Professional Documents
Culture Documents
MARLIES TEICHM(~LLER
Geologisches Landesamt Nordrhein- Westfalen, de Greiff Str. 195, 4150 Krefeld, F.R. Germany
(Received June 15, 1988; revised and accepted September 26, 1988)
ABSTRACT
Teichmfiller, M., 1989. The genesis of coal from the viewpoint of coal petrology. In: P.C. Lyons
and B. Alperu (Editors), Peat and Coal: Origin, Facies, and Depositional Models. Int. J. Coal
Geol., 12: 1-87.
The genesis of the microscopic constituents of coal (macerals) and of maceral associations
(microlithotypes) representing various coal facies is discussed in the light of recent advances that
have been made in the study of coals and modern peats. Peat microscopy especially promoted the
understanding of humification and biological gelification, both of which are decisive for the gen-
esis of huminites/vitrinites in brown coals and hard coals, respectively. Microbial activity during
peatification has been documented by chemists, microbiologists and petrologists and, recently, by
electron-microscopical observations in coals. This activity leads to the incorporation of lipid sub-
stances into the humic matter and, later, influences the chemical, physical and technological prop-
erties of vitrinites. Geochemical gelification transforms the huminites of brown coals into the
vitrinites of.bituminous coals and is probably caused by the onset of bitumen generation in coal.
In this process, the hydrogel brown coal is transformed to the bitumogel bituminous coal. Coal as
a source rock for oil has become an important research subject for coal petrologists and oil explo-
ration. The formation of more or less liquid bitumen and its later cracking to gaseous hydrocarbons
leads to the "coalification jumps" of the macerals, especially liptinites and vitrinites and to the
generation of secondary macerals like exsudatinite (bitumen) and micrinite (dead carbon). Bi-
tuminization in coal has been revealed by the use of fluorescence microscopy which also found the
presence of new liptinite macerals (bituminite, fluorinite and exsudatinite) and suggests a higher
proportion of algal material in coals than was thought earlier. The genesis of various types of
inertinite macerals will probably become an increasingly important subject of research, especially
with regard to "rank-inertinites" that seem to attain their high inertinitic reflectance initially
during coalification.
Besides the origin of macerals, the origin of various coal facies in terms of maceral associations
is considered in relation to the palaeogeographic depositional milieu, the peat-forming vegetation,
palaeoclimate, water and nutrient supply, acidity, marine and calcareous influence and fire, with
examples from Euramerican Carboniferous coals, Gondwana coals, and Tertiary brown coals. Veg-
etation, water and oxygen supply (Eh-conditions) are most important for the generation of coal
facies.
Vegetation has been reconstructed with the help of palaeobotany, including palynology, cutic-
INTRODUCTION
Coal is a rock derived mainly from plant remains that suffered peatification
and coalification. Due to a relatively good preservation and the possibility of
comparing plant remains with modern plants, it is easier to reconstruct coal-
forming vegetation in peats and brown coals than in bituminous or hard coals.
To understand the genesis of coal constituents, the application of combined
botanical and coal petrological methods has been most effective. Such studies
have been carried out in the past on hard coals, among others, by Thiessen and
White (1913), Stopes (1919), Thiessen (1920), Seyler (1928), Hickling and
Marshall (1932, 1933), Thiessen and Sprunk (1941), Teichmiiller (1952),
Hoehne (1954), Teichmiiller and Schonefeld (1955), Kosanke and Harrison
(1957) and, recently, by Phillips et al. (1985) and Winston (1986). These
authors studied the microscopic appearance of botanically identified, coalified
plant remains, occurring either in clastic rocks or in coal seams, or they traced
plant fossils from petrified peats in coal balls into the coal seam.
Another relatively small group applied "cuticular analysis" (Jurasky, 1934/
1935 ) to identify the epiderms of leaves that contributed to peat formation in
Tertiary brown coals (Weyland, 1956; Benda, 1960; Kilpper, 1960; Schneider,
1980). Many authors used palynological methods to draw conclusions from
spores and pollen occurring in coals to the peat-forming vegetation (e.g.,
Thomson, 1950/1951; Hunger, 1955; Smith, 1962, 1968; Hacquebard and Don-
aldson, 1969; Von der Brelie and Wolf, 1981a,b; Sontag and Schneider, 1982;
Bartram, 1987). Most important and effective were microscopic studies of
modern peats in relation to coal genesis (Koch, 1966, 1969b, 1970a; Cohen,
1968, 1973, 1974; Cohen and Spackman, 1977, 1980; Cohen et al., 1987; Styan
and Bustin 1983a,b). Besides botany and peat microscopy, the study of mineral
occurrence (e.g., pyrite, clay partings ) in coal seams, chemical analyses of iso-
lated coal constituents as well as the comparison of "coal facies" with the sed-
imentology of accompanying rocks helped to clarify problems of coal genesis.
From the viewpoint of coal petrology, the genesis of coal is primarily the
genesis of macerals, microlithotypes, and lithotypes. Macerals are the most
uniform microscopical constituents of coal and are comparable with minerals
in other rocks. Microlithotypes are typical maceral associations that can be
identified under the microscope, and lithotypes are layers of coal seams which
can be distinguished with the naked eye. After a short survey of the genesis of
macerals, including most important changes during peatification and coalifi-
cation, the genesis of hard-coal microlithotypes and lithotypes and the much
discussed origin of brown-coal lithotypes will be considered, thereby mainly
introducing results that are not yet included in the Textbook of Coal Petrology
(Stach et al., 1982 ).
1 ORIGINOF MACERALS
Besides the parent plant material and the initial decomposition before and
during the peat stage, the degree of coalification (=rank) is decisive for the
microscopic appearance of macerals. Morphology and reflectance under inci-
dent light are the main properties to distinguish macerals and maceral groups
under the microscope (Table 1 ). In low-rank coals, the relatively hydrogen-
rich liptinites show the lowest reflectance, the relatively oxygen-rich vitrinites
a medium reflectance, and the relatively carbon-rich inertinites the highest
reflectance. In the stage of low-volatile bituminous coals, vitrinite reflectance
is surpassed by liptinite reflectance (Fig. 1 ) and at the meta-anthracite stage
vitrinite and (former) liptinite reflectances surpass the reflectance of inertin-
ites (Alpern and Lemos de Sousa, 1970).
Whereas liptinite and inertinite macerals have the same names in brown
coals and hard coals, the precursors of vitrinites in the brown-coal stage are
the huminites, which are much more differentiated than the vitrinites (Table
2).
4
TABLE 1
25
20
X
0O
El5
10
05
0 05 10 15 20
% Rmax vitrinite
volatile yield (wt. %)
60 50 40 30 20 12
I I, I i I I I I
70 80 85 90
carbon ( w t %)
Fig. 1. Coalification tracks of the three maceral groups. Modified after Smith and Cook (1980).
Rmax = mean maximum reflectance; wt. = weight.
al. (1985) found in peats of the Okefenokee Swamp that cellulose decreases
from 16% (of the total organic matter) at the peat surface to less than 1% at
a depth of 2 m, and that the microbial activity is high at the peat surface but
by 15 to 20 cm depth is already very low. With increasing depth, fungal and
aerobic bacterial activity is replaced by anaerobic bacterial activity. According
to Belyaev et al. (1981), quoted in Given and Miller (1985), for example, the
bacterium Clostridium sp. ferments cellulose under anaerobic conditions and
converts it to lower fatty acids. Nevertheless, small parts of both cellulose and
lignin are still present in soft brown coals (Teichmiiller and Thomson 1958)~
Hatcher et al. (1981) even found 75% lignin and 25% cellulose in a piece of
wood embedded in a Miocene brown coal. Bacterial substances including pro-
teins and fats, as well as the metabolic products of bacteria and fungi, enter
the humification process in addition to lignin, cellulose and tannins. They rep-
resent the lipid parent material of huminites (and vitrinites) (cf. Taylor and
Liu, 1987). The same is valid for algae that have become structurally wholly
TABLE 2
Correlation of the huminite macerals of brown coal with the vitrinite macerals of hard coals (after Alpern and Teichmfiller, 1971, and International
Handbook of Coal Petrography 1971, 1975)
Maceral Maceral Maceral Maceral Type Maceral Maceral Type Maceral Maceral
Group Subgroup Variety group
Textinite A (dark)
B (bright)
A
Humotelinite Texto-Ulminite Telinite 1
B
Ulminite Telinite
A
Eu-Ulminite Telinite 2
B
I ign in o
i
C6- C3- compounds
I deco m . " ~
position
I
C6- Cl - c om p ounds I polymerisates
oliphotic
Y i polymeri - ;
1
decomposition.
compounds i sates I
I
1
energy metabo-
I
i
I
I
decompo -~
:
i
I
lism of m i c r o - i sition i
\ ; organisms f t
÷ N - c o n l o i n i n g compounds derived f r o m the
\ decomposition of proteins /
V
humic substances
humic acids
I
decomposition
Fig. 2. Scheme of the chemical reactions during humification. From Flaig (1965).
reports that the native, non-lignified cell wall fluoresces blue (under UV-light
and that, after lignification, the colour can change to greenish or yellowish.
However, after solution of all other substances, the pure lignin lacks fluores-
cence. On the other hand, Frey-Wyssling ( 1959, p. 280) in his book "The plant
cell wall" states that lignin fluoresces weakly with a blue colour, whereas "cel-
lulose and chitin transmit ultraviolet light and, therefore, are not fluorescent"
(the latter statement is suspect since incident light was not used for excitation ).
Koch (1969b) distinguished in thin sections of peat five stages of cell-wall
humification, the latest stages (IV and V) representing the beginning and
completion, respectively, of so-called biochemical gelification. Stage V is char-
acterized by a dark brown colour, total loss of cell structure, and homogeniza-
tion to a pure gel with dessication cracks, all typical of telogelinites.
In a recent paper, Stout and Spackman (1987), likewise, described micro-
scopic changes of ligno-cellulosic cell walls in peats, the changes not being
influenced by increasing depth of burial. They differentiated the four stages:
(1) "alteration"; (2) "degradation"; (3) "humification"; and (4) "gelifica-
tion". Their "humification" (as stage 3) is understood as a stage of structural
decomposition. Therefore, it is not comparable with the chemical and micro~
bial process that normally is named humification. The latest stage (4) of Stout
and Spackman (1987) is characterized by a slight swelling of cell walls and the
beginning of porigelinite formation. It corresponds to the very beginning of
what normally is called "biochemical gelification".
The chemical genesis of huminitic cell walls has been studied recently by
Stout et al. (1987) using Curie-point pyrolysis-mass spectrometry and pyrol-
ysis-gas chromatography/mass spectrometry methods. The main processes are:
( 1 ) a rapid decrease of hemicellulose; (2) the introduction of fungal carbohy-
drates; (3) biochemical depolymerization of cellulose; (4) biological demeth-
ylation, demethoxylation and further defunctionalization of lignin; and (5)
"additional geochemical transformation of lignin leading to a predominantly
aromatic hydrocarbon network". The authors assume that the loss of hemi-
cellulose and cellulose during peatification promotes an early gelification
(known as "geochemical gelification") due to a disruption of the crystalline
framework and the resulting homogenization of the cell wall.
The humotelinites are subdivided into textinites (not gelified) and the + gel-
ified ulminites (Plate I-1 ) of brown coals. Textinite A is distinguished by a
very low reflectance which, for its part, may be caused by relics of cellulose (cf.
Plate III-6) and/or by resinous impregnations in the cell wall. According to
Jurasky (1940, p. 68) impregnations of cell walls with resin are restricted to
coniferous woods. Russel and Barron (1984) concluded that "the principal
cellulose-bearing submaceral appears to be textinite". Most textinites and tel-
inites in brown coals are derived from coniferous wood, whereas angiosper-
mous wood and the non-lignified tissues of herbaceous plants are structurally
more or less decomposed. Schneider (1984) gave an excellent survey of the
various humotelinites in Tertiary brown coals of Lusatia with many photo-
micrographs, according to their origin from wood ("xylo-textite"), bark ("per-
idermo-textite"), leaves ("phyllo-textite") and roots ("rhizo-textite"). In-
grown roots are especially well preserved in peats and coals because they were
protected from oxidation at the peat surface and often reached beneath the
peatigenic layer (cf. Plate II-1 and 7).
The successors of humotelinites after the geochemical gelification are the
telinites and telocoUinites of hard coals. Telinite is from cell walls and distin-
guished by its visibility within a cell structure, whereas telocollinite is struc-
tureless in incident light but may show the cell walls in thin sections or after
etching in incident light.
According to Raistrick and Marshall (1939, p. 182) the following cell struc-
tures could be identified in Carboniferous vitrinites on the basis of compari-
sons with botanically identified compressed plant remains overlying coal seams:
Bothrodendron bark, Lepidodendron bark, Sigillaria bark and gymnospermous
wood related to cordaites. In Mesozoic coals Cycadophyte wood was identified.
PLATE I
(Width of photomicrographs in parentheses)
1. Biochemical gelification of a piece of wood found in a layer of clay in the Miocene Rhenish
brown coal. The gelification is complete at the right-hand side (eu-ulminite). Polished section,
oil immersion, 270×, (0.24 mm).
2. Dark filamentous structure (probably fungal) surrounded by open-textured biodegraded zone.
Lipid-rich bodies (L) are light. Subbituminous coal, Bass Strait, Australia. Electron (TEM)
photomicrograph, 25, 800×, (0.0025 mm). From Taylor and Liu (1987). Courtesy of G.H.
Taylor.
3. Humocollinite (vitrinite A) and desmocollinite (vitrinite B) in a low rank bituminous coal
from the Saar District. Polished section, oil immersion, 440×, {0.145 mm).
4. Phlobaphinite (corpohuminite) as cell fillings of (?) root tissues in a compressed ombrogenous
peat of Ireland. Polished section, oil immersion, 270 ×, (0.24 mm).
5,6. Cracks in vitrite and clarite of an Oligocene subbituminous coal from Upper Bavaria. As seen
under normal white light (5) the cracks seem to be empty, but under blue light irradiation (6)
they reveal to be filled with fluorescing exsudatinite. Polished section, oil immersion, 500 N,
(0.13 mm).
7. Degradofusinite as the result of fungal attack in a parenchymatousous tissue. For details see
Teichmtiller (1950, p. 440). Miocene brown coal of Konin, Poland. Polished section, oil im-
mersion, 200×, (0.32 mm).
8. Naturally charred forest peat. Charring below the peat surface. Note the high porosity and the
fragile structure of the peat-coke. Polished section, oil immersion, 80 ×, (0.8 mm).
9. Pyrofusinite from a birch-root, charred below the peat surface. Note the very fine structure of
the wood tissue (left) and the charred cortex (right). Polished surface, oil immersion, 80×,
(0.8 mm).
12
The gelinites of brown coals are either biochemically totally gelified plant
tissues (telogelinites, as shown in Plate I-1 ) or gelified humic detritus (detro-
gelinite), or pure humic gels derived from colloidal solutions that entered for-
mer voids (eugelinite). Plate III-6 shows porigelinite with typical dessication
cracks between the cell walls ofMarcoduria inopinata. Biochemical gelification
seems to be promoted under water. It is characteristic of anaerobic subaquatic
facies types, such as humic gyttjae (Teichmfiller, 1950). However, oxidation
of peat and brown coal in the presence of water also leads to early gelification.
Calcium-rich coals are especially rich in gelinites, often precipitated as Ca-
humates (dopplerite). The gelinites of the brown-coal stage correspond to the
collinites of the hard-coal stage.
13
more than any other process during coalification: the colour of coal changes
from brown to black, its lustre from dull to bright, its hardness from soft to
hard and its microscopic picture of the cellulose-lignin-derived material from
a loosely packed agglomerate of many different huminite macerals to the densely
packed, compressed and homogenized vitrinite macerals. The causes of geo-
chemical gelification, clearly, must be connected with the rising temperature
and load pressure because, in contrast to the biochemical gelification, geo-
chemical gelification affects all huminites at a certain rank stage. Cook and
Struckmeyer (1986) suggested that vitrinitization is the result mainly of load
pressure which also causes water release. In fact, decrease of porosity and - -
as a consequence of it - - dewatering are the most important physical processes
during coalification of brown coals ("Braunkohle") and lignites, respectively.
But, as shown in Figure 3, pressure and the resulting loss of porosity do not
cause gelification, i.e., homogenization of the humic particles. Because geo-
chemical gelification ( = vitrinitization) coincides with the beginning of the
"oil window", i.e., with the formation of more or less liquid bitumen in coal,
the author suggests that this newly formed bitumen serves as the fluid com-
ponent in a new colloidal system in which the solid part is represented by the
stable aromatic groups of huminites/vitrinites. Thus, the "hydrogel" brown
Fig. 3. Effect of compression on soft brown coal as seen under the microscope. Polished sections,
oil immersion, 250 X and 125 X respectively, (width of pictures 0.17 mm and 0.32 mm, respectively ).
15
Fig. 4. "Pitch coal" from seam No. 7, Harmattan Mine, Illinois (0.42% Rr vitrinite). Note the
glass-like appearance with conchoidal fracture (width of picture 10.5 cm).
Cook and Struckmeyer (1986) assumed that the earliest oil generating in coal
stems from fatty acids, esters and alcohols which are preferentially associated
with huminites/vitrinites. This is in accordance with earlier results of Otten-
jann (1985,1988) who concluded that vitrinites generate oil earlier than spor-
inites on the basis of fluorescence alteration. In fact, Hirsch (1954) has de-
scribed the "liquid structure" of bituminous coals on the basis of X-ray studies
already more than 30 years ago, and, recently, Rouzaud (1984) was able to
demonstrate under the electron microscope small oily droplets between the
aromatic units of vitrinites in the bituminization range of coalification. Bitu-
minization has also been revealed by a striking secondary fluorescence of vi-
trinites beginning at about 0.5% random reflectance (Rr) and reaching its
maximum at about 1.1.% Rr (Teichmiiller, 1982a,b, 1984; Cook and Struck-
meyer, 1986). Combined microscopical and geochemical studies showed that
this is the range in which the yields of extract from humic coals increase con-
siderably, as do the amounts of n-alkanes and aromatic hydrocarbons in the
extracts (Radke et al., 1980 ). Bituminization causes the softening and agglom-
eration of vitrinites during carbonization and is the reason why bituminous
coals can form coke. These relationships, argued since the early seventies
(Teichmiiller 1974a,b,c), have been ascertained recently by the systematic
studies of Ottenjann et al. (1982) in Germany and of L i n e t al. (1986) in the
U.S.A. Bituminization also explains why low-rank bituminous coals (0.5-1.3%
Rr) are suitable for hydrogenation.
The liquid structure of bituminous coals (Hirsch, 1954) facilitates the ar-
rangement of the aromatic lamellae of vitrinites parallel to the bedding plane
and causes a higher anisotropy. It is not yet well known that the degree of
anisotropy at given temperature/pressure conditions depends on the hydrogen
content of vitrinites (and other macerals) (Teichmiiller, 1987, p. 143).
It is well known that the reflectance of huminites/vitrinites rises more or
less steadily during coalification (see Fig. 1 ). The degree of reflectance in-
crease is different in the different rank stages (Teichmtiller and Teichmiiller,
1982, pp. 41-51; Teichmfiller, 1982a, pp. 242-245) and is caused by increasing
aromatization of the vitrinite "molecule" which, roughly speaking, consists of
an aromatic nucleus surrounded by aliphatic groups (Van Krevelen, 1961 ).
Liptinites are derived from hydrogen-rich plant organs as well as from algal
and bacterial substances and decomposition products. Plant lipids, proteins,
cellulose and other carbohydrates are characteristic source materials of liptin-
ites. Exsudatinite is a secondary maceral, formed during the coalification pro-
cess at the beginning of bituminization.
17
Cutinite is derived from cuticles and cuticular layers which occur at the sur-
face of leaves, twigs and other areal parts of plants as a protection from des-
sication (Plate III-1 ). The chemical substance is called cutin and is composed
of fatty acids and waxes. In 1934/1935 the palaeobotanist and coal petrologist
Jurasky introduced "cuticular analysis" in order to identify plants whose cu-
ticles are embedded in German brown coals. This method relies, as does paly-
nology, on the great resistance of cuticles against oxidizing reagents. Cuticular
analysis has contributed much to the understanding of the genesis of brown
coal lithotypes (see pp. 50,52 ). It is, however, rarely, that the botanical origin
of cutinite can be identified directly in coal sections. The only case known to
the author is the cutinite from needles of the conifer Abietites linkii which were
first identified from the needles enriched in a Wealden claystone. This cutinite
is distinguished by a great thickness and well preserved stomata; it became a
coal petrological fossil of German Wealden coals (Teichmfiller, 1982a, Fig.
