This document discusses principles of welding, including the effects of hydrogen on welds. It explains that hydrogen can cause embrittlement in steels, reducing fracture strength, and that this effect is most severe at temperatures from -60 to 20°C and strain rates typical of tensile testing. The degree of embrittlement depends on microstructure, with untempered martensite most severely affected. Hydrogen enters steels interstitially and diffuses rapidly, interacting with defects. Reactions at surfaces or in molten iron provide hydrogen for embrittlement.
Original Description:
asd
Original Title
Principles of Welding Processes Physics Chemistry Metallurgy Messler 1999
This document discusses principles of welding, including the effects of hydrogen on welds. It explains that hydrogen can cause embrittlement in steels, reducing fracture strength, and that this effect is most severe at temperatures from -60 to 20°C and strain rates typical of tensile testing. The degree of embrittlement depends on microstructure, with untempered martensite most severely affected. Hydrogen enters steels interstitially and diffuses rapidly, interacting with defects. Reactions at surfaces or in molten iron provide hydrogen for embrittlement.
This document discusses principles of welding, including the effects of hydrogen on welds. It explains that hydrogen can cause embrittlement in steels, reducing fracture strength, and that this effect is most severe at temperatures from -60 to 20°C and strain rates typical of tensile testing. The degree of embrittlement depends on microstructure, with untempered martensite most severely affected. Hydrogen enters steels interstitially and diffuses rapidly, interacting with defects. Reactions at surfaces or in molten iron provide hydrogen for embrittlement.
WELDING Processes, Physics, Chemistry, and Metallurgy
ROBERT W. MESSLER, Jr.
Materials Science and Engineering Department Rensselaer Polytechnic Institute Troy, NY
WILEY- VCH WILEY-VCH Verlag GmbH & Co. KGaA 330 MOLTEN METAL AND WELD POOL REACTIONS
range, the embrittling effect disappears. Similarly, when the temperature is
raised much above room temperature, any embrittlement gradually disappears, primarily because the increase in temperature increases the diffusion rate of the hydrogen and promotes its escape to the surrounding atmosphere. The true fracture stress (i.e., load at fracture divided by the actual cross-sectional area at fracture) for a construction steel containing hydrogen can be reduced by 35-40% between -60 and +2O"C (-75 and +75"F) and yet show little degradation at temperatures either far below or significantly above this range. The rate of plastic deformation has been shown to have a marked influence on the extent of hydrogen embrittlement as well. Hydrogen embrittlement disappears at very rapid strain rates (above about lo3 s - l ) and becomes negligible at very slow strain rates (below loM4sec- '). Insidiously, the embrit- tlement due to dissolved hydrogen is most severe in the range of strain rates normally encountered in conventional tensile testing (i.e., to s- ') and service. The degree to which hydrogen embrittles a steel has also been shown to be strongly dependent on the microstructure present. In general, microstructures produced by transformation of austenite at high temperatures or slower cooling are less severely embrittled than those that depart significantly from equilibrium, forming at temperatures well below the equilibrium eutectoid temperature or at high cooling rates. For example, untempered martensite loses almost all of its limited ductility in the presence of hydrogen, while lamellar pearlite loses about 40% of its ductility, and spheroidized pearlite loses less than 30% of its ductility. Bainite too can exhibit susceptibility to hydrogen em brittlemen t. Hydrogen enters the Fe lattice in steels only in atomic form, and occupies interstitial sites. When in solution in Fe, there is strong evidence that hydrogen atoms give up their sole valence electron to become a hydrogen ion or proton, with a single positive charge and an extremely small diameter. Thus, hydrogen in solution in iron can diffuse very readily and rapidly by migrating in the lattice from interstice to interstice. In fact, the form that hydrogen ultimately takes when dissolved in a material depends on the size of the imperfection with which it associates. At vacancies and dislocation lines, the hydrogen probably exists in its ionized form as a proton. At dislocation pile-ups and small-angle grain boundaries, it probably exists as nascent or atomic hydrogen, while at voids, cracks, and in porosity, it probably exists as diatomic hydrogen (H,) molecules or as gaseous hydrogen (Bastien, 1961). Since hydrogen cannot enter the crystal (e.g., iron) lattice except in atomic or ionic form, reactions that provide a source of such nascent hydrogen or ions at the surface of a solid (or in liquid iron) can act as potent sources of hydrogen for embrittlement. Since the solubility of hydrogen varies with both the temperature and the state of aggregation (i.e., phase) of iron, as indicated in Figure 11.3, the majority of hydrogen involved in the degradation of properties of weldments is probably absorbed when the iron is in the molten state. The solubility of hydrogen in molten iron at 2795F (at 0.0024 w t X ) is roughly 4 x
Oxy-Acetylene Welding and Cutting: Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon