+1 Chemistry Brain Storm (Medical)

1. Which of the following statements is incorrect in regard to the B – F bond in BF3?

(a) All the three B – F bond lengths are equal (1.30Å) and each of them is shorter than the sum of
the covalent radii of boron (0.80 Å) and fluorine (0.72 Å)
(b) The bond energy of the B – F bond is highest (646 kJ mol–1) among halide
(c) The usually short bond length and high bond strength of the B – F bond is due to p - p
interaction between the boron and flourine atoms.
(d) The short length and high strength of the bonds is due to p - d interaction
D
2. The correct sequence of the stability of dihalides of group –14 elements is:

(a) SiX2 < SnX2 < GeX2 < PbX2 (b) SiX2 > SnX2 >GeX2 > PbX2
(c) SiX2 > GeX2 > SnX2 > PbX2 (d) SiX2 < GeX2 < SnX2 < PbX2
D
Sol. As due to inert pair effect stability of divalent compound increase  gp.
3. In a multielectron atom, which of the following orbitals described by three quantum numbers will have
same energy in the absence of magnetic field and electric field :
(I) n = 1,  = 0, m = 0 (II) n = 2,  = 0, m = 0
(III) n = 3,  = 1, m = 1 (IV) n = 3,  = 2, m = 1 (V) n = 3,  = 2, m = 0

(a) I and II (b) II and III (c) III and IV (d) IV and V
D
Sol. Energies of orbitals are compared by ‘n + ’. In IV and V cases ‘n + ’ values are 5 and n value are 3
4. Which of the following ion will have maximum paramagnetism: [At. No. Cr=24; Mn = 25; Fe = 26;
Ni = 28]

(a) Ni+2 (b) Fe+2 (c) Mn+2 (d) Cr+2

C
Sol. Mn+2 = d5 = 5 unpaired electron
5. A sample of H2O2 labelled as ‘20’ volume will have strength in gm/lit. (approximately)

(a) 60 (b) 20 (c) 40 (d) 10

A
68
Sol. Strength (gm/lit) = × Volume strength
22.4
6. In the case of alkali metals, the ionic character decreases in the order

(a) MF > MCl > MBr > MI (b) MF > MCl > MI > MBr
(c) MI > MBr > MCl > MF (d) MCl > MI > MBr > MF
A
Sol. Alkali metals are highly electropositive and halogens are electronegative. Thus for the halides of a
given alkali metal, the ionic character increases with increase in electronegativity of halogens.
7. Which of the following will have highest pH?

(a) 0.1 M NaCN (b) 0.1 M NaCl (c) 0.1 M NaNO3 (d) 0.1 M Na2SO4
A
Sol. It is salt of strong base & weak acid

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8. For hydrogen gas Cp – Cv = X and for nitrogen gas Cp – Cv = Y. Thus, X and Y are related as:

(a) X = 4 Y (b) 16 X = Y (c) X = 16 Y (d) X = Y

D
Sol. Cp – Cv = R (for all gases)
9. Which of the following group of compounds are lewis acid?

(a) CH2 = CH2, NO; BeCl2 (b) SnCl2; BH3; AlCl3

(c) SnCl4; CO; CO2 (d) SiCl4, BF3; Al2Cl6
B
10. Consider the following statements about dihydrogen:
I. It is colourless, odourless, tasteless combustible gas.
II. It is lighter than air
III. H–H bond energy is the highest for a single bond between two atoms of any element.
Choose the correct statements.

(a) Only II (b) I & II only (c) II & III only (d) I, II & III
D
11. The IUPAC nomenclature of

F
(a) 1-Fluorocyclopentene (b) 3-Fluorocyclopent-1-ene
(c) 1-Fluorocyclo-pent-2-ene (d) 5-Fluorocyclopent-1-ene
B
12. The correct decreasing order of priority for the functional groups of organic compounds in IUPAC
system of nomenclature is:

O O
|| ||
(a) –CONH2, –CHO, –SO3H, –COOH,  C  R (b) –COOH, –SO3H, –CONH2, –CHO,  C  R
O O
|| ||
(c) –SO3H, –COOH, –CONH2, –CHO,  C  R (d) –CHO, –COOH, –SO3H, –CONH2,  C  R
B
13. Consider the following statements. In diborane :
1. Boron is approximately sp3 hybridized
2. B – H –B angle is 1800
3. There are two terminal B – H bond for each Boron atom
4. There are only 12 bonding electrons available
of these statements

(a) 1,2 & 4 are correct (b) 1,2 & 3 are correct
(c) 2,3 & 4 are correct (d) 1,3 & 4 are correct
D
14. Which of the properties of interstitial hydrides is correct?