77a,b). The "leaf coal" or "paper coal" of the Pottsville Formation (basal
Pennsylvanian) in Indiana (U.S.A.) contains cutinite of Sphenopteris brad-
fordii (Guennel and Neavel, 1959 ) and of the pteridosperm Karinopteris (Nel-
son et al., 1985). The "leaf coal" of Mississippian age in the Moscow Basin
contains cutinite derived from stems of Lepidodendron and Bothrodendron
(Guennel, 1960). It is not known whether these cutinites can be identified only
18
PLATE II
(Width of photomicrographs in parentheses )
1. Petrified peat in a coal ball from the Katharina seam, Ruhr District. Cross section of a stem of
Lyginopteris oldhamia with opaque, coaly cell groups in the pith. Note the ingrown stigmarian
appendices (rootlets = R) between the inner and outer cortex. Polished thin section, transmit-
ted light, 2.5× (2.6 cm).
2. One of the dark coaly bodies from the pith of Lyginopteris oldhamia in 1, under incident light
and at a much higher magnification. Compared with vitrinitic inclusions in the coal ball, the
reflectance of these cell groups is inertinitic. Example of primary fusinite. Polished thin section,
incident light, oil immersion, 110 X (0.6 mm).
3,4. Thin rims of meta-exsudatinite along cell walls of semifusinite in a high-volatile bituminous
coal from the Saar District, Germany. Vitrinite reflectance (Rr) around 1%. 3 is taken with
one polarizer, 4 is taken under crossed polarizers. Polished section, oil immersion, 270 X (0.24
mm). Photomicrographs courtesy of the late Dr. K. Hoehne.
5. Meta-cutinite (white bands of "secondary inertinite") in a Carboniferous anthracite from Ib-
benbtiren, Germany. The reflectance of the formerly dark cutinite has surpassed the vitrinite
reflectance (which is 2.8% Rmax). Polished section, oil immersion, 500X (0.13 mm).
6. Carboniferous boghead coal ( Ruhr District) in the stage of high- to medium-volatile bituminous
coal (vitrinite reflectance is 1.12% Rr in the accompanying humic coal). The concentration of
micrinite represents the solid relic of the former bituminite groundmass. The Botryococcus
alginite (grey lenses) attained a relatively high reflectance. Polished section, oil immersion,
500× {0.13 mm).
7. Dolomitized root peat in a coal ball of the Katharina seam, Lower Rhine District, Germany.
The appendices of stigmarians are nearly uncompressed. Thin section, transmitted light, 11 X
(5.8 mm).
8. Silicified calamitean peat (showing compression and microbedding) from a layer below the top
of HauptflSz seam, near Essen/Ruhr. The Calamostachyscone in the center contains sporangia
filled with spores (tiny black dots). Thin section, transmitted light, 5× (13 mm).
20
Although we must assume that many other types of algae contributed to the
formation of coal, it is surprising that up to the present time the green alga
Botryococcus braunnii, which is unusual in that it secretes fat, is the only alga
identified in coal seams. According to Liu and Taylor (1987), this alga (which
is still living at the present) is distinguished by a very high content of hydro-
carbons (up to 76% in the dry substance) in its brown resting stage which may
account for its good preservation in coals and may explain its strong yellow
fluorescence. Wolf and Wolff-Fischer ( 1984 ), Corr~a da Silva et al. (1986) and
Liu and Taylor ( 1987 ) drew attention to strongly yellow fluorescing liptinites
occurring in Carboniferous coals of the Saar Basin and in Gondwana coals of
Brazil and Australia, respectively. They call these constituents "alginite" be-
cause of their Botryococcus-like fluorescence. Part of these "alginites" resem-
ble the "lamalginite" that Hutton et al. (1980) described from oil shales. They
are thin, anastomosing filaments between inertodetrinites (Liu and Taylor,
1987 ), or they show a net-like structure, or pore canals running perpendicular
to the surface of the cell wall (Corr~a da Silva et al., 1986). But these constit-
uents have not yet been identified as algae by palaeobotanists, as is the case
for Botryococcus and the many marine algae that are known from oil shales
(M~idler, 1963; Hutton et al., 1980). On the other hand, we must assume that
a high amount of algal material participated in peat formation, even in forest
swamps and reed marshes where, at the present time, thick algal mats may
form (Plate IV-3). Obviously most algae disintegrate morphologically at the
peat surface. As a consequence of high contents of cellulose and proteins, they
are easily attacked by bacteria. The product of the microbial degradation prob-
ably goes into the amorphous liptinite maceral bituminite as well as into the
aliphatic molecular groups of vitrinites, mainly desmocollinites. According to
Liu and Taylor ( 1987 ), experiments of Verma and Martin (1976) showed that
algal decomposition products may be stabilized through complexing with humic-
acid-type phenolic polymers.
The maceral resinite is derived not only from resins but also from balsams,
latexes, fats and waxes. Chemically one should distinguish between terpene
resinite (from resins, balsams, copals, latexes and essential oils) and lipid re-
sinites (from fats and waxes). Terpenes are relatively stable condensation
products of isoprene molecules (C6Hs), whereas lipids of fats and waxes are
extractable mixtures of fatty acids with glycerin esters (fats) and of fatty acids
with higher alcohols (waxes), respectively. Isolated resinites from coals have
been analyzed by, among others, Murchison (1966), Mukhopadhyay and
Gormly (1984), and Lyons et al. (1984).
Botanically, resinites are secretions of cell walls, filling cell lumens and ca-
nals. Many conifer stems, when wounded, sweat out resin drops and lumps
which may form resinite in coals. Isolated resinite bodies are relics of structural
degradation. Surface corrosion and/or higher reflecting oxidation rims at the
surface indicate deposition under aerobic conditions, either at the peat surface
or under oxygenated water. Lyons et al. (1984), who described large resin rod-
lets (1-6 mm long, 0.4-1.7 mm broad) occurring as phytoclasts and in a Cre-
taceous subbituminous A coal, gave many references of fossil resins that were
found in coals and accompanying rocks.
Terpene resinites display highly variable optical and physical properties (re-
flectance, fluorescence, hardness). Recently, Teerman et al. (1987) and Crell-
ing et al. (1982) distinguished, on the basis of fluorescence colours, 4 to 5
different resinite cell fillings in individual coals of Palaeocene and Cretaceous
age, respectively. Although resinite cell fillings are known from sigillarian bark
and cordaitean wood of Carboniferous coals, Tertiary coals are known to be
especially rich in resinites, due to be abundance of conifers in Tertiary flora.
But it is well known that in the tropics many angiosperms are also rich in
resins, latexes, oils and fats, substances which may be the source material for
resinite. The Eocene brown coals of Germany, which were deposited in a trop-
ical climate, contain latex ducts referred to by the miners as "monkey hairs",
and the pale lithotypes (see p. 56) of these coals are enriched in lipid resinite.
In contrast to the resins, the waxes (lipid resinites) are deposited on the
surface of leaves and fruits as fine grains and rodlets or as crusts, particularly
in the tropics. It is difficult to recognize these fine lipid resinites in coals under
'2 '2
the microscope. Normally, they are included with the maceral liptodetrinite
( see below).
Resinites tend to be converted to bitumen (partly exsudatinite i during the
early stages of coalification.
