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COMPUTATIONAL MODEL OF THE COMBUSTION OF SUGARCANE BAGASSE IN

A WARD-CIMPA COMBUSTION CHAMBER FROM A BROWN SUGAR CANE


FURNACE

JAVIER GUEVARA, OMAR LÓPEZ, GERARDO GORDILLO


Mechanical Engineering Department, Faculty of Engineering, los Andes University
Bogotá, Colombia, July 2014

ABSTRACT
This paper presents a bi-dimensional model for the simulation of a WARD-CIMPA combustion chamber in a brown sugar
cane furnace. The model was implemented in commercial software ANSYS FLUENT 14 as a species transport problem
with finite rate chemistry where bed particles were represented using DPM (Discrete Phase Model), considering each
particle as a combination of water, volatiles, carbon and ash which evolves from green bagasse to ash while moving by a
fixed path through the bed. The model was solved for eight (8) combinations of primary and secondary air flow with a fixed
fuel flow of 487 kg/h of sugarcane bagasse with a moisture content of 50%. According to results obtained it was estimated
the effect of primary / secondary air ratio and excess air in the combustion chamber performance from which it was
determined and optimum value of 1.3 for the equivalence ratio in the lower section of combustion chamber, while optimum
value for excess air could not be determined as it was necessary to model the whole furnace and the model was limited to
combustion chamber. Information available about real performance of the modeled furnace was limited to flue gas
temperature and CO mass percentage; the temperatures obtained were in agreement with existing information while
predicted CO content were 27 to 50% lower than expected.

INTRODUCTION PROBLEM FORMULATION AND RESEARCH


“Panela” is the name given to dehydrated sugar cane JUSTIFICATION
juice in Colombia; this product is worldwide known with In Colombia there are approximately 20,000 sugar cane
different names such as jaggery, piloncillo, raspadura, mills and about 80% aren’t self-sufficient (Garcia, 2003),
papelón, chancaca, among others. Colombia is the this means that sugar cane bagasse produced cannot
second world producer of panela with the largest per provide the required heat and they require and additional
capita consumption. Its raw material, sugarcane, has the fuel such as tires, coal and/or wood which cause
second largest cultivated area in this country; making its environmental issues of deforestation, harmful flue gas
waste material, sugarcane bagasse, an important source emissions and greenhouse effect.
of biomass fuel. Up to date, there have been experiments (Valderama,
Panela or brown sugar cane is produced in a sugarcane 1999) and mathematical models of sugar cane furnaces
mill, where the sugarcane is crushed to extract its juice, (Ortiz, 2011, Prada et al., 2012) that characterize the
and the remaining bagasse, known as green bagasse is global combustion process with no details about
burned in a furnace where the flue gases are used to distribution of chemical reactions, species and
provide heat for juice dehydration. temperatures in the combustion chamber; also there
Few researches has been carried on brown sugar cane have been CFD simulations with a domain covering only
furnaces, these researches have achieved higher flue gas duct and stack (Osorio et al., 2009), and CFD
thermal efficiencies, mainly by the optimization of the models of combustion chambers with similar geometry
combustion chamber; the latest and most efficient but burning different kind of fuels and not considering the
design is known as WARD-CIMPA (Figure 1) which drying process of the fuel on the drying sub-chamber,
incorporates independent inlets for primary air, nor the independent entries of primary and secondary air
secondary air and bagasse, together with a drying sub- (Borello et al., 2012).
chamber that allows burning high moisture bagasse. A CFD model of the combustion chamber in sugar cane
furnaces will be an important tool to improve furnace
design and operation procedures in order to maximize
furnace efficiency and minimize environmental
emissions.