(a) They generally form non–stoichiometric species

(b) These are ionic in nature
(c) They have low m.pt.
(d) These are hydride of non-metal
A
15. Which one is used as an air purifier in space craft?

(a) Quick lime (b) Potassium super oxide

(c) Caustic soda (d) H2O2
B
Sol. KO2 give KOH, H2O2 and O2 with water, H2O2 oxidises CO to CO2 which is absorbed by KOH
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16. The dissociation constant for acids HA, HB, HC and HD are 1.3  1013, 1.8  102, 6.23  107 and
8.5  108 respectively. The weakest acid among these

(a) HA (b) HB (c) HC (d) HD

A
17. For C60 fullerenes, which of the following statement is not true?

(a) 20 six membered ring and 12 five membered rings

(b) Six membered rings are connected to other 5 and 6 membered rings
(c) Five membered rings are connected to other 5 and 6 membered rings
(d) All the carbons are in sp2 hybrid state
C
18. Real gases behave differently from ideal gases because:
(i) The molecules of real gases are in constant motion
(ii) Molecules of real gases collide with the walls of the container
(iii) Molecules of real gases have more volume
(iv) Molecules of real gases attract each other

(a) (i) and (ii) (b) (iii) only (c) (iii) and (iv) (d) All of these
C

19. In vinyl cation CH2 = CH , the hybrid states of the two carbon atoms are respectively:

(a) sp2, sp (b) sp, sp (c) sp2, sp2 (d) sp3, sp2
A
20. The correct stability order is/are:
(I) MgCO3 < CaCO3 < Na2CO3 (II) Li2CO3 < Na2CO3 < K2CO3
(III) CaO < MgO < BeO (IV) BaSO4 < SrSO4 < MgSO4

(a) II, IV (b) I, IV (c) II, III, IV (d) I, II, III

D
Sol. Group I are Thermally stable.
21. Among CaH2, NH3, NaH and B2H6, which are covalent hydrides?

(a) NH3 and B2H6 (b) NaH and CaH2 (c) NaH and NH3 (d) CaH2 and B2H6
A
Sol. NH3 and B2H6 are covalent hydrides, while CaH2 and NaH are ionic hydrides.
22. Match List – I with List – II for the compositions of substances and select the correct answer using the
code given below the lists:

List – I (Substances) List – II (Composition)

(A) Plaster of paris (i) CaSO4.2H2O
(B) Epsom salt (ii) CaSO4. ½ H2O
(C) Dead Burnt (iii) MgSO4.7 H2O
(D) Gypsum (iv) MgSO4.H2O
(v) CaSO4
Code:
(A) (B) (C) (D) (A) (B) (C) (D)
(a) (iv) (iii) (ii) (i) (b) (iii) (iv) (i) (ii)
(c) (ii) (iii) (v) (i) (d) (i) (ii) (iii) (v)
C
23. Which of the following pair is not the functional isomer

(a) glucose & fructose (b) CH3CH2CHO & CH3COCH3

(c) CH3 – O – CH = CH2 and CH3 – CH2CHO (d) 1-Propanol and 2-propanol
D

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24. Which of the following functional group Exert +M effect on benzene
O
O  || 
(a)  C  N (b)  N (c)  O CH 3 (d)  C  O  CH 3
O  
C
25. The equilibrium constant Kc for the reaction
P4(g) 2P2(g)
is 1.4 at 400°C. Suppose that 3 moles of P4(g) and 2 moles of P2(g) are mixed in 2 litre container at
400°C. What is the value of reaction quotient (Q)?

