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Feasibility study of water purification using vertical porous concrete filter

Article  in  International journal of Environmental Science and Technology · September 2007


DOI: 10.1007/BF03325987 · Source: DOAJ

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Int. J. Environ. Sci. Tech., 4 (4): 505-512, Autumn 2007
ISSN: 1735-1472 M. M. Taghizadeh, et al.
© IRSEN, CEERS, IAU

Feasibility study of water purification using vertical porous


concrete filter
¹*M. M. Taghizadeh; ²A. Torabian; 1M. Borghei; ¹A. H. Hassani

¹ Department of Environmental Engineering, Graduate School of the Environment and Energy, Islamic Azad University
Science and Research Campus, Tehran, Iran
² Department of Environmental Engineering, Graduate Faculty of the Environment, University of Tehran, Tehran, Iran
Received 5 June 2007; revised 8 July 2007; accepted 16 August 2007; available online 1 September 2007

ABSTRACT: Cheapest and simplest techniques of filtration systems are required for rural water treatment in
developing countries. Using a filter made of blocks for the water treatment enables us to make porous concrete filter and
use it vertically. It is expected that the required area would decrease by more than 70 % if porous concrete filters were
used vertically. The operation and backwash mode would be simpler than using horizontal sand filters as filters made
of blocks would be used instead. The feasibility study focused on finding adequate materials, compositions and
methods of making a block with enough resistance to water pressure, sufficient porosity for water transformation and
using inexpensive and available materials. A pilot study was performed to determine an appropriate thickness of filter.
Testing the porous filter in another pilot study using the low overflow rate of river water showed biological growth in
that media and an adequate efficiency of about 90-100 % was obtained for decreasing the coliform bacteria. The required
backwash water was 2.9 % of total treated water.

Key words: Slow sand filter, block filter, coliform bacteria, turbidity, porous concrete

INTRODUCTION
Filtration is a fundamental unit operation that as a great amount of filter materials. The overall function
separates suspended particle matter from water. of the horizontal flow roughing filter in removing
Although industrial applications of this operation vary turbidity and TSS is acceptable (Jafari, et al., 2007). It
significantly, all filtration equipment operate by passing is necessary to meet the above mentioned needs in
the solution or suspension through a porous order to conduct some research on a new filter that has
membrane or medium, upon which the solid particles the same capability as the slow sand filter. It is
are retained on the medium’s surface or within the pores supposed that by using attached sand to form a block;
of the medium, while the fluid, referred to as the filtrate, one can make a vertical form of the slow filter bed, in
passes through. Most pollutants, such as viruses and order to eliminate the factor of excessive required area.
heavy metals may be accompanied with particles. A porous concrete is a mixture of Portland cement, water
Heavy metals accumulate in some fauna and flora, so and fine aggregate that provides suitable infiltration.
the elimination of the particles improves the quality of Porous concrete, the so-called sponge concrete, is
the water (Karbassi, et al., 2006). Sand filters were widely used to cover pavements in order to prevent
proved to be beneficial for the prevention of water the collection and adsorption of water (Richard, et al.,
borne diseases in 1892 (Baker, 1949). Using a slow filter 1982). Some researchers have used porous concrete as
was the first modern technique for treatment of surface a contact media to culture bacteria (Yasunary, et al.,
water. It can eliminate up to 99.9 % of the water born 2006; Branson, et al., 2003). Sand (1997) has reported
bacteria. It has been also used to prevent that various living species, such as microorganisms
gastrointestinal diseases for the last 150 years (Hicks, including protozoa stick to the porous concrete and
2002). Slow sand filtration has several limitations; the grow. This fact confirms the potentiality for growth of
most important of all is excessive required area, as well biological layer in these filters, as in the slow sand
*Corresponding Author Email: tgmehdi@yahoo.com filters. Hence, it seems that one may be able to utilize
Tel.: +98 917 313 5359 Fax: +98 0711 830 1414 the greatest advantage of the slow sand filter; which is
M. M. Taghizadeh, et al.