RESEARCH OBJECTIVES

GENERAL OBJECTIVE
Implement a CFD model of the combustion of sugar
cane bagasse in a WARD-CIMPA combustion chamber
from a brown sugar cane furnace.
Figure 1. Furnace with WARD-CIMPA combustion chamber
SPECIFIC OBJECTIVES
1) Implement a computational model using the According to Di Blasi, 2004, char gasification and
commercial CFD software ANSYS FLUENT, considering combustion zones overlaps and both take place in a
independent inlets for primary air, secondary air and narrow layer in the bed bottom, while the heating and
green sugar cane bagasse. drying of bagasse is a process carried almost instantly in
2) Model combustion process of sugar cane, a narrow layer on top of bed. The pyrolysis zone will be
represented as a combination of moisture, volatile matter, also located next to the top of the bed and the remaining
carbon and ash. bed section will comprise a char inert heating zone
3) Model the effects of excess air and primary/secondary (Figure 2).
air ratio in combustion process. The mesh size was selected by a convergence analysis
4) Define relevant chemical reactions, and estimate using cold air to solve flow distribution in the chamber
species and temperature distribution along combustion until velocity magnitude at flue gas outlet didn’t change
chamber. with a higher cell number. It was finally selected a block
5) Comparison of results with information of existing structured mesh with 186,461 quadrilateral cells.
furnaces. The model domain boundaries were defined as
6) Propose optimization opportunities to improve combustion chamber walls, inlets of primary air,
combustion chamber performance, and recommend secondary air and fuel, and the beginning of pan No. 1.
topics for new related researches. Gas mix properties such as mass diffusion ( ,
viscosity ( and thermal conductivity ( are
PROPOSED MODEL derived from Purmono et al., 1990 and were introduced
The model consists of a combustion chamber from a to the model by a UDF:
furnace where 487 kg/h of green sugar cane with a
moisture content of 50% are burned and the hot flue ( ) [ ] (1)
gases are used to dehydrate sugar cane juice and
produce 160 kg/h of brown sugar cane. The combustion ( ) [ ] (2)
chamber is a WARD-CIMPA type which is composed of [ ] (3)
two sections connected, lower section receives primary
air from below and green sugar cane from a side door, SIMPLIFICATIONS ADOPTED
and acts as an up-draft (counter-flow) fixed bed gasifier, 1) Bi-Dimensional model.
while the upper section receives hot gases from 2) Stationary state.
gasification process which complete their combustion by 3) Adiabatic and no slip walls.
the addition of secondary air. 4) Pressure loss through bed is estimated considering
In the lower section, primary air enters at atmospheric bed as a porous media with constant porosity.
pressure and room temperature by a grill located in the 5) Bed material is modelled as spheres with constant
bottom over which is resting the bed. Green bagasse is diameter.
fed at room temperature by lots through a side door at 6) Non reacting ash.
regular time intervals. The bed surface is an open zone 7) Laminar flow through the bed.
where the produced gases converge and then pass to
upper section of chamber. Assumption 4 is widely used in gasification process
The char content of the bagasse is partially combusted models (Hobbs et al., 1992; Di Blasi, 2004), and
in the bottom of the lower section of the chamber; this assumption 5 is recommended by Hobbs (1992) when
combustion provides heat for other processes taking no further information is available.
place in the bed such as heating, drying, pyrolysis and Combustion chamber model is implemented in
gasification of remaining char. commercial software ANSYS FLUENT 14 as a species
transport problem with finite rate chemistry, and solid
particles are represented using DPM (Discrete Phase
Model). Mass and energy exchange with gas phase are
calculated by DPM model, while momentum interaction
is calculated as momentum source terms using the
porous media approach.

CHARACTERIZATION OF GREEN SUGARCANE


BAGASSE
Green Sugarcane Bagasse characterization was taken
from Rodríguez et al, 2012, see Table 1.
The empirical formula of green sugarcane bagasse was
obtained using ultimate analysis together with atomic
weights of each element, then chemical equation was
balanced to determine the stoichiometric air required

Empirical Formula: C H2.0526 O0.6658 N0.0076 S0.0009


Figure 2. Modeled combustion Chamber Molecular Weight: Mbagasse = 24.87 g/mol(Bagasse)
volume-area average ( gives better results
CH2.0526O0.6658 + 1.18(O2+3.76N2) + 1.37 H2O when representing momentum interaction between solid
(4)
 CO2 + 2.40 H2O + 4.44 N2 and gas phases, while area-volume average ( )
gives better results when representing mass transfer
Table 1. Characterization of sugarcane bagasse between phases such as reaction rates.
As Received Dry Basis DAF
Moisture Content MC 50.00% 0 0 ∑
Volatile Matter VM 41.25% 82.50% 83.67% (5)