3 2 3 4
(a) (b) (c) (d)
2 3 2 5
B
[P2 (g)]2 (1)2 2
Sol. QC   
[P4 (g)] (3 / 2) 3

P4   3 ; P2   2
2 2
26. At 527°C, the reaction given below has Kc = 4
1 3
NH3(g) N2(g) + H2(g)
2 2
What is the Kp for the reaction?
N2(g) + 3H2(g) 2NH3(g)

2 2
 800R   1  1
(a) 16 × (800 R) 2
(b)   (c)   (d)
 4   4  800R  16
C
Sol. Kp = Kc ((RT)ng
ng = - 2 for N2 + 3H2  2NH3 (Reversed & multiplied by 2)
2
 1
Kc   
4
2 2
 1  1 
Kp     
 4   RT 
27. The equilibrium constant for the reaction N2(g) + O2(g) 2NO(g) is 4 × 10–4 at 200 K. In presence of
a catalyst, equilibrium is attained ten times faster. Therefore, the equilibrium constant in presence of
the catalyst at 200 K is:
(a) 40 × 10–4 (b) 4 × 10–4 (c) 4 × 10–3
(d) difficult to compute without more data
B
28. Consider the reactions

(i) 2CO(g) + 2H2O(g) 2CO2(g) + 2H2(g); Eqm. Constant = K1

(ii) CH4(g) + H2O(g) CO(g) + 3H2(g); Eqm. Constant = K2
(iii) CH4(g) + 2H2O(g) CO2(g) + 4H2(g); Eqm. Constant = K3

Which of the following relation is correct?

K1 K2
(a) K 3  (b) K 3  1 (c) K3 = K1K2 (d) K 3  K1  K 2
K2 K 22
D

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29. The equilibrium constant Kc for the reaction SO2(g) + NO2(g) SO3(g) + NO(g) is 16. If 1 mole of
each of all the four gases is taken in 1 dm3 vessel, the equilibrium concentration of NO would be:

(a) 0.4 M (b) 0.6 M (c) 1.4 M (d) 1.6 M

D
(1  x )2
Sol. K c  ; x = 0.6
(1  x )2
30. Consider the following reactions at equilibrium and determine which of the indicated changes will
cause the reaction to proceed to the right.
(1) CO(g)+3H2(g) CH4(g) + H2O(g) (add CH4)
(2) N2(g) + 3H2(g) 2NH3(g) (remove NH3)
(3) H2(g) + F2(g) 2HF(g) (add F2)
(4) BaO(s) + SO3(g) BaSO4(s) (add BaO)

(a) 2, 3 (b) 1, 4 (c) 2, 4 (d) 2, 3, 4

A
31. In which case(s), vapour density remains unchanged on dissociation?

(a) N2O4(g) 2NO2(g) (b) N2(g) + O2(g) 2 NO(g)

(c) PCl5(g) PCl3(g) + Cl2(g) (d) In all of the above cases
B
Sol. If there is no change in no. of moles vapour density not change
32. Consider following equilibria at 300 K and 400 K with their equilibrium constants

300 K 400 K
I : A(g) 2 B(g) Keq = 10 Keq = 5
II: C(g) D (g) Keq = 2 Keq = 5
Thus,

(a) I is enothermic, II is exothermic (b) I is exothermic, II is endothermic

(c) I and II both are endothermic (d) I and II both are exothermic
B
33. For the reaction: FeCO3(s)  FeO(s) + CO2(g); H = 82.8 kJ at 25°C, what is (E or U) at 25°C?

(a) 82.8 kJ (b) 80.32 kJ (c) – 2394.77 kJ (d) 85.28 kJ

B
Sol. H = E + ngRT
1 8.314  298
 82.8 = E +
1000
 E = 80.32
34. Predict which of the following reaction(s) has a positive entropy change?
I. Ag+ (aq) + Cl– (aq)  AgCl(s)
II. NH4Cl(s)  NH3(g) + HCl(g)
III. 2NH3(g)  N2(g) + 3H2 (g)

(a) I and II (b) III (c) II and III (d) II

C
Sol. ng is +ve
35. Consider the Gf and Hf (kJ/mol) for the following oxides. Which oxide can be most easily
decomposed to form the metal and oxygen gas?

