MasterSeal 7000 CR: Proof of Performance.

Tests and certificates

Elisabeth Casas Bolivar

Specification Manager
Industrial Concrete Refurbishment Europe
MasterSeal 7000 CR: Proof of Performance
Outline / Table of Contents

1 A Unique Combination of Properties

2 Chemical Resistance

3 Crack bridging

4 Application Properties

5 Proven Durability

Project “Battlefield Map” 2

MasterSeal 7000 CR : A unique combination of
properties that addresses the challenges in
wastewater collection and treatment
Specific chemical resistance
to high concentrations of
biogenic sulphuric acid and a
large range of other chemicals

Reduced downtimes Crack bridging

Short overcoating and Ability to bridge cracks
return to service times of up to 0.7 mm

Proven
durability
Fast and easy application Maximum
By rolling or spraying at moisture tolerance
+5°C to +35°C Can be applied on
moist substrates
MasterSeal 7000 CR: Proof of Performance
Tests and Certificates
Biogenic Sulfuric Acid Resistance Available Test Reports

- Fraunhofer Institute Test Report - Report of tests

according to EN 1504-
2 @Applus (external
Institute)

- ITT & DoP including all

results of tests
according to EN 1504-
2, @Applus@PCI

- Official test report from

PCI including results of
additional tests
conducted that are not
required for CE
marking
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MasterSeal 7000 CR: Proof of Performance
Outline / Table of Contents

1 A Unique Combination of Properties

2 Chemical resistance

3 Crack Bridging

4 Application Properties

5 Proven Durability

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Severe chemical attack EN 1504-2
Tested for all groups @28days WITH Pressure

Note! Class III is 28 days of contact

WITH pressure
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MasterSeal 7000 CR
Chemical Resistance (EN 13529)
Technology / Chemistry Epoxy-based Epoxy-Novolac PU-based PUA-based Xolutec
HPU Ucrete
MasterTop Coroflake MasterSeal MasterSeal MasterSeal
Properties: all grades
1278 (AS) 200 M 808 M 689 (AS) 7000 CR
Elastic / Crack-bridging low no high high medium no
Traffic load high high? foot only high high very high

UV-resistant yes (yellow ing) yes (yellow ing) yes (yellow ing) yes (yellow ing) yes (yellow ing) yes (yellow ing)

Fully bonded system yes yes yes yes yes yes

Permanent immersion possible not recommended yes yes depends yes yes
Group EN 13529 / WHG Sim plified Flooring Flooring Waterproofing Waterproofing Waterproofing Flooring
DF 15
1 Cyclic
Gasoline and
and acyclic A Fuels III (AS) depends II* I
DF Mono- polyvalent G Ethers I (8h) [AS] NO* NO NO I -IIIII III
III
DF 2 ethers
Aviation(including
alcohols 15a)
(up to a max.
fuels A Fuels III (AS) II* II I III III
DF 5 C Alcohols III depends II I - II III III
DF 15a Acyclic
48
All vol.-%ethers
methanol),
hydrocarbons as G Ethers I (8-72h) [AS] NO* NO III III
Amines
glycol as w ell as their
w ell asethers
mixtures
DF 13
DF 4 salts (in aqueous JA Amines
Fuels III
III II*
depends NO
II NO I I -IIIII III
II
containing
All alcohols benzol w ith
and glycol
DF 5a solution) C Alcohols III NO* NO I - II III III
max. 5 (incl.
ethers Vol. % 5 and 5b)
Aqueous
Benzene
Single solutions
andand benzeneof
multi-valent
DF 5b
DF 14 K Alcohols
C Tensides III
III II*
II* II* I -IIIII* III
III III
III
DF 4a organic
alcohols
containing surfactants
≥ C2
mixtures A Fuels III II* NO NO III*** III
Aqueous
organicsolutions
(incl.4)
All esters and of D Esters &
DF 7 III NO* NO NO II III
DF 7b organic
ketones
Biodiesel acids
(including.
fuel 7a) M Organic
Ketones
A Fuels III depends
DF 9 III NO* IIII III
III III*
III*** III
III
(carboxylic)
Aromatic upfuel
esters
Fuel oil, Diesel toand
10
and% Acids
D <10%
Esters &
DF 7a III NO* NO* NO II III
DF 3 as w ell
ketones
other their salts
unused Ketones
B Oils III II* II III III III
Organic
Aqueous
combustion acids
solutions
motor oilsof
DF
DF 8
4b (carboxylic,
aliphatic
Crude oils apart from
aldehyde up to N
E Organic
B Aldehydes
Oils III
III II*
II* II I -IIIII III
DF 9a NO* II NO I -IIIII III
III
formic
40 % acids) as w ell as Acids >10%
Usedsalts
their combustion motor
Halogen hydrocarbons≥ F Halogen
DF 6 oil and used
Mineral acidsautomotive
(non I (8-72h) NO* NO III III
DF 4c C2 (incl. 6b) B Oils
hydrocarbons III II* III III III
transmission
oxidizing) up oil w ith a
to 20%
O Inorganic
DF 10 flash
and point
All halogen >
inorganical55 °C in
salts III II* II III III III
Acids
F Halogen
DF 6a aqueous solution
hydrocarbons (incl. 6 I (8h) depends II NO I - II III
hydrocarbons
(pH<6)
and 6b)except HF
Aromatic halogen F Halogen
DF 6b I - II I* NO III III
hydrocarbons hydrocarbons
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MasterSeal 7000 CR
Conclusions: Chemical resistance

