Professional Documents
Culture Documents
Introduction
A lot of chemicals are added to the process for cleaning and dyeing purposes.
Obviously the wastewater effluent from this unit contains considerable amounts
of hazardous pollutants, and where heavy metals are very common. In
Bangladesh most of the effluent from the textile industry is discharged untreated
into rivers. Today 20% of available river water in Bangladesh is polluted by
textile waste water
Water treatment is a very important step to change these conditions and to
achieve a sustainable situation. Bangladesh’s government has an awareness of
this and limits for water effluent quality exist. Unfortunately, this regulation is
not closely supervised and a lot of places do not follow the regulation.
Parameter Limit
PH 6-9
BOD < 50 PPM or mg/L
COD < 200 PPM or mg/L
TSS <100 PPM or mg/L
TDS < 2,500 PPM or mg/L
OIL & GREASE < 10 PPM or mg/L
COLOUR CLEAN
TEMPERATURE < 30 0C
Total suspended Solids (TSS): TSS is mainly organic in nature, are visible and
can be removed from the wastewater by physical/ mechanical means e.g.
screening and sedimentation. TSS is measured by filtering a certain quantity of
effluent and then drying the filtrate at certain temperature e.g. 1050C followed
by weighing. TSS is expressed as parts per million or in milligram/liter. The
pore size of the filter paper is very important in estimating the TSS, the nominal
pore size 1.58 micro metre.
Total Dissolved Solids (TDS): TDS are the solids that are actually in solution,
similar for example to mix sugar into hot coffee. Dissolved solids generally pass
through the system unaffected. TDS is the sum total of all of the dissolved
things in a given body of water. It is everything in the water that's not actually
water. It includes hardness, alkalinity, cyanuric acid, chlorides, bromides,
sulfates, silicates, and all manner of organic compounds. Every time we add
anything to the water, we are increasing its TDS. This includes not only
sanitizing and pH adjusting chemicals, but also conditioner, algaecides, and tile
and surface cleaners. TDS also includes airborne pollutants and bather waste as
well as dissolved minerals in the fill water. TDS is referred to as the total
amount of mobile charged ions, including minerals, salts or metals dissolved in
a given volume of water, and are expressed in units of mg per unit volume of
water (ppm).
List of some of the waste materials generated at each level of cotton textile
processing:
Process Air emissions Wastewater Residual wastes
Fiber Little or no air Little or no Fiber waste;
preparation emissions wastewater packaging waste;
generated generated hard waste.
Yarn spinning Little or no air Little or no Packaging waste;
emissions wastewater sized yarn; fiber
generated generated waste; cleaning
and processing
waste
Slashing/sizing Volatile organic BOD; COD; Fiber lint; yarn
compounds metals; cleaning waste; packaging
waste, size waste; unused
starch-based sizes
Weaving Little or no air Little or no Packaging waste;
emissions wastewater yarn and fabric
generated generated scraps; off-spec
fabric; used oil.
Knitting Little or no air Little or no Packaging waste;
emissions wastewater yarn and fabric
generated generated scraps; off-spec
fabric.
Tufting Little or no air Little or no Packaging waste;
emissions wastewater yarn and fabric
generated generated Scraps; off-spec
fabric.
Desizing Volatile organic BOD from water- Packaging waste;
compounds soluble sizes; fiber lint; yarn
from glycol ethers synthetic size; waste;
lubricants; cleaning
biocides; anti- materials, such as
static wipes, rags
compounds and filters;
cleaning and
maintenance
Wastes containing
solvents.
Scouring Volatile organic Disinfectants and Little or no
compounds insecticide residual waste
from glycol ethers residues; NaOH; generated.
and detergents;
scouring solvents fats; oils; pectin;
wax; knitting
lubricants; spin
finishes; spent
solvents
Bleaching Little or no air Hydrogen Little or no
emissions peroxide, sodium residual waste
generated silicate or organic generated.
stabilizer;
high pH
Singeing Small amounts of Little or no Little or no
exhaust wastewater residual waste
gasses from the generated generated.
burners.
Mercerizing Little or no air High pH; NaOH. Little or no
emissions residual waste
generated. generated.
Heat setting Volatilization of Little or no Little or no
spin finish agents wastewater residual waste
applied during generated. generated.
synthetic fiber
manufacture.
Dyeing Volatile organic Metals; salt; Little or no
compounds surfactants; residual waste
toxics; organic generated.
processing
assistance;
cationic materials;
color; BOD;
sulfide; acidity/
alkalinity; spent
solvents.