(a) ZnO (G° = - 318.4, H° = - 348.3) (b) Cu2O(G° = - 146.0, H° = - 168.8)
(c) HgO (G° = - 58.5, H° = - 90.8) (d) PbO (G° = - 187.9, H° = - 217.3)
C
Sol. Oxide with lowest –ve G°.

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36. Which of the following is correct order of stability of alkene:

CH 3 \
(a) C  CH 2  CH 3  CH  CH 2  CH 2  CH 2
H3C /
H
| CH3 \
(b) CH 3  C  C CH 3  CH 3  C  C CH 3  C  CH 2
| | | H3C /
H H H
H
|
(c) CH 3  C  CH 2  CH 3  C  C CH 3  CH 3  C  C CH 3
| | | |
CH3 H H H
(d) CH2=CH2<CH3–CH=CH2<CH3–CH2–CH= CH2
B
Sol. Stable Hyperconjugation structure for Isobutene
37. In figure (1) below oxygen molecules represented by unshaded spheres, and chlorine molecules,
represented by shaded spheres, are in separate compartments. Figure(2) shows the equilibrium state of
the system after the stopcock separating the two compartments is opened. Assuming that oxygen and
the chlorine behave as ideal gases, what are the signs (+, -, or 0) of H, S, and G for this process?

(1) (2)

(a) H = +, S = -, G = + (b) H = 0, S = +, G = -
(c) H = 0, S = -, G = + (d) H = -, S = +, G = -
B
38. Which of the following is correct order of stability

CH3 CH3
| |  
(a) CH 3  C  CH 3  CH 3  CH  C H3  CH 3  CH 2

Θ Θ Θ Θ
(b) CH 2  CH  CH 3 CH 2  CH 3  CH 2  NO 2
CH 3
  |
(c) CH 3  C H  CH 3  CH 3  CH 2  C H2  CH 3  CH2  CH 3  C  CH 3
 
   
(d) CH 2  CH  CH 2  CH 3  CH  CH 3  CH 3  CH 2  CH 2  CH 3
D
39. Correct IUPAC name of the following compound is

CH2  CH  CH2

COOH COOH COOH

(a) Pentanetrioic acid (b) Propane-1,2,3-tricarboxylic acid

(c) 2-carboxypentanedioic acid (d) Propanetrioic acid
B

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40. Which of the following statement is/are true for carbide
(i) Silicon & Boron carbides are covalent
(ii) Silicon & Boron carbides are hydrolysed
(iii) Calcium & Barium carbide on hydrolysis give ethyne (acetylene)
(iv) Berrylium carbide resembles to Aluminium carbide as both give methane on hydrolysis

(a) (i) and (ii) (b) (i), (ii) and (iii) (c) (i), (iii) and (iv) (d) all are true
C
41. What is degree of unsaturation of following compound
O

(a) 14 (b) 10 (c) 12 (d) 8

A
Sol. Four rings and 10 double bond present
42. Which of the following is least favourable resonating structure
Θ
OH O  H O  H CN C=N C=N
Θ

Θ 
(a) (b)
Θ 

Cl  Cl  Cl
 

(c) Θ (d) Θ
Θ
D Θ
Sol. Both the rings are antiaromatic
43. Which one of the following pairs of solution is not an acidic buffer ?

(a) H2CO3 and Na2CO3 (b) H3PO4 and Na3PO4

(c) HClO4 and NaClO4 (d) CH3COOH and CH3COONa
C
Sol. HClO4 and NaClO4 cannot act as an acidic buffer as HClO4 is strong Acid
44. How many isomers are possible for formula C3H8O?

(a) 3 (b) 4 (c) 2 (d) 5

A
Sol. CH3 – O – CH2 – CH3; CH 3  CH 2  CH2 ; CH 3  CH  CH 3
| |
OH OH
45. Which of the following statements is not correct for a nucleophile ?

(a) Nucleophiles attack at low electron density sites

(b) Nucleophiles are not electron seeking
(c) Nucleophile is a Lewis acid
(d) Ammonia is a nucleophile
C
Sol. Reason : Nucleophiles are electron rich species so act as Lewis base.

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