Although probably originating from essential oils, fluorinite has been sepa-
rated from the resinite macerats because of its striking optical properties. His-
torically it was detected relatively late using the fluorescence method (Teich-
mtiller, 1974a,c ). Under short-wavelength light it shows a very striking bright-
yellow fluorescence, whereas in normal white light it cannot be distinguished
from voids or clay inclusions in coals. A typical occurrence is in the small cells
of phyllovitrinite, which, in turn, is surrounded by cutinite. Thus, at least part
of fluorinite seems to be derived from lipid cell inclusions in certain leaves.
Recently, Cook and Struckmeyer (1986) and Hageman (1987) pointed to the
possibility that fluorinite may represent secondary high-pour oil that was gen-
erated in the coal from certain cell fillings. Hageman observed a negative flu-
orescence alteration, a behaviour which normally indicates maturity, i.e., gen-
eration of oil (Teichmtiller and Ottenjann, 1977).
like substances begin to form, a second "jump" (0.8-1.0% Rr) coincides with
the maximum of oil generation and a third "jump" (1.3% Rr) corresponds to
the "death line" of oil generation when sporinites attain the same reflectance
as vitrinite (Fig. 1) and fluorescence is more or less lost. The microscopical
changes coincide with yield and composition of extracts from liptinite-rich
coals (Radke et al., 1980). After oil generation (bituminization) some liptin-
ites "disappear" (fluorinite) or leave behind micrinite as a solid relic (from
resinite, bituminite) (see Plate II-6). Others shrink fairly considerably and
finally attain a higher reflectance than vitrinite (sporinite, cutinite ) (see Plate
II-5). The reflectance of exsudatinite surpasses that of vitrinite in the rela-
tively early stage of coking coals. Many meta-exsudatinites are distinguished
by a high degree of anisotropy (cf. Plate II-4). It is obvious that the most
striking changes of liptinite reflectance and fluorescence occur in the "oil win-
dow", i.e., when oil is generated and, later, when oily products are cracked to
gaseous hydrocarbons.
not only of' fusinites but of' all inertinites in peats and brown coal {Plate I-8
and 9). Pyrofusinites are preserved in coal balls. In Illinois they contribute
2.5-7%, sometimes as much as 10% of the peat biomass and include partially
fusinized stigmarian roots {Phillips et al., 1985). The latter indicate charring
of the peat.
Permian and Carboniferous hard coals are rich in "degradofusinite" and,
especially in "degrado-semifusinite" which, in contrast to the pyrofusinites,
are distinguished by poorly preserved cell structures and are thought to be a
product of mouldering, oxidation and dehydration. It is not well known that
fungal attack of wood (e.g., by the dry-rot species Merulius lacrymans) also
alters the unused part of wood into highly reflecting humic substances {Teich-
mtiller, 1950, 1982a). Plate I-7 shows that fungal hyphae (appearing as tiny
circular cross sections) attacked a parenchymatous tissue and converted part
of its cells into highly reflecting degradofusinite. Non-attacked cells {Plate I-
7, right border) are low reflecting (humotelinite). Koch (1969b) noticed in
German peats that inertinitic tissues are often associated with fungal remains,
so he assumed a genetic connection. Recently, Cohen and Spackman (1980)
and Cohen et al. ( 1987 ) described the darkening of cell walls (in thin sections )
and an increase of reflectance around sites of fungal attack in subtropical peats
of the U.S.A. Styan and Bustin (1983a) found fungal sclerotinite together with
degrado- and pyro-fusinite in cool-climate peats of the Frazer River delta, Brit-
ish Columbia.
Pyro- and degrado-fusinites (and -semifusinites) generally are regarded as
indications of a relatively dry environment of deposition. Phillips et al. ( 1985 )
found in coal balls a rise of fusinite abundance during drier periods of the U.S.
Pennsylvanian. Likewise, Harvey and Dillon ( 1985 ) explained the increase of
inertinites in Illinois coals which were deposited in Missourian-Virgilian (Up-
per Pennsylvanian) times as compared with coals deposited in Desmoinesian
and older {Middle Pennsylvanian) times as due to a drier climate during the
Late Pennsylvanian.
plants. Chemically, they are distinguished by a high carbon content (as high
as the C-content of subbituminous coals! ) and a low hydrogen content.
"Rank fusinites" attain their high reflectance only during early coalification
(see Fig. 1 and p. 29). Possibly they stem from cell walls that were initially
impregnated with certain bituminous substances (like resins) or which still
contained cellulose in the brown-coal stage (Teichm~iller, 1982a, p. 275 ft.).
Their formation implies the generation of fluid or gaseous coalification prod-
ucts at very low rank stages and may explain the occurrence of some important
deposits of early petroleum and gas, for example, in the Canadian arctic
(Snowdon and Powell, 1982). Recently, Cook and Struckmeyer (1986) drew
attention to a possible very early bituminization in coals. From this point of
view, the Figures 3 and 4 of Plate II may be of interest because they show the
co-occurrence of semifusinite and highly anisotropic meta-exsudatinite. The
very close association of thin, highly reflecting and anisotropic rims around
fusinite cell walls has been observed by the late Dr. K Hoehne in Saar coals.
The rims may be exudates of cellulose-rich or resinous cell walls in the stage
of over-maturity. It is well known that both cellulose and resins generate bi-
tumen relatively early. An especially strong anisotropy of former bitumen at
higher-rank stages is also known, and, in this case, has been probably caused
by local magmatic heat (a sill is present in the substrata).
unfavourable conditions, like droughts) are known from the fungi Claviceps
purpurea (which attacks Gramineae) and Rhytisma acerium, living on maple
leaves. Black fungal plectenchyme occurs as mycorrhiza, i.e., a symbiosis of
tungi and roots of higher plants. Thus, only certain, melanin-rich fungi are
predestined for the formation of sclerotinite. The old opinion that chitin (the
main substance of fungi) causes the high reflectance of sclerotinite cannot be
substantiated. On the contrary, the chitin of scorpion cuticles found in Car-
boniferous bituminous coals of Yorkshire, England (Bartram et al., 1987), and
the chitin of presumable zoo-epiderms found in Canadian subbituminous coal
(Goodarzi, 1984) is translucent and fluorescent. According to Frey-Wyssling
(1959) chitin resembles cellulose in its optical properties. Thus, most fungal
material deposited in peats will not form sclerotinite.
Today it is generally assumed that the greatest part of the so called "scler-
otinite" in Carboniferous and Permian coals stems from cell secretions (of
tannins and/or resins) which suffered oxidation or carbonization before or
shortly after deposition at the peat surface (Taylor and Cook, 1962; Koch,
1970 ). The cellular, thick-walled tissue associated with strongly reflecting rod-
lets whose cross sections have been mistaken for sclerotia in former times are
sclerenchymatous strands with an inertinitic reflectance according to Lyons
et al. (1982). They are associated with resin canals in MeduUosa and related
PLATE III
(Width of photomicrographs in parentheses )
1. Well microlayered cutinite-rich clarite, probably deposited under water, characteristic of Saar
coals. The coalified leaves consist of relatively low reflecting perhydrous phyllovitrinite with
many inclusions of resinite. Seam 1, Luisenthal Mine, Saar District, F.R. Germany. Polished
section, oil immersion, 270×, (0.24 mm).