Fixed Carbon FC 8.05% 16.10% 16.33%
Ash Hash 0.70% 1.40% 0
H2O 50.00% 0 0 (6)
Ash 0.70% 1.40% 0 ∑
%C 23.81% 47.62% 48.30%
%H 4.10% 8.20% 8.32%
%O 21.12% 42.24% 42.84% The volume-area average diameter is then used to
%N 0.21% 0.42% 0.43% calculate viscous resistance (1/α) and inertial resistance
%S 0.05% 0.11% 0.11% (C2) from the correlations derived by Ergun, 1952.
HHV (kJ/kg) 8700 17975
(
(7),(8)
COMPOSITION OF VOLATILE MATTER (
In order to estimate composition of volatile matter
released during pyrolysis, it was used the software CEA The area-volume average diameter is used for particle
(Chemical Equilibrium and Species) developed by NASA injections and the User Defined Function (UDF)
which allows the determination of equilibrium implemented for heterogeneous reaction rate calculation.
3
composition and molar fraction of more than 150 Apparent density of bagasse fed is 127 kg/m and
possible species for a given fuel composition, porosity is 0.6 (Leiva et al., 2012), so particle density at
temperature and pressure. bed surface is 317.5 kg/m3 and will decrease while
According to the thermo-gravimetric analysis (TGA) of approaching the bottom of the bed.
sugar cane bagasse developed by Rodríguez et al, 2012,
the pyrolysis takes place between 500 and 700K, so the EVOLUTION OF BAGASSE PARTICLES
latter temperature and atmospheric pressure were used A bagasse particle evolves from green bagasse to ash
in the model to determine volatile composition (Table 2). while traveling through the combustion chamber;
particle’s evolution stages are shown in Figure 3.
Table 2. Volatiles composition at 700K
Species Molar Fraction
CH4 0.1496
CO 0.0035
CO2 0.0830
H2 0.1014
H2O 0.2574
C 0.4051

POROUS MEDIA DEFINITION


Sugarcane bagasse size distribution expressed as
diameter of equivalent spheres (Rainey et al., 2012) was
used to estimate an average equivalent diameter for
bagasse particles. See Table 3.

Table 3. Sugarcane bagasse size distribution Figure 3. Particle evolution stages.

Size range ( ) Mass fraction (Y) Initial Inert Heating


< 10µm 0.65 Takes place when green sugarcane bagasse is fed to
10 – 50 µm 2.03 combustion chamber at ambient temperature and then
50 – 100 µm 2.64 heated to moisture evaporation. During this process
100 – 500 µm 25.81 there is no mass exchange, and energy exchange is
500 – 1000 µm 32.34 given by:
1000 – 5000 µm 34.78
5000 – 10000 µm 1.65
> 10000 µm 0.1 ( ) ( ) (9)

According to Souza-Santos, 2004, when determining an


average particle diameter from a size distribution chart,
Inert heating/cooling processes also take place from the ( ) (14)
end of drying to the start of pyrolysis, from the end of
pyrolysis to start of char combustion, and from the end of
combustion until ash particle leaves the model domain. Heat and mass transferred between phases during
pyrolysis is determined according to:
Drying
Bagasse moisture content is modeled as a volume ( )
fraction of liquid water added to the particle surface. The
drying process consists of the evaporation of bagasse ( ) (15)
moisture content when particle temperature reach
moisture evaporating temperature, and bagasse Where ΔHpyrolysis is the latent heat of devolatilized
moisture boiling when particle temperature reach species (pyrolysis enthalpy of reaction), according to Di
moisture boiling temperature, and continues while Blasi, 2004, this enthalpy is near zero and can be
particle mass is greater than initial mass of dry particle. neglected.

