Sri Chaitanya Paper2

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Super 10
IIT - JEE 2010
Mock Test 1
Paper - 2
SOLUTIONS
General Instructions : Max. Marks : 285

Sectoion - I contains 5 Questions each carries 3 Marks for Wrong attempted Question –1 mark will be deducted
Sectoion - II contains 5 Questions each carries 4 Marks for Wrong attempted Question –1 mark will be deducted
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Sectoion - III contains 6 Questions each carries 4 Marks for Wrong attempted Question –1 mark will be deducted
Sectoion - IV contains 2 Questions each carries 8 Marks for Wrong attempted Question 0 mark will be deducted
Sectoion - V contains 5 Questions each carries 4 Marks for Wrong attempted Question -1 mark will be deducted
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About your Institute : g.
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Sri Chaitanya IIT Academy., India
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Asia’s largest Educational Institution

________________________________________________________________________
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Inception – 1986
Ø 23 years of impeccable track record at the 10 + 2 level.
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Ø More than 150 branches across Andhra Pradesh spanning 17 districts and 7 states across the Republic of India.
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Ø Un-challenged leader in Intermediate Education offering integrated coaching for IIT-JEE, AIEEE, AFMC, AIIMS,
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BITSAT etc.
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Ø Scaling new heights and setting unparalleled bench marks with concept based academic programmes to crack
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national level entrance examinations:

• ICON for IIT-JEE
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• NEON for AIEEE / NIT / BITSAT

• MEDICON for AFMC / AIIMS / JIPMER
Ø Customised practice / study material ensuring top and seat securing ranks to the average student to strep into
India’s premier professional colleges at the national level – IITs, NITs, AFMC, AIIMS, BITS etc.
Ø Matchless performance in IIT-JEE – 2008 & 2009
• All India 1st and 3rd ranks (OBC)
• All India 7th rank (Gen. Cat.)
• A Record 854 seats in IIT-JEE – 2008
• 32 ranks below 100 (under all categories) in 2009
• Created History with 1024 ranks in IIT-JEE 2009
Sri Chaitanya IIT Academy

Campus
Address : Sri Chaitanya IIT Academy.,A.P.

ICON Central Office - Madhapur - Hyd
Ph No : 040-64566177 Email : madhapuripl@srichaitanya.net
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Mock Test 1 Campus /Pg 2
# P-2 CHEMISTRY - SOLUTIONS :
1. Iodine exists in +30.5 basic properties of I2
O
I2 + CH3 C HNO3
O I(CH3COO)3
CH3 C
O
2. K2 MnO 4 + CO2 → KMnO4 + MnO2 + K2CO2
OH
om
OH
CHO O O
CH 3 − C −O −O − CH 3
 →  →
c
3. CHCl 3 / NaOH
CH COONa
g.
3
A
ng
O OH O O
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C=O
CH=CH
.m
A
w
4. Millimoles of NH3 = 100 x 0.05 = 5 mmoles

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Added HCl = 10 x 1.0M = 10 mmoles

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NH3 gets completely neutralised, solution turns acidic that is now not the buffer solution
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CH 3
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CH 3 − CH 2 − CH −CH 2 − CH 3 
Cl 2 / hv
→ Cl − CH 2 − CH 2 − CHCH 2 − CH 3 ( 2 active isomers − 1 pair )
*
+
Cl
*
CH 3 − CH − CH − CH 2 − CH 3 (2 chiral centres - 2 pairs)
*
CH 3
+ Cl
CH 5 − CH 2 − C − C H 2 CH 3
CH 3
+
C H 2 Cl
CH 3 − CH 2 − C H − C H 2C H 3
5.
Mock Test 1 Sri Chaitanya IIT Academy /Pg 3

Campus
6. H3 BO3; H3 PO2 & HPO3 → are monobasic
OH OH
H2O
B B + H+
a) HO OH HO OH
OH
H H
HO - P
b) H - P - OH d) HO - P = O
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c)
O OH
O
c
7. a) N(CH3 )3 - pyrmidal
g.
ng
Cl Cl
Cl
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I I planar
b)
Cl Cl Cl
.m
w
F
c) F B planar
w
F
w
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Cl Cl
d) B B planar
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Cl Cl
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8. ∆E = q − W ; work done = 0 ; Heat is given out = –q. Temperature falls, thus the internal energy decreases.
9. k1 = k2
2
⇒ rd of A has reacted for [A] = [C] = [D]
3
1 [ A]0
k1 + k2 = ln
t 1 A
∴ [ ]0
3
1 1 1
⇒t = ln 3 = ln 3 = ln 3
k1 + k3 2k1 2 k2