2. Gondwana coal from the Bowen Basin, Australia. The typical microlithotype is inertite, con-
sisting of a high concentration of inertodetrinite with inclusions of mineral matter (black). In
the center a thin band of vitrinite. Polished section, oil immersion, 500 × , (0.13 mm).
3. Reed coal from a light layer of the Rhenish brown coal, consisting of more than 90% loosely
packed humodetrinite. Note the crumbly texture. In the center a fungal spore (white). Polished
section, oil immersion, 250×, (0.26 mm).
4. Taxodiaceae-forest coal from a dark layer of the Rhenish brown coal with preserved cell struc-
tures (humotelinite). Polished section, oil immersion, 250 × , (0.26 mm).
5. Pollen-rich fine-detrital gyttja, deposited under water, from the Rhenish brown coal. Polished
section, oil immersion, 250×, (0.26 mm).
6. Finely layered dark cell walls of Marcoduria inopinata, rich in cellulose. The thin lignin-rich
middle lamella (arrow) is lighter grey. Between the cell walls dense porigelinite (light grey).
Polished section, oil immersion, 440 × , (0.145 mm).
7. A dessicated face of Rhenish brown coal in the Wachtberg open mine, showing the banding of
dark brown and lighter brown layers. (ca. 25 m).
8. "Schwelkohle" (used for tar production) from a pale layer of Eocene brown coal of eastern
Germany. The dark bituminite groundmass contains particulated liptinites which, however,
remain invisible under white incident light. The light tissue in the centre (humotelinite) rep-
resents an ingrown root. Polished section, oil immersion, 250 × , (0.26 mm ).
i~ ~ • ~
--.1
seed ferns. It seems that they are primary inertinites, just like the sclerenchy-
matous cells in the pith of Lyginopteris oldhamia (see. p. 24). Later, Lyons et
al. (1986) proposed the name "secretinite" as a maceral term for these rodlets
and other highly reflecting cell secretions. Recently Cohen et al. (1987) de-
scribed secondary cell fillings from modern peats. They are relatively dark in
transmitted light and their formation seems to be related to fungal attack of'
certain tissues. They may form "secretion sclerotinite" in the hard-coat stage.
The term inertodetrinite is used for small particles of inertinite (Plate III-
2), for example, splinters of pyro-fusinite and relics of degrado-semifusinite
which may have been blown in by the wind or washed in by water. Inertode-
trinite is a characteristic maceral of subaquatic coal facies and of clastic rocks.
Smyth (1980b) assumes that the inertodetrinite of Triassic Australian coals
which were deposited in a sub-arctic climate was derived from mosses and
lichens.
when these were shrivelled due to drying. Moreover tissues showing evidence
of microbial attack were often darkened around the area of attack. The authors
suggest that the darkening process ("inertinization") occurs under more aero-
bic conditions than those in which huminites/vitrinites are formed.
The different genetic types of coal lithotypes, recognizable by eye, are char-
acterized by the types and amounts of microlithotypes and their macerals and
mineral inclusions as well as by textural properties such as the extent of mi-
crolayering {see Fig. 8). Microlithotypes refer to the naturally occurring as-
sociations of macerals both as seen under the microscope. Chemically, sulfur
and nitrogen as well as the hydrogen content of vitrinites are facies dependent.
Table 3 shows for hard coals the main microlithotypes and their maceral com-
position as well as the main lithotypes in which they typically occur.
In brown coals, lithotypes rather than microlithotypes have been used so far
to distinguish certain coal facies (see pp. 47-59 and Figs. 13,15,16). The dif-
ferent methods of lithotype classification of brown coal vary widely, and no
international agreement has yet been reached. Generally, it has been accepted
by coal petrologists that:
(1) cannels and bogheads, the sapropelic coals, are subaquatic muds deposited
in still-water ponds,
30
TABLE ;~
The main microlithotypes, their maceral composition, and the lithotypes in which they occur
by sand bars ("overbank swamps") in lagoons and in deltaic areas. Such sites
of "paralic coals" are often distinguished from those of "limnic coals" which
were deposited farther inland along rivers ("back swamps"), around lakes (in
a lacustrine environment) or in other depressions, e.g., those of glacial origin.
A new trend of coal petrology is to search for relationships between the pal-
aeogeographical-sedimentological position of peat formation and the petrol-
ogical composition of coals (e.g., Smyth, 1979, 1980a, 1984; Styan and Bustin
1983a,b; Harvey and Dillon 1985; Diesse11986; Cohen et al. 1987). The authors
compare the facies (lithology, palaeontology) of the coal-bearing strata with
the facies of the accompanying coal. Pioneering work was done by Hacquebard
and Donaldson (1969) and by Smyth (1975, 1979, 1984). Figure 5 shows a
scheme of depositional areas of coal formation (fluvial, lacustrine, upper and
lower deltaic, lagoonal) and the main associated microlithotypes of Australian
coals. Durite + inertinite-rich coals were found to have been deposited mainly
in lakes and in the lower delta plain, whereas vitrite + clarite-rich coals oc-
,,:!:#:~?:
i, ~( ....
...'.~':'L"(: I A LACUSTRINE
CI .:Cic!T~I~,::.~ •..... B FLUVIAL
( ) " ~ ! ! ! ~ ~ I ~ " F L U V AL (b) C BRACKISHWATER
; ' ~ ~i' J {GRETACOALMEASURES}
"~'~;~"["~':;'. | [~ UPPERDELTAC
UPPER~~"~!~ !::~'~::. ~, E Lo WER DELTA,C
t ....
DELTAIC:~ ~ i
VITRITE +CLARITE
FLUV,AL
10 50 90
INTERMEDIATES DURrFE+ INERTITE
Fig. 5. Depositional milieus of peat formation (a) and related microlithotypes (b) of Australian
hard coals. From Smyth (1984).
curred in upper deltaic fluvial and lagoonal environments. Intermediates be-
tween these two petrographic types are regarded as characteristic of delta plains.
Smyth (1984) regarded the ratio vitrite + clarite : durite + inertite as an indi-
cator of oxidation of the peats of the liptinite-poor Australian Gondwana coals.
She suggests (1980a) that especially thick Australian seams t > 15 m) which
contain much inertinite have been deposited in small basins on a stable craton.
In contrast to seams deposited in foredeeps, they accumulated at times of still-
stand either in lacustrine, partly fluviatile environments, or in raised bogs.
The majority of Gondwana coals of Australia, India, South Africa and Bras-
ilia (?) are rich in dull coal, often with pure inertite (a microlithotype with
more than 95% inertinite! ). These coals have mainly been deposited in depres-
sions of glacial origin (lakes, valleys). Some Gondwana coals, however, have
been deposited in foredeeps, for example, in the Permian foredeep running
north-south along the present eastern coast of Australia and are rich in vitrite
and clarite as, e.g., coals in the northern coal field of the Sydney Basin (Shi-
baoka and Smyth, 1975).