Mass transferred between phases is equal to the weight Pyrolysis is then modeled as a single global reaction:
of water evaporated/boiled by the heat received by the
particle; energy transferred is equal to evaporating latent Dry Bagasse  Volatiles + Char (16)
heat of such amount of water during evaporation and
boiling, and the sensible heat due to temperature CH2.0526O0.6658  0.2334 CH4 + 0.0054 CO +
change during evaporation. 0.1295 CO2 + 0.1581 H2 + 0.4014 H2O +
0.6317 C (17)
Mass and energy exchange during moisture evaporation:
Particle Combustion
Particle combustion process starts when particle
( ) (10) releases all its moisture and volatile content, and
continues while particle mass is greater than their initial
content of ash.
( ) ( )
There are many models available to describe particle
(11)
surface reaction kinetics, in this case it was selected an
exposed unreacted core model in which reaction rate
Mass and energy exchange during moisture boiling:
considers gas film diffusion resistance together with
chemical reaction kinetics, with no consideration of
( ) ( ) (12) resistance through ash layer. This model was selected
because of the low ash content of bagasse, Di Blasi,
2004.
FLUENT doesn’t consider condensation of vapor when
its partial pressure reach water saturation pressure (
which take place when water vapor rises through the ( ) (18)
bed and find cold particles of green bagasse on its way.
Because of this, it was introduced an UDF that define a
new DPM law which re-condenses excess water vapor Chemical reaction rate (k j) is described by an Arrhenius
on particle surface when relative humidity exceeds 100%, equation:
and transfers condensation latent heat and mass from
( ) (19)
vapor to particle.

Devolatilization (Pyrolysis): Mass and energy interaction between phases is defined


During this process, dry bagasse particle is decomposed according to:
into a mix of gases and char (carbon and ash) by the
action of temperature. The gases mix composition was
estimated using CEA. This process takes place when ( )
particle temperature reaches pyrolysis start temperature ( ) (20)
and particle mass is greater than its initial mass of char.
Pyrolysis start temperature was estimated around 500K
Where fh is the fraction of energy from chemical reaction
in Thermo-gravimetric Analysis performed by Rodriguez
that is absorbed by particle.
et al, 2012 where it was also determined that leading
mechanism for devolatilization kinetics of sugarcane
MOVEMENT OF PARTICLES IN THE BED
bagasse, is a first order reaction:
There is not previous information about bed zones
where take place each of the interaction processes
( ( ) (13) between gas and solid phases, hence, instead of
decomposing bagasse feeding into individual sources of
moisture, volatiles, carbon and ash, each one injected in CARBON OXIDIZING REACTION
a different zone of the bed (as in Barreto, 2010), it was Carbon oxidation is a heterogeneous reaction in which
supposed an uniform flow of bagasse from bed surface carbon oxidizes to CO and CO2 according to:
to bottom grill, each particle following a given path where
it evolves according to gas composition and ΩC + O2  2(Ω-1)CO + (2- Ω)CO2 (21)
temperatures encountered on its way.
Considering the simplification used in the model about It was selected the correlation from Evans et al, 1977 for
constant porosity and particle diameter, the bagasse CO/CO2 ratio and temperature, given its capacity to
volumetric flow will be constant and particle vertical predict CO/CO2 ratios at high temperatures (Mehrabian,
velocity at a given location will be a function of the cross 2012):
sectional area of furnace. ( ⁄ )
Once the vertical velocity has been calculated, the [ ]
horizontal velocity is then calculated to keep the particle ( ⁄ )
(22)
in its pre-defined path. (Figure 4.)
y1 The total disappearance rate of C on particle surface (r1)
is calculated using a UDF (User Defined Function in
FLUENT) where is also calculated the parameter Ω
y according to particle surface temperature.

y2 Carbon oxidizing reaction was included in the model as


two independent reactions: oxidation to CO2 and
x oxidation to CO. The software calculates heat and mass
transfer between phases for each reaction according to
y3 calculated reaction rate (r1) and parameter Ω.
Figure 4. Pre-defined paths of particles in the bed.