10. Ans : ABD
11. Ans : C
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g.
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12. Ans : B
Three dimensional gas equation pV = nRT
.m
Now, n, R and T are independent of length and the two dimensional equivalent for pressure(p) would be surface
pressure ( π ) and the two dimensional equivalent for volume (V) would be area (A)
w
w
π A = nRT
w
nRT 0.0158 × 8.314 × 293

For surface pressure, π = =
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A 2020
tp
ht
= 0.019Nm–2
13. Ans : A
The pressure of Franklin's film is much higher than the pressure at which the acid sublimes (2D-solid to 2D-gas
transition). Therefore, Franklin's film can be considered a 'solid'.
+
14. →H+ → →
OH OH OH +
OH OH
+
-H+

Campus
O CH3 CH3 CH3 CH3

Mg/Hg H+
15. Ph - C - CH3 Ph - C - C - Ph Ph - C - C - Ph
Hydrolysis -H2O +
OH OH OH
CH3
+
CH3 - C - C - Ph
OH Ph
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O CH3 CH3
CH3 - C - C - Ph CH3 - C - C - Ph
c
-H+
g.
Ph OH Ph
+
ng
ye
Cl
Cl Cl Cl Cl
.m
w
16. H+ +
C X Ph C C Cl
w
C C C
+
OH OH OH
w
Ph OH
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tp
ht
Cl Cl
Ph - C - C - Ph Ph - C - C - Ph - CH
-H+
Ph Ph O 10
+

[CO(NH3)6]3+
eg
17. A)
t2g
CFSE > P.E
∆0
[COF6]-3
eg
B) CFSE < P.I t2g paramagnetic
∆0
om
[Fe(OX) 3]-3 eg
c
C) t2g paramagnetic
∆0< P.E
g.
ng
optically active non-super imposable mirror images
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O O
O O
.m
O O
Fe Fe
w
O O O O
w
O O
w
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[Cr(H2O) 2 (en) 2 (NH3)2] +3

tp
eg
3d 4s 4p
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d)
t2g
d2 sp3 hybridisation innter optical complex

paramagnetic
NH 3
NH 3
N H3 H 2O
en Cr en Cr
H2O H 2O CiS form is optically active
H 2O H 2O
C iS trans
geometrical isomerism

Campus
18. Ans : A - p,r,s B - r, C - p,r,s D - q,r
Solution 'A' & 'C' is non ideal solution is positive deviation so ∆H & ∆V is will be positive and ∆S for
dissolution is always positive irrespective of the ideality & non-ideality in behaviour.
Solution B is ideal so only ∆S is positive solution 'D' is showing negative deviation so ∆H is negative
19. NO neutral molecule denotes 3 electrons
20. 3 chiral centres are present
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21. HO SH . In this compound no.of acidic are four..
c
N
g.
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H
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22. Ans : 6
.m
23. Ans : 2
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# P-2 PHYSICS- SOLUTIONS :

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24. Solution : ANS : B

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Let the vertical through C, the middle point of the rod, meet the horizontal line through B in the point D and let
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the weight of the rod be W.

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There are only three force acting on the rod, viz., the force F, the weight W, and the unknown reaction, P, of the
hinge.
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These three forces must therefore meet in a point.

