Professional Documents
Culture Documents
The Cement Factory of Matola is part of a group of the three factories for the
production of Cement, belonging to the group CIMPOR -- Cimentos de Portugal.
The facility activities started in 1920 with a wet production line and an installed
production capacity of 45 thousand tons of cement per year. The other two units
are the factory of Dondo, in Sofala Province, and the factory of Nacala, in the
Nampula Province.
The cement facility is located amidst other industrial enterprises including the
Industrial Company of Matola (CIM), Grain Silos and Terminal of Matola
(STEMA), PETROMOC reservoirs of hydrocarbons, the coal terminal,
Matola, silos of alumina (Terminal of MOZAL), and the General Chemistry
facility (Paralysed). Close by are housing and small economic infrastructures.
The surrounding industrial companies are unanimous in saying that the dust
stemming from the cement facility accumulates in huge quantities in their sites,
forcing them to make constant cleansing and shortening the life expectancy of
their equipment and refrigeration appliances.
On the local communities, the effect of dust is most noticeable in the Saline
quarter and in quarter 17. Depending on the winds direction, the particles of dust
are deposited in these places and the assets of these communities are filled of
dust which obliges them to make constant cleaning. The communities suffer from
respiratory diseases, irritation of eyes and conjunctivitis but no scientific evidence
relates these facts to operation of the cement facility and its dust emissions.
The communities also complained about odours emanating from the usage of the
Matola cement kiln to burn hazardous substances, a task occasionally performed
at this facility. We found no evidence of such statements and the factory
management refuted such allegations ensuring that all activities of burning of
obsolete products are performed in a clean way and in the presence of
government authorities, particularly representatives of the Ministry of
Environment (MICOA).
To check the situation and verify the level of compliance of environmental, labour
and industry legislation, MICOA, in coordination with the Directorate of National
Industry, the City Council of Matola and the Provincial Directorate of
Industry and Commerce, carried out in April 2005, an audit of the factory,
having actually found several irregularities in environmental performance of
the plant, including the lack of internal written procedures for environmental,
occupational health and safety management.
There are three broad categories of cement products: Portland cement, Portland
cement with the addition of PFA or blast furnace slag and special cements. All
but certain special cements are manufactured by using substantially the same
process route (Figure 8), which is discussed in this report. A fundamental
difference between cement manufacturing routes is whether the kiln process is
wet or dry. However, all processes have the following stages in common:
• raw material procurement (from on site quarry or importing);
• raw material preparation (crushing, and grinding of raw materials -
principally limestone and clay - and blending to achieve a given
homogenous chemical specification);
• fuel handling (fuel grinding if solid fuels are used);
• kiln processing (where raw materials are chemically reacted – calcinated -
by the application of heat in a kiln system to produce clinker);
• Clinker cooling
• cement milling (addition of gypsum and clinker size reduction); and
• cement packing and dispatch.
Figure 8: Cement Production Process
Carbon dioxide is released during the production of clinker, a component of cement, in
which calcium carbonate (CaCO3) is heated in a rotary kiln to induce a series of
complex chemical reactions (IPCC Guidelines). Specifically, CO2 is released as a by-
product during calcination, which occurs in the upper, cooler end of the kiln, or a
precalciner, at temperatures of 600-900°C, and results in the conversion of carbonates
to oxides. The simplified stoichiometric relationship is as follows:
At higher temperatures in the lower end of the kiln, the lime (CaO) reacts with silica,
aluminum and iron-containing materials to produce minerals in the clinker, an
intermediate product of cement manufacture. The clinker is then removed from the kiln
to cool, ground to a fine powder, and mixed with a small fraction (about five percent) of
gypsum to create the most common form of cement known as Portland cement.
Portland cement is defined as an active hydraulic binder based on ground clinker
formed from a predetermined homogenous mixture of materials comprising lime (CaO),
silica (SiO2) and a small proportion of alumina (Al2O3) and generally iron oxide (Fe2O3).
Some of the main impacts to the environment stemming from the cement production are
summarised in Figure 9.
Lime stone-Clay-Additives
Storage
Hot air
Flue gas (CO, NOx,
Preheating
SO2, dust…)
Pre-calcining
Energy
Hot air
Rotary kiln Slag
Energy
Cooling Dust
Clinker Storage
Gypsum
Additives Crushing Cement milling Dust, Noise
Energy
Cement Storage
Packaging Packaging
Energy Bulk load Storage
waste-Dust
The process generates a variety of wastes, including dust, which is captured and
recycled to the process. The generation of fine particulates is inherent in the process,
but most are recovered and recycled. Approximately 10–20% of the kiln feed can be
suspended in the kiln exhaust gases, captured, and returned to the feed. Other sources
of dust emissions include the clinker cooler, crushers, grinders, and materials-handling
equipment.