Printing Solvents, acetic Suspended solids; Little or no
acid from urea; residual waste
dyeing and curing solvents; color; generated
oven metals; heat;
emissions; BOD; foam
combustion
gasses; particulate
matter.
Finishing Volatile organic BOD; COD; Fabric scraps and
compounds; suspended solids trimmings;
contaminants in toxics; spent packaging waste.
purchased solvents.
chemicals;
formaldehyde
vapor; combustion
gasses;
particulate matter.
Product Little or no air Little or no Fabric scraps.
Fabrication emissions wastewater
generated generated
TYPES:
Lime
Reaction
Control
Tank
FeSo4
Polym Filter
er
Acid
Aeration tank
Water Discharge
E
f Equalization tank
f
l
u
e
n Blower
t
I Hydro
n extract
or
Primary Secondar
clarifier y clarifier
Sludge
tank2
Sludge
2
1. Detergent (non-ionic).
2. Anti creasing agent.
3. Hydrogen per oxide.
4. stabilizer
5. Caustic soda.
6. Soda ash.
7. Common salt
8. Glaubers’ salt
9. Washing off agent.
10.Acetic Acid.
11.Softener.
12.Anti foaming agent
13.Optical brightener.
14.Strong alkaline soap
Without these they use a lot of chemicals those vary due to order requirement.
They use two types of dyes; reactive dyes & disperse dyes. Dyes and chemicals
are soluble in water or in colloidal state. Some of suspended solid like wastages
are also flow with raw effluent. They are mainly cotton fibers’ flocks or the
yarn. The raw color of effluent is brown/ blue / black. All the liquors are
coming through same drain of wet processing unit. So washing liquor, dye
liquor, soaping liquor, scouring liquor, acid liquor all are getting mixture from
the very beginning. The temperature, pH, BOD & COD of raw effluent liquor is
given in the following table. In Bangladesh basically these four criteria are
controlled for textile effluent.
Sl CHEMICAL CHARACTERISTICS
NO
PARAMETERS UNIT AMOUNT
1. pH 11.8
2. Suspended solids mg/L 378.8
3. Biological Oxygen mg/L 416
Demand(BOD)
4. Chemical Oxygen mg/L 850
Demand(COD)
PHYSICAL CHARECTERISTICS
5. Color Brown to black
6. Odour Not distinct
7. Temperature 65
Screening:
The effluent from the dyeing and finishing is first drained into the screening
chamber. This chamber performs few physical filtrations. There is a series of
netted filters positioned serially. For removing solid particles including
suspended solids, yarn, fibers flocks, thickeners, etc, this process is important.
After passing through these filters the effluent is free from solid bodies.
This chamber has a capability to keep the flowing effluent for two minutes as it
has a volume of 2 cubic meters. The very first netted filter is made of M.S.Bar
rod which is then followed by the second filter made of the same material
having a hole of 4 square centimeter and the last but not the list is a filter made
of stainless still having five holes per square centimeter.
Collection/Equalization Tank:
Here collection tank is nothing but the proper mixing of effluents of different
types. It’s a rectangular tank of 20 m diameter and 2.5 meter surface water
depth. So the volume effluent carrying is 800.75 cubic meter. Effluent is treated
here for 10 hour 40 minutes. Here effluent without suspended solid and oil is
mixed with air by means blower. Air is filtered first and then blows air at 1260
m3 per hour. 585 diffusers are used to supply air to the effluent for treatment.
Here dissolved oxygen of water is increased by the air. The dissolved oxygen’s
quantity is increasing to meet the Chemical oxygen demand by the effluent. 3
blowers are used to blow air for 16 hours continuously. And each blower is
keeping working off for 8 hours. So 2 blowers of 50 kw/ hr are blowing air to
the collection tank. After mixing properly effluent is allowed to pump to
reaction tank.
Equalization tank
Reaction tank:
Effluent from the collection tank is directly passes to reaction tank for treating
with chemicals used in physico-chemical process. In reaction tank the main
chemistry of physico-chemical method for effluent treating is involved. It bears
maximum maintenance cost for the treatment. This is a highlighted demerit for
this method.
Primary clarifier:
Primary clarifier is used to sediment sludge and discharge clear water without
color. As we discussed above that coagulation and flocculation removed all
polis used to sediment sludge and discharge clear water without color. As we
discussed above that coagulation and flocculation removed the toxic elements
from here the crystal clear water is formed but it is alkaline. Here 2 chambers
are used as primary clarifier. Each chamber is allowed to keep 105.625 cubic
meter of effluent. And effluent’s treatment duration is about 2 hour 49 minutes.