Recently, Diessel ( 1986 ) distinguished between Australian Gondwana coals
deposited in lower and upper delta plains and in piedmont plains. He intro-
duced a "Gelification Index" (GI) and a "Tissue Preservation Index (TPI) to
characterize these coals:
vitrinite + macrinite
GI = semifusinite + fusinite + inertodetrinite
telinite + telocollinite + semifusinite + fusinite
TPI-
desmocollinite + macrinite + inertodetrinite
Wet conditions of peat formation are distinguished by high GI-and high TPI-
indices, whereas dry conditions lead to low GI- and low TPI-indices (Fig. 6).
The latter is the case for seams extremely rich in inertodetrinite which, ac-
cording to Diessel, were deposited in piedmont plains where "severe oxidation
restricted the formation of telinite and telocollinite, and under conditions of
falling water table, even structured inertinite will disintegrate to form in-situ
inertodetrinite, commonly coupled with an increase in inherent ash and the
rather resistant sporinite". On the other hand, coals deposited in upper delta
plains and in fluviatile environments are rich in vitrinites (wet-forest swamps
in Fig. 6) but also in clastic clay minerals. Brackish coals deposited in delta
plains, partly as marsh peats, are distinguished by a high Gelification Index
and a low Tissue Preservation Index, as well as by high amounts of pyrite and
organic sulfur, due to marine transgressions.
According to Neavel ( 1981 ), coals deposited in lagoons carry abundant hu-
modetrinite/desmocollinite, whereas coals of landward {freshwater) environ-
ments are though to be richer in telinite, resinite and inertinite.
Figure 7 shows that the vitrinite: inertinite ratio in the Herrin coal of Illinois
33
MARSH 0
0 0
• u 0 '~ A
-o/
o., -
--
" F
: RES
:oZ - - -
G~ l terrestrial
. . . . w . . . . f . . . . , . . . . r . . . . , ,
: : :i : :::: :::::::!ii!iiiiiii!!ii!i!iiiiiiiiiiiii!i!!I¸~¸¸~" •
•-.-... ~ .....
Vitrinite- InertiniteR
(mineral and micrinite f ~ ~ ~
~8-11
Fig. 7. The v i t r i n i t e : inex~inite ratio in the Hex~rin No. 6 coal of Illinois in r e h t i o n to paheogeo-
graphical conditions.From Harveyand Dillon (1985).
35
atively poor in clastic minerals and sulfur. The authors point out that this
is the only environment where mineable coals would develop.
Cohen et al. (1987) consider that deltaic models for coal formation have
been greatly over-applied by geologists, because, in deltas, the influence of in-
organic sedimentation is too great to produce mineable coal seams. In deltas,
only convex peat deposits, caused by high rainfall, would prevent the influx of
mineral matter (see also Styan and Bustin, 1983 ). Recent examples of convex,
ombrogenous forest bogs in delta sites are known from Malaysia (Anderson,
1964).
The coal facies is highly dependent on the plant material that contributed
to peat formation. The vegetation in mires is influenced by the climate (which
may vary from sub-arctic to tropical), by the height of the groundwater table
(wet to dry), by nutrient supply, acidity, and marine influences. The height of
groundwater is most important not only for the kind of vegetation but also for
the redox-potential (oxic to anoxic) which determines the mode of preserva-
tion of plant remains. Peat may form in forest-swamps from various plant
associations, or in marshes with herbaceous vegetation (sedges, grasses), or in
open swamps with predominantly submerged and floating plants, or in raised
bogs with mosses or shrubs or trees. Therefore, it is usual to separate "forest
peats" from "reed peats", "subaquatic peats" (or "organic muds") and peats
of raised bogs. Plate IV (Fig. 1 to 4) shows the main types of peat-forming
vegetation and the hydrology of well known mires of the southeastern Atlantic
coastal plain of U.S.A.
Because geological age, palaeoclimate and the associated vegetation have a
great influence on the coal facies and because most coal petrological studies
have been carried out on certain coal deposits, the following sections will treat
mainly Carboniferous hard coals of Euramerica, Permian hard coals of Aus-
tralia, and Tertiary brown coals of Germany and Australia. In addition, certain
problems of coal facies which are under discussion will be dealt with separately.
Recent results on the influence of palaeoclimate will be found in section 2.4
(eutrophic-oligotrophic coals).
in water as described by Scott (1980). The main and most important vegeta-
tion of Carboniferous coals were certainly lycopod forests with minor amounts
of pteridosperms and ferns as well as of cordaitean trees, the latter increasing
in the later Westphalian.
One may distinguish between a limnotelmatic forest swamp where the trees
were standing in deep water and a drier telmatic forest swamp. These forest
peats are the parent material for Carboniferous vitrites and liptinite-poor clar-
ites. If the groundwater table sinks below the peat surface, oxidation will take
place and will lead to the formation of inertinite-rich durites ("grey durains" ),
fusites and semifusites. This scheme has been used, partly with supplements,
by many coal petrologists, including Hacquebard and Donaldson (1969),
Kalkreuth (1982), Diessel (1986)and Marchioni (1981).
Hacquebard and Donaldson (1969) studied Canadian Carboniferous coals
by combining coal petrological with sedimentological and palynological meth-
ods. They distinguished the following petrographic types and interpreted them
as follows:
~grounbwa(e~
(able
fusites, dorites vitriles and sporinile- poor clarifes sporinite -rich sporinite* rich dorites, canneis and
poor in sporlnite clarites d~stlnctly mlcro-layered ciarites, bogheads
cutinife clarites
Fig. 8. The presumed moor types and the relating microlithotypes of Carboniferous coals. From
Teichmiiller (1962, 1982a).
PLATE IV
I. Margin of Taxodium (cypress) forest in the Okefenokee Swamp of Georgia (U.S.A.) with
bushes in the undergrowth and open-water plants in the foreground.
2. Reed marsh of the Everglades, southern Florida (U.S.A.), in the wet season. A tree island
("hammock") in the background. Blooming water lily (Crinurn) in the foreground.
3. Algal mat between sedges (Eleocharis) in the reed marsh of the Everglades, southern Florida
(U.S.A.). In the wet season the water table stands half a metre above the peat surface.
4. Change of moor type after a fire in the Okefenokee Swamp of Georgia, U.S.A. Charred stumps
and dried, thin stems of Taxodium trees are relics of the previous moor type (Taxodium-forest
swamp) before the fire. After the fire an open-water marsh with aquatic plants and reed grasses
and sedges developed as the present moor type.
Petrographic Type Environment, Vegetation
A = spore-rich clarite + duroclarite RM = reed moor (telmatic)
B = fusito-clarite with distinct FtM = forest terrestial moor
lenses of fusite ( relatively dry )
C = vitro-clarite + cuticle clarite FM = forest moor (telmatic)
D = duroclarite + durite + OM = open moor (timnic,
carbargilite subaquatic )
Lycospora is the typical spore for the forest swamps, whereas Punctatosporites
favouring "a more herbaceous type of flora" is characteristic of the reed-marsh
facies. Dull coals with spore-rich clarites and durites, together with clay part-
ings have a wide regional distribution and are interpreted as subaquatic de-
posits (see Fig. 8 ). This scheme, however, contrasts with ideas by Smith (1962,
1968) who, for the first time, developed a concept of oligotrophic durites, rich
in thick-walled microspores ("crassispores" of Stach, 1955) (see pp. 60-62).
