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high-pressure
"All degrees of electron donation are
supercritical gases possible, ranging from nearly zero in the
than previously case of weak (but specific) intermolecular
attractions, and idealized ion associations, to
believed. This paper complete transfer of one or more electrons
suggests that by using reduced properties for where P is the value of the property in the
density (ρr) [ratio of apparent density (ρ) to solvent of interest, Po is the value of the
critical density (ρc)] the following equation property in some reference state (preferably,
roughly approximates solubility parameters but not necessarily, the gas phase or some
of compressed gases at higher pressures: inert solvent). α describes the sensitivity of α, β and ξ are determined by least squares
the property to solvent basicity, β its multiple parameter regression analysis by
sensitivity to solvent acidity, ξ its sensitivity measuring P in a variety of systems of known
to nonspecific dispersion forces. The DN, AN and δd, The values can then be
property in question may be a spectral used to calculate P in other systems.
Gas-Elastomer Interactions. Ender(3) transition, the logarithm of a rate constant or For your system:
verifies increasing gas density does increase an
the swelling effect on elastomers. This is not
the complete story, however. Consider Fig.
4, developed from Ender's data. If solubility
parameter δ was the entire story, one might
simplistically rationalize the following based
on elastomer chemical structures:
EPDM nonfluorinated
Aflas* half-fluorinated
EPDM
Kalrez* totally-fluorinated
EPDM