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BookIX-Cutlip.fm Page 710 Thursday, August 16, 2007 8:54 AM
710 INDEX
INDEX 711
712 INDEX
Diffusion (Cont.) E
multicomponent, gases in a porous
Effect of round-off errors in ill-conditioned
layer, 419
algebraic and differential
Stefan tube, 383 systems, 207
Stefan-Maxwell equations, 414 Effective diffusivity, 514
unsteady-state, with reaction in a for catalyst particle, 400
semi- infinite slab, 434 for porous catalyst layer, 407
unsteady-state, within a slab, 428 for porous layer, 419
with concurrent reaction of A and B in for substrate in an enzymatic
liquid film, 422 reaction, 630
with first-order reaction, 218 Effective emissivity, 353
with first-order reaction in a slab, Effectiveness factor
analytical solution, 218 catalytic layer, 410
with first-order reaction in a slab, enzyme catalyst on porous support, 630
cylinder, and sphere, 404
general calculation for first-order
with multiple reactions in catalyst reactions, 404
particles, 514
nonisothermal, 425, 427
with reaction in fall laminar liquid film
porous catalyst particles with various
of finite thickness, 438
geometries, 400
with reaction in spherical enzyme
similarity of solutions for first-order
particles, 630
reactions, 404
with reversible reaction in a catalytic
Elemental balances used in equilibrium
layer, 406
calculations, 281
with second order reaction in finite Elementary steps in enzymatic reaction, 496
liquid film, 421
Endothermic reaction, 122, 502
Diffusivity
Energy balance, 46, 122, 230, 334, 338, 342,
binary, 385, 414 348, 349, 353, 354, 355, 357, 369,
effect of temperature, 386 376, 424, 506
effective, 406 batch reactor, 502
for porous materials, 400, 631 control, 575, 586, 610
molecular, 384 distillation, 551, 552, 558
thermal, 229, 378 fermenter, 610
Dilatant fluid, 289, 295 flash evaporator, 525
Dissolution of pill coating, 396 heat exchanger, 361, 363
Distillation column, 544, 551, 558 lumped unsteady-state, 374
Dittus-Boelter correlation, 362
mechanica, 110, 165, 307, 308, 315,
Drag coefficient, 323 317, 318, 320
Drag coefficient on a spherical particle at
packed bed catalytic reactor, 511
terminal velocity, 299
series of heated tanks, 54
Draining time for a tank
steady-state, 209
laminar flow, 320
unsteady-state, 53, 207
turbulent flow, 317
Enthalpy estimation, 523
BookIX-Cutlip.fm Page 713 Thursday, August 16, 2007 8:54 AM
INDEX 713
Enzymatic reaction, 496 Excel ten problem examples, 17, 18, 24, 32,
Enzyme 55, 60, 222, 225, 228, 300, 511, 592
catalyst, 496, 617, 626, 628 Excess Gibbs energy expression, 81, 272
effectiveness factor, 632 Exothermic reversible reaction, 509, 512
supported, 630 Expediting the solution of nonlinear equa-
complex with substrate, 618 tions, 224
degradation, 628
immobilized, 630 F
inhibition, 623 Fanning friction factor, 301, 303, 309, 310
kinetics, 626, 628, 638 Fenske correlation, 544, 546, 550
modeling inhibition, 622 Fick’s law, 384, 407, 423, 437
Michaelis-Menten kinetics, 622 neglecting bulk flow terms, 423
temperature deactivation, 626, 628 Finite difference, 435
Enzyme kinetics, approximation formulas, 676
Lineweaver-Burk linearized implicit, 408
expression, 622 second-order backward, 376, 408, 441
Lineweaver-Burk plot, 622 second-order central, 435
Equation of state second-order forward, 409, 430,
Beattie-Bridgeman, 38, 248 437, 443
Peng-Robinson, 38, 248, 264 First-order linear system, 565
Redlich-Kwong, 19, 101, 153, 251, 255, First-order plus dead-time model, 576,
258, 259, 263 593, 596
Soave-Redlich-Kwong, 38, 248 Fitting a polynomial to rate data in a batch
