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Surface area is the measure of how much exposed area a solid object has, expressed in
square units. Mathematical description of the surface area is considerably more involved
than the definition of arc length of a curve. For polyhedra (objects with flat polygonal
faces) the surface area is the sum of the areas of its faces. Smooth surfaces, such as a
sphere, are assigned surface area using their representation as parametric surfaces. This
definition of the surface area is based on methods of infinitesimal calculus and involves
partial derivatives and double integration.
General definition of surface area was sought by Henri Lebesgue and Hermann
Minkowski at the turn of the twentieth century. Their work led to the development of
geometric measure theory which studies various notions of surface area for irregular
objects of any dimension. An important example is the Minkowski content of a surface.
While areas of many simple surfaces have been known since antiquity, a rigorous
mathematical definition of area requires a lot of care. Surface area is an assignment
of a positive real number to a certain class of surfaces that satisfies several natural
requirements. The most fundamental property of the surface area is its additivity: the
area of the whole is the sum of the areas of the parts. More rigorously, if a surface S is a
union of finitely many pieces S1, …, Sr which do not overlap except at their boundaries
then
Surface areas of flat polygonal shapes must agree with their geometrically defined area.
Since surface area is a geometric notion, areas of congruent surfaces must be the same
and area must depend only on the shape of the surface, but not on its position and
orientation in space. This means that surface area is invariant under the group of
Euclidean motions. These properties uniquely characterize surface area for a wide class
of geometric surfaces called piecewise smooth. Such surfaces consist of finitely many
pieces that can be represented in the parametric form
One of the subtleties of surface area, as compared to arc length of curves, is that surface
area cannot be defined simply as the limit of areas of polyhedral shapes approximating a
given smooth surface. It was demonstrated by Hermann Schwarz that already for the
cylinder, different choices of approximating flat surfaces can lead to different limiting
values of the area.
Various approaches to general definition of surface area were developed in the late
nineteenth and the early twentieth century by Henri Lebesgue and Hermann Minkowski.
While for piecewise smooth surfaces there is a unique natural notion of surface area, if a
surface is very irregular, or rough, then it may not be possible to assign any area at all to
it. A typical example is given by a surface with spikes spread throughout in a dense
fashion. Many surfaces of this type occur in the theory of fractals. Extensions of the
notion of area which partially fulfill its function and may be defined even for very badly
irregular surfaces are studied in the geometric measure theory. A specific example of
such an extension is the Minkowski content of a surface.
Surface-area-to-volume ratio
The surface-area-to-volume ratio also called the surface-to-volume ratio and variously
denoted sa/vol or SA:V, is the amount of surface area per unit volume of an object or
collection of objects. The surface area to volume ratio is measured in units of inverse
distance. A cube with sides of length a will have a surface area of 6a2 and a volume of a3.
For a given shape, SA:V decreases linearly with increasing size. A cube 2 m on a side has
a ratio of 3 m−1, half that of a cube 1 m on a side. Conversely, preserving SA:V as size
increases requires changing to a less compact shape.
Physical chemistry
In involving a solid material, the surface area to volume ratio is an important factor for
the reactivity; that is, the rate at which the chemical reaction will proceed. Materials with
large surface area to volume ratios (e.g., very small diameter, or very porous or otherwise
not compact) react at much faster rates than monolithic materials, because more surface is
available to react. Examples include grain dust; while grain isn't typically flammable,
grain dust is explosive. Finely ground salt dissolves much more quickly than coarse salt.
High surface area to volume ratio provides a strong "driving force" to speed up
thermodynamic processes that minimize thermodynamic free energy.
Statistics
Statistics is the science of the collection, organization, and interpretation of data.[1][2] It
deals with all aspects of this, including the planning of data collection in terms of the
design of surveys and experiments.[1] Statistics is closely related to probability theory,
with which it is often grouped.
Scope
Statisticians improve the quality of data with the design of experiments and survey
sampling. Statistics also provides tools for prediction and forecasting using data and
statistical models. Statistics is applicable to a wide variety of academic disciplines,
including natural and social sciences, government, and business.
[edit] History
Main article: History of statistics
Some scholars pinpoint the origin of statistics to 1663, with the publication of Natural
and Political Observations upon the Bills of Mortality by John Graunt.[10] Early
applications of statistical thinking revolved around the needs of states to base policy on
demographic and economic data, hence its stat- etymology. The scope of the discipline of
statistics broadened in the early 19th century to include the collection and analysis of data
in general. Today, statistics is widely employed in government, business, and the natural
and social sciences.
Its mathematical foundations were laid in the 17th century with the development of
probability theory by Blaise Pascal and Pierre de Fermat. Probability theory arose from
the study of games of chance. The method of least squares was first described by Carl
Friedrich Gauss around 1794. The use of modern computers has expedited large-scale
statistical computation, and has also made possible new methods that are impractical to
perform manually.
Statistical methods
Experimental and observational studies