Picture: X-section of primary clarifier and the surface primary clarifier.
Aeration tank:
Diffusers are kept at bottom of the tank floor. Blower takes air from atmosphere
and then it passes though pipe to the diffusers. Then diffusers supply air as well
as oxygen to the effluent. These blowers possesses the 25% cost of the plan.
Blowers are highly stronger than the normal. These blowers are micro chipped
program with the reader JUMO GMBH (it is a dissolve oxygen reader). When
the dissolved oxygen comes up to 7.6 mg/L then the inverter of blowers’ motor
worked to reduce rpm of blower.
These are the description of plan for aeration tank. Now the question how does
the function of air? This aeration does nothing but increase the quantity of
dissolve oxygen. 4700cubic meter effluent is treated here for 47 hours, it’s a
huge time. During this time oxidative chemicals are liked to fill up their oxygen
demand from the water. That’s why increasing amount of dissolved oxygen is
required to meet the demand. Without this the aquatic life in this tank ie,
bacteria demands oxygen which is also filled up by this dissolved oxygen.
These are all about air, at aeration tank. During aeration bacteria is also
involved to degrade effluents. Next chemical reactions will describe better.
.Secondary clarifier:
Picture: Secondary clarifier
Filtration: In filters, such as Pressure Sand Filter (PSF), the filtered waste
water has to be regularly checked for quality (such as total suspended solids,
trace elements, and residual chlorine) so that backwashing can be affected at the
right time. Since regular sampling and analysis may not be possible in a large
treatment facility, backwashing is automated with regular time intervals when
the filtration flow is expected to decrease to a certain level. The chosen time
interval for backwash operation is normally fixed arbitrarily based on the
experience and expertise of the plant operator. Choosing an arbitrary backwash
interval may not be a perfect decision. It is possible that the planned time
interval for backwash operation may either be longer or, shorter than it is
actually necessary in most of the cases – as the feed quality and the condition of
the treatment unit changes continuously. If frequent backwash is carried out, it
may increase the downtime and reduce overall treatment capacity. Since
backwash operation is normally conducted with water recovered from the
reverse osmosis system down the line, frequent backwash can also result in
overall decrease in the output of reusable water. Instead, if the backwash is
delayed, it may reduce the operating capacity and filter efficiency. Thus, it is
vital to optimize the filters for better performance to increase operating
efficiency and reduce the maintenance cost.
Picture of filter
Outlet water:
Outlet water is colorless and odourless. Before draining the ETP water pH
should be controlled in at range of 6-9.
Picture of outlet water
Sludge tank:
In sludge tank there is a sand filtration system in which 2 feet of sand layer is
kept and above that sand sludge is deposited. At the ground of tank there is a
pipe arrangement with filtration which allows effluent without sludge passing to
the collection tank. This is again treated.
Hydro extractor:
Bangladesh Quality
S Effluent Quality Concentratio Concentratio Standard at Discharge
L parameters n n Public
N present in present in Inland Swear at Irrigat
O raw effluent treated surface secondar ed
. effluent water y land
treatmen
t plant
mg/L (WASA
) mg/L
mg/L mg/L
mg/L
Biological
2 Oxygen Demand 450 45 50 250 100
(BOD)
3 Chemical Oxygen
Demand (COD) 750 180 200 400 400
4 Time 50 hours
Costing:
Costing is a secret thing that did not provide me of authority of Alliance Knit
Composite Ltd. They have provided me approximately cost of ETP that is
tk10000 for 720 m3. So per m3 cost is approximately tk1.39.
1. This process posses a very low fixed cost which is around 80, 00,000 tk.
2. Discharge effluent is colorless.
3. Effluent is 100% pollutant free.
4. Non-biodegradable chemicals can treat here.
5. Its maintenance does not demand highly skill professionals.
6. It is applicable from all kinds of textile industries.
7. It is very simple in technology.
8. Dyer does not need to select chemicals with respect to its effluent
treatment.
9. It occupies minimal spaces around 15 kathas.
10. It possesses less treatment duration rather than biological treatment
method which is around 50hours.
1. Treatment cost is very high around 12.92 tk per cubic meter. Cost will
be equivalent with its fixed cost within 396 days (14 months) from its
installation. Economically it brings loss.
2. This method is not that much modernized.
3. It is chemical based for this reason treatment efficiency is highly
depended on its chemicals strength.
P : Pump