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CHEMISTRY
Q.1) Which of the following compound can show geometrical as well as optical isomerism?
a) CH3CH(Me) CH2CH=CHCl
b*) Et CH(Me) CH2CH=CHCl
c) Et CH(Et) CH2CH=CH2
d) Et CH(Me) CH2CH=CH2
Q.3) Identify the set of Acids having lower pKa value than C6H5COOH :
a) HCOOH, CH3CH2COOH, NO2CH2COOH
b*) CF3COOH, HCOOH, NC–CH2COOH
c) ,
d) (CH3)2CHCOOH, HCOOH
Q.4) Which of the following set of Bases are stronger than (CH3)3N in aqueous solution?
a) (CH3)2NH, C6H5NH2, CH3NH2
b*) (CH3)2NH, CH3NH2
c) C6H5NH2 only
d) N, N–Dimethyl aniline only
Q.5) Which of the following is optically active with configuration at asymmetric carbon? (if applicable)
a*) b) c) d)
a)
b*)
c)
d)
Q.7) Which one of the following does not have sp hybridized carbon?
a) Allene (C3H4)
b*) 3-Butadiene
c) Acetylene
d) Benzonitrate
a)
b*)
c)
d)
b*)
c) CO32–
d) Vinyl Alcohol
Q.10) Identify the compound have maximum enol forms (consider isomers separately).
a) b) c) d*)
a*) F O2 N3
b) k Li Na
c) B > Be > N
Q.15) In which of the following arrangement the order is not according to the property indicated against
it?
a) SO2 > P2O3 > SiO2 > Al2O3 (Acidic nature)
b) N > O > C > B (Ionisation potential)
Q.20) Identify the correct order of energy of electrons with the following quantum numbers
Electron Q.Number
1 n = 5, =1
2 n = 4, =2
3 n = 5, =0
4 n = 4, =1
Q.22) The radius of which of the following orbit is same as Ist Bohr’s orbit of Hydrogen atom?
a) He+ (n = 2)
b) Li2+ (n = 3)
2+
c) Li (n = 2)
d*) Be3+ (n = 2)
Find the standard enthalpy change of the reaction (in kJ) of Hf for CO2(g) CO(g) and H2O(g)
are –393.5, –110.5, –241.8 kJ mol–1 respectively.
a*) 41.2
b) –41.2
c) 524.1
d) –262.5
Q.28) The enthalpy of vaporization of liquid is 30 kJ mol–1 and entropy of vaporization is 75 J mol–1 k.
What is the boiling point of the liquid at 1 atm?
a) 250 k
b*) 400 k
c) 450 k
d) 600 k
x
y