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Answer:
Since the conversion of ethanol to ethanoic acid involves the addition of oxygen to ethanol,
it is an oxidation reaction.
Answer:
We can distinguish between an alcohol and a carboxylic acid on the basis of their reaction
with carbonates and hydrogen carbonates. Acid reacts with carbonate and hydrogen
carbonate to evolve CO2 gas that turns lime water milky.
Alcohols, on the other hand, do not react with carbonates and hydrogen carbonates.
Answer:
Some substances such as alkaline potassium permanganate and acidified potassium
dichromate are capable of adding oxygen to others. These are known as oxidizing agents.
Heating ethanol at 443 K with excess concentrated sulphuric acid results in the
dehydration of ethanol to give ethane.
The concentrated sulphuric acid can be regarded as a dehydrating agent which removes
water from ethanol.
(i) Esterification reaction: Esters are most commonly formed by reaction of an acid and
an alcohol.
Ethanoic acid reacts with absolute ethanol in the presence of an acid catalyst to give an
ester.
Esters are sweet-smelling substances. These are used in making perfumes and as
flavouring agents.
(ii) Reaction with a base: Like mineral acids, ethanoic acid reacts with a base such as
sodium hydroxide to give a salt (sodium ethanoate or commonly called sodium acetate)
and water:
(Sodium ethanoate or
Sodium acetate)
(iii) Reaction with carbonates and hydrogen carbonates: Ethanoic acid reacts with
carbonates and hydrogen carbonates to give rise to a salt, carbon dioxide and water.
The salt produced is commonly called Sodium ethanoate or Sodium acetate.
When esters react with sodium hydroxide an alkali, the esters are converted again back
into alcohol and sodium salt of carboxylic acid. This reaction is known as saponification
because it is used in the preparation of soap.
Answer: Compound A contains –COOH group while compound B contains –OH group.
Since carboxylic acids and alcohols react with each other to form an ester, out of A and B, one is
an alcohol and the other is a carboxylic acid. This is further strengthened by reaction of both
with Na to evolve hydrogen gas.
Only carboxylic acids react with Na2CO3 to evolve CO2, A contains –COOH group while B
contains –OH group.
14. An organic compound 'X' is widely used as a preservative in pickles and has a molecular
formula C2H2O2. This compound reacts with ethanol to form a sweet smelling compound ‘Y'.
a. Identify the compound ‘X’
b. Write the chemical equation for its reaction with ethanol to form compound ‘Y’.
c. How can we get compound ‘X’ back from ‘Y’?
d. Name the process and write corresponding chemical equation.
e. Which gas is produced when compound ‘X’ reacts with washing soda? Write the chemical
equation.
Answer:
a. Compound X is ethanoic acid which gives and ester (Y) when reacts with ethanol.
b. CH3COOH + CH3CH2OH → CH3COOC2H5
c. Esters give back alcohol and carboxylic acid in the presence of acid or base.
d. CH3COOC2H5 ---NaOH → C2H5OH + CH3COOH
e. CO2 gas is released.
CH3COOH + Na2CO3 → 2CH3COONa + H2O + CO2