It is not easy to reconstruct the vegetation of Carboniferous coals. The many
identifiable compressed plant remains occurring in accompanying rocks may
not be characteristic of the swamp flora. Spores may be blown into the mires.
According to Scott and Rex (1985) "vegetation preserved in coal balls repre-
sents the most complete data set for any plant habitat". Coal balls are early
petrified (mostly carbonatized, sometimes silicified) peats and occur in cer-
tain, often marine-covered seams.
Recently, valuable results were obtained by Phillips and Peppers (1984)
who evaluated coal-ball studies as well as palynological investigations carried
out on Euramerican Carboniferous coals. Some of their conclusions referring
to the Carboniferous climatic changes and the various types of vegetation in
Carboniferous mires are reported in the following.
The flora preserved with all anatomical details in the coal balls together with
spores and compression floras in clastic rocks indicate a moist tropical climate
throughout the coal-bearing Upper Carboniferous, with nevertheless wetter
and drier periods (Fig. 9). The wettest period was the Westphalian D, the
driest the Stephanian, although the Westphalian B was relatively dry too.
In the swamps, lycopods dominated in the Westphalian. According to Figure
10 cordaites were abundant only during the Westphalian B to D, with their
maximum in the Upper Westphalian C (Middle Pennsylvanian). Most Late
Pennsylvanian (Stephanian) coal swamps of the U.S.A. were dominated by
tree ferns. Wetter and drier environments in Illinois swamps are correlated
with Lepidophloios as the wet extreme and Sigillaria as the representative of
driest conditions. The highly dominating Lepidophloios forest stood in water
without canopies and ground plants. About 90% of the sporomorph Lycospora
come from Lepidophloios haUii. Figure 11 shows the distribution of this spore
in the Herrin No. 6 seam of Illinois. Interestingly, the highest amounts of Ly-
39
}-
b-
to
w
Fig. 9. A wet/dry climatic curve for Euramericancoal swampsduring the Pennsylvanian (West-
phalian A to Stephanian). The hatched part indicatesthe degreeof climaticwetness.From Phil-
lips and Peppers (1984).
cospora (indicating very moist forests) were found near and within a shallow
lake in the east and along the banks of a river running southward. The drier
sigillarian forests are thought to have had a higher diversity of plant assem-
blages with seed ferns and tree ferns as well as with a plant ground cover (al-
though this seems to have been different at places in the Ruhr Carboniferous,
as is shown on p. 65 and in Fig. 20 ). Cordaites became abundant in swamps
only where conditions were relatively dry or brackish.
Of great interest for facies problems of coal formation are the following ob-
servations of Phillips and Peppers (1984): "Pronounced changes in the kinds
and abundances of lycopod-dominated forests in the Herrin profiles usually
occurred at mineral-rich or clastic bands which indicate abiotic disruptions of
fresh-water regimes like drops in water level, flood, fire and changes in nutrient
supply." Commonly the flora changes from the predominance of one lycopod
to another lycopod (e.g., from Lepidophloios to Lepidodendron) and tree ferns
become more abundant. Seed ferns were usually more abundant immediately
below and above mineral bands. These observations clearly indicate topogen-
ous (not ombrogenous) peat formation in the Pennsylvanian of Illinois (cf.
Section 2.4 ). Similar results were obtained by Mahaffy (1985) who compared
the spore assemblages in coal balls with the spores in the accompanying coal
of the Herrin No. 6 seam. He found a good agreement between the two. Five
horizons could be distinguished which are separated either by clastic bands or
by fusain layers.
40
(~ [[PENNSYLVAN/CARBONI
IANTUPPER I
FEROUS
I
~--~,
M,OSPORES,COAL)IM' DCuO."sT
X"E"TpESTERN EUROPEPEAT(COAL BALLS)
VIRGILIAN
STEPHANIAN
MISSOURIAN
MAXIMUM
EIR TREE F E R N S ~
|~"..:-:!t.YCOP0 DS :':'..':'..~
DECLINE ~':".~:[LYC0 P0 D$ ~'.'::'_::]82%
DECLINE
WESTPHALIAN D ~/",,~ CORDAI TES ~/',/A 1%
[///2 C0ROA GE S>"/~ DESMOINESIAN
MAXIMUM
r///~. CORDA IT E S~/.//~>
ATOKAN 1WESTPHALIAN C
in
I~XPAN$1QN B
o R
~TREE FERNS~
i WESTPHALIAN B 0
EXPANSION
MORROWAN i
(/_.//~CORDAITES~/A IO%
#:
WESTPHALIAN A
MAXIMUM
[,:~:?:': LYCOPODS~i:'",~ ! ?~:!:' LYCOPODS~!~."::.196%
Fig. 10. The stratigraphic occurrence of lycopods, cordaites and tree ferns in Carboniferouscoal
swamps of Euramerica, on the basis of palynological results from Illinois coals (left) and of bo-
tanical identifications in Euramerican coal balls (right). From Phillips and Peppers (1984).
Phillips and DiMichele (1981), in their thorough study of coal balls in the
Herrin No. 6 seam of Illinois, described the contribution of different plants and
plant organs. Lycopods contribute 63-73% of the peat, ferns 15-17%, pterido-
sperms 6-16%, sphenopsids 4-5% and cordaites less than 0.7%. The lycopods
were the most important contributors for bark and root (Stigmaria), Psaron-
ius tree ferns are largely presented by roots whereas pteridosperms like Med-
ullosa contributed much foliage, and the sphenopsids are mainly represented
by wood from stems and roots. Four to five percent of the plant tissues are
fusinized and belong to aerial tissues of lycopods, pteridosperms and sphen-
opsids, the latter two contributing particularly to the formation of fusinite.
The predominance of root tissues in the petrified peats of coal balls has been
described by most investigators. Plate II-7 shows a petrified root peat with
41
,~:,-, .............................. !
1
I
J I
I
1¢
i,
L
60 km
"t 7 ~
- - 6 0 - - Percent LycOspora
• Sample site
~':'~,'~, ]<e,>~Uclry
Lake
Fig. 11. Relative abundance of Lycospora in the Herrin No. 6 seam of Illinois in relation to the
palaeogeography of the Carboniferous swamp area. From Phillips and Peppers (1984).
cross sections of stigmarian appendices from the Katharina seam of the Lower
Rhine District, and in Plate II-1 ) the rootlets are ingrown in a stem from the
seed fern Lyginopteris oldhamia. Phillips et al. (1985) gave quantitative infor-
mation: according to their observations of coal balls the "shoot:root ratio"
which would be 4:1 for a whole tree, commonly is only 1:1. This indicates enor-
mous loss of aerial plant material. The shoot: root ratio is highest ( > 1) in
lycopod peats in which periderm is predominant compared with wood (36%
periderm, 4% wood). Lycopod peats predominate in the Lower and Middle
Pennsylvanian. They are much rarer in the Upper Pennsylvanian (Stephan-
42
Jan