ability to eliminate infectious bacteria. The goal of this Startup


research is to study the capability of porous concrete At the start up point, the velocity of the outflow
as a vertical filter for water treatment in comparison from the pilot was fixed at about 0.25 m/h in order to
with the slow sand filter. establish the growth of the biological mass on the
filter. The water elevation at the inlet was fixed at
MATERIALS AND METHODS 110 cm. This was carried out by setting a spillway at
Preparation of porous concrete this height. The outflow velocity was controlled by
130 types of concrete blocks were prepared using a valve. The difference in the height of the water
various combination of cement, water and sand in between the two parts at each time was the head
various sizes as follows: loss caused by the filter, which was measured daily.
• Variation in water cement ratio: these ratios were The temperature at the site of the experiment varied
0.45, 0.5, 0.55, 0.6 and 0.65. in the range of 43-49 °C.
• Variation in aggregate cement ratio: the amount
Investigation of bacteria removal
of aggregate in different mixtures were 150, 175,
Since there are nearly 300 coliforms in 100 mL of
200 and 225 kg /m3 raw water, after the pretreatment phase, this amount
• Using of various mixing conditions: reached to 85-140 in 100 mL. These experiments were
A: ordinary method, adequate amounts of cement, performed daily using multiple tube techniques
water and aggregate were mixed: according to the standard method (APHA, 1992). It
B: suction method, a great amount of water was was not a suitable standard by which to estimate
added to the mixture, and then the excess water the capability of the filter to eliminate the fecal
was collected by rapid suction. coliforms because the number of fecal coliforms
• Adding air entering aids such as aluminum declined drastically after passing the pretreatment
powder. units, and sometimes reached to zero. On the other
hand, the growth of the useful bacteria in the filter
• Using of various types of cement, such as: type would not permit a count of the total bacteria to be
I, high alumina cement and polymeric cement. the yardstick.
• Variation in aggregate genes: cilice and powders
of porous mineral materials were used. Investigation of the turbidity removal
The porous concretes were in cylindrical shapes with The pilot filter was set up at water treatment plant
diameter and height of 25 cm and 2.5 cm, respectively. treating Karoon river water, situated in south of Iran.
Because of the high turbidity, the inflowing water
Physical characteristics of the porous concretes passed through a pressured, rapid sand filter and an
The physical characteristics of the porous 80 cm layer with a media grading of the slow sand
concretes such as their compressive strength and filter. Thus, the inflowing turbidity of the filter was
permeability coefficient were investigated. at most 15 NTU. Furthermore, the effluent of flow
turbidity was examined daily.
Investigation of adequate thickness
The appropriate thickness was studied in another Filter run time evaluation
pilot study by constructing block samples with The inflow and outflow of the pilot rate controlled
dimensions of 2.5×31×31 cm 3 in which the blocks closely. When the head loss reached a maximum level,
were placed horizontally (Fig. 1). By examining the the effects of the increased head loss caused the
water flow rate from the block, an acceptable effluent velocity to decline. Along with this decline,
thickness of selected block was established. the washing phase decreased. The velocity was
prevented from reaching zero, because a total jam in
Pilot study of water treatment the filter can make the washing process impossible.
A block with 98 cm width and 130 cm length was
shaped like a trapezoid and with a thickness of 5-12 Investigation of backwash process
cm was devised and used in the second pilot (Fig. 2). The backwash was carried out under pressure by a

506
Int. J. Environ. M.
Sci.M. Taghizadeh,
Tech., et al. Autumn 2007
4 (4): 505-512,

pump and a pressure control faucet. Fig. 2 shows the RESULTS


schematic of the washing process. An appropriate Physical characteristics
pressure for washing was obtained by trying different Table 1 shows the best physical characteristics that
pressures and studying the results. Sufficient time for were obtained from the examination of 130 types of
washing was calculated so that the turbidity of the block samples. Results show that the porous concrete
effluent water would be equal to the inflowing water. made from high alumina cement with characteristic of
The filter was washed several times and restarted, but No. 5 has the best compressive strength and
after two start-ups the operation of the filter run at permeability coefficient. Table 1 shows that the item
higher rates (0.35 m/h and 0.4 m/h) and turbidities (25 No. 5 is the best mixture of aggregate.
NTU) were checked.

