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KEMA Power Generation & Sustainables, P.O. Box 9035, NL 6800 ET Arnhem, the
Netherlands, telephone +31-26-3562225, fax +31-26-4453659, e-mail: r.meij@kema.nl
KEYWORDS: leaching, field tests, laboratory tests, diffusion test, availability test, bricks,
concrete, hydrology, coal fly ash
SUMMARY
In the Netherlands building materials must comply with leaching limits as laid down in the
Buildings Materials Decree. The leaching behaviour of the building materials has to be
determined by standardised tests at the laboratory. The results of these tests are used as
input in formulas that calculate the cumulative emissions over 100 years. The question
arises whether this approach is a good prediction of what will happen in the field. At
KEMA a major research item is to investigate leaching behaviour under field conditions.
This paper presents the results of field leaching of two types of bricks for five and a half
years and of concrete for two years. For these three types of building material two forms
are tested, one ordinary form and one in which 20% coal fly ash (CFA) is used. The
results are compared between the different types of clay, between materials with and
without CFA and between prolonged field tests and brief laboratory leaching tests.
The use of CFA as a raw material in bricks and concrete increases the leaching of As, Mo
and sulphate. Vanadium also shows this increase of leaching in bricks, but not in
concrete. The effect of using CFA in one type of brick is that the Cr leaching increases,
while in another type of brick and in concrete it decreases. In all cases and for all
elements the leaching stays well below the limits as laid down in the Building Materials
Decree, so CFA can well be used in building materials without contaminating the soil or
surface water.
Compared to the 5½ years field test, the extrapolation of the diffusion test to 5½ years
gives a reasonable prediction of the leaching of molybdenum and vanadium; however,
the diffusion test overestimates the leaching of arsenic and barium and it underestimates
the leaching of chromium and sulphate.
Field leaching behaviour of
building materials
ý Introduction
ý Conclusions
Arnhem
t •Ni
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Lexington, Kentucky * October 22-24 2001 International Ash Utilisation Symposium 6
Characteristics of the various leaching
tests for unmoulded materials
type of leaching Dutch column Dutch cascade EPA test 1) Dutch availability
test test test test
Ical.(Y) = Edif(64d)·fext,v(h,x%,De)·ftem
Ical.(Y) = calculated immissions after Y years in mg.m-2
18
bronze fired
16
bronze fired + PFA
14
red fired
mg/kg (g/kg SO4)
10
As Ba Cr M o V SO4
red fired
red fired + PFA
60
mortal
50
40
30
20
10
As Ba Cr Mo V SO4
B bronze+CFA
5
C red
3
D red+CFA
0
0 50 100 150 200 250 300 F red hollow
weeks
As Mo
diffusion in mg/m2 8
diffusion in mg/m2
Cumulative
20
10
Field
3
leaching of
0 0
1 100
Ba
bricks
V
A bronze
1 75
diffusion in mg/m2
diffusion in mg/m2
B bronze+CFA
in 5½
1 C red 50
D red+CFA
years
0 25
F red hollow
under field
0 0
30 30
Cr S O 4 2-
conditions
25
diffusion in mg/m2
diffusion in g/m2
20 20
15
10 10
0 0
0 50 100 150 200 250 300 weeks 0 50 100 150 200 250 300
B
20 bronze
+CFA
C red
10
D
red+CF
A
0 F red
0 50 100 150 200 250 300 hollow
weeks
As
field leaching in %
of availability test
1,0%
0,5%
0,0%
0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70
L/S in l/kg
As
25 25%
Mo
field leaching in % of 20%
field leaching in % of
Cumulative
availability test
availability test
1,0%
15%
10%
0,5%
Field
5%
0,0% 0%
leaching of
0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70
0.2 0,2%
Ba A bronze
15
15%
bricks
field leaching in % of
0,2% B bronze+CFA
field leaching in % of
availability test
availability test
C red 10%
0,1%
D red+CFA
in 5½
F hollow+CFA 5%
0,1%
years
0,0%
0%
0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70
0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70
120
under field
120% 100%
Cr 100 SO4
2-
field leaching in % of
field leaching in % of
75%
availability test
availability test
conditions
80%
50%
40%
25%
0% 0%
0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70
L/S in l/kg L/S in l/kg
Mo
cumulative diffusion in mg/m2
0,2
0,1 G concrete
H concrete+CFA
0,0
0 20 40 60 80 100 120
weeks
As V
cumulative diffusion in mg/m2
2,5
Field
0,1
G Concrete
G concrete
H concrete+CFA 1,3
H concrete+CFA
leaching of
0,0 0,0
6,0 2,0
S O 4-2
concrete
Cr
1,5
4,0
in 2 years
G concrete
1,0
H concrete+CFA
`
2,0 G concrete
0,5 H concrete+CFA
0,0
0,3
0,0
0 20 40
w e6e0k s 80 100 120 under field
cumulative diffusion in mg/m2
conditions
Mo
0,2
G concrete
0,1
H concrete+CFA
0,0
0 20 40 w e6e0k s 80 100 120
1400%
1200%
1000% As
800% Ba
Cr
600%
Mo
400% V
200% SO4
0% V
A Cr
B + F+
As
C
D+
200%
180%
160%
140% As
120% Ba
100% Cr
80% Mo
60%
V
40%
SO4
20%
0% V
A Cr
B + F+
As
C
D+