Table 4. Chemical reactions considered in the model


E
ID Nombre Equation ΔHR A Reaction Rate ri
[J/kmol]

ΩC + O2 → 2(Ω-1)CO + (2- 7
(
combustion-1 1.715 Tp 7.483x10 ( )
Ω)CO2

combustion- -32750
1 C + O2 → CO2 [ ( ]
1a [kJ/kgC]
combustion- -9250
2 C + ½ O2 → CO [( ]
1b [kJ/kgC]

14250 8
(
3 gasification C + CO2 → 2CO 3.42 Tp 1.297x10 ( )
[kJ/kgC]

Volatiles → aCH4 + bCO + cCO2


4 pyrolysis 0 5x10
22
2.67x10
8
( ( )
+ dH2 + eH2O
-10107 2.239 8
5 combustion-2 CO + ½O2 → CO2 12 1.7 x10
[kJ/kgCO] x10
6410 8 8
6 dissociation CO2 → CO + ½O2 5x10 1.7x10
[kJ/kgCO2]
-32375 5.012 8
7 combustion-3 CH4 + 1.5O2 → CO + 2H2O 11 2x10
[kJ/kgCH4] x10
-120500 8 7
8 combustion-4 H2 + ½O2 → H2O 9.87x10 3.1x10
[kJ/kgH]
water-gas- -1470 7
9 CO + H2O ↔ CO2 + H2 2780 1.258x10 ( )
shift [kJ/kgCO]

CHEMICAL REACTIONS radiation energy source in conservation equation is


Chemical reaction included in the model, together with calculated as the divergence of the radiation flux.
their kinetics constants are described in Table 4.
Reactions ID 1 to ID 3 are heterogeneous while
reactions ID 4 to ID 9 are homogeneous. ( ) ( )
(23)
RADIATION MODEL Where Ep is the equivalent emission of the particles, ap
Radiation was included in the simulation using P-1 is the equivalent absorption coefficient, n is the refractive
model which is the simplest case of the P-N model. The index of the medium and G is the incident radiation.
P-1 radiation model is only valid for porosity values near RESULTS
1 when is used together with discrete phase model, The model was solved for eight (8) cases composed of
otherwise it will consider all particles in the bed are four PA flows (four ER values at bed) and two EA values.
receiving radiation even if the particle is located behind Cases considered are shown in Table 5. Mass weighted
another particle, in order to avoid this as bed porosity is averages of temperature and species mass percentage
0.6, it was included an UDF that only enables radiation at inlet of pan No. 1 are shown in Table 6.
model for the particles located in the top of the bed, For every case analyzed, the model performed similarly
while the heat transfer due to radiation of particles with a few differences that will be pointed next.
located below the top is included in the heat transfer by Char combustion and gasification take place in a narrow
conduction, using an effective thermal conductivity ( layer at the bottom of the bed, as predicted by Di Blasi,
modelled as in Goldman et al, 1984: 2004. The primary air entering from the bottom grill is
preheated and then supply oxygen for char combustion
where carbon is primarily oxidized to CO2 with just a few
[ ( ] portion oxidized directly to CO; CO2 formed is
(24)
immediately converted to CO by gasification and
dissociation reactions (ID 2 and 6 respectively), then the
, (25),(26) resulting CO, N2 and O2, continue rising through an inert
thick layer until bed top where devolatilization and drying
(27) take place in another narrow layer.

Table 5. Cases Considered

Case No. 1 2 3 4 5 6 7 8
Primary air flow [kg/s] 0.3544 0.3544 0.2953 0.2953 0.2531 0.2531 0.2215 0.2215
Percentage of total air flow [%] 80.0% 66.7% 66.7% 55.6% 57.1% 47.6% 50.0% 41.7%
Equivalence relation at lower section of chamber 1.25 1.25 1.5 1.5 1.75 1.75 2.00 2.00

Secondary air flow [kg/s] 0.0886 0.1772 0.1477 0.2363 0.1899 0.2785 0.2215 0.3101
Percentage of total air flow [%] 20.0% 33.3% 33.3% 44.4% 42.9% 52.4% 50.0% 58.3%

Total air flow [kg/s] 0.4430 0.5316 0.4430 0.5316 0.4430 0.5316 0.4430 0.5316
Excess Air (EA) [%] 0% 20% 0% 20% 0% 20% 0% 20%
Primary air / Secondary air Ratio (PA/SA) 4.00 2.00 2.00 1.25 1.33 0.91 1.00 0.71

Equivalence relation (ER) for char combustion 0.66 0.66 0.79 0.79 0.92 0.92 1.06 1.06

