Mont 1 STD 12

P25-16
® Code
0
MAIN PATTERN ONLINE TEST-1 (MONT-1) XII
TARGET : JEE (MAIN+ADVANCED) 2017
COURSE : VIJETA (JP), VISHWAAS (JF), ANOOP (EP), AKHIL (EF)
Date (fnukad) : 23-01-2017 Time: 3 Hours(le; : 3 ?k.Vsa) Max. Marks (egÙke vad) : 360
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
Ñi;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
INSTRUCTIONS / funsZ'k :
A. General : A. lkekU; %
1. This booklet is your Question Paper. Do not break 1. ;g iqfLrdk vkidk iz'u&i=k gSA bldh eqgjsa rc rd u
the seals of this booklet before being instructed to do rksMsa tc rd fujh{kdksa ds }kjk bldk funsZ'k u fn;k tk;sA
so by the invigilators.
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

2. Blank spaces and blank pages are provided in the 2. dPps dke ds fy;s [kkyh i`"B vkSj [kkyh txg bl
question paper for your rough work. No additional iqfLrdk esa gh gSA dPps dke ds fy, dksbZ vfrfjDr dkxt
sheets will be provided for rough work.
ugha fn;k tk;sxkA
3. Blank papers, clipboards, log tables, slide rules, 3. dksjs dkxt] fDyi cksMZ (CLIP BOARD)] ykWx rkfydk]
calculators, cameras, cellular phones, pagers and LykbM:y] dSYdqysVj] dSejk] lsyQksu] istj vkSj fdlh
electronic gadgets are NOT allowed inside the
examination hall. izdkj ds bysDVªkfud midj.k ijh{kk d{k esa vuqefr ugha
tc rd ifjos"kd funsZ'k ugha nsa rc rd iz'u i=k dh lhy dks ugha [kksaysA
gSA
4. Write you name and roll number in the space 4. bl iqfLrdk ds fiNys i`"B ij fn, x, LFkku esa viuk uke
provided on the back cover of this booklet. vkSj jksy uEcj fyf[k,A
5. Using a black ball point pen, darken the bubbles 5. Åijh ewy i`"B ds cqycqyksa (BUBBLES) dks dkys ckWy
on the upper original sheet. IokbaV dye ls dkyk djsaA
6. DO NOT TAMPER WITH/MUTILATE THE ORS OR 6. vks-vkj-,l- (ORS) ;k bl iqfLrdk esa gsj&Qsj@foÑfr u
THE BOOKLET. djsaA
7. On breaking the seals of the booklet check that it 7. bl iqfLrdk dh eqgjsa rksM+us ds i'pkr~ Ñi;k tk¡p ysa fd
contains all the 90 questions and corresponding blesa lHkh 90 iz'u vkSj muds mÙkj fodYi Bhd ls i<+s tk
answer choices are legible. Read carefully the
Instructions printed at the beginning of each section. ldrs gSaA lHkh [kaMksa ds izkjaHk esa fn;s gq, funsZ'kksa dks /;ku ls
i<+saA
B. Filling the ORS B. vks-vkj-,l (ORS) Hkjuk % ORS dks Hkjus ds fy, dsoy dkys
Use only Black ball point pen only for filling the ORS. ck¡y iSu dk mi;ksx dhft,A
8. Write your Roll no. in the boxes given at the top left 8. ORS ds lcls Åij cka;s dksus esa fn, x, ck¡Dl esa viuk
corner of your ORS with black ball point pen. Also, jksy uEcj dkys ck¡y ikbUV ls fyf[k, rFkk laxr xksys Hkh
darken the corresponding bubbles with Black ball
point pen only. Also fill your roll no on the back side of dsoy dkys isu ls Hkfj;sA ORS ds ihNs dh rjQ Hkh viuk
your ORS in the space provided (if the ORS is both side jksy uEcj fyf[k, (;fn ORS nksuksa rjQ Nih gqbZ gSA)
printed).
9. Fill your Paper Code as mentioned on the Test Paper 9. ORS ij viuk isij dksM fyf[k, rFkk laxr xksyksa dks dkys
and darken the corresponding bubble with Black ball ck¡y isu ls dkys dhft,A
point pen.
10. If student does not fill his/her roll no. and paper code 10. ;fn fo|kFkhZ viuk jksy uEcj rFkk isij dksM lgh vkSj
correctly and properly, then his/her marks will not be mfpr rjhds ugha Hkjrk gS rc mldk ifj.kke jksd fy;k
displayed and 5 marks will be deducted (paper wise)
from the total. tkosxk rFkk iz'u&i=k esa izkIrkad ls 5 vad dkV fy, tkosaxsaA
(Please read the last page of this booklet for rest of the instructions)
Ñi;k 'ks"k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA
Resonance Eduventures Ltd.

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PHYSICS
PART-I : PHYSICS
PHYSICS
SECTION - I
Straight Objective Type
This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out of which ONLY ONE is correct.
[k.M- I
lh/ks oLrqfu"B izdkj
bl [k.M esa 15 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (A), (B), (C) rFkk (D) gSa] ftuesa ls flQZ ,d
lgh gSA
1. An object and a plane mirror are shown in figure. Mirror is moved with velocity V as shown. The
velocity of image is :
(A) 2 V sin (B) 2 V (C) 2V cos (D) none of these
oLrq ¼tM+or~½
niZ.k
fp=k esa ,d lery niZ.k rFkk ,d oLrq iznf'kZr gSA niZ.k dks V osx ls fp=kkuqlkj pyk;k tkrk gS rks izfrfcEc
dk tehu ds lkis{k osx gksxk &
(A) 2 V sin (B) 2 V (C) 2V cos (D) bueas ls dksbZ ughaA
2L  x 
2. A reflecting surface is represented by the equation y = sin   , 0 < x < L. A ray travelling
  L 
horizontal becomes vertical after reflection. The co-coordinates of the point(s) on which this ray is
incident.
2L x
,d ijkorZu lrg dh lehdj.k y = sin   , 0 < x < L }kjk çnf'kZr gSA {kSfrt fn'kk esa lapfjr ,d
  L 
çdk'k dh fdj.k ijorZu ds i'pkr~ Å/okZ/kj gks tkrh gSA lrg ds ml fcUnq ds funsZ'kkad tgk¡ ;g fdj.k
vkifrr gksrh gS] gksaxs &Space for Rough Work (dPps dk;Z ds fy, LFkku)
 L 2L   L 3L   3L 2L   4L 3L 
(A)  ; (B)  ; (C)  ; (D)  ;
 4    3    4    3 
 
      
Space for Rough Work / (dPps dk;Z ds fy, LFkku)
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
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Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PLC024029
PHYSICS
3. Two point objects are placed on principal axis of a thin converging lens. One is 20 cm from the
PHYSICS
lens and other is on the other side of lens at a distance of 40 cm from the lens. The images of both
objects coincide. The magnitude of focal length of lens is
nks fcUnqor~ oLrqvksa dks ,d irys vfHklkjh ysUl ds eq[; v{k ij j[kk x;k gSA buesa ls ,d oLrq ySUl ls
20 cm ij gS o nwljh oLrq dks ysUl ds nwljh rjQ ySal ls 40 cm nwjh ij j[kk x;k gSA nksuksa oLrqvksa ds
izfrfcEc lEikrh gksrs gS ySUl dh Qksdl nwjh dk ifjek.k gS &
80 40 20
(A) cm (B) cm (C) 40 cm (D) cm
3 3 3
4. Inside a solid glass sphere of radius R  a point source of light lies at a distance x ( x < R) from
centre of the sphere. The solid sphere is surrounded by air of refractive index 1. The maximum
angle of incidence for rays incident on the spherical glass- air interface directly from the point
source is:
R f=kT;k ds ,d Bksl dk¡p ds xksys esa ,d izdk'k fcUnq L=kksr xksys ds dsUnz ls x ( x < R) nwjh ij gSA ,d Bksl
xksyk gok (viorZukad 1) ls pkjks vksj ls f?kjk gqvk gSA fcUnq L=kksr ls lh/ks gh xksykdkj dk¡p gok vUrZlrg ij
vkifrr fdj.kksa ds fy, vf/kdre vkiru dks.k dk eku D;k gS &
x x x x
(A) cos–1 (B) sin–1 (C) cos–1 (D) sin–1
R R R R
5. A concave spherical surface of radius of curvature 10 cm separates two mediums X and Y of

refractive indices 4/3 and 3/2 respectively. Centre of curvature of the surface lies in the medium X.
An object is placed in medium X.
(A) Image is always real
(B) Image is real if the object distance is greater than 90 cm.
(C) Image is always virtual
(D) Image is virtual only if the object distance is less than 90 cm.
10 cm oØrk f=kT;k dh ,d xksyh; lrg] X rFkk Y nks ek/;eksa dks foHkkftr djrh gS ftuds viorZukad Øe'k%
4/3 o 3/2 gSA lrg dk odzrk dsUnz ek/;e X esa fLFkr gS] ,d fcEc ek/;e X esa j[kk gSA
(A) izfrfcEc ges'kk okLrfod gksxkA
(B) izfrfcEc okLrfod gksxk ;fn fcEc dh nwjh 90 cm ls vf/kd gSA
(C) izfrfcEc ges'kk vkHkklh
Space for Rough Work (dPps dk;Z ds fy, LFkku)
gksxkA
(D) izfrfcEc vkHkklh rHkh gksxk tcfd fcEc dh nwjh 90 cm ls de gksA
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PHYSICS
6. Choose the most appropriate graph of imin v/s A, for a light ray which is incident on one face of a
PHYSICS
prism and is coming out from the opposite face (without TIR). (The symbols have their standard
meanings).
fizTe ds ,d ry ij vkifrr fdj.k nwljs foijhr ry ls fudyus okyh fdj.k ¼fcuk vkUrfjd ijkorZu ds½ ds
fy, imin vkSj A ds chp lcls mi;qDr xzkQ pqfu;sA ¼ladsrksa dks muds ekud vFkksaZ esa ekus½
(A) (B)
(C) (D)
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PHYSICS
7. A horizontal light ray passes through a prism (µ = 1.5) of angle 4°. Further, it is incident on a plane
PHYSICS
mirror M, that has been placed vertically. By what angle the mirror is rotated so that the ray after
reflection becomes horizontal?
,d {kSfrt fdj.k 4° fizTe dks.k ds fizTe (µ = 1.5) ls xqtjrh gSA ckn esa] ;g ,d lery niZ.k M ij vkifrr
gksrh gS] ftldks Å/okZ/kj j[kk x;k gSA niZ.k dks fdrus dks.k ls ?kqek;k tk;s ftlls fdj.k ijkorZu ds i'pkr~
{kSfrt gks tk;sA
4°
(A) 1° (B) 2° (C) 4° (D) 8°
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PHYSICS
8. Figure shows an object placed in front of a lens of focal length 10 cm, at a distance 20 cm from the
PHYSICS
lens. On the other side, a convex mirror (f = 5 cm) (with same principle axis as that of lens) is
placed such that all light rays after refracting through lens strike the mirror simultaneously. The
distance between the mirror and the lens is :
(A) 5 cm (B) 10 cm (C) 30 cm (D) cannot be determined
fp=k esa fn[kk;s vuqlkj 10 lseh- Qksdl nwjh okys ySal ds lkeus blls 20 lseh- dh nwjh ij ,d oLrq j[kh gSA
nwljh rjQ] f = 5 lseh- dk ,d mÙky niZ.k (ftldk eq[; v{k ySal ds leku gS) bl izdkj j[kk gS lHkh izdk'k
fdj.ksa ySal ls viofrZr gksus ds i'pkr~ niZ.k ij ,d lkFk Vdjkrh gSa rks niZ.k rFkk ySal ds e/; nwjh D;k
gksxh&
(A) 5 cm (B) 10 cm (C) 30 cm (D) Kkr ugha dj ldrs gSA
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PHYSICS
9. A convex lens is cut into two parts in different ways that are arranged in four manners, as shown.
PHYSICS
Which arrangement will give maximum optical power ?
,d mÙky ySUl dks fHkUu&fHkUu rjhdksa ls nks Hkkxksa esa dkVdj n'kkZ;s vuqlkj pkj fLFkfr;ksa esa la;ksftr fd;k
x;k gSA dkSu lk la;kstu egRre izdk'kh; 'kfä nsxk &
(A) (B) (C) (D)
10. The magnifying power of a telescope can be increased