Table 1: Physical characteristics of the best samples


Permeability
Type of Water/ Aggregate– Compressive
No. Diameters of aggregates (mm) Mixture manner coefficient
cement cement cement ratio strength (MPa)
(m/h)
1 0.15-4.45 1 0.45 Ordinary 5.25 12 6.25
2 1.18-4.45 Polyorton - Ordinary 20 8.5 7.1
3 Mineral cartridge 1 0.45 Ordinary 5.25 13 7.1
1.18-9.5
4 015-4.45 1 4 Suction method 5.25 10 6.5
5 0.15-4.45 High Al 4 Suction method 5.25 12 8.5

Fig. 1: First pilot, the blocks are placed horizontally

inlet
outlet

Presure
controler
Fig 2: Second pilot, the blocks are placed vertically

507
Feasibility study M. M. Taghizadeh,
of water purificationet using
al. vertical porous...

It’s effective size and uniformity coefficient were layer. To separate these materials appropriatley, force
determined as 0.35 and 2.5, respectively. must be exerted to make an influence in the depth of
the filter. Usually, the washing in rapid sand filters which
Investigation of optimum thickness should be cleaned by backwashing, is practicable with
Fig. 3 shows the result of the investigation of a high pressure of water for the friction between the
adequate thickness for block No. 5. As the results show, sands to achieve a perfect cleaning. But 100 % cleaning
the velocity of the water passing through a thickness of the porous concretes is impossible. Furthermore, it
of 5-7.5 cm will be optimal. Increasing the thickness to is not desirable, as the presence of bacteria is essential.
more than 7.5 cm makes the velocity too low to The washing in this filter is possible if the water
influence the water and at smaller thicknesses, the pressure in the opposite direction is increased to be
ability of the filter to trap particles will be very low. The more than when operating normally. A pressure greater
pilot investigation represents various thicknesses in than 6.5 m breaks the filter. Hence, a test to determine a
water heads from 0 to 110 cm. The final result of these suitable water pressure of 4 m on the opposite direction
investigations shows that the trapezoidal filter with was implied by a pump, a pressure regulating valve
top and bottom thickness of 5 and 12.5 cm respectively and a barometer to measure the flow and the outlet
is the best alternative. turbidity at different times until it reached 5 NTU. Fig.
2 shows the backwash system. The backwash was
Pilot study of water treatment performed by the reserved water with turbidity less
In this experiment, the filtration rate was set at about than 1 NTU. The results can be seen in Table 2. As the
0.25 m/h, equal to the removal flow rate of sand filter, in filter becomes cleaner, the velocity of the water in
order to allow the biological mass to grow. The curve backwash system increases. So, the filter would be
in Fig. 4 illustrates the changes in the efficiency of the cleaned in 130 min, under 4 m water pressure. Tables 4
bacteria elimination versus time. The diagram shows and 5 show the results for 2 m and 3 m pressure. In the
that, the efficiency is low at the outlet that gradually best design, the amount of necessary water for
increased logarithmically. Fig. 4 also compares the backwashing in the rapid sand filter is 3% of the whole
removal efficiency in different phases of operation. The filtered water (Kawmura, 1999). The volume of water
pressure declines in the second phase reaching its used for backwashing is 1.13 m3 per 38.4 m3 of treated
maximum for 6–7 days between the two washes. After water, i.e. 2.9 %, of the total water which is passed.
stabilizing the biological mass, the function of the filter
at higher velocities was examined. Fig. 4 shows the Filtration mechanism
results at 0.35 m/h. Along with the velocity, the head With the aid of a microscope with the source of light
loss increased and the number of days for productivity set above it, the porosity of the filter was found to be
decreased to four days at this velocity. In subsequent 40 % and the diameter of the pores was found to be
days this velocity tended to be 0.25-0.1 m/h. In the about 0.1 mm. Fig. 5 shows part of the filter in the
next experiment, at the maximum head loss, velocity microscopic image. Evidently, this filter could not
and the outlet efficiency were studied. In this case, the remove the coliforms and particles that cause turbidity
maximum flow rate was 0.43 m/h which gradually in conformity with the straining mechanism. The
decreased in the subsequent days. Efficiency changes straining mechanism is not an important issue when
are seen in Fig. 4. It also shows the function of the the ratio (diameter of particles/dimensions of media) is
filter when the turbidity is 25 NTU. An apparent decline greater than 0.2 in the porous environment, whereas if
in the efficiency is a sign of the inadequacy of the filter the average diameter is measured in microns, this ratio
at high turbidities. At this turbidity, a rapid growth of would grow a hundredfold because of the diameter of
head loss and a considerable decline in the velocity fine aggregate, which is 350 µm. (Boller, 1980) and
were observed at the outlet. (Herzig, 1970). Screening in the porous environment is
the predominant mechanism for the removal of particles
Backwash method with an approximate diameter greater than 100 µm, while
The goal of backwash is to remove the particle smaller particles in the filter are not eliminated (Thien,
trapped in the pores of the filter. The particles that 1976), (Maroudas and Eisenklam, 1965). Besides the
cause turbidity are trapped deeply inside the biological particles with diameters in the range of 0.001-10 µm

508
Int. J. Environ. Sci.
M. M.Tech.,
Int. J. Environ. Sci. 4Tech.,
(4): 4505-512,
Taghizadeh, et al.
(4): Autumn 2007
-, 2007

Table 2: Results of backwashing under 4 m water pressure


Time (min.) 0 10 20 30 40 50 60 70 80 90 100 110 120 130
Flow (m³/h) 0.3 0.33 0.37 0.43 0.46 0.5 053 0.58 0.59 0.62 0.64 0.68 0.72 0.75
Turbidity (NTU) 59 54 48 42 38 36 32 28 25 22 16 10 7 5

Table 3: Results of backwashing under 3 m water pressure Table 4: Results of backwashing under 2 m water pressure
Time (min.) 0 10 20 30 40 50 60 Time (min.) 0 10 20 30 40 50 60
Flow (m³/h) 0.15 0.15 0.17 0.18 0.2 0.22 0.22 Flow (m³/h) 0.2 0.2 0.2 0.2 0.2 0.22 0.22
Turbidity (NTU) 60 59 59 56 54 54 54 Turbidity (NTU) 58 57 54 53 50 45 43

Table 5: VSS in block after washing and after 17 days


Time of sampling VS (mg/cm3) positions. As these Figs. Show, in the vertical position
17 days after the first setup 8.23 the particle direction is longer than horizontal one (blue
Just after backwashing 6.28
line shows the particle direction). It could justify the
(Thien, 1976), (Maroudas and Eisenklam, 1965). Besides small thickness of these filters.
the particles with diameters in the range of 0.001-10 µm
cause turbidity (Roberts, 1975). The dimensions of the DISCUSSION AND CONCLUSION
bacteria are in the range of 0.2-8 µm. Hence, another These studies show that slow horizontal filtration is
mechanism must be sought for their elimination. In slow feasible with the blocks which are made of the porous
sand filters, the biological layer plays the key role in concrete and to the growth of the biological mass are
the removal of bacteria and turbidity on the surface of efficient for bacteria removal. There is a restriction on
the filter. At high speeds of water flow through the the increase in the inlet turbidity as in the slow filter.
filter, the biological mass has no chance to grow in the Increasing the filtration rate causes in reduction of
filter and would be washed out with the stream. To be exploitation time. Cleaning this filter is practicable,
assured of the biological mass growth, a sample with under 4 m water pressure for 130 min., consuming only
dimensions of 10×20×20 (mm×mm) was cut from the 2.9 % of the used water. The required area of two filters
upper part of the filter. It was dried at 105 °C and with 2.6 m² vertical area and the height of 130 cm was
weighed. The difference in its weight at 505 ْC was 0.8 m². So, the required area is 70 % less than
then determined in order to measure the weight of corresponding required area of slow filters.
organic materials. The difference in weight was The average thickness of this filter (9 cm) and the
assumed to be related to volatile solid (VS), which use of clear materials, with a 90 % saving in the total
pertains to the biological mass. The experiment was material are required compared with the slow filters.
repeated after the filter washing. The results are given The price of cement and sand in the region contributes
in Table 5. CTRN/W is finite element software that can more economy. Back washing in the filter reduces the
be used to model the movement of particle through labor costs. Given the simplicity of the operation and
porous materials. Figs. 6 and 7 show the results of the inexpensive media, this filter is acceptable for water
passing particle from two same horizontal and vertical treatment in small communities or villages.