Combustion of volatiles only takes place at bed top as increases, gas temperatures leaving lower section of
predicted by Hallett, 2005. The combustion chamber chamber also increases, given that equivalence ratio in
geometry causes that hot gases and remaining oxygen lower section of chamber remains above 1.
after char combustion and gasification to be distributed Part of the heat from volatiles combustion is transferred
mainly by the bed side opposed to feeding gate, while to particles in the top of bed making these particles
the gate side receives little flow for heating and volatiles hotter than particles in the char combustion/gasification
combustion, according to this, feeding gate side reaches zone. Temperature profiles for a given particle path
lower temperatures and higher concentrations of species varies with EA values, as an example, Figure 5 shows
CH4, H2 and H2O than opposite side. temperature profiles for particle path 540 of 684.
Temperature distribution in the lower section of chamber
can be divided in two sections: in the bed and above bed.
The cases modeled consider a primary air flow higher p540
than required for oxidation of char, thus the bed
temperature will decrease as air flow increases, since
there’s a fixed amount of char to release heat during
oxidation; all additional air must be heated and so will
decrease bed temperature.
By other hand, the cases modeled consider reducing
atmospheres in the lower section of combustion
chamber (ER>1), thus the air that didn’t react with char
will oxidize volatiles above the bed, and any additional
air will allow more volatiles to be oxidized, it was
observed that heat released during volatiles combustion
compensates the lower temperatures achieved in the
Figure 5. Bed temperature profiles for a given particle path
bed when increasing primary air flow, thus as primary air
Table 6. Temperature and species at inlet of pan No. 1.

Caso 1 2 3 4 5 6 7 8
AP/AS 4.00 2.00 2.00 1.25 1.33 0.91 1.00 0.71
T (K) 1150 1121 1119 1071 1063 1035 1016 966
%mass CH4 0.15% 0.14% 0.49% 0.37% 0.87% 0.85% 0.96% 0.59%
%mass O2 1.04% 3.10% 2.19% 5.09% 3.76% 5.40% 5.29% 7.79%
%mass CO2 18.81% 18.97% 19.67% 16.22% 16.92% 17.95% 17.52% 14.69%
%mass CO 1.52% 1.35% 1.72% 1.34% 1.81% 1.70% 1.92% 1.45%
%mass H2O 19.52% 18.23% 18.55% 18.86% 17.63% 16.04% 16.16% 16.90%
%mass H2 0.02% 0.02% 0.04% 0.03% 0.08% 0.06% 0.12% 0.08%
%mass N2 58.94% 58.19% 57.34% 58.08% 58.92% 58.00% 58.04% 58.51%

EFFECT OF PA/SA RATIO ON FLUE GASES


TEMPERATURE
Figure 6 shows the relationship between mass weighted
average of gas temperature at inlet of pan No. 1 and
PA/SA ratio, for 0% and 20% EA.

Figure 7. Effect of PA/SA ratio on flue gas composition

As PA/SA ratio approaches its optimum value (maximum


Figure 6. Effect of PA/Sa ratio on flue gas temperature flue gas temperature) for each EA, combustible species
content (CO, CH4, H2) decreases, and resulting species
For 0% EA, maximum gas temperature is achieved for a (CO2, H2O) increases. When increasing EA, O2
PA/SA ratio of 3.25 equivalent to a 1.31 ER at lower increases while combustible species slightly decreases.
section of chamber, while for 20% EA maximum gas
temperature is achieved for a PA/SA ratio of 1.88 TEMPERATURE, CO, CO2 AND VELOCITY PROFILES
equivalent to a 1.28 ER at lower section of camera. AT FLUE GAS OUTLET
Distribution of parameters along cross-section of duct at
EFFECT OF PA/SA RATIO ON FLUE GASES the inlet of pan No. 1 is not uniform; there is a clearly
COMPOSITION visible gas path with higher velocities, temperatures and
Figure 7 shows the relationship between mass weighted combustible gas concentrations; the zone above this
average of species mass percentage at inlet of pan No. path is rich in oxygen with lower temperatures; the zone
1 and PA/SA ratio, for 0% and 20% EA. below this path is a recirculation zone with low
temperatures and velocities near zero, in the opposite
direction of the main flow (see Figure 8).
a)

Figure 9. Peak temperatures in combustion chamber


b)
When bed ER increases, peak temp. at upper section
tends to be higher than peak temp. at lower section, but
none of the simulated cases exceeds the 1800 K
threshold, when NOx formation rate becomes important.