(A) by increasing focal lengths of both lenses (B) by fitting eyepiece of high power
(C) by fitting eyepiece of low power (D) by increasing the distance of object
,d nwjn'khZ dh vko/kZu {kerk c<+k;h tk ldrh gSA
(A) nksuksa ySalks dh Qksdl nwfj;k¡ c<+kdj (B) mPp 'kfDr dk vfHkus=k ySal yxkdj
(C) fuEu (Low) 'kfDr dk vfHkus=k ySal yxkdj (D) oLrq dh nwjh dks c<+kdj
11. A red postage stamp is viewed in yellow (monochromatic) light. It appears

(A) light grey (B) orange (C) black (D) deep yellow
,d yky iksLV fVdV (postage stamp) ihys ¼,do.khZ;½ çdk'k esa ns[kk tkrk gS rks ;g fn[kkbZ nsxk &
(A) gYdk LysVh (B) ukjaxh (C) dkyk (D) xgjk ihyk
12. In a compound microscope

(A) the objective has a shorter focal length (B) the objective has a shorter aperture
(C) (A) and (B) both are correct (D) the aperture of objective and eyepiece are same.
,d la;qDr lw{en'khZ esa &
(A) vfHkn`';d ySal de Qksdl nwjh dk gksrk gS (B) vfHkn`';d ySal dk }kjd de gksrk gS
(C) (A) o (B) nksauks lgh gS (D) vfHkn`';d o vfHkus=k ySal dk }kjd leku gksrk gSA
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PHYSICS
13. An electromagnetic wave travelling through a transparent medium is given by
PHYSICS
 y 
E x (y,t)  Eox sin 2  7
 3  1014 t  in S unit then the refractive index of medium is :
 5  10 
 y 
,d ikjn'khZ ek/;e esa fo|qrpqEcdh; rjax E x (y,t)  Eox sin 2  7
 3  1014 t  , (S esa bdkbZ½ esa py
 5  10 
jgh gS rks ek/;e dk viorZukad gS –
(A) 1.2 (B) 1.50 (C) 1.33 (D) 2
14. Two light waves travelling in same medium are given by, E1 = 2 sin (100  t - k x + 30º) and
E2 = 3 cos (200  t - k x + 60º). The ratio of intensity of first wave to that of second wave is :
nks izdk'k rjaxs leku ek/;e esa xfr'khy gS ftudh lehdj.ksa E1 = 2 sin (100  t - k x + 30º rFkk
E2 = 3 cos (200  t - k x + 60º) ls nh tkrh gSaA rks igyh o nwljh rjaxksa dh rhozrk dk vuqikr gSA
2 4 1 1
(A) (B) (C) (D)
3 9 9 3
15. In a young’s double slit experiment a very large screen is used. When a transparent film is kept
infront of one of the slits then
(A) all maxima will shift by same distance
(B) all maxima may shift by same distance
(C) distance of nearest minima from the point of zero path difference will be equal to fringe width
(D) distance of nearest maxima from the point of zero path difference will be equal to fringe width
,d ;ax f}&fLyV iz;ksx esa ,d cgqr cM+k inkZ dke es fy;k tkrk gSA tc fdlh ,d fLyV ds lkeus ikjn'khZ
fQYe j[kh tkrh gS rks
(A) lHkh mfPp"B leku nwjh ls foLFkkfir gksaxs A
(B) lHkh mfPp"B leku nwjh ls foLFkkfir gks ldrs gSaA
(C) 'kwU; iFkkUrj okys fcUnq ls fudVre fuEu"B dh nwjh fÝUt pkSM+kbZ ds cjkcj gksxhA
(D) 'kwU; iFkkUrj okys fcUnq ls fudVre mfPp"B dh nwjh fÝUt pkSM+kbZ ds cjkcj gksxhA
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PHYSICS
SECTION - II
PHYSICS
Integer value correct Type
This section contains 15 questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive).
[k.M - II
iw.kk±d eku lgh çdkj
bl [k.M esa 15 ç'u gSaA çR;sd ç'u dk mÙkj 0 ls 9 rd ¼nksuksa 'kkfey½ ds chp dk ,dy vadh; iw.kk±d gSA
16. A point object is placed at a distance 20 cm from the focus of a concave mirror of radius of
curvature 20 cm. Find the distance (in cm) of the image from the focus.
20 cm oØrk f=kT;k ds vory niZ.k ds Qksdl ls 20 cm nwjh ij fcUnqor oLrq j[kh gSA Qksdl ls çfrfcEc
dh nwjh (cm esa) Kkr djksA
17. A small wooden rod of length 5mm is fixed at the bottom of the container filled with water
4
(water = ). It is making an angle 37º with vertical. If an observer (in air) observes the rod
3

paraxially, and the rod is appeareing at an angle radian with vertical then the find the value of x.
x
4
5mm yEckbZ dh NksVh dk"B NM+ , ty (ty = ) ls Hkjs ik=k dh ryh esa tM+or~ gSA ;g Å/oZ ls 37º dks.k
3

cuk jgh gSA ;fn ,d çs{kd (ok;q esa) lek{kh; fdj.kksa ds çs{k.k }kjk ikrk gS fd NM+ Å/oZ ls jsfM;u dk
x
dks.k cuk jgh gS rks x dk eku Kkr dhft,A
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PHYSICS
18. A ray is incident on a sphere of refractive index 2 as shown in figure. Angle of refraction of the
PHYSICS
ray inside sphere is 30º. If total deviation suffered by the ray is 30xº, then find x.
,d çdk'k dh fdj.k fp=kkuqlkj 2 viorZukad ds xksys ij vkifrr gks jgh gSA xksys ds vUnj fdj.k dk
viorZu dks.k 30º gSA ;fn fdj.k }kjk cuk;k x;k dqy fopyu 30xº gS ] rks x Kkr djksA
19. Distance between two images formed by upper and lower part of the point object placed at 30 cm
from given lens is (60 + x) cm, then the value of x is :
fn;s x;s ySUl ls 30 cm dh nwjh ij j[ks ,d fcUnq oLrq ds Åijh Hkkx rFkk fupys Hkkx }kjk cuk;s x;s nksauks
çfrfcEcksa ds e/; nwjh (60 + x)cm gS] rc x dk eku gksxkA
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PHYSICS
20. The minimum magnifying power of an astronomical telescope is M. If the focal length of its
PHYSICS
eye-lens is halved, how much times the minimum magnifying power will increase:
[kxksyh; nwjn'khZ dh U;wure vko/kZu {kerk M gS] ;fn usf=kdk dh Qksdl nwjh vk/kh dj nh tk;s rks U;wure
vko/kZu {kerk fdrus xquk gks tk;sxhA
21. The dispersive power of the material of a lens is 0.04 and the focal length of the lens is 10 cm.
Find the difference in the focal length (in mm) of the lens for violet and red colour.
inkFkZ dh fo{ksi.k {kerk 0.04 rFkk ySal dh Qksdl nwjh 10 cm gSA cSaxuh o yky jax ds fy, Qksdl nwjh es
vUrj (mm eas) gSA
3 4
22. A thin prism of glass is placed in air and water respectively. If ng =
and nw = , then the ratio of
2 3
deviation produced by the prism for a small angle of incidence when placed in air and water
separately is :
3 4
,d dk¡p dk iryk fizTe Øe'k% ok;q o ty esa j[kk x;k gSA ;fn ng = rFkk nw = , gS] rks Øe'k% ok;q
2 3
rFkk ty esa j[kus ij fizTe }kjk vYi vkiru dks.kksa ds fy, mRiUu fopyu dk vuqikr gksxkA
23. A fiber of length 10 km is illuminated with light from an light emitting diode (LED) which is turned
on and off repeatedely for equal amount of time. The speed of the pulses of light are
2.00 × 108 m/s and 2.1 × 108 m/s in fiber. Maximum frequency of LED so that pulse arrive without
overlapping is 60X (KHz). Calculate X.
,d izdkf'kd rUrq ¼QkbZcj½ ftldh yEckbZ 10 km gS dks izdk'k mRltZd Mk;ksM (LED) dh lgk;rk ls
izdkf'kr fd;k tkrk gSA LED fu;r leku le;Urjky ij ckj&ckj pkyw (ON) rFkk cUn (OFF) gksrk gSA rUrq
esa Lianks (pulses) dh pky 2.00 × 108 m/s rFkk 2.1 × 108 m/s gSA fcuk fdlh vfrO;kiu (overlapping) ls
Lianks ds xfr dj ldus ds fy, LED dh vf/kdre vko`fr 60X (KHz) gSA X dh x.kuk dhft;sA
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PHYSICS
24. Figure shows two coherent sources S1-S2 vibrating in same phase. AB is an irregular wire lying at
PHYSICS

a far distance from the sources S1 and S2. Let = 10–3m,  BOA = 0.12°. How many bright spots
d
will be seen on the wire, including points A and B.
fp=kkuqlkj S1 o S2 nks dyklEc) lzksr leku dyk esa dfEir gSA AB ,d vlefer rkj gSA tksfd S1 rFkk S2

ls cgqr nwj fLFkr gSA ;fn = 10–3,  BOA = 0.12° gS rks A o B dks feykdj fdrus pedhys /kCcs rkj ij
d
fn[kkbZ nsxsA
25. In Young's Double slit experiment, a thin glass mica strip of thickness (t = 8  ) is pasted infront of
slit S1. If the same strip is now shifted in front of other slit S2. If the number of fringes which will
cross the central point on the screen is N. Find N ? (d >> D,  << d and nmica = 1.5)
;ax f}&fLyV ç;ksx esa] ekbZdk dk¡p dh iryh ifêdk (eksVkbZ t = 8  ) fLyV S1 ds lkeus fLFkr gSA ;fn bl
ifêdk dks vc fLyV S2 ds lkeus foLFkkfir dj fn;k tk;s rks insZ ds dsUnzh; fcUnq ls xqtjus okyh fÝUtksa dh
la[;k N gSA rks N Kkr djks ? (d >> D,  << d rFkk nmica = 1.5)
26. In a Young's double slit experiment, the slits are 1 mm apart and are illuminated with a mixture of two
wavelengths  = 750 nm and ' = 900 nm and distance between slit and screen is 2m. At what
minimum distance (in mm) from the common central bright fringe on a screen the bright fringe from
one interference pattern coincides with a bright fringe from the other?
;ax ds f}&fLyV ç;ksx esa, fLyVksa ds e/; nwjh 1 mm gS rFkk nks rjaxnZ/;Z  = 750 nm rFkk ' = 900 nm ds feJ
çdk'k ls vkyksfdr fd;k x;k gSA fLyVksa ls 2m nwj fLFkr LØhu ij mHk;fu"B dsUnzh; mfPp"B ls fdruh U;uwre
nwjh (mm ek=kd esa) ij ,d ds O;frdj.k çk:i dh nhIr fÝUt ] nwljs dh nhIr fÝUt ls lEikrh gksxh ?
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PHYSICS
4
27. A thin oil film of refractive index 1.2 floats on the surface of water ( = ). When a light of
PHYSICS
3
wavelength  = 9.6 × 10–7 m falls normally on the film from air, then it appears dark when seen
normally. The minimum change in its thickness for which it will appear bright in normally reflected
light by the same light is Z x 107 m. Then find Z.
4
1.2 viorZukad dh ,d iryh rsy fQYe] ikuh ( = ) dh lrg ij rSjrh gSA tc  = 9.6 × 10–7 m dh
3
rjaxnS/;Z dk izdk'k gok ls bl fQYe ij yEcor~ vkifrr gksrk gS rc ;g YkEcor~ ns[kus ij dkyh ¼vnhIr½
izrhr gksrh gSA bldh eksVkbZ esa U;wuÙke ifjorZu ftlds fy;s ;g mlh izdk'k }kjk yEcor~ ijkofrZr izdk'k esa
pedhyh ¼nhIr½ fn[kkbZ nsrh gS mldk eku Z x 107 m gS] rks Z dk eku crk,sA
28. Radiowaves of wavelength 3 m are incident on a rectangular hole of width 5 m. A screen is placed
at a distance 200 m from the hole. The width of the central maxima is 100b m. Then find b.
3 m rjax nS/;Z dh jsfM+;ksa rjaxs 5 m pkSM+kbZ ds ,d vk;rkdkj fNnz ij vkifrr gksrh gaSA fNnz ls 200 m dh
nwjh ij ,d inkZ j[kk gqvk gSA dsUnzh; mfPp"B dh pkSM+kbZ 100b ehVj gS rks b dk eku Kkr djksA
29. In the figure shown, the maximum number of reflections will be :

fn;s x;s fp=k esa] ijkorZuksa dh vf/kdre la[;k gksxh
30. In the fraunhaufer differaction from a single slit illuminated by polychromatic light, the first minimum
with wavelength 1 is found to be coincident with the third minimum at 2. Then find the value of
1
2
cgqo.khZ izdk'k }kjk nhIr ,d ,dy fLyV ls ÝkugkWQj foorZu esa 1 rjaxnS/;Z dk izFke fuEufu"B 2 rjaxnS/;Z
Space for Rough Work (dPps dk;Z ds fy, LFkku)
ds r`rh; fuEufu"B ij lEikfr ik;k tkrk gSA rc 1 dk eku Kkr djksA
2
®
CHEMISTRY
PART-II : CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION – I ([k.M- I)
Straight Objective Type (lh/ks oLrqfu"B izdkj)
This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONLY ONE is correct.
(bl [k.M esa 15 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (A), (B), (C) rFkk (D) gSa] ftuesa ls flQZ ,d lgh gSA)
31. A 0.2 molal aqueous solution of a weak acid (HX) is 20 percent ionised. The freezing point of this
–1
solution is (Given Kf = 1.86ºC Kg mol for water) :
,d nqcZy vEy (HX) dk 0.2 eksyy tyh; foy;u 20 izfr'kr vk;fur gksrk gSA bl foy;u dk fgekad gS
(fn;k gS] ty ds fy, Kf = 1.86ºC Kg mol–1 ) :
(A) –0.45ºC (B) – 0.90ºC
(C) –0.31 ºC (D) – 0.53ºC.
32. For a linear plot of logP v/s logx for solubility (x) of a gas in a given solvent under pressure (P)
which of the following statement is correct? (KH is Henry's constant).
(A) KH appears as intercept and slope is 1.
(B) logKH appears as slope and intercept is 1.
(C) logKH appears as intercept and slope is 1.
(D) Intercept is 0 and slope is logKH
Space for Rough Work ¼dPps dk;Z ds fy, LFkku½
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CJP/JFMONT1230117C0-13
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CHEMISTRY
nkc (P) ds vUrxZr ,d fn, x;s foyk;d es ,d xSl dh foys;rk (x) ds fy, logP rFkk logx ds ,d js[kh;
vkys[k ds fy, fuEu es ls dkSulk dFku lgh gS \ ¼KH gsujh fu;rkad gS½
CHEMISTRY
(A) KH vUr%[k.M ds :i es mifLFkr gksrk gS rFkk <+ky 1 gSA
(B) logKH <+ky ds :i es mifLFkr gksrk gS rFkk vUr%[k.M 1 gSA
(C) logKH vUr%[k.M ds :i es mifLFkr gksrk gS rFkk <+ky 1 gSA
(D) vUr%[k.M 0 gS rFkk <+ky logKH gSA
33. Consider the following aqueous solution.

(a) 0.1M Glucose solution (b) 0.1M Na2SO4(aq) (c) 0.1M NaCl(aq) (d) 0.1M Na3PO4(aq)
The increasing order of elevation in boiling point is( assuming  = 1)
fuEu tyh; foy;uks dk voyksdu dhft,A
(a) 0.1M Xywdkst foy;u (b) 0.1M Na2SO4(aq) (c) 0.1M NaCl(aq) (d) 0.1M Na3PO4(aq)
DoFkukad es mUu;u dk c<+rk gqvk Øe gS & ¼ekuk  = 1½

(A) a < c < b < d (B) d < b < c < a (C) a = b = c=d (D) c < b < d < a
–1
34. Calculate the cryoscopic constant in (K Kg mol ) of cyclohexane. Given that its heat of fusion is
2630 J/mol and it freezing point is 6.6ºC.
lkbDyksgsDlsu es fgekadferh; fu;rkad (K Kg mol–1 esa) ifjdfyr dhft,A fn;k gS fd blds xyu dh Å"ek
2630 J/mol gS rFkk bldk fgekad 6.6ºC gSA
(A) 20.76 (B) 28.33 (C) 23.15 (D) 18.15
CHEMISTRY
35. The vapour pressure of the solution of two liquids A(pº = 80 mm) and B(pº = 120 mm) is found to
be 100 mm of Hg when xA = 0.4. The result shows that :
CHEMISTRY
(A) solution exhibits ideal behaviour
(B) Hsolution < 0
(C) solution shows positive deviation
(D) solution will show positive deviation for lower concentration and negative deviation for higher
concentration.
nks nzoksa A(pº = 80 mm) rFkk B(pº = 120 mm) ds foy;u dk ok"i nkc 100 mm ik;k tkrk gS] tc xA = 0.4
gSA ifj.kke n'kkZrk gS fd
(A) foy;u vkn'kZ O;ogkj iznf'kZr djrk gSA
(B) Hfoy;u < 0
(C) foy;u /kukRed fopyu n'kkZrk gSA
(D) foy;u U;wu lkUnzrk ds fy, /kukRed fopyu rFkk mPp lkUnzrk ds fy, _.kkRed foy;u n'kkZ,xkA
36. The spin magnetic moment of cobalt in Hg[Co(SCN)4] is :

Hg[Co(SCN)4] esa dksckWYV dk pØ.k pqEcdh; vk?kw.kZ gS &
(A) 3 (B) 8 (C) 15 (D) 24
37. Find the correct formula of complex Iron() hexacyanoferrate(),

ladqy vk;ju() gsDlklk;uksQsjsV()dk lgh lw=k Kkr dhft,A
(A) Fe[Fe(CN)6] (B) Fe2[Fe(CN)6] (C) Fe4[Fe(CN6)]3 (D) Fe [Fe(CN6)]3
CHEMISTRY
38. Which complex shown minimum of three types of isomerism ?
dkSulk ladqy U;wure rhu izdkj dh leko;ork n'kkZrk gS \
CHEMISTRY
(A) [Co(en)2(NO2)(SCN)]Cl (B) [Co(en)3]Cl3
2+
(C) [Co(NO2)3(NH3)3] (D) [CoCl(NH3)5]
3+ – 3– 3+
39. Co ion forms octahedral complex with ligands like F and NH3 as [CoF6] and [Co(NH3)6] .
These two complexes differ in :
(A) No. of unpaired electron(s) (B) Hybridisation
(C) 0 (Crystal field splitting) (D) All of these
3+
Co vk;u F– rFkk NH3 tSls fyxs.Mksa ds lkFk [CoF6]3– rFkk [Co(NH3)6]3+, v"VQydh; ladqy cukrk gS ;gk¡
nks ladqy fuEu es fHkUu gksrs gSa &
(A) v;qfXer bysDVªkWuks dh la[;k (B) ladj.k
(C) 0 ¼fØLVy {kS=k foikVu½ (D) mijksDr lHkh


40. Which of the following compound will not produce methane gas on reaction with CH3MgBr.
fuEu esa ls dkSulk ;kSfxd CH3MgBr ds lkFk vfHkfØ;k ij esFksu xSl mRié ugha djsaxkA
(A) H2O (B)
(C) H3C–CH2–CCH (D)
CHEMISTRY
41. Which of the following compound represent correct configuration ?
fuEu esa ls dkSulk ;kSfxd lgh foU;kl n'kZrk gS \
CHEMISTRY
H
H OH
(A) Cl CONH2
CH3 (B)
H 3C COOH
'S' 'S'
Br C2H5
C=C
(C) (D) None of these (buesa ls dksbZ ugha½
H 3C Cl
'E'
42. Correct Nucleophilicity order is

ukfHkd Lusfgrk dk lgh Øe gS %&
– – – – – –
(A) NO3 > CH3COO > CH3O > PhO (B) CH3O > PhO > NO3 > CH3COO
– – – – – –
(C) CH3COO > PhO > CH3O > NO3 (D) CH3–O > Ph–O > CH3COO > NO3
43. Which reaction is not an example of nucleophilic addition reaction ?

fuEu esa ls dkSulh vfHkfØ;k ukfHkd Lusgh ;ksxkRed vfHkfØ;k dk ,d mnkgj.k ugha gS\
OH OH
(1)LiAlD4 HCN
(A) CH3–CHO  H3C–C–D (B) H3C–CHO  H3C–CH–CN
(2)H2O
H
OH
1 CH3MgBr 2 NH
(C) H3C–CHO 
 2  H2O

 H3C–CH–CH3 (D) H3C–COOCH3 
 CH O–
 H3C–CONH2
3
CHEMISTRY
44. Select the incorrect pair.
O
CHEMISTRY
N
(A) S  Electrophile (B) H H  Nucleophile
O O H

(C) CH2  Nucleophile (D) CH3  Electron deficient species
xyr ;qXe dk p;u dhft, %&
O
N
(A) S  bysDVkWu Lusgh (B) H H  ukfHkd Lusgh
O O H

(C) CH2  ukfHkd Lusgh (D) CH3  bysDVªkWu U;wu Lih'kht
45. Incorrect order of the following with respect to nucleophilic addition reaction of carbonyl
compound is.
(A) Reactivity HCHO > CH3CHO > CH3COCH3
(B) Reactivity PHCHO > HCHO
(C) Electrophilicity of carbonyl carbon HCHO > CH3CHO > CH3COCH3
(D) Electrophilicity of carbonyl carbon : HCHO > PhCHO
fuEu esa ls dkSulk Øe dkckZsfuy ;kSfxdksa ds ukfHkd Lusgh ;ksxkRed vfHkfØ;k ds lanHkZ esa xyr gS &
(A) fØ;k'khyrk HCHO > CH3CHO > CH3COCH3
(B) fØ;k'khyrk PHCHO > HCHO
(C) dkckZsfuy dkcZu dh bysDVªkWu Lusfgrk: HCHO > CH3CHO > CH3COCH3
(D) dkckZsfuy dkcZu dh bysDVªkWu Lusfgrk : HCHO > PhCHO
CHEMISTRY
SECTION – II ([k.M – II)
CHEMISTRY
Integer value correct Type (iw.kk±d eku lgh çdkj)
This section contains 15 questions. The answer to each question is a single digit integer, ranging from
0 to 9 (both inclusive). (bl [k.M esa 15 ç'u gSaA çR;sd ç'u dk mÙkj 0 ls 9 rd ¼nksuksa 'kkfey½ ds chp dk ,dy
vadh; iw.kk±d gSA)
46. An aqueous glucose solution has a boiling point of 374.19K. Another aqueous glucose solution
has a freezing point of 272.22K. Find the molality ratio of two solution. Boiling point and freezing
point of H2O 373.15K and 273.15K respectively.

–1 –1
kb (H2O) = 0.52 K. kg mol ; kf (H2O) = 1.86 K. kg mol
Xywdkst dk tyh; foy;u 374.19K DoFkukad j[krk gSA Xywdkst dk vU; tyh; foy;u 272.22 K fgekad
j[krk gSA nks foy;uks dk eksyyrk vuqikr Kkr dhft,A H2O dk DoFkukad rFkk fgekad Øe'k% 373.15 K rFkk
273.15 K gSA kb (H2O) = 0.52 K. kg mol–1 ; kf (H2O) = 1.86 K. kg mol–1
CHEMISTRY
47. Consider the following pairs of miscible liquids A and B :
feJ.kh; nzoksa A rFkk B ds fuEu ;qXeksa dk voyksdu dhft,A
CHEMISTRY
Liquid A + Liquid B
nzo A + nzo B
(i) C2H5Br + CS2
(ii) CHCl3 + CH3COCH3
(iii) HCl + H2O
(iv) CH3COOH + C5H5N
(v) C6H5Cl + C6H5Br
(vi) CH3COCH3 + CCl4
If solutions showing Hmixing > 0 = x, solutions showing Smixing > 0 = y, solutions showing Vmixing <
0 = z,
Then find |x + y – z|.
;fn Hmixing > 0 n'kkZus okys foy;u = x gS] Smixing > 0 n'kkZus okys foy;u = y gS] Vmixing < 0 n'kkZus okys
foy;u = z gS] rc |x + y – z| Kkr dhft,A
48. How many type of isomerism is exhibited by the complex [Co(NH3)4(NO2)2]Cl ?
ladqy [Co(NH3)4(NO2)2]Cl }kjk fdrus izdkj dh leko;ork n'kkZ;h tkrh gS ?
CHEMISTRY
49. When 36.0 g of a non-volatile, non-electrolyte solute having an empirical formula CH2O is
dissolved in 1.20 Kg of water. The solution freezes at –0.93ºC. What is the no. of oxygen atoms
CHEMISTRY
–1
present per molecule of solute? Kf of H2O = 1.86 K kg mol ; Freezing point of H2O = 273K
tc ewykuqikrh lw=k CH2O j[kus okys 36.0 g vok"i'khy] oS|qrvuvi?kV~; foys; dks 1.20 Kg ty es ?kksyk
tkrk gS] rks foy;u –0.93ºC ij terk gSA foys; ds izfr v.kq mifLFkr vkWDlhtu ijek.kqvksa dh la[;k D;k
gS\ H2O dk Kf = 1.86 K kg mol–1 ; H2O dk fgekad = 273K
50. Two solutions of non-volatile and non-electrolyte solute A and B are prepared separately. The
M 1
molar mass ratio A  . Both are prepared as 5% by weight solution in water. Then what is the
MB 3
( Tƒ )A
ratio of freezing point depressions, of the solutions?
( Tƒ )B
nks vok"i'khy rFkk oS|qr vuvi?kV~; (non-electrolyte) foys; A rFkk B ds nks foy;u i`Fkd&i`Fkd cuk;s
MA 1
x;sA buds eksyj nzO;ekuksa dk vuqikr  gSA nksuksa dk foy;u] ty esa Hkkj ds vuqlkj 5% cuk;k x;k]
MB 3
( Tƒ )A
rc bu foy;uksa ds fgekad esa voueu dk vuqikr D;k gS \
( Tƒ )B
51. A six co-ordinate complex has the formula CoCl3.5NH3.H2O. Electrical conductance
measurements indicate the presence of three ions in one formula unit. How many moles of AgCl
will be percipitated with excess AgNO3 solution with two mole of complex ?
,d milgla;ksth ladqy dh leUo; la[;k N% gS] bldk lw=k CoCl3.5NH3.H2O gSA fo|qr pkydrk ekiu ,d
lw=kh; bdkbZ esa rhu vk;uksa dh mifLFkfr dks bafxr ¼iznf'kZr½ djrk gSA ladqy ds nks eksy dks AgNO3 foy;u
ds vkf/kD; ds lkFk mipkfjr djus ij AgCl ds fdrus eksy vo{ksfir gksxsa \
CHEMISTRY
52. For [Ma2b2c2], no. of isomer with resultant dipole moment not equal to zero are :
CHEMISTRY
[Ma2b2c2] ds fy,] 'kwU; ds cjkcj ifjek.kh f}/kzqo vk?kw.kZ ugha j[kus okys leko;oh dh la[;k gksxh &
53. Find the number of correct statement

(i) t = 0.44 0, and SP = 1.3 0
(ii) Complex [Pt (NH3)(Br)(I)(Py)] has three geometrical isomers.
3–
(iii) [Cr(C2O4)3] exhibit both Geometrical and optical isomerism.
(iv) EAN of ferrocene is 34
(v) IUPAC name of [Co(NH3)6][Co(NH3)2(NO2)4]3 is Hexaamminecobalt() diamminetetranitrito-N
Cobalt()
lgh dFkuks dh la[;k crkb, &
(i) t = 0.44 0, rFkk SP = 1.3 0
(ii) ladqy [Pt (NH3)(Br)(I)(Py)] rhu T;kfefr; leko;oh j[krk gSA

3–
(iii) [Cr(C2O4)3] T;kfefr; rFkk izdkf'kd nksuks leko;ork n'kkZrk gSA
(iv) Qsjkslhu dk EAN 34 gSA
(v) [Co(NH3)6][Co(NH3)2(NO2)4]3 dk IUPAC uke gsDlk,Eehu dksckYV(III) MkbZ,EehuVsVªkukbVªkbVks-N-
dksckYV() gSA
CHEMISTRY
3+
54. CFSE for the complex [r(NH3)6] is :
 0.4  x 
 t 2g  0  0.6  y eg  0  ZP 
  
CHEMISTRY
 
Find the addition of x + y.
ladqy [r(NH3)6]3+ ds fy, CFSE gS &
 0.4  x 
 t 2g  0  0.6  y eg  0  ZP 
   
x + y dk ;ksx Kkr dhft,A
–
55. In [Fe(edta)] , number of 5 membered rings is
–
[Fe(edta)] esa 5 lnL; okyh oy;ksa dh la[;k gS&
56. How many reactions show correct major product :

fuEu esa ls fdruh dkcZfud vfHkfØ;k,¡ lgh eq[; mRikn n'kkZrh gSa %&
O O O
C–Cl CH COOH C–O–C–CH3

(i) 3

 + HCl
O O
HCl
(ii)   + NH3
NH2 Cl
18
COOH OH
O
18dil.H2SO 4 ruq.H2SO 4
(iii) Ph–C–O–Ph     +
O
O O–C–CH3 O OCH3
C C
CH ONa
(iv) 3
  + CH3COONa
O NH2 ONa
NaNH2
(v)   +
O O O O
CHEMISTRY
57. Total number of position isomers of trichlorocyclohexane which can show geometrical isomerism.
VªkbZDyksjkslkbDyksgSDlsu ds dqy fdrus fLFkfr leko;oh T;kfefr leko;ork n'kkZrs gSA
CHEMISTRY
58. Pure enantiomer of lactic acid has an optical rotation of +1.6º. A sample of lactic acid has an
1
optical rotation of +0.8º. The enantiomer excess is X ×10 %. Find X.
ysfDVd vEy dk 'kq) izfrfcEc leko;oh +1.6º dk izdkf'kd ?kw.kZu j[krk gSA ysfDVd vEy dk ,d izkn'kZ
1
+0.8º dk ,d izdkf'kd ?kw.kZu j[krk gSA izfrfcEc leko;oh vkf/kD; X ×10 % gS rc X dk eku Kkr
dhft,A
3
CHO
O
59. On which position grignard reagent will react first in H C–C CCH
3
2 1
3
CHO
O
;kSfxd H3C–C CCH esa dkSulh fLFkfr ij fxzU;kj vfHkdeZd igys fØ;k djsxkA
2 1
Me
60. Number of geometrical isomers possible of
Et
Me
ds laHko T;kferh; leko;fo;ksa dh la[;k gS %&
Et
MATHEMATICS
PART-III : MATHEMATICS
MATHEMATICS
SECTION – I ([k.M- I)
Straight Objective Type (lh/ks oLrqfu"B izdkj )
This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONLY ONE is correct.
bl [k.M esa 15 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (A), (B), (C) rFkk (D) gSa] ftuesa ls flQZ ,d lgh gSA
61. Let f(x) be a function whose domain is [– 5, 7]. Let g(x) = |2x + 5|, then domain of (fog) (x) is
ekuk f(x) ,d Qyu gS ftldk izkUr [– 5, 7] gSA ;fn g(x) = |2x + 5| gks] rks (fog) (x) dk izkUr gSa&
(A) [– 4, 1] (B) [– 5, 1]
(C) [– 6, 1] (D) [–3, 1]
62. Let f(x) = xx ; x (1, ) and g(x) be inverse function of f(x). g (x) must be equal to
1 1
(A) (B)
x (1  n x) x (1  n (g(x)))
1
(C) (D) non existent
g(x).(1  n(g(x))
ekuk f(x) = xx ; x (1, ) rFkk g(x), f(x) dk izfrykse Qyu gS] rc g (x) cjkcj gksxk&
1 1
(A) (B)
x (1  n x) x (1  n (g(x)))
1
(C) (D) fo|eku ugha
g(x).(1  n(g(x))
® Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
MJP/JFMONT1230117C0-25
MATHEMATICS
63. Suppose that f(x) is an even periodic function with period 2 such that f(x) = x for all x in the interval
MATHEMATICS
[0, 1]. The value of f (3.14) equals
ekukfd f(x) ,d le vkorhZ Qyu ftldk vkorZdky 2 bl izdkj gS fd f(x) = x vUrjky [0, 1] esa x ds lHkh
ekuksa ds fy, f (3.14) dk eku cjkcj gS&
(A) –3.14 (B) –0.14
(C) 0.14 (D) 0.86
    
cot sin1  2  3   cos1  12   sec 1
  
64. Find the value of cos – 1   2  is
   4   4 
  
  
   2 3   12  

cos – 1 cot sin1 
  4
  cos1 
  4 
 sec 1  2  dk eku gS &
      

(A) 0 (B)
4
 
(C) (D)
6 2

65. The number of real solutions of cos–1x + cos–12x = is
4
(A) 0 (B) 1
(C) 2 (D) infinitely many

cos–1x + cos–12x = ds okLrfod gyksa dh la[;k gS&
4
(A) 0 (B) 1
(C) 2 (D) vuUr
MATHEMATICS
   3 
66. If sin–1  tan  – sin–1  = 0 and x2 = y then x is equal to
MATHEMATICS
 –
 4  
 y  6
   3 
;fn sin–1  tan  – sin–1   – = 0 vkSj x2 = y gS] rc x cjkcj gS&
 4  y 6
(A) 2 (B) 4
(C) 2 (D) 3
67. The greatest value of (sin–1 x)3 + (cos–1 x)3 is

(sin–1 x)3 + (cos–1 x)3 dk vf/kdre eku gS&
3 3
(A) (B)
32 8
7 3
(C) (D) none of these (buesa ls dksbZ ugha)
8
68. The number of ordered triplets (x, y, z) satisfying the equation

3 2
(sin–1x)2 + (sin–1y)2 + (sin–1z)2 = are
4
3 2
lehdj.k (sin–1x)2 + (sin–1y)2 + (sin–1z)2 = dks larq"V djus okys f=k;Zd (x, y, z) ;qXeksa dh la[;k
4
gS&
(A) 1 (B) 2
(C) 3 (D) None of these (bueas ls dksbZ ugha)
MATHEMATICS
 1
69. If y = tan–1 x + tan–1   + cosec–1 x , x  (– , –1]  [1, ), then y 
MATHEMATICS
x
1
;fn y = tan–1 x + tan–1   + cosec–1 x , x  (– , –1]  [1, ) gS] rks y 
x
     
(A)   ,     ,  (B)   , 
 2  2   2 2
  
(C) (0, ) (D) 0,    ,  
 2 2 
 
70. Find lim sin  [sin x]  , where [.] is a greatest integer function and n .
x (2n 1)  
 6 
1
(A) 0 (B)
2
1
(C) – (D) none of these
2
 
lim sin  [sin x]  dk eku, tgk¡ [.] egÙke iw.kk±d Qyu gS vkSj n .
x (2n 1)  
 6
1
(A) 0 (B)
2
1
(C) – (D) buesa ls dksbZ ugha
2
MATHEMATICS
f(c  h)  f(c – h) – 2f(c)
71. If f (c) exists and is non-zero then lim is equal to
MATHEMATICS
x 0 h
(A) f (c) (B) 0
(C) 2f (c) (D) none of these
f(c  h)  f(c – h) – 2f(c)
;fn f (c) fo|eku gS vkSj v'kwU; gS rks lim dk eku gS&
x 0 h
(A) f (c) (B) 0
(C) 2f (c) (D) buesa ls dksbZ ugha
 x 
72. lim (1– x) tan   is equal to
x1  2 
 x 
lim (1– x) tan   cjkcj gS&
x1  2 
 2
(A) (B)
2 
 2
(C) – (D) –
2 
2
73. If f(x) = 1– e – x , then at x = 0, f(x) is
(A) differentiable as well as continuous (B) continuous but not differentiable
(C) differentiable but not continuous (D) neither differetiable nor continuous
2
;fn f(x) = 1– e – x , rks x = 0, f(x) gS &
(A) lrr~ vkS j vodyuh; gS A (B) lrr~ ij vodyuh; ugha gS A
(C) lrr~ ugha gS ij vodyuh; gS A (D) uk gh lrr~ vkS j uk gh vodyuh;
MATHEMATICS
74. If [.] and {.} denote greatest integer and fractional part functions respectively and
MATHEMATICS
  e[x]|x|  2 
x   , x0
f(x) =   [x]  {2x}  , then

 1 , x0
(A) f(x) is differentiable every where (B) f(x) is continuous at x = 0
(C) f(x) is continuous every where (D) f(x) is not differentiable at x = 0
;fn [.] rFkk {.} Øe'k% egÙke iw.kk±d rFkk fHkUukRed Hkkx Qyu dks iznf'kZr djrssa gS rFkk
  e[x]|x|  2 
x   , x0
f(x) =   [x]  {2x}  gks] rks &

 1 , x0
(A) f(x) lHkh x ds fy, vodyuh; gSA (B) x = 0 ij f(x) lrr~ gSA
(C) f(x) lHkh x ds fy, lrr~ gSA (D) x = 0 ij f(x) vodyuh; ugha gSA
 
 1– sin x ,
x
2 is continuous at x =  , then  is equal to
75. If f(x) =  1  cos 2x
 ,  2
 x
 2
 
 1– sin x ,
x
2 , x= 
;fn f(x) =  1  cos 2x ij lrr~ gS] rks cjkcj gS&
 ,  2
 x
 2
1
(A) 2 (B)
2
1 1
(C) (D) –
4 4
MATHEMATICS
SECTION – II ([k.M – II)
MATHEMATICS
Integer value correct Type (iw.kk±d eku lgh çdkj)
This section contains 15 questions. The answer to each question is a single digit integer, ranging from
0 to 9 (both inclusive).
bl [k.M esa 15 ç'u gSaA çR;sd ç'u dk mÙkj 0 ls 9 rd ¼nksuksa 'kkfey½ ds chp dk ,dy vadh; iw.kk±d gSA
x x
n tan  tan3 r 1
2r 1
2 f(x)
76. If f(x) = lim  then find lim =
n 
r 0 2 x x 0 x
1– tan r 1
2
x 3 x
n tan r 1  tan
;fn f(x) = nlim 2 2r 1 rc lim f(x) dk eku

 x x 0 x
Kkr dhft,A
r 0
1– tan2 r 1
2
1
3n
 Cn  n A 1/3 1/4
77. If lim  2n  = , where A & B are relatively prime numbers, then A + B is equal to-
n
 Cn  B
1
3n
 Cn  n A
;fn lim  2n  = tgk¡ A ,oa B lgvHkkT; la[;k,¡ gS rc A1/3 + B1/4 cjkcj gS -
n
 Cn  B
 1 1 1 
78. lim    .......   = kn 6, then find the value of k.
n 
n 1 n  2 6n 
 1 1 1 
lim    .......   = kn 6 gS] rks k dk eku Kkr dhft,A
n 
 n  1 n  2 6n 
MATHEMATICS
79. For positive integers k = 1, 2, 3 ...... n, let Sk denotes the area of AOBk (where 'O' is origin) such
MATHEMATICS
n
k  1 
that AOBK = , OA = 1 and OBk = k. find the value of  lim 2 S K  . (where [.] denotes
2n  n  n
k 1 
greatest integer function)
/kukRed iw.kk±dksa k = 1, 2, 3 ...... n ds fy,, ekuk Sk ds f=kHkqt AOBk dks {ks=kQy dks O;Dr djrk gS
n
k  1 
(tgk¡ 'O' ewy fcUnq gS) bl izdkj gS fd AOBK = , OA = 1 rFkk OBk = k rc nlim S K  dk eku
2n 
 n2 k 1 
Kkr dhft,A (tgk¡ [.] egÙke iw.kk±d Qyu dks iznf'kZr djrk gS)
 
 2 
80. Number of solutions of the equation sec–1   +  cos x = 0 is
 1  x 
x 
 
 2 
lehdj.k sec–1   +  cos x = 0 ds gyksa dh la[;k gS&
 1  x 
x 
(cot x)(e x – 1) – cos2 x  11

81. If lim  K , K  R then find the value of K   , where [.] represents the
x 0 sin x  7
greatest integer function.
(cot x)(e x – 1) – cos2 x 11
;fn lim K,KR rc K   tgk¡ [.] egÙke iw.kk±d Qyu dks n'kkZrk gS&
x 0 sin x  7
MATHEMATICS
–1 –1 –1
82. Domain of f(x) = cos x + cot x + cosec x has number of elements in it
MATHEMATICS
–1 –1 –1
f(x) = cos x+ cot x+ cosec x ds izkUr esa vo;oksa dh la[;k gS -
3 5 a
83. If f(x) = x +x and g(x) is inverse of f(x) if value of g'(2) is (where, a,b are co prime then a + b is
b
equal to
a
;fn f(x) = x3 +x5 rFkk g(x), f(x) dk izfrykse gS ;fn g'(2) dk eku gS (tgk¡ a, b lgvHkkT; gS) rc a + b
b
cjkcj gS -
84. If range of f(x) = n({x} 2  6{x}  11) is [na, nb) then, b – a is equal to
(where {.} denotes fractional part function )
;fn f(x) = n({x} 2  6{x}  11) dk ifjlj [na, nb) gS rc, b – a cjkcj gS -
(tgk¡ {.} fHkUukRed HkkxQyu gSA)
x 2 )  sin (sin (x+1)) is [p,q] then find the value of

–1 –1
85. If the complete set of the inequation cos (cos
24 –1
sin (q – p).

24
;fn vlfedk cos(cos–1 x 2 )  sin (sin–1(x+1)) dk lEiw.kZ gy leqPp; [p,q] gS rc –1
sin (q – p) dk

eku Kkr dhft,A
MATHEMATICS

1  n1 1 2
86. If   cot 2 then 25 sin  is equal to
MATHEMATICS
 n 
n1  2 

1
;fn   cot 1  2n1  n 
rc 25 sin2 cjkcj gS -
n1  2 
–1 –1 x  ab
87. If domain of f(x) = sin (cosx) + cos  10  is [–a, b) then 10 is equal to (given that [ ] is GIF)
 
x ab
;fn f(x) = sin–1(cosx) + cos–1   dk izkUr [–a, b) gS rc dk eku gS (fn;k x;k gS fd [ ] egÙke
10
  10
iw.kkZad Qyu gS)
(x  3)x  cos 1 x 2  3x  1 is valid for two values of x let say x = a, b ,

–1
88. The function f(x) = cot
then |a–b| has the value
Qyu f(x) = cot–1 (x  3)x  cos 1 x 2  3x  1 x ds Bhd nks ekuksa ds fy, lR; gS ekuk x = a, b , ds fy,
rc |a – b| dk eku cjkcj gS -
–1 2 –1 2 4
89. Maximum value of (sec x) + (cosec x) is  then is equal to
2
–1 2 –1 2 4
(sec x) + (cosec x) dk vf/kdre eku  gS rc cjkcj gS -
2
–1 –1
90. If f(x) = sin (cos (x+1)) – cos(tan x) and f(a) = 0 then |2a| is equal to
;fn f(x) = sin (cos–1 (x+1)) – cos(tan–1x) vkSj f(a) = 0 rc |2a| cjkcj gS -
MAIN PATTERN ONLINE TEST-1 Code
P25-16
(MONT-1) XII 0
TARGET : JEE (MAIN+ADVANCED) 2017
DATE : 23-01-2017 | COURSE : VIJETA (JP), VISHWAAS (JF), ANOOP (EP), AKHIL (EF)
11. Since it is not possible to erase and correct pen filled 11. pawfd isu ls Hkjs x, xksys feVkuk vkSj lq/kkjuk laHko ugha gS
bubble, you are advised to be extremely careful while
blfy, vki lko/kkuh iwoZd vius mÙkj ds xksyksa dks HkjsaA
darken the bubble corresponding to your answer.
12. Neither try to erase / rub / scratch the option nor 12. fodYi dks u feVk,a@u LØsp djsa vkSj u gh xyr (X) fpUg
make the Cross (X) mark on the option once filled.
dks HkjsaA ORS dks dkVs u gh QkMs u gh xUnk ugha djsa rFkk
Do not scribble, smudge, cut, tear, or wrinkle the
dksbZ Hkh fu'kku ;k lQsnh ORS ij ugha yxk;sA
ORS. Do not put any stray marks or whitener
anywhere on the ORS.
13. If there is any discrepancy between the written data 13. ;fn ORS esa fdlh izdkj dh fy[ks x, vkadMksa rFkk xksys
and the bubbled data in your ORS, the bubbled data
fd, vkadMksa esa fojks/kkHkkl gS] rks xksys fd, vkadMksa dks gh
will be taken as final.
lgh ekuk tkosxkA
C. Question Paper Format C. iz'u&i=k dk izk:i
This question paper consists of three part. Each part bl iz'u&i=k esa rhu Hkkx gSaA izR;sd Hkkx esa nks [kaM gSaA
consists are two section.
14. Section 1 contains 15 multiple choice questions. 14. [kaM 1 esa 15 cgqfodYi iz'u gaSA gj iz'u esa pkj fodYi (A),
Each question has Four choices (A), (B), (C) and (D) (B), (C) vkSj (D) gSa ftuesa ls dsoy ,d lgh gSA
out of which only ONE is correct.
15. Section 2 contains 15 questions. The answer to 15. [kaM 2 esa 15 iz'u gSaA izR;sd iz'u dk mÙkj 0 ls 9 rd ¼nksuksa
each question is a single-digit integer, ranging from 'kkfey½ ds chp ,d ,dy vadh; iw.kkZad gSA
0 to 9 (both inclusive).
D. Marking Scheme D. vadu ;kstuk
16. For each question in Section 1, you will be awarded 16. [kaM 1 esa gj iz'u esa dsoy lgh mÙkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to
dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ughaa djus ij
only the correct answer and zero mark if no bubbles
(0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa _.kkRed ,d
are darkened. In all other cases, minus one (–1) mark
will be awarded. (–1) vad iznku fd;k tk;sxkA
17. For each question in Section 2, you will be awarded 17. [kaM 2 esa gj iz'u esa dsoy lgh mÙkj okys cqycqys(BUBBLES)
4 marks if you darken the bubble corresponding to dks dkyk djus ij 4 vad vkSj dksbZ Hkh cqycwyk dkyk ugha djus
only the correct answer and zero mark if no bubbles ij (0) vad iznku fd, tk;saxsA vU; lHkh fLFkfr;ksa esa (0) vad
are darkened. In all other cases, zero will be
iznku fd;k tk;sxkA
awarded.
Name of the Candidate (ijh{kkFkhZ dk uke) : Roll Number (jksy uEcj) :
I have read all the instructions and shall I have verified all the information filled by
abide by them the candidate.
eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk ijh{kkFkhZ }kjk Hkjh xbZ lkjh tkudkjh dks eSusa
vo'; ikyu d:¡xk@d:¡xhA tk¡p fy;k gSA
...................................... ......................................
Signature of the Candidate Signature of the Invigilator
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj
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MAIN PATTERN ONLINE TEST-1
(MONT-1) XII
TARGET : JEE (MAIN+ADVNACED) 2017
DATE : 23-01-2017 COURSE : VIJETA (JP), VISHWAAS (JF), ANOOP (EP), AKHIL (EF)
HINTS & SOLUTIONS ¼la d s r ,oa gy½
PART-I PHYSICS
1. An object and ......................
fp=k esa ,d lery ......................
 
Sol V m = V0m (normal to plane mirror) ¼lery niZ.k ds
vfHkyEcor~½
   
 V m  Vm = – ( V0  Vm )

V  V sin  = – (0 – V sin) OA x
i = sin–1 = sin–1
V = 2V sin OP R
2. A reflecting surface ...................... 5. A concave spherical ......................

,d ijkorZu lrg ...................... 10 cm oØrk f=kT;k ......................
dy Sol. (Moderate) Let there be two point objects O1 and O2, Incident
 2x 
Sol. = 2cos   = –1 rays from O1 and O2 at point P shall both bend towards normal
dx  L 
and hence the corresponding refracted rays shall intersect the
x 1
cos =– principal axis in the left medium. Therefore image formed under
L 2 given condition shall always be virtual.
L 2L ekuk fd O1 rFkk O2 nks fcUnq fcEc gSaA fcUnq P ij O1 rFkk O2 ls
x= ,
3 3 vkifrr fdj.ksa] nksuksa vfHkyEc dh vksj >qd tkrh gS blfy;s laxr
3. Two point objects ...................... viofrZr fdj.ksa cka;s ek/;e esa eq[; v{k ij izfrPNsn djrh gSA
nks fcUnqor~ oLrqvksa ...................... blfy;s nh xbZ fLFkfr esa cuk izfrfcEc ges'kk vkHkklh gksxkA
Sol. for object O1 O1 oLrq ds fy, normal
1 1 1 n=4/3
P n=3/2
  .... (1)
v 20 f
for object O2 O2 oLrq ds fy,
O1 C O2
X Y
7. A horizontal ......................
,d {kSfrt fdj.k ......................
Sol.  = (µ – 1) A = 2°
1 1 1 So by rotating mirro by 1° in clockwise direction, emergent ray
  .... (2)
v 40 f after reflection will become horizontal.
from equation 1 and 2 we get vr% niZ.k dks 1° nf{k.kkorZ ?kqekus ij] fuxZr fdj.k ijkorZu ds i'pkr~
lehdj.k 1 o 2 ls {kSfrt gks tk;sxhA
f = 80/3
8. Figure shows ......................
4. Inside a solid ...................... fp=k esa fn[kk;s ......................
R f=kT;k ds ,d ......................
1 1 1
Sol. Let O be the centre and A be the point source for ray Sol.  
incident v u 
at any point P to angle have maximum angle of incidence i,
1 1 1 2 1 1
ekuk O dsUnz gS rFkk A fcUnq L=kksr gSA fdlh fcUnq P    = =  v = 20 cm.
ij fdj.k ds vkiru ds fy, vf/kdre vkiru dks.k i, v 20 10 20 20
mirror = 5 cm.  Rmirror = 10 cm.
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
SOLJP/JFMONT1230117-1
 FL = 20 cm
1 1 2 1
= – =–
f 10 20 5
1 1 1 1 1 1
+ =  = –
v 30 5 v 30 5
 x = 20 – 10 = 10 cm. Ans.
1 1 1
for lens – = ySal ds fy,
9. A convex lens ...................... v 30 20
,d mÙky ySUl ......................
Sol. Focal length is minimum in case I, therefore power is 21. The dispersive ......................
maximum. inkFkZ dh fo{ksi.k ......................
izFke fLFkfr esa Qksdl nwjh U;wure gS blfy,] 'kfDr vf/kdre gSA
1  1 1  df  1 1 
Sol. = (n  1)      2 =    dn
14. Two light waves ...................... f  R1 R2  f  R1 R2 
nks izdk'k rjaxs ...................... differentiating both sidesnksuks rjQ vodyu djus ij
I1 22 df  1 1   1 1 
Sol. I A2   = =4/9
I2 32   (n  1)    =   dn
f  R1 R2   R1 R2 
16. A point object is ......................
20 cm oØrk ...................... dn
 df = f
Sol. Using newton’s formula n 1
U;wVu lw=k ls
nV  nR
xy = f2 but fdUrq dn = nv  nR   d f = f 
 20 y = (10)2  y = 5 cm.
n1
 df =  wf  fv  fR =  wf
17. A small wooden ...................... =  0.04  10 = 0.4 cm Ans.: fR  fv = 4 mm
5mm yEckbZ dh NksVh ......................
Sol. 22. A thin prism of ......................
,d dk¡p dk ......................
3  A
Sol. a =  2  1 × A = 2
 
 3/2  A
W =  4 / 3  1 A = 8
 
air 4
=
18. A ray is incident ......................  water 1
,d çdk'k dh ......................
sini 23. A fiber of length ......................
Sol.  2  i = 45º ,d izdkf'kd ......................
sinr
10km 10km
Sol. t = 8
–
2  10 2.1 108
3
10  10  2.1  2  1 1
=  4.2  = 10 4  (42)
108  
f = 42 × 104 = 420 Khz = 60 × Khz  X=7
24. Figure shows ......................

fp=kkuqlkj S1 o S2 ......................

Total deviation Sol. Angular width = = 10–3 (given)
dqy fopyu d
= (45º – 30º) + 180º –2(30º) + (45º – 30º)
 No. of fringes within 0.12° will be
= 30º + 120º
= 150º = 30x 0.12° ds vanj fQzatksa dh la[;k gksxhA:
x = 5. 0.12  2
n=  [2.09]
19. Distance between ...................... 360  10 3
fn;s x;s ySUl ls ......................  The number of bright spots will be three.
pedhys /kCckas dh la[;k rhu gksxhA
1 3  1 1 
Sol. =   1    Hence vr% (B).
fL  2   20 20 
 28. Radiowaves of ......................
gy dks.kh; pkSM+kbZ = = 10–3 (fn;k gS) 3 m rjax nS/;Z dh ......................
d Sol.
 0.12° esa fÝUtksa dh la[;k :
0.12  2
n=  [2.09]
360  10 3
 rhu pedhyh fÝUts cusxhA vr% (B). a 
25. In Young's Double ......................

;ax f}&fLyV ...................... D
Sol. ( – 1)t = n
n – number of fringes shifted foLFkkfir fÝUtks dh la[;k
 3
(1.5 – 1)8 = n sin   
n=4 a 5
Total number of fringes shifted dqy foLFkkfir fÝUtks dh la[;k  = 37°
= 8. w
tan =
26. In a Young's ...................... 2D
;ax ds f}&fLyV ...................... 3 w

Sol. The mth bright fringe of the  pattern and the nth bright 4 400
fringe of the ' pattern are located at w = 300 m
 çk:i dh mth nhIr fÝUt o ' çk:i dh nth nhIr fÝUt dh
29. In the figure shown ......................
fLFkfr
fn;s x;s fp=k ......................
mD n'D ' Sol. As after third reflection finally emergent ray is parallel to mirror
ym = and vkSj ym' = gksxh
d d M2. Hence possible no. of reflections = 3.
m 6 tSlk fd rhljs ijkorZu ds i'pkr~ fuxZr fdj.k niZ.k M2 ds lekUrj

Equating them bUgsa rqY; djus ij = gks tkrh gS] vr% lEHko ijkorZuksa dh la[;k = 3 gSA
n 5
Hence the first position at which overlaping occurs is M2
vr% çFke fLFkfr tgk¡ vfrO;kiu gksxk
6  2  750  10 9 Normal
y6 = y5' = m = 9 mm.
1 10 3 10º
Normal
27. A thin oil film ...................... 10º Normal
1.2 viorZukad dh ......................
30º
Sol. For normal incidence path difference between ray 1 and ray 50º 50º
30º
2 is 2 1 t 40º 40º
M1

For minimum thickness increment 2 t =
2
PART-II CHEMISTRY
31. A 0.2 molal aqueous solution………
,d nqcZy vEy (HX) dk 0.2 eksyy………
Sol. Tf = 0.2 × 1.2 × 1.86 = 0.45
therefore freezing point = – 0.45ºC
vr% fgekad = – 0.45ºC
 9.6  10 –7
 (t2 – t1) = = = 2 × 10–7 m 32. For a linear plot of logP v/s ………
41 4  1.2
nkc (P) ds vUrxZr ,d fn, x;s………
gy% yEcor~ vkiru ds fy, 1 o 2 ds e/; iFkkUrj 2 1 t
Sol. P = KHx
logP = logKH + logx
y = C + mx
 intercept = logKH. Slope = 1
 vUr%[k.M = logKH. <+ky = 1
 33. Consider the following aqueous………
lcls U;wure eksVkbZ esa ifjorZu ds fy, 2 t =
2 fuEu tyh; foy;uks dk voyksdu ………
 9.6  10 –7
 (t2 – t1) = = = 2 × 10–7 m Sol. Tb  No. of moles of solute particles in aqueous solution.
41 4  1.2
Tb  tyh; foy;u es foys; d.kks ds eksyks dh la[;kA
34. Calculate the cryoscopic constant……… 39. Co3+ ion forms octahedral ………
lkbDyksgsDlsu es fgekadferh; fu;rkad……… Co3+ vk;u F– rFkk NH3 ………
Sol. [CoF6]3–
Msolvent .R Tf2 Mfoyk; d .R Tf2
Sol. Kf = 3+
1000. HFusion 1000. Hxyu Co
2 3d
84  8.314   279.60 
= = 20.76
1000  2630
4s 4p 4d
35. The vapour pressure of the………
nks nzoksa A(pº = 80 mm) rFkk ……… 3 2
sp d
Sol. PTotal = 0.4 × 80 + 0.6 × 120 = 104 > 100 mm of Hg.
Pdqy= 0.4 × 80 + 0.6 × 120 = 104 > 100 mm Hg. [Co(NH3)6]3+
3+
36. The spin magnetic moment ………
Co
Hg[Co(SCN)4] esa dksckWYV dk ……… 3d 4s 4p
Sol. Hg[Co(SCN)4]   Hg2+ + [Co(SCN)4]2– 2 3
d sp
Oxidation state of cobalt x + 4 × (–1) = –2
x = 4 – 2 = +2
In +2 oxidation state cobalt have 3 unpaired electron (d7
electronic configurations). 4d
So s  3(3  2)  15 B.M. –
As F is a W.F.L. and NH3 is a S.F.L.
Hg[Co(SCN)4]  Hg2+ + [Co(SCN)4]2– 0 of [Co(NH3)6]3+ > 0 of [CoF6]3–
dksckYV ds fy;s vkWDlhdj.k voLFkk x + 4 × (–1) = –2 D;ksafd F– nqcZy {kS=k fyxs.M gS rFkk NH3 izcy {kS=k fyxs.M gSA
x = 4 – 2 = +2
[Co(NH3)6]3+ dk 0 > [CoF6]3– dk 0
+2 vkWDlhdj.k voLFkk esa dksckYV 3 v;qfXer bysDVªkWu j[krk gSA
(d7 bysDVªkWfud foU;kl).
41. Which of the following compound ………
vr% s  3(3  2)  15 B.M. fuEu esa ls dkSulk ;kSfxd lgh ………
Br C 2H 5
37. Find the correct formula ……… (1) (2)
Sol. C=C
ladqy vk;ju() gsDlklk;uksQsjsV………
H 3C Cl
Sol. Cation is Fe3+ and anion is [Fe(CN)6]4–, then charge balance (2) (1)
b/w cation and anion. E-isomer

3+ 4– E-leko;oh
/kuk;u Fe gS rFkk _.kk;u [Fe(CN)6] gS] rc /kuk;u rFkk
43. Which reaction is not an………
_.kk;u ds e/; lUrqfyr vkos'k
fuEu esa ls dkSulh vfHkfØ;k………
4 × Fe3+ = 3 × [Fe(CN)6]4– Sol. Reaction (D) is an example of SN2 Th reaction.
 Fe4[Fe(CN)6] 3
vfHkfØ;k (D) SN2 vfHkfØ;k dk mnkgj.k gSA
44. Select the incorrect ………

38. Which complex shown ……… xyr ;qXe dk p;u ………
dkSulk ladqy U;wure rhu ……… Sol. CH2 is a Nucleophile. CH2 ukfHkd Lusgh gSA
Sol. 1 Linkage, Ioniation, Geometrical, Optical 45. Incorrect order of the following ………
2  Optical fuEu esa ls dkSulk Øe dkckZsfuy ………
Sol. Polarity of carbonyl group is reduced in Ph-CHO due to
3  Linkage, Geomerical resonance. Hence the respective carbonyl carbon is less
4  No isomerism electrophilic than that of propanal and therefore less reactive.
Hence reactivity order (H3CCH2CHO > PhCHO).
gy- 1 ca/ku] vk;uu] T;kfefr;] izdkf'kd dkckZsfuy lewg dh ojh;rk vuqukn ds dkj.k Ph-CHO esa ?kV tkrh
2  izdkf'kd gSA vr% lEcfU/kr dkckZsfuy dkcZu izksisusy dh rqyuk esa de bysDVªkWu
Lusgh gksrk gS rFkk bl izdkj de fØ;k'khy gksrk gSA vr% fØ;k'khyrk
3  ca/ku] T;kfefr; dk Øe (H3CCH2CHO > PhCHO) gSA
4  leko;ork ugh n'kkZrk 46. An aqueous glucose ………
Xywdkst dk tyh; foy;u………
Sol. Tb = kb. m1 Tf= kf. m2
 Tb s  Tbo  k b .m1 Tfo   Tf s  k f .m2 nks vok"i'khy rFkk oS|qr vuvi?kV~;………
Sol. Tƒ = kƒ × m
374.19 – 373.15 = 0.52 × m1  (A)
273.15 – 272.22= 1.86 × m2  (B) 5  1000
(Tƒ)A = kƒ ×
MA  95
1 1.04 0.52  m1
 
