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(Extended only) Define the mole and the Avogadro constant
● Chemical amounts are measured in moles (therefore it is the amount of
substance). The symbol for the unit mole is mol.
o Mole = amount of substance
● The number of atoms, molecules or ions in a mole of a given substance is the
Avogadro constant: 6.02 x 1023 per mole.
(Extended only) Use the molar gas volume, taken as 24dm3 at room
temperature and pressure
● Equal amounts in mol. of gases occupy the same volume under the same
conditions of temperature and pressure (e.g. RTP)
● Volume of 1 mol. of any gas at RTP (room temperature and pressure: 20˚C and 1
atmosphere pressure) is 24 dm3
● This sets up the equation:
Volume (dm3) of gas at RTP = Mol. x 24
● Use this equation to calculate the volumes of gaseous reactants and products at
RTP
● You can convert between moles and grams by using this triangle:
o moles = mass ÷ formula mass
● You can work out the moles or volume of a gas at RTP using the
equation:
o volume = moles x 24
o rearranged to: moles = volume ÷ 24
● You can work out concentrations of solutions in g/dm3 using the equation:
o concentration = mass of solute ÷ volume
● you can work out concentrations of solutions in mol/dm3 using the equation:
o concentration = moles of solute ÷ volume
● to convert between concentration in mol/dm3 and g/dm3:
o mol/dm3 → g/dm3 multiply by Mr
o g/dm3 → mol/dm3 divide by Mr
● if you are given a reacting mass/volume/concentration and are asked to work
out the mass/volume/concentration of another reactant or a product:
o calculate the number of moles (use the appropriate equation from
above)
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o use the large numbers in the balanced equation to work out the mole
ratio (e.g. for the equation H2 + Cl2 → 2HCl, one mole of H2 reacts to form
2 moles of HCl, so the mole ratio is 1:2)
o use the mole ratio to work out how many moles of the other reactant or
product you have (in the example above, if you had 2 moles of H2, you
would make 4 moles of HCl)
o using the number of moles and the appropriate equation above, calculate
the mass/volume/concentration
● limiting reagents:
o in a reaction, often one of the reactants will be a limiting reagent. This
means that this reactant will be used up first and will cause the reaction
to stop.
o in calculations, if given the mass/volume of a limiting reagent and
another reagent, you must use the mass/volume of the limiting reagent.
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