Sulfur dioxide (SO2) is the main gas causing acid rain. Emissions of SO2 from the
cement process originate from volatile sulfur in the raw material. Sulfur present in the
fuel is largely incorporated into the clinker itself and not emitted to the atmosphere.
Nitrogen oxides (NOx) are in part responsible for the photochemical smogs that occur
over urban areas. Emissions of around 2,000 g/tonne clinker can be achieved through
careful process control, but lower emissions require additional flue gas treatment.
Regulations in many countries do not require continuous NO x measurement. In some
cases, alternative fuels can be used to reduce NOx emissions.
Volatile organic compounds (VOCs) play a role in creating low-level ozone that can
cause respiratory problems. Emissions from cement plants largely depend on the
organic content of the natural raw materials used. To reduce emissions, it is necessary
to limit the content of organic components in alternative raw materials, and ensure
effective combustion. Regulations in most countries do not require measurement of
VOCs, except when using some waste materials.
Solid waste - cement kiln dust (CKD) and bypass dust are the only significant solid
wastes produced by the cement production process. The y are only extracted and
discarded when this is necessary to decrease the sodium and potassium concentrations
in the cement, and the chlorine content of the process. CKD is especially an issue in
North America, where cement standards require low alkali concentrations; elsewhere,
CKD is recycled back into the process. For this reason, 6% of production is discarded
as CKD in North America, compared to less than 2.5% in Western Europe and around
1% in Asia and Latin America.
Mercury is the only heavy metal that is highly volatile in the kiln system. It is important to
control the content of mercury in the wastes used as alternative fuels.
The present study concluded that the negative impacts associated with the factory are
basically dust in the combustion gases released into the air and Emission of noise
located, and in small quantities, generation of solid waste, and adverse impacts on
occupational health and safety of workers and local communities.
The rate of emission of dust in the factory of the Matola cement is quite high, affecting,
first, the local environment and peripherals, and second
place, the efficiency of the production process itself. The mass balance held
By CIMPOR in 2000 shows that when the factory operates at its maximum
capacity, or 108 tons/h, the amount of dust retrieved from electrostatic filters reaches
values estimated at 5 tons/h.
The cement milling as well as the crushing of limestone are the most
Dust generating activities in the factory, followed by the cooling of clinker, the packaging
of cement and grinding of the coal.
The cement plant workers are exposed to inhalation of dust and gases of combustion, a
situation that is exacerbated by the absence of mandatory use of personal protective
equipment.
The gaseous emissions from the factory are normal for this type of activities. The
gases emitted are mainly CO2, in fact, greenhouse, result from the thermal
decomposition of CaCO3 and MgCO3.
The noise is generated in the factory especially by the system of mills of raw materials
and cement, as well as fans installed in the areas of crushing and milling of cement. We
have noticed with concern the lack of use of protective equipment, such as headsets,
personnel uniform, glasses and respiratory masks.
Solid waste usually generated in the factory includes office and household waste, as
well as refractory bricks and scrap iron. The bricks are incorporated into raw material
crushing, while household waste generated in the office is collected and removed from
the site daily by a waste management contractor. Finally, it is appropriate to state that
the factory must find appropriate solutions
to contain the emission of dust and other pollutants and adopt generally accepted
standards of environmental quality. Figure 10 gives an overview of the process in terms
of inputs and outputs.