 2  0.93 1.86  m2 5  1000
(Tƒ)B = kƒ ×
MB  95
m1 1.04  1.86 1.9344
 = =4
m2 0.93  0.52 0.4836 ( Tƒ )A  MB  3
=  M  = 1 = 3.
( Tƒ )B A
47. Consider the following pairs ………
feJ.kh; nzoksa A rFkk B ds fuEu ……… 51. A six co-ordinate complex………
Sol. Positive deviation, = i, vi, x = 2 ,d milgla;ksth ladqy dh………
Negative deviation = ii, iii, iv, z = 3

Ideal solution = v, ÉÉÉ
Sol. [Co(NH3 )5 Cl] Cl2.H2O(aq) [Co(NH3 )5 Cl]2 (aq) +
y = 6.
So, x + y – z = 2 + 6–3 = 5 Ans. 2Cl– (aq)
/kukRed fopyu = i, vi, x = 2 2Ag+ + 2Cl–  2AgCl  (white) ('osr).
_.kkRed fopyu = ii, iii, iv, z = 3
52. For [Ma2b2c2], no. of isomer………
vkn'kZ foy;u = v,
[Ma2b2c2] ds fy,] 'kwU; ds cjkcj………
y = 6.
vr% x + y – z = 2 + 6–3 = 5 Ans. Sol. Total 5 isomer are possible out of which one has  = 0.
dqy 5 leko;oh lEHko gS bues ls ,d  = 0 j[krk gSA
48. How many type of isomerism………
ladqy [Co(NH3)4(NO2)2]Cl }kjk……… a a a
Sol. (i) Ionisation isomers
c b c a c a
[Co(NH3)4(NO2)2]C and [Co(NH3)4(NO2)(C)]NO2
(ii) Linkage isomers
[Co(NH3)4(NO2)2]C and [Co(NH3)4(ONO)2 ]C Co Co Co
(iii) Geometrical isomers ; cis & trans
(i) vk;uu leko;oh b c b c b
c
[Co(NH3)4(NO2)2]C rFkk [Co(NH3)4(NO2)(C)]NO2
a b b
(ii) fyadst ¼ca/ku½ leko;oh
=0 0 0
[Co(NH3)4(NO2)2]C rFkk [Co(NH3)4(ONO)2 ]C a b
(iii) T;kferh; leko;oh ; lei{k rFkk foi{k
c c a a
49. When 36.0 g of a non-volatile………

Co Co
tc ewykuqikrh lw=k CH2O j[kus………
b b b c
36 1000
Sol. 0.93 = 1.86 ×  a b
M.wt 1200 0 0
Molecular weight = 60 53. Find the number of correct………
Empirical weight = 30 lgh dFkuks dh la[;k crkb, ………
 Molecular formula = C2H4O2
Sol. i & ii are correct.
36 1000 i rFkk ii lgh
gy- 0.93 = 1.86 ×  gSA
M.wt 1200
54. CFSE for the complex………
v.kqHkkj = 60 ladqy [r(NH3)6]3+ ds fy, ………
eqykuqikrh lw=k = 30 Sol. x = 6
 v.kqlw=k = C2H4O2 y=0
x+y=6
55. In [Fe(edta)]–, number of ………

50. Two solutions of non-volatile………
[Fe(edta)]– esa 5 lnL; okyh……… 3
CHO
Sol. x = 5
–
– CH2COO O
OOCH2C
 1 lokZf/kd fØ;k'khy gSA
H3C–C CCH
N – CH2 – CH2 – N 2 1
– Reactivity order of RMgX towards different function groups is:-
-–
OOCH2C CH2COO
O O
acidic H > R–C–H > R–C–R

Fe
3+ fHké fØ;kRed lewg ds izfr RMgX dh fØ;k'khyrk dk Øe:- acidic
56. How many reactions show………
O O
fuEu esa ls fdruh dkcZfud ……… H > R–C–H > R–C–R
Sol. i, iv, v  Possible
ii, iii  Not possible 60. Number of geometrical isomers………
i, iv, v  lHkao Me
ii, iii  laHko ugha ds laHko T;kferh; ………
O Et
HCl Sol. Two geometrical isomers. They are Trans and cis isomers.
(ii)   No SN2Th because Cl– is
NH2 nks T;kferh; leko;oh gSA ;s lei{k o foi{k leko;oh gSA
–
a poor nucleophile than NH2 .
PART-III MATHEMATICS
O
HCl
(ii)   No SN2Th vfHkfØ;k ugha 61. Let f(x) be a function...............
NH2 ekuk f(x) ,d Qyu gS ...............
D;ksafd Cl– NH2– dh rqyuk esa nqcZy ukfHkd Lusgh gSA Sol. Domain of f(g(x))
f(g(x)) ds iz k Ur ds fy,
O Range of g(x)  Domain of f(x)
18 g(x) ifjlj  f(x) iz k Ur
18 Hydrolysis
(iii) Ph—C—O—Ph  Ph – COOH  Ph  OH

– 5  |2x + 5|  7
0  |2x + 5|  7
O 18
–7  2x + 5  7
(iii) 18
ty vi?kVu
  Ph – COOH  Ph  OH – 12  2x  2
Ph—C—O—Ph
– 6  x  1
62. Let f(x) = xx ; x (1, ) and ...............

57. Total number of position isomers ………
ekuk f(x) = xx ; x (1, ) ...............
VªkbZDyksjkslkbDyksgSDlsu ds dqy fdrus………
Sol. we have;gk¡ f(g(x)) = g(x) g(x) = x
Cl Cl
Sol. also rFkk g (f (x) ) = x
Cl Cl Cl 1
 g (f (x)) . f(x) = 1 g (f (x)) =
Cl Cl Cl Cl f  (x)
58. Pure enantiomer of lactic acid……… 1
 g (f (x)) =
x
ysfDVd vEy dk 'kq) izfrfcEc……… x .(1  n x)
Sol. Enantiomer excess = 0.8  100 = 50% = 5 × 101 1
1.6  g  (f(g(x))) =
g(x)
izfrfcEc :ih vkf/kD; = 0.8  100 = 50% = 5 × 101  g(x) .(1  n(g(x)))
1.6
1
 g (x) =
59. On which position grignard ……… x (1  n g(x))
3
CHO
63. Suppose that f(x) is an ...............
ekukfd f(x) ,d le vkorhZ...............
O
;kSfxd esa dkSulh ……… Sol. f (3.14) = f(3.14 – 4) = f(–0.86) = f(0.86) = 0.86
H3C–C CCH
2 1 64. Find the value of ...............
3  2 3   2 3 
CHO
Sol. sin–1   = tan–1   = tan–1(2 – 3)
 2   2 3 
O    
Sol.  1 is Most reactive 
H3C–C CCH =
2 1 12
2
 12   3  3 3   1 
cos–1 
 4 
= cos–1 
 2 
=
6
=
32
+
2  sin x  4 
     
2 2
     3 
 sec–1( 2 ) = pwafd  sin1 x     –
and since vkSj 
4  4   4 
 2 3   12   The greatest value is dk vf/kdre eku
 sin–1   + cos–1   + sec–1( 2 )
 2   4  3 9 2 3 7 3
   +  =
32 16 2 8
   
= + + = 68. The number of ordered ...............
12 6 4 2
lehdj.k (sin–1x)2 + (sin–1y)2 ...............
  Sol. x, y, z {–1, 1}
 cot = 0 and vkS j cos–1(0) =
2 2 x, y, z
–1 –1 –1
65. The number of real ............... –1 1 1
 1 –1 1
cos–1x + cos–12x = ds ............... 1 1 –1
4 1 1 1
1 1 1 –1 –1
Sol. –  x  –1 1 –1
2 2 –1 –1 1
 2 
cos–1x + cos–12x   3  0, 3    69. If y = tan–1 x + tan–1 
 1
   ...............
x
  5 
cos–1x + cos–12x  3 , 3   1
;fn y = tan–1 x + tan–1   ...............
 
no solution dksbZ gy ugha x
1  
 3 1   cos ec x , x0
  –1
Sol. y = tan x + tan + cosec–1x =  2
–1
66. If sin–1  tan  – sin–1  ............... x 
 4  y   1    cos ec x , x  0
   2
   3 
;fn sin–1  tan  – sin–1  ............... if ;fn x > 0, then rc <y
 4  y  2
 
 3 
 if ;fn x < 0, then rc –  y < –
Sol. sin–1(1) – sin–1   – =0 2
 y 6
   
 3  3 3
 y   ,  2    2 ,  
 sin –1
= =    
 y  3

  2 y
 
y=4 x=±2 70. Find lim sin  [sin x]  ...............
x (2n 1)   6 
67. The greatest value of ...............
 
(sin–1 x)3 + (cos–1 x)3 dk ............... lim sin  [sin x]  dk eku...............
Sol. We have fn;k gSA (sin–1 x)3 + (cos–1 x)3 x (2n 1)  
 6
= (sin–1 x + cos–1 x)3 – 3sin–1 xcos–1 x(sin–1 x + cos–1 x) Sol. lim [sinx] = – 1
x (2n 1) 
3 
= – 3(sin–1x cos–1x)   1
8 2  lim sin ([sinx] ) = – sin =–
x (2n 1)   6 6 2
3 3 –1  1 
= – sin x  2 – sin x 
8 2 71. If f (c) exists and is ...............
 
;fn f (c) fo|eku gS vkSj ...............
3 32 –1 3 f(c  h)  f(c – h) – 2f(c)
= – sin x + (sin–1 x)2 Sol. lim
8 4 2 x 0 h
3 3   
= + (sin1 x)2  sin1 x  f(c  h) – f(c) f(c – h) – f(c)
8 2  2  = lim 
2
h 0 h h
3
 3    1    3 3 f(c – h) – f(c)
= +  sin x    – = f (c) – lim = f (c) – f (c) = 0
8 2  4  32 h 0 –h
 
 x  
1– sin x x

72. lim (1– x) tan   is ...............  , 2 ...............
75. If f(x) =  1  cos 2x
x1  2  
 , 
 x
 x   2
lim (1– x) tan   cjkcj ...............
x1  2   
 1– sin x ,
x
2 ...............
 x  ;fn f(x) =  1  cos 2x
Sol. lim (1– x) tan   (0 .  form:i) , 
 2 
x1   x
 2
1– x 0 –1 1– sin x
= lim   = lim Sol.  = lim = lim
– cos x
x1   x   0  x1  x   1  cos 2x
cot   – cos ec 2  
x  / 2 x  / 2 –2 sin 2x
 2   2 2 – sin x = 1
 = lim
2  x  2 x  / 2 4cos2x 4
= lim sin2  =
 x1  2  
76. If f(x) = lim ...............
n 
2
73. If f(x) = 1– e – x , then ...............
;fn f(x) = lim ...............
n 
–x 2 A
;fn f(x) = 1– e , rks ............... A 2 tan
2 – tan A
Sol. we have ge tkurs gS tanA – tan =
Sol. Lf cka ; h vks j ls (0) 2 2 A 2
1– tan
2 2
f(0 – h) – f(0) 1– e –h
= lim = lim A A
h 0 –h h 0 –h tan  tan3
1/ 2 = 2 2
  h4  2 A
2 1– tan
1–  1– h  – .......   2
  2! 
  n
= lim  x x  f(x)
h 0 –h f(x) = lim   tan 2 r
– tan r 1 
= tanx  lim =1
n 
r 0 2  x  0 x
1/ 2
 h4  1
h. 1–  ..... 3n
2!  Cn  n A
  77. If lim   = , where...............
= lim =–1 n 2n
Cn  B
h 0 –h 
2 1
f(0  h) – f(0) 1– e –h  3n
Cn  n A
Rf (0) = lim = lim =1 ;fn lim 
h 0 h h 0 h 2n  = tgk¡ ...............
n
 Cn  B
Hence, f(x) is not differentiable at x = 0. Since Lf (0) = Rf 1/ n
A  (2n  1)(2n  2)(2n  3).......(2n  n) 
(0) = 0 (finite), therefore, f(x) is continuous at x = 0. Sol. = lim  
Hence, f(x) is continuous but not differentiable at x = 0. B n 
 (n  1)(n  2)(n  3).........(n  n) 
blfy, f(x), x = 0 ij vodyuh; ugha gS A pw a f d cka ; h r 

lhek ls f (0) = nka ; h vks j ls f (0) = 0 (ifjfer ) A 1 n  2 n 
ln ( ) = lim  ln 
blfy, f(x), x = 0 ij lrr~ gS ij vodyuh; ugha gS A B n  n