Specific chemical resistance against Biogenic Sulfuric Acid, which

makes it suitable for the Waste Water Industry, even in the most
aggressive environments, where other “chemically resistant”
systems may fail.
Chemical
Test method Request
Resistance
After accelerated test:
Accelerated 6 month
Resistance to - No significant change in tensile strength and
period equivalent to 48
biogenic acid permeability.
to 60 month period in
corrosion - Adhesion tests show cohesive failure on concrete
real sewer system
substrate.

Class III (28 days with pressure)

No defects for Groups 1, 2, 3, 4, 5, 5a, 6, 7, 10, 11, 12, 14, 15a
Resistance to EN 13529
Class II (28 days without pressure)
severe chemical Reduction in hardness
No defects for Groups 1, 2 ,3, 4, 5, 5a, 6, 7, 10, 11, 12, 14, 15a
attack of less than 50%
With and without pressure 5 days
No defects for Groups 4a, 6a, 9, 9a, 13 and 15

The resistance against many other media other than just sulfuric
acid, makes it a good solution also for Secondary Containment

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MasterSeal 7000 CR: Proof of Performance
Outline / Table of Contents

1 A Unique Combination of Properties

2 Chemical resistance

3 Crack-bridging

4 Application Properties

5 Proven Durability

9
Crack bridging capacities
Substrates move, cracks open and close
Waterproofing membranes have to
accommodate this movements without
damages to prevent water, carbon
dioxide or other pollutants from
penetrating the concrete.

Two types of crack bridging capacities:

 Static
 Dynamic

Conditioning Method before test: 7 days

at 70ºC according to EN 1062-11 4.1

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Crack bridging capacities
Method A: Static bending test (EN 1062-7 Method B: dynamic tensile test (EN 1062-7)

Crack Number
Frequency
Crack width Class width of
Class (Hz)
(mm) (mm) cycles
A1 0,1 B1 0,1 – 0,15 100 0,03

A2 0,25 B2 0,1 – 0,15 1000 0,03

A3 0,5 B3.1 0,1 – 0,3 1000 0,03

B3.2 0,1 – 0,3 20000 1
A4 1,25
B4.1 0,2 – 0,5 1000 0,03
A5 2,5
B4.2 0,2 – 0,5 20000 1
Note! These methods require measurement after weathering of the membrane.
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MasterSeal 7000 CR
Crack bridging capacities
Crack Bridging Static (A) Dynamic (B)

Temperature +20º C 0° C -10º C +20º C -10º C -+20° C

MasterSeal 7000 CR A3 A3 A2 B3.1 B2

Polyurea A5 B4.2

Polyurethane A4 B2

Weathering does not affect crack bridging performance of the

MasterSeal 7000 CR
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MasterSeal 7000 CR
Crack-bridging