E l e c t r o s t a t i c p r e c i p i t a t o Lr s o N wa n O - bd x u r n e r s
b a g h of ou rs e c s o l l e c t i o n a n d L o w - s u lf u r f u e l s i n t h e k i l n ( n a t u r a l
r e c y c l i n g o f f i n e p a r t i c u g l aa st e is n s t e a d o f o il )
R a w m a t e r i a l s
L i m e s t o n e
C l a y
M a r l
C o n t r o l S y s t e m s
C o n t i n u o u s m o n it o r in g o f d u s t ,
N O, S xO a 2 nV d O C
A i r E m i s s i o n s
P e r i o d i c m e a s u r e m e n t ( a t l e a s t
P a r i c u l a t e s
C 2O o n c e p e r y e a r ) o f m e t a ls ,
d io / xf u i n r , sa n s b e n z e n e a n d
E l e c t r i c i t y N xO
Q u a r r y i n g a m m o n ia
S 2O
E q u ip m e n t c a lib r a t io n ( a t l e a s t
t w ic e p e r y e a r ) b y a n e x t e r n a l,
W a t e r c o m p e t e n t o r g a n iz a t io n
F u e l
F u e l - o i l I m p r o v e d q u a r r y m a n a g e m e n t
D i e s e l R a w M a t e r i a l s C o m p u t e r o p t i m i z a t i o n o f l a y - o u t s
P r e p a r a t i o n R a w m a t e r i a l s u s e a n d o p e r a t i o n s
C h e m i c a l s P a r t ia l s u b s t it u t io n o f c lin k e r b y
PLA N T
C o
o l i n g w a t e r t r e a t m e n t c e m e mn t ai t to e u r s i a l s ( f ly a s h , b la s t
W a s t e w a t e r t r e a t m e n t f u r n a c e s la g )
L a b o r a t o r y c h e m i c a l s
S o l v e n t s & c l e a n e r s
N o n - c o m b u s t i o n S o l i d
CEM EN T
L u b r i c a n t s K i l n P r o c e s s i n g W a s t e
O i l s T
r a s h & g a r b a g e C o m m e r c ia l L a n d f ill
G r e a s e U n r e c o v e r a b l e e q u i p m e n t & s u p p l i e s
C o n s t r u c t i o n d e b r i s
A s b e s t o s
P a c k a g i n g
P a l l e t s & c r a t e s
C a r d b o a r d
P a p e r
C e m e n t M i l li n g D r y p r o pc r e e s h s e a ( a n w t de i r t s h
p r e c a ) l c i n i n s e t er sa d o f W e t p r o c e s s
M i. s E c q u i p m e n t & S u p p l i e s
e hV i c l e s
E n e r g y
S p a r e p a r t s
T o o l s E n e r g y r e c o v e r y b y u s i n g g a s e s
L i g h t i n g f r o m c l i n k e r c o o l i n g a s s e c o n d a r y
R a g s & t o w e l s c o m b u s t i o n a i r
P a c k a g i n g a n d
D i s p a t c h R e
c o v e r a b l e
C o o l a n t s &
R e
c y c l a b l e M a t e r i a l
M e t a l s R e c y c l in g V e n d o r s
P a p e r & O f f i c e S u p p l i e s U s e d o il & f il t e r s
P a p e r W o o d & p a lle t s
C o m p u t e r s & C o p i e r s L a m p s & b a t t e r ie s
P a p e r & c a r d b o a r d
H a z a r d o u s / T o x i c
w a s t e H a z a r d o u s W a s t e D is p o s a l
S o l v e n t s
The priority in the Matola cement facility is to minimize the emissions of particulates by
reducing the mass load emitted from the stacks, from fugitive emissions, and from other
sources. Collection and recycling of dust in kiln gases is required to improve the
efficiency of the operation and to reduce atmospheric emissions. Electrostatic
precipitators (ESPs) and fabric filter systems (bag houses) are the principal options for
collection and control (achieving over 99% removal efficiency) of fine particulates. ESPs
are sensitive to gas characteristics, such as temperature, and to variation in voltage;
bag houses are generally regarded as more reliable.
• Install equipment covers and filters for crushing, grinding, and milling operations.
• Use enclosed adjustable conveyors to minimize drop distances.
• Wet down intermediate and finished product storage piles.
.
• Use low sulfur fuels in the kiln. SOx emissions are best controlled by using low-
sulfur fuels and raw materials. The absorption capacity of the cement must be
assessed to determine the quantity of sulfur dioxide emitted, which may be up to
about half the sulfur load on the kiln. Pre-calcining with low-NOx secondary firing
can reduce nitrogen oxide emissions. Use low-NOx burners with the optimum
level of excess air. NOx emissions should be controlled by using proper kiln
design, low-NOx burners, and an optimum level of excess air. NOx emissions
from a dry kiln with pre-heater and pre-calciner are typically 1.5 kg/t of clinker, as
against 4.5 kg/t for the wet process. The nitrogen oxide emissions can be
reduced further, to 0.5 kg/t of clinker, by afterburning in a reducing atmosphere,
and the energy of the gases can be recovered in a pre-heater/Pre-calciner
• Burning natural gas instead of oil the fuel consumption can reduce the energy
consumption, with a reduction in CO2 emissions. The major environmental
benefits are related to the reduction of gases emissions.
• Operate control systems to achieve the required emissions levels.
Raw-material substitution
Other than fuel, the essential raw materials for cement production are limestone, marl
and clay, which are obtained by quarrying. An operating quarry obviously has major
impacts on the local landscape and ecology, and can cause noise and traffic problems
for local communities.
Using computer-generated quarry maps, materials with the required qualities can be
extracted and homogenized in the correct proportions, to minimize wastage of natural
resources. Quarry layouts and operations are also optimized with respect to location of
crushers and haulage roads, to minimize noise, transport and visual impact.
Energy recovery
Since the process is very energy-intensive, gases from clinker cooler should be used as
secondary combustion air. The dry process, using pre-heaters and pre-calciners, is both
economically and environmentally preferable to the wet process because the energy
consumption - 200 joules per kilogram (J/kg) - is approximately half of that for the wet
process.