1 r / n 
r 1
 
 
1
74. If [.] and {.} denote greatest...............  (2  x)  27
;fn [.] rFkk {.} Øe'k% egÙke............... 0 ln  (1  x)  dx = n
16
 ex  2  1
Sol. lim f(x) = lim x   = –  –1 A = 27 & B = 16
x 0 
x 0  2x 
  2
 1 1 1 
 f(x) is not continuous at x = 0 78. lim    .......   ...............
 f(x) is not differentiable at x = 0 n 1 n  2
n  6n 
 ex  2  1  1 1 1 
Hindi. lim f(x) = lim x   = –  –1 Sol. lim    .......  
2 n  n 1 n 2 6n
 2x 
      
x 0 x 0
5n 5n 5
 x = 0 ij f(x) lrr~ ugha gSA 1 1 1 1
= lim  = lim  . =  dx
 x = 0 ij f(x) vodyuh; ugha gSA n 
r 1 n  r
n 
r 1 n  r  0 1 x
1
 n
 
5
=  n (1  x)0 = n 6 – n 1 = n 6
79. For positive integers ...............
(cot x)(e x – 1) – cos2 x
/kukRed iw.kk±dksa k = 1, 2, 3............... 81. If lim  K ...............
x 0 sin x
Y Bk (cot x)(e x – 1) – cos2 x
;fn lim  K ...............
Sol. x 0 sin x
k
A cot x( e x  1)  cos2 x
Sol. lim
x0 sin x
O
X e x  1  cos x sin x
= lim
k x 0 sin2 x
OBk = k, AOBk =
2n 1
e x  1  sin 2x
Sk =
1
k sin
k
(using  =
1
ab sinls) = lim
2
2 2n 2 x0 x2
lim
1 n
k 
k  x2 1  ( 2x )3  
L=
n  n2
S k =
2n2
 sin 2n x    2x  
k 1 k 1
 2 2 3!  
 1 = lim = 1/2 = K
1 k k 1 x x 0 x2
=
2n  n
sin =
2n 2  x.sin 2
dx
11   29 
k 1 0 
 K      = 2
1  –2 x
1
2 x 
1
 7   14 
=  x cos  cos dx  
2   2 0  2 
 0  82. Domain of f(x) = cos–1x...............
1 f(x) = cos–1x+ cot–1x+ cosec–1x ds izkUr ...............
1  2 2 x   2 Sol. cos–1x so –1 x  1
= 0  .  sin   = 2 ……(i)
2    2 0   cosec–1x so x  –1 and x1 ……(ii)
cot–1x so x R ……(iii)
from (i) (ii) and (iii)
80. Number of solutions...............
(i) (ii) vkSj (iii) ls
  x –1, 1so number of elements = 2
 2 
lehdj.k sec  –1 x –1, 1blfy, vo;oksa dh la[;k = 2
 ...............
 1  x  83. If f(x) = x3 +x5 and g(x) ...............
x  ;fn f(x) = x3 +x5 rFkk ...............
  Sol. Given that fn;k x;k gS
–1
 2   2x  g(f(x)) = x f(x) = x3 + x5
Sol. sec   = sec–1  2  (g' f(x)). f'(x) = 1 f('x) = 3x2 + 5x4
1
  x   1 x  when tc f(x) = 2 then rc x = 1 f '(1) = 8
x  g' (2). f'(1) = 1
  1 1
 2  g' (2) =  g' (2) =
domain of sec  –1
 is x = 1, –1 f '(1) 8
 1  x  a+b=1+8=9
x  84. If range of f(x) = ...............
  ;fn f(x) = n({x} 2  6{x}  11) ...............
 2 
sec–1   dk izkUr x = 1, –1 gSA Sol. ({x} 2  6{x}  11  ({x}  3)2  2
 1  x   x
x  ({x} + 3)2  [9, 16)
x = 1 does not satisfy larq"V ugha djrk gSA
(({x}  3)2  2)  [11,18)
If ;fn x = – 1, then rc
so f(x) [n11, n18)
 
b+a=7  
 2 
sec–1   +  cos x = sec–1(–1) +  cos (–) =  –  85. If the complete set of the...............
1
  x 
2
x  ;fn vlfedk cos(cos–1 x ) ...............
=0
2
there is one solution. ,d gy gSA Sol. cos(cos–1 x )  sin(sin–1(x+1)
 |x|  x+1 and vkSj –1 |x| 1 and vkSj –1 x +1 1
x[–1, 1] and vkSj x[–2, 0]
so blfy, x[–1, 0]
Now vc |x| x + 1 x–1, 
89. Maximum value of ...............
so |x| = –x
–x x +1 (sec–1x)2 + (cosec–1x)2 dk ...............
1 Sol. f(x) = (sec x) + (cosec–1x)2
–1 2
x  
2 f(x) = (sec–1x + cosec–1x)2 – 2(sec–1x)(cosec–1x)
2
 1  1   1 
x   ,0  P=– , q=0
 2  –2 sec x  2  sec x 
–1
f(x) =
 2  2    
24 –1 24 –1  1 
 sin (q–p) = sin   = 4 2
  2 f(x) = –  sec–1x + 2 (sec–1x)2
4

1  n1 1  1 2  1 2 
f(x) = 2 (sec x)  sec x 
86. If   cot
n1
2

  then...............
2n   2
  
8 
2

1   2

cot 1  2n1  n  rc...............  f(x) = 2  sec 1 x   
;fn  
n1  2   4 8
2

2n    2 5 2
1 
 f(x) = 2      
Sol.  tan  2n1  4 8 4
2  1  
n1 
4

 2n1  2n   =5
    tan1  2
 1  2n 2n1 
n1  
 90. If f(x) = sin (cos–1 (x+1)) – ...............
1 n1 ;fn f(x) = sin (cos–1 (x+1)) ...............
  tan (2 ) – tan–1(2n)
n1 Sol. f(x) = 0
 sin (cot–1(x+1)) = cos (tan–1x)
   tan1(2)  cot –1(2)
2  
1  1 
1 2
sin sin–1   = cos cos–1  
cot = 2 sin = 25 sin  = 5  1  (x  1)2   2 
5    1 x 
 1  1
87. If domain of f(x) = sin–1(cosx) ...............   =
;fn f(x) = sin–1(cosx) + cos–1............... 
 1  (1  x)2  1 x2
Sol. domain of sin–1(cosx) is R
x  1 + x2 = x2 + 2x + 2
domain of cos–1  10  is [–10, 20)
  1
so domain of f(x) is [–10, 20) x= =a
a = 10, b = 20 2
ab |2a| = 1
=3
10
Hindi sin–1(cosx) dk izkUr R gSA
x 
cos–1  10  dk izkUr [–10, 20) gSA
 
blfy, f(x) dk izkUr [–10, 20) gSA
a = 10, b = 20
ab
=3
10
88. The function f(x) = cot–1 ...............
Qyu f(x) = cot–1 (x  3)x  ...............
Sol. f(x) = – cot–1 (x  3)x  cos 1 x 2  3x  1

(x+3) x 0 and rFkk 0 x2 + 3x + 1  1
x(–0, –3] and rFkk x2 + 3x + 1  0 and rFkk x2 +
3x 0 x[–3, 0]
so blfy, x = {–3, 0} |a–b| = 3
MAIN PATTERN ONLINE TEST-1
(MONT-1) XII
TARGET : JEE (MAIN+ADVNACED) 2017
DATE : 23-01-2017 COURSE : VIJETA (JP), VISHWAAS (JF), ANOOP (EP), AKHIL (EF)
ANSWER KEY
CODE-0
PART-I PHYSICS
1. (A) 2. (B) 3. (A) 4. (B) 5. (C) 6. (B) 7. (A)
8. (B) 9. (A) 10. (B) 11. (C) 12. (C) 13. (D) 14. (B)
15. (D) 16. (5) 17. (4) 18. (5) 19. (6) 20. (2) 21. (4)
22. (4) 23. (7) 24. (3) 25. (8) 26. (9) 27. (2) 28. (3)
29. (3) 30. (3)
PART-II CHEMISTRY
31. (A) 32. (C) 33. (A) 34. (A) 35. (B) 36. (C) 37. (C)
38. (A) 39. (D) 40. (B) 41. (C) 42. (D) 43. (D) 44. (C)
45. (B) 46. (4) 47. (5) 48. (3) 49. (2) 50. (3) 51. (4)
52. (4) 53. (2) 54. (6) 55. (5) 56. (3) 57. (3) 58. (5)
59. (1) 60. (2)
PART- III MATHEMATICS
61. (C) 62. (B) 63. (D) 64. (D) 65. (A) 66. (A) 67. (C)
68. (D) 69. (A) 70. (C) 71. (B) 72. (B) 73. (B) 74. (D)
75. (C) 76. (1) 77. (5) 78. (1) 79. (0) 80. (1) 81. (2)
82. (2) 83. (9) 84. (7) 85. (4) 86. (5) 87. (3) 88. (3)
89. (5) 90. (1)

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P25-16

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Space for Rough Work / (dPps dk;Z ds fy, LFkku)

5. A concave spherical surface of radius of curvature 10 cm separates two mediums X and Y of

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

reflection becomes horizontal?

{kSfrt gks tk;sA

(A) 1° (B) 2° (C) 4° (D) 8°

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

distance between the mirror and the lens is :

(A) 5 cm (B) 10 cm (C) 30 cm (D) cannot be determined

(A) 5 cm (B) 10 cm (C) 30 cm (D) Kkr ugha dj ldrs gSA

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

(A) (B) (C) (D)

10. The magnifying power of a telescope can be increased

11. A red postage stamp is viewed in yellow (monochromatic) light. It appears

12. In a compound microscope

Space for Rough Work (dPps dk;Z ds fy, LFkku)

13. An electromagnetic wave travelling through a transparent medium is given by

Space for Rough Work (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

Space for Rough Work (dPps dk;Z ds fy, LFkku)

29. In the figure shown, the maximum number of reflections will be :

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

33. Consider the following aqueous solution.

DoFkukad es mUu;u dk c<+rk gqvk Øe gS & ¼ekuk  = 1½

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

36. The spin magnetic moment of cobalt in Hg[Co(SCN)4] is :

37. Find the correct formula of complex Iron() hexacyanoferrate(),

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

(C) 0 ¼fØLVy {kS=k foikVu½ (D) mijksDr lHkh

(A) H2O (B)

(C) H3C–CH2–CCH (D)

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

42. Correct Nucleophilicity order is

43. Which reaction is not an example of nucleophilic addition reaction ?

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

SECTION – II ([k.M – II)

vadh; iw.kk±d gSA)

point of H2O 373.15K and 273.15K respectively.

273.15 K gSA kb (H2O) = 0.52 K. kg mol–1 ; kf (H2O) = 1.86 K. kg mol–1

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

48. How many type of isomerism is exhibited by the complex [Co(NH3)4(NO2)2]Cl ?

ladqy [Co(NH3)4(NO2)2]Cl }kjk fdrus izdkj dh leko;ork n'kkZ;h tkrh gS ?

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

53. Find the number of correct statement

(ii) ladqy [Pt (NH3)(Br)(I)(Py)] rhu T;kfefr; leko;oh j[krk gSA

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

56. How many reactions show correct major product :

C–Cl CH COOH C–O–C–CH3

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½

Space for Rough Work ¼dPps dk;Z ds fy, LFkku½