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ISSN 2321 3361 © 2016 IJESC
Abstract:
Since the discovery of electron spin resonance (ESR) by Zaviosky in 1945, the technique has been an inevitable tool for physicist,
chemist and material scientist interested in the properties of solid on an atomic scale. Zavoisky was able to detect faint signals
corresponding to multiple para magnetic species. It involves atom and molecules with unpaired spins of electrons. Such systems
display net magnetic moment and they interact with the applied magnetic field. Electron spin resonance is an important tool in the
field of molecular analysis where free electrons are present. It gives insight to the spin interaction of a substance and therefore its
structure. The technique of electron spin resonance was used to study the lande g- Factor of DPPH (Diphenyl Picryl Hydrazyl) at
different frequencies by varying the current in the Helmholtz coils. From the experiment the lande g- Factor was found to be 1.97
and 1.99 for the frequencies 13MHz and 14MHz. a g- factor of 2.08 and 2.1 was obtained for the frequencies 15MHz and 16MHz.
The theoretical g- Factor for DPPH is 2.0036. The precautions to be taken for more accurate result were also stated.
Key Words: lande’s g- factor, magnetic field of sample at resonance in Gauss and the value of the slope QI.
International Journal of Engineering Science and Computing, April 2016 3811 http://ijesc.org/
EXPERIMENTAL SETUP
The following figure shows the block diagram of the ESR setup.
Description of the ESR spectrometer: magnetic field of intensity . Then the moment will
Basic circuit: ESR spectrometer (model-105), the precess around with an angular larmor frequency,
circuit consists of critically adjusted radio frequency
oscillator having a frequency range of approximately ………. (1)
10-17MHz.
Phase shifter: this can compensate the undetermined g being the lande g- factor(g=1for pure orbital momentum
phase difference which may be introduced in the and g=2 for a free electron spin).
amplification stages of the spectrometer and Let us proceed to the quantum picture of elementary
oscilloscope. magnetic resonance. Suppose that the intrinsic angular
momentum of the electron couples with the orbital angular
50 Hz sweep unit: For modulation with low frequency momentum of the electron to give a resultant . We know,
magnetic field, a 50 Hz current flows through the that J+1 magnetic sublevels labelled by the magnetic field
Helmholtz coils. by equal energy difference,
Sample: the test sample, Diphenyl picryl Hydrazyl Also, if a particle is subjected to perturbation by an
(DPPH) is placed in a plastic tube inside the R.F coil. alternate magnetic field with a frequency such that the
quantum h is exactly the same as the difference between
the levels, and if the direction of the alternating field is
Oscilloscope: The Oscilloscope for the observation of
perpendicular to the direction of the static magnetic field,
ESR resonance has:
then there will be induced transition between neighbouring
Screen diameter : 12.5 cm
Vertical amplifier sensitivity : 50 m V/cm sublevels according to the selection rules for
magnetic dipole radiation
Theory
In terms of simple classical concept, let us consider a particle Therefore the resonance condition is
having a magnetic moment which is placed in a uniform ………. (4)
International Journal of Engineering Science and Computing, April 2016 3812 http://ijesc.org/
Where is the resonance frequency. This requirement is ii. Frequency = 14MHz
identical with classical condition .
………. (5)
Therefore,
………. (10)
i. Frequency = 13MHz
International Journal of Engineering Science and Computing, April 2016 3813 http://ijesc.org/
CONCLUSION
The main aim of this research work is to study and
determine the lande g- Factor of DPPH. The slope (QI) of
the frequency versus applied magnetic field was used to
calculate the lande g- Factor of DPPH using different
frequencies. The calculated g- values obtain from the
experiment for the four different frequencies are;
From the result obtained one can see that the best possible
resonance peaks are obtained by varying the frequency in the
range of 13 and 14 MHz and the Y sensitivity of the
oscilloscope.
References
1. G. E. Pake, Paramagnetic Resonance, (W. A.
Benjamin, 1962).
International Journal of Engineering Science and Computing, April 2016 3814 http://ijesc.org/