _____________________
Work through Test Yourself on p. 29. For additional practice, work through Problems 2.32 and 2.38
in the Student Workbook.
Read Section 2.7e and Appendix A.1 on the Method of Least Squares.
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Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Inputs
Outputs
Here we have feed (input) and product (output) from the “big box (process)”. Inside the box (process)
you have individual boxes (processes) with their own inputs and outputs.
What do we want to know about these streams? Temperature, pressure, volumetric flow, mass flow,
chemical composition. Some will be given, others we will measure, but many we will calculate.
Molecular weight: Sum of atomic weights of the atoms of a molecule (12C has A.W. = 12.0000....)
Values in table reflect mixture of isotopes found in nature.
Mole: Amount of a species whose mass is numerically equal to its molecular weight.
1 g-mole CH3OH (or 1 mol CH3OH) = 32.04 g CH3OH (= 6.02x1023 molecules of CH3OH)
1 lb-mole CH3OH = 32.04 lbm CH3OH
1 kg-mol CH3OH (or 1 kmol CH3OH) = 32.04 kg CH3OH = 1000 mol CH3OH
1-12
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Density: Ratio of mass to volume. Density is a conversion factor between mass and volume (or between
mass flow rate & volumetric flow rate of a process stream)
M (l ) = 0.792 kg/L (= 0.792 g/cm3 = 49.44 lbm/ft3) [Note: M is methanol, and l in M(l) means liquid]
Liquid and solid densities vary slightly with temperature, almost not at all with pressure. Gas
densities depend heavily on both T and P. Look up a liquid or solid density at one T & P, use at
another set of conditions without introducing much error.
Specific gravity (SG): Ratio of density of a species to the density of a reference species, usually liquid
water at 4oC and 1 atm. (What about gases? Use Equation of State, covered in Ch. 5)
SG where ref =1.000 g/cm3 = 1000. kg/m3 = 62.43 lbm/ft3 (3.1-2)
ref
Look up SG for liquids and solids at 20oC & 1 atm in Table B.1, use values to estimate density at any
T and P.
Q: What is the mass of 395 gallons of acetone at 40oC?
A: First, acetone must be a liquid at 40oC because ________________________________________.
395 gal _________ ft 3 __________________ lb m
Then mA 2607 lb m 2610 lb m
_________ gal _________ ft 3
mA(kg)
mT(kg)
nA(mol)
nT(mol)
VA (L) mB(kg)
VT (L)
nB(mol)
VB (L)
If you don’t have density data for a liquid mixture, assume volume additivity of the components.
1-14
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
A container of a fluid of density (kg/m3) has height h(m) and cross-sectional area A(m2). A
uniform pressure Po(N/m2) is exerted on the upper surface of the fluid.
Po(N/m2) A(m2)
(kg/m3) h(m)
2
P(N/m )
Q: How much does the fluid weigh? (Let g denote the acceleration of gravity.)
A: Wf = ______________________________________________________
Q: What is the pressure exerted by the fluid on the bottom surface of the container?
A: Let Fo and F be the forces exerted on the top and bottom surfaces. Then
F 1 1
P 2
[ Fo (N) W f (N)] [__________________]
A A (m ) A
P Po gh (3.4-1)
Pressure expressed as a head of fluid. Using Eq. 3.4-1, you can express any pressure as a head of a
particular fluid with known density ()—that is, the height (h) of a column of that fluid with a surface
pressure of zero (Po = 0). So, for example, a pressure of 14.7 lbf/in2 can also be expressed as a head of
mercury (specific gravity = 13.6).
P
h(mm) =
g
14.7 lb f ______ in 2 ft 3 _______ lb m ft / s 2 ________ mm
in 2 1 ft 2 13.6 _______ lb m _______ ft/s 2 1 lb f ______ ft
= 760 mm Hg (= 760 torr ) g
Conversion factors for pressure (including the one just calculated) are given in the inside front cover
of the book.
Atmospheric pressure (or barometric pressure): The earth’s atmosphere can be considered a very tall
column of fluid (air). The pressure at the bottom of that column is atmospheric pressure. At sea level,
Patm is typically on the order of 760 mm Hg (or 760 torr). By definition, 760 torr = 1 atm.
1-15
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Questions:
Would atmospheric pressure at a ski resort be greater or less than atmospheric pressure at sea
level? Explain your answer.
Is the average density of the atmosphere on a stormy day greater or less than the atmospheric
pressure on a fair day? Explain.
Suppose you are given the height of the atmosphere. Why can’t you use P = Po + gh to calculate
atmospheric pressure?
Absolute pressure and gauge pressure. The absolute pressure of a fluid is its pressure relative to a
perfect vacuum (P = 0). The gauge pressure is its pressure relative to atmospheric pressure. (It is
called that because many pressure gauges, such as the Bourdon gauge shown on p. 57 of the text, are
calibrated to read 0 when P = Patm.) Thus
Unless you are told otherwise, assume that given pressures are absolute.
Q: The absolute pressure of a gas on a sunny day is 3.67 atm. A storm comes up. If the conditions in
the gas cylinder remain unchanged, does the absolute pressure of the gas increase, decrease, or
remain the same? What about the gauge pressure?
Work through the Test Yourself on p. 56.
Pressure measurement. You can find descriptions of the most common pressure measurement devices
in the Visual Encyclopedia of Chemical Engineering Equipment. (In the main menu, click on
“Process Parameters” “Pressure Measurement.”)
1-16
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
If you equate the pressures at (a) and (b), you get the general manometer equation:
What if P1 and P2 are expressed in units of heads of manometer fluid (i.e. mm Hg or m H2O)?
Archimedes Principle: The mass of a floating object equals the mass of the fluid displaced by that
object.
1-17
Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)
CHE 205 – Chemical Process Principles
Section 1: EPCP, Chapters 2–3
Temperature (3.5)
To convert a temperature in one unit to an equivalent unit:
T(oK) = T(oC) + 273.15
T(oR) = T(oF) + 459.67
T(oR) = 1.8 T(oK)
T(oF) = 1.8 T(oC) + 32
To convert one temperature interval to another temperature interval, use the following conversion factors:
1.8o F 1.8o R 1o F 1o C
, o , o , o
1o C 1K 1R 1K
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Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2009)