Now F and W meet at D ; hence the direction of the action at the hinge must be the line DA.
Draw AE perpendicular to EB, and let the angle ADE be q.
AE 2 AE
Then tan q = = = 2tan600 = 2 3.
ED EB
also, by Lami’s Theorem,
F W P
i.e., = =
sin(90 + q ) sin(180 - q ) sin90 0
0 0
cos q W W
\ F =W = W cot q = = 3,
sin q 2 3 6

1 13
and P = W = W 1 + cot 2 q = W .
sin q 12
25. Solution : ANS : B
10 - F1 = 2 x 2
F1 = 6 N ® (1)
Since the motion of rod is translatary net moment of force about centre of mass rod is zero. Let ‘C’ be the
centre rod..
ælö æl ö
F1 çç ÷÷÷ = F2 çç - a÷÷÷
çè 2 ø çè 2 ø
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6l 10 l
= - 200
2 2
c
g.
4l
200 =
2
ng
l = 100 cm .
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26. ANS : D
.m
a
(a)
a
w
T
Case (i) T
w
B
w
T A R
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R
N
tp
40kg 20kg
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Equation of motion for A :

T - R = 40a ® (1)
Equation of motion for B :
20 g -T = 20a ® ( 2)
R = 20a ® (3)
(1) + (2) + (3)
Þ 20 g = 80a
on a = g 4

Campus
g
\ Net acceleration of B is a 2 =
2 2
Case (ii)
T T
T B
A
N
40kg 20kg
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Equation of motion for A :
T = 40a | ® ( 4)
c
Equation of motion for B:
g.
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20 g -T = 20a| ® (5)
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(4) + (5)
20 g = 60a|
.m
Þ a| = g / 3
w
w
g
\ ratio is 2 2= 3
w
g /3 2 2
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tp
27.
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360
w.r.t the man, Sun turns through = 600 in 4 hours.
6
From Snell’s law at P,
2
(1) sin 90 = mw sin60 Þ mw = .
3
28 Ans : A
∴ Motional emf will be induced across both PQ & DC
Integrating p.d. across dx ⇒
2a  µ0i0 
∫ de = ∫ a   dx (velocity)
 2π x 
c om
g.
ng
ye
.m
V µ0i0
eDC =
w
ln2 with D at higher potential

2π
w
2V µ 0 i0
ePQ =
w
2π ln2 with P at higher potential

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Relative velocity of the rod PQ w.r.t. u frame Vrel = 2V − V = V

tp
l
Time taken by it to loose contact with the frame t =
ht
V
From equivalent electric network
Net emf in the closed loop QPDC

Campus
V µ 0 i0
e = e PQ − eDC = ln 2
2π
Growth of current in the LR circuit is given by
e
i = i0 (1 − e − tR / L ) =   (1 − e −tR / L )
R
l e
At t = , i =   (1 − e−lR / LV )
V R
v m0 i0 - lR
i= ln 2 1-e Lv
2p R
omc
g.
ng
ye
.m
w
w
w
://
tp
ht

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General Instructions : Max. Marks : 285

Asia’s largest Educational Institution

national level entrance examinations:

• NEON for AIEEE / NIT / BITSAT

Sri Chaitanya IIT Academy

Address : Sri Chaitanya IIT Academy.,A.P.

Sri Chaitanya IIT Academy

2. K2 MnO 4 + CO2 → KMnO4 + MnO2 + K2CO2

4. Millimoles of NH3 = 100 x 0.05 = 5 mmoles

Added HCl = 10 x 1.0M = 10 mmoles

Mock Test 1 Sri Chaitanya IIT Academy /Pg 3

6. H3 BO3; H3 PO2 & HPO3 → are monobasic

Sri Chaitanya IIT Academy

nRT 0.0158 × 8.314 × 293

Mock Test 1 Sri Chaitanya IIT Academy /Pg 5

O CH3 CH3 CH3 CH3

Sri Chaitanya IIT Academy

CFSE > P.E

[Cr(H2O) 2 (en) 2 (NH3)2] +3

d2 sp3 hybridisation innter optical complex

Mock Test 1 Sri Chaitanya IIT Academy /Pg 7

# P-2 PHYSICS- SOLUTIONS :

24. Solution : ANS : B

the weight of the rod be W.

These three forces must therefore meet in a point.

Sri Chaitanya IIT Academy

Equation of motion for A :

Mock Test 1 Sri Chaitanya IIT Academy /Pg 9

Sri Chaitanya IIT Academy

ln2 with D at higher potential

2π ln2 with P at higher potential

Relative velocity of the rod PQ w.r.t. u frame Vrel = 2V − V = V

Mock Test 1 Sri Chaitanya IIT Academy /Pg 11

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