EFFECT OF EA ON FLUE GASES TEMPERATURE


It can be seen that when increasing global EA, gas
volume to be heated increases and thus flue gas
temperature is reduced, but higher oxygen content and
secondary air velocity improve mixing of air with
unreacted volatiles which reduces combusting species at
c) flue gas outlet, and improves combustion efficiency; this
can be verified when comparing flue gas temperature to
adiabatic equilibrium temperature estimated by CEA as
seen in Figure 10, where the flue gas temperature for
cases with 20% EA are closer to their adiabatic
equilibrium temperature than cases with 0% EA.

d)

Recirculation
zone Figure 10. Comparison between flue gases temperatures
and estimated adiabatic equilibrium temperature.

COMPARISON OF RESULTS TO REAL DATA


AVAILABLE
Figure 8. Cross section distribution at inlet of Pan No .1: a) Real data from existing furnaces are scarce, the only
Temp., b) %mass O2, c) Horizontal Velocity, d) %mass CO available data is the design data from of an existing
furnace, performed in a zero dimensional model and
PEAK TEMPERATURES IN COMBUSTION CHAMBER claimed to be representative of actual furnace
In the lower section of chamber, peak temperature is performance. According to this information, the flue
located above bed top in the side opposed to feeding gases temperature entering to pan No. 1 is 932°C (1205
gate where the flow of hot gases and remaining oxygen K), and mass percentage of CO at flue gas outlet is
from char combustion and gasification is higher. 2.63%, which validates temperatures range estimated by
Peak temperature in upper section of chamber is located model, while CO mass content tends to be under
next to SA inlet where injected oxygen completes predicted by the model with values 27 to 50% lower
combustion of volatiles. when compared to mass weighted average, but
Figure 9 shows behavior of peak temperatures as ER in consistent with peak values estimated when compared
the lower section of chamber and global EA varies. to cross section distribution. See Figures 8-a & 8-c.
NOMENCLATURE = mean incident radiation temp. Subscripts
= particle superficial area = Volume g = gas phase
= Particle specific heat Yi = mass fraction of specie i i = species CH4, O2, CO, CO2, H2,
C2 = inertial resistance H2O, N2
Greek j = reactions (ID 1 to ID 9)
= diffusivity
= permeability mix = mix of gases in chamber
H = enthalpy
= particle emissivity p = particle
= latent heat of moisture
= porosity
= convective coefficient Abbreviations
= thermal conductivity of fluid
= rate constant of reaction j EA = excess air
µ = viscosity
= mass transfer coefficient ER = equivalence ratio
= gas phase density
M = molecular weight SA = secondary air
= mass of particle  = Estefan Boltzmann constant
PA = primary air
= particle diameter
= Temperature
= sphericity

CONCLUSIONS BIBLIOGRAPHY
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as PA/SA ratio increases until a maximum. This Gasification Model to Estimate the Quality of Gases Produced
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Borello D, et al. Prediction of multiphase combustion and
remain constant at 1.3. ash deposition within a biomass furnace. Appl. Energy. 2012
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but temperature of gases leaving lower section of Countercurrent Fixed-Bed Reactor,” AIChE Journal, 50:2306-
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available for volatiles combustion. Eng. Prog. 48, no. 2: 89-94, 1952.
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efficiency at combustion chamber with higher flue Fire Safety Journal 1 (1977) 57-66.
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impacto ambiental. CORPOICA. Colombia. 2003
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balance the effect of higher flue gases with the effect Department of Mechanical Engineering, University of Ottawa,
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during drying process, but also promotes preferential de Hornillas Paneleras Utilizando EES. Tesis de Pregrado,
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Gasification Using Air-Steam For Partial Oxidation and N as
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ANNEXES
Next are included Figures of distribution of temperature, mass fraction of species, velocity, density and pressure through
combustion chamber for case 3, taken as representative of all simulated cases.

a) Temperature b) O2 c) CO

d) CH4 e) H2 f) H2O

g) CO2 h) N2 i) Velocity

j) Density k) Pressure

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