reactor, 465, 474
van der Waals, 15, 38, 243, 263
Flash evaporation, 267, 523
Virial, 248
Fluid mechanics, 283– 332
Equilibrium calculations, expediting the
solution, 223 (See also Table I-3 on page 721)
Equilibrium constant, 88, 455, 458, 664 Fluidized bed reactor
variation with temperature, 280, 510 dynamic model leading to multiple
steady states, 207
Error function, 326, 677, 678
Fourier’s law, 209, 333, 338, 356, 376, 424
Excel detailed problem solving examples,
Free radicals, 499
adiabatic operation of a tubular reactor
Friction factor correlations for turbulent
for cracking of acetone, 119
pipe flow, 301
calculation of the flow rate in a
Fugacity coefficients
pipeline, 110
calculatio, 265
complex chemical equilibrium by Gibbs
energy minimization, 144 from experimental data, 265
correlation of the physical properties of
ethane, 128 G
molar volume and compressibility from Gas absorption
Redlich-Kwong equation, 101 into a liquid film with chemical
problem solving, 101– 152 reaction, 421
BookIX-Cutlip.fm Page 714 Thursday, August 16, 2007 8:54 AM
714 INDEX
unsteady-state, into a falling laminar Integral time, 582, 587, 593, 605, 613
liquid film of finite Integration of fitted polynomials, 34
thickness, 438 Integration of higher-order ordinary
Generalized enthalpy and entropy differential equations, 219
departure for ideal gas, 261 Internal model control (IMC) controller
Gibbs-Duhem equation, 274 tuning, 593
Gilliland correlation, 544, 548, 550 Isothermal compression of gases, 251
Growth of biomass from substrate, 203
L
H l’Hôpital’s rule, 274, 276
Half-life method for rate data analysis, 471 Laminar boundary layer on a flat plate, 328
Heat capacity, 34 Latent heat of vaporization, 36
mean, 34 Least-squares objective function, 26, 58
Heat exchanger Linear equations, 23
cocurrent and countercurrent Linear regression, 25, 33, 36, 73, 79, 80,
operation, 361 93, 94, 95, 272
double-pipe, 361 confidence intervals, 96
with convective heat transfer on tube detailed calculations, 95
side, 357 half-life data in a batch reactor, 471
Heat of reaction, 424 identification of possible dependency
Heat source due to electrical current, 338 among variables, 89
Heat transfer, 333– 382 rate data in a batch reactor, 465,
(See also Table I-4 on page 722) 467, 468
Heat transfer coefficient rate data in a catalytic reaction, 481
for natural convection from a top rate data in a plug-flow reactor,
surface under calm 477, 479
conditions, 365 variance, 96
for natural convection from surface of Linearization
cylinder to air, 346 catalytic rate expression, 93, 483
for natural convection from vertical side heat transfer correlation from
of cylinder, 366 dimensional analysis, 74, 80
for top and side of cylindrical tank, 366 nth order rate expression, 465
natural convection, 335, 339 Linearization of nonlinear functions, 580
Log mean area for heat transfer, 344
I Log mean temperature difference in heat
Implicit finite difference, 408 exchanger, 357
Initial rate method of data analysis, 470 Lumped analysis in heat transfer, 373
Integral control, 580, 586, 593, 604, 605,
609, 612 M
Integral method in plug-flow reactor, 479 Maple ten problem examples, 17, 18, 24,
Integral method of rate data analysis, 468 32, 55, 60, 222, 225, 228, 300,
batch reactor, 467, 468 511, 592
plug-flow reactor, 479 Margules equations, 81, 86, 273
BookIX-Cutlip.fm Page 715 Thursday, August 16, 2007 8:54 AM
INDEX 715
716 INDEX
INDEX 717
718 INDEX
INDEX 719
720 INDEX
INDEX 721
722 INDEX
INDEX 723
724 INDEX
INDEX 725
726 INDEX
727 INDEX