Alimentación Fondos Destilado

Densidad (kg/L) 0.8994 0.9336 0.8531

Fracción de Agua 0.5100 0.7000 0.2528
Fracción de etanol 0.4900 0.3000 0.7472
Cantidad en L 4.5000 2.3600 2.2350
Cantidad en Kg 4.0473 2.2033 1.9067
PM Agua (kg/kmol) 18.0153 18.0153 18.0153
PM etanol (Kg/Kmol) 46.0700 46.0700 46.0700
Cantidad de Kmol de Agua 0.1146 0.0856 0.0268
Cantidad de Kmol de Etanol 0.0430 0.0143 0.0309
Kmoles Totales 0.1576 0.09996 0.0577
Fracción Agua 0.7269 0.8565 0.4639
Fracción de Etanol 0.2731 0.1435 0.5361
Balance de Materia Global
>𝐴=𝐷+𝑅
> 𝐴(𝑋𝑎) = 𝐷(𝑋𝑑) + 𝑅𝑓(𝑋𝑓)
> A= 157.62 Moles; Rf= 99.96 Moles; D= 57.68 Moles
> Xa= 0.2731; Xf= 0.1435; Xd= 0.5361
Balance de Materia en el Condensador
>V=L+D
> V(Yv) = L(XL) + D(Xd)
Balance de Materia en la Caldera
> A + L = Rf + V
> A(Xa) + L(XL) = Rf (Xf) + V(Yv)

𝐿
𝑟= = 0.31 → 𝑅𝑒𝑙𝑎𝑐𝑖ó𝑛 𝑑𝑒 𝑅𝑒𝑓𝑙𝑢𝑗𝑜
𝐷
𝐿 = 𝑟𝐷 = (0.31)(57.68) = 17.88 𝑀𝑜𝑙𝑒𝑠
𝑉 = 𝐷 + 𝑟𝐷 = 𝐷(𝑟 + 1) = 57.68(0.31 + 1) = 75.56 𝑀𝑜𝑙𝑒𝑠
𝐿 𝐷𝑋𝑑 𝑟 𝑋𝑑
𝑌𝑣 = 𝑋𝐿 + → 𝑌𝑣 = 𝑋𝐿 +
𝑉 𝑉 𝑟+1 𝑟+1
𝑟 𝑋𝑑 𝑋𝑑 0.5361
𝑌𝑣 = 𝑋𝐿 + ;𝑋 = 0 → 𝑌𝑣 = = = 0.4092
𝑟+1 𝑟+1 𝐿 𝑟 + 1 0.31 + 1
𝑅𝑓 (𝑋𝑓) + 𝑉(𝑌𝑣) − 𝐴(𝑋𝑎)
𝑋𝐿 = = 0.124
𝐿
 𝐷 ∗ 𝑋𝑑 (57.68 ∗ 0.5361)
% 𝑅𝑒𝑐𝑢𝑝𝑒𝑟𝑎𝑐𝑖ó𝑛 = ∗ 100 = ∗ 100 = 71.83%
𝐴 ∗ 𝑋𝑎 (157.62 ∗ 0.2731)
𝑚𝑜𝑙𝑒𝑠 𝑑𝑒 𝑒𝑡𝑎𝑛𝑜𝑙 𝑟𝑒𝑐𝑢𝑝𝑒𝑟𝑑𝑜𝑠 𝐷 ∗ 𝑋𝑑 (57.68 ∗ 0.5361)
𝑅𝑒𝑛𝑑𝑖𝑚𝑖𝑒𝑛𝑡𝑜 = = = = 0.1961
𝑚𝑜𝑙𝑒𝑠 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠 𝐴 157.62
𝑚𝑜𝑙𝑒𝑠 𝑑𝑒 𝑒𝑡𝑎𝑛𝑜𝑙
𝑅𝑒𝑛𝑑𝑖𝑚𝑖𝑒𝑛𝑡𝑜 0.1961 𝑚𝑜𝑙𝑒𝑠 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠 𝑚𝑜𝑙𝑒𝑠 𝑑𝑒 𝑒𝑡𝑎𝑛𝑜𝑙 𝑟𝑒𝑐𝑢𝑝𝑒𝑟𝑑𝑜𝑠
𝑃𝑟𝑜𝑑𝑢𝑐𝑡𝑖𝑣𝑖𝑑𝑎𝑑 = = = 0.0023
𝑇𝑖𝑒𝑚𝑝𝑜 84 𝑚𝑖𝑛 𝑚𝑜𝑙𝑒𝑠 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠 ∗ 𝑚𝑖𝑛

