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4.
Find
the
pH
during
the
titration
of
20.00
mL
of
0.1000
M
formic
acid,
HCOOH
(K !
=
1.8
x
10-‐4),
with
0.1000
M
NaOH
solution
after
the
following
additions
of
titrant
(NaOH):
(a) 0
mL
[2.37]
(b) 10.00
mL
[3.74]
(c) 15.00
mL
[4.22]
(d) 19.00
mL
[5.02]
(e) 19.95
mL
[6.34]
(f) 20.00
mL
[8.22]
(g) 20.05
mL
[10.10]
(h) 25.00
mL
[12.05]
Now,
sketch
the
graph
pH
vs.
volume
of
NaOH
added
(in
mL)
and
identify
the
following
points
on
the
graph:
(a) pH
when
the
[HCOOH]
=
[HCOO! ]
called
the
“half-‐equivalence”
point
[3.74]
(b) pH
at
the
equivalence
point
[8.22]
What
indicator
would
be
most
suitable
for
this
titration
(See
Fig.
19.9
on
p.
861)?