Crack-bridging is necessary to protect concrete effectively

Both dynamic and static crack bridging abilities are important

The fact that the system remains watertight, even in the case
that cracks appear in concrete, reduces the maintenance of the
operating structure

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MasterSeal 7000 CR: Proof of Performance
Outline / Table of Contents

1 A Unique Combination of Properties

2 Chemical resistance

3 Crack bridging

4 Application Properties

5 Proven Durability

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MasterSeal 7000 CR
Moisture tolerance with MasterSeal P 770

Adhesion on wet concrete

Adhesion: EN 1542 > 2,9 N/mm2
Adhesion after thermal EN 13687-1
> 2,7 N/mm2
compatibility: EN 13687-2
Adhesion on wet
EN 13578 > 2,2 N/mm2
concrete

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MasterSeal P 770
for MasterSeal Systems

Adhesion of MasterSeal P 770 with MasterSeal WP membranes

Adhesion acc. EN 1542

MasterSeal P 770 in combination with:
(N/mm²)
MasterSeal M 790 (Xolutec) > 2.9

MasterSeal M 820 (polyurea hybrid, hot-spray) > 2.5

MasterSeal M 210 (polyurethane) > 2.5

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MasterSeal P 770
for MasterSeal Systems

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MasterSeal P 770 primer for MasterSeal
for damp substrate AND rising moisture!

Resistance of MasterSeal P 770 against rising moisture

Plates coated and immersed
for 8 weeks

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MasterSeal 7000 CR
Curing properties

Overcoat times
23°C / 50%rH 5°C / 50% rH

MasterSeal P 770 after 5 hours after 11 hours

MasterSeal M 790 after 8 hours after 25 hours

Return to service water and chemicals @23° C

after 24 hours
MasterSeal M 790 (24h) Mass loss Shore D Changes
immersed for 18 days:
H2SO4 50% -0,5% 6,0%
KOH 20% 0,2% 7,5%
H2SO4 20%/Lactic 5% 1,8% -3,0%
@ 50°C

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MasterSeal 7000 CR
Conclusions: Moisture tolerance and fast curing

In Waste Water collection and treatment: substrates are

always damp.
The high adhesion on damp substrates and the fast curing
properties of MasterSeal 7000 CR reduce downtime
significantly.

The combination with MasterSeal P 770, due its tolerance

to moisture increases adhesion and durability, and the damp
substrate conditions during application or even in case of rising
moisture after application will not affect the performance of the
system.

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MasterSeal 7000 CR: Proof of Performance
Outline / Table of Contents

1 A Unique Combination of Properties

2 A Unique Set of Properties

3 Performance Properties

4 Application Properties

5 Proven Durability

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MasterSeal 7000 CR
proven durability by specific tests

Results show no significant change in

the properties of MasterSeal 7000 CR
after the weathering test

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MasterSeal 7000 CR
Additional properties

Additional performance properties enhancing durability

Required EN 1504-1 MasterSeal 7000 CR

Abrasion resistance < 3000 mg <194 mg

Impact resistance Class III > 20 Nm 24,5 Nm

Resistance to positive - 5 bar

water pressure

Resistance to - Up to 2 bar (depending

negative water on the fairing coat!)
pressure

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MasterSeal 7000 CR
Conclusion: Proven durability

With a durability of at least 5 years (as shown through the results of the
test at the Fraunhofer Institute) and with an expectation of 10 or more
years under real conditions without replacing or having to repair
the coating.

Proven durability

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Summary: MasterSeal 7000 CR
Crack-bridging concrete protection system specifically
developed for wastewater areas where Biogenic Sulphuric Acid
attack occurs

 MasterSeal 7000 CR
▪ MasterSeal 7000 CR is a concrete protection system with a unique
combination of application and performance properties

▪ meeting the challenges in wastewater environments and other industries

▪ with proven durability of minimum 5 years

 How to sell it
▪ Engineers/Owners to understand benefits > project specifications

▪ Applicators to have a unique offer. With spray equipment: added value offer

 Waste water market offer: technology gap for a big market

▪ Many existing waterproofing or protection technologies in the market need
constant maintenance and can be complex and time consuming to be installed
▪ Master Builders Solutions >> Own developed XOLUTEC technology

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