𝑃𝑙𝑎𝑡𝑜𝑠 𝑡𝑒ó𝑟𝑖𝑐𝑜𝑠 𝑃𝑙𝑎𝑡𝑜𝑠 𝑡𝑒ó𝑟𝑖𝑐𝑜𝑠 4

𝜂= → 𝑃𝑙𝑎𝑡𝑜𝑠 𝑅𝑒𝑎𝑙𝑒𝑠 = = = 5.57 ≈ 6
𝑃𝑙𝑎𝑡𝑜𝑠 𝑟𝑒𝑎𝑙𝑒𝑠 𝜂 0.7183
Volatilidad Relativa
𝛼𝐴 𝑃𝐴 𝑋𝐵 𝑌𝐴 (1 − 𝑋𝐴 ) 0.4092(1 − 0.2731)
𝛼𝐴𝐵 = = = = = 1.84
𝛼𝐵 𝑃𝐵 𝑋𝐴 𝑋𝐴 (1 − 𝑌𝐴 ) 0.2731(1 − 0.4092)
Balance de Energía
𝐾𝑔
ṁ𝑐 = 0.1027 → 𝐹𝑙𝑢𝑗𝑜 𝑑𝑒 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑐𝑖𝑜𝑛 𝑑𝑒𝑙 𝑡𝑎𝑛𝑞𝑢𝑒 𝑑𝑒 𝑒𝑛𝑓𝑟𝑖𝑎𝑚𝑖𝑒𝑛𝑡𝑜
𝑠
𝐾𝐽
𝐶𝑝𝐴𝑔𝑢𝑎 = 4.18
𝐾𝑔 °𝐶
∆𝑇1 = (𝑇1 − 𝑇2) = (20°𝐶 − 27°𝐶) = −7°𝐶
∆𝑇2 = (𝑇1 − 𝑇2) = (24°𝐶 − 27°𝐶) = −3°𝐶
𝑘𝑔 𝐾𝐽 𝐾𝐽
𝑄𝑐 = ṁ𝑐 𝐶𝑝𝐴𝑔𝑢𝑎 (∆𝑇1 + ∆𝑇2) = (0.1027 ) (4.18 ) (−10°𝐶) = −4.29286
𝑠 𝐾𝑔°𝐶 𝑠
𝑄𝐶 = −4.29286 𝐾𝑊

(𝐴)(𝐻𝐴 ) + (𝑄𝑅 ) = (𝐷)(ℎ𝐷 ) + (𝑅𝑓)(ℎ𝑓 ) + (𝑄𝐶 )

𝐾𝐽 𝐾𝐽 𝐾𝐽
𝐻𝐴 = 38.6 ; ℎ𝐷 = 12.892 ; ℎ𝑓 = 19.622
𝑚𝑜𝑙 𝑚𝑜𝑙 𝑚𝑜𝑙
(𝑄𝑅 ) = (𝐷)(ℎ𝐷 ) + (𝑅𝑓)(ℎ𝑓 ) + (𝑄𝐶 ) − (𝐴)(𝐻𝐴 )
𝑚𝑜𝑙 𝐾𝐽 𝑚𝑜𝑙 𝐾𝐽 𝐾𝐽 𝑚𝑜𝑙 𝐾𝐽
𝑄𝑅 = (0.02002 ) (12.892 ) + (0.0347 ) (19.622 ) + (4.29286 ) − (0.05472 ) (38.6 )
𝑠 𝑚𝑜𝑙 𝑠 𝑚𝑜𝑙 𝑠 𝑠 𝑚𝑜𝑙
𝐾𝐽
𝑄𝑅 = 3.12 = 3.12 𝐾𝑊
𝑠

% 96 80 70 60 50 30 10 0
Alcohol
Densidad 0.7999 0.8434 0.8571 0.8775 0.9156 0.9399 0.9691 0.9739
(g/mL)
 Agua de Agua de salida
Alimentación Vapor Destilado Reflujo Fondos entrada del del
Condensador Condensador
Corriente 1 2 3 4 5 6 7
Flujo (mol/h) 197.025 94.45 72.1 22.35 124.95 8309 8309
Agua
53.808 38.649 38.653 2.771 19.930 1 1
(mol/h)
Componentes
Etanol
143.217 55.801 33.447 19.579 107.020 0 0
(mol/h)