7
6
water flow rate (m/h)

5
4
3
2
1
0
2.5 5 7.5
Thickness (cm)
Fig. 3: Result of investigations into adequate thickness for block No. 5

509
M. M. Taghizadeh, et al.

120
100

Head loss (cm)


80
60
40
20 (a)
0
0 5 10 15 20
T ime (day)
Head loss
lost in -first set up turbidity
turbidity15NT U-flowrate0.25m/h
15 NTU flowrate at 0.25 m/h
Head loss
lost after back washing turbidity
T urbidity15
15NT
NTUU-flowrate0.25m/h
flowrate at 0.25 m/h
Head loss
lost
lost in
in flow rate0.35
flowrate m/h-T
at 0.35 m/hurbidity15NT U
turbidity 15 NTU
Head loss
lost in turbidity25NT
NTUU-flowrate0.25m/h
flowrate at 0.25 m/h
120
100
80
Efficiency

60
40
20 (b)
0
0 5 10 15 20
Time (day )
At firststart
Initial startup
upflowrate
flow rateat0.25
0.25m/h
m/h-15NT U
-15NTU
T he second result after washing flow rate at
flowrate 0.25 m/h
0.25 m/h
Flow rate 0.35 m/hm/h
at 0.35
T urbidity 25 NT U
Fig. 4: Comparison of the coliform, removal efficiency (a) and head loss (b) at various velocities

3 mm

Fig. 5: Microscope image of filter

510
Int. J. Environ. Sci.
Int. J. M. M.Tech.,
Environ. Sci.4Tech.,
(4): 505-512,
Taghizadeh, 4 et
(4): Autumn 2007
al.-, 2007

1.2

1.1

1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2
10 20 30 40 50 60 70 80
(x 0.001)
Fig. 6: Tracing particle from vertical filter

80

60

40

20
0.06 0.16 0.26 0.36 0.46 0.56 0.66 0.76 0.86 0.96
Fig. 7: Tracing particle from horizontal filter

ACKNOWLEDGMENT
The authors would like to express their sincere gratitude Branson, P.G.; Frederick, P.H.; Robert, P.G., (2003). Algea
to Pourab Company for accepting a part of the financial attachment on carbonated cements in fresh and brackish
waters- preliminary result. Eco. Eng., 20 (4), 309-319.
support for this research.
Herzig, J.R., (1970) Flow of suspensions through porous media,
Application to Deep filtration. Ind. Eng. Chem. 6 (2), 5-8.
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AUTHOR (S) BIOSKETCHES


Taghizadeh, M. M., M.Sc., Ph.D student in environmental engineering , Department of Environmental
Engineering, Graduate School of the Environment and Energy, Islamic Azad University, Science and Research
Campus, Tehran, Iran. Email: tgmehdi@yahoo.com

Torabian, A., associate professor, Graduate Faculty of the Environment, University of Tehran, Tehran, Iran.
Email: altorabian@yahoo.com

Borghei, M., professor, Graduate School of the Environment and Energy, Islamic Azad University, Science
and Research Campus and College of the Chemistry, Sharif University of Technology, Tehran, Iran.
Email: mborghei@sharif.edu

Hassani, A. H., assistant professor, Department of Environmental Engineering, Graduate School of the
Environment and Energy, Islamic Azad University, Science and Research Campus, Tehran, Iran.
Email: ahhassani@gmail.com

This article should be referenced as follows:


Taghizadeh, M.M.; Torabian, A.; Borghei, M.; Hassani, A. H., (2007). Feasibility study of water purification
using vertical porous concrete filter. Int. J. Environ. Sci. Tech., 4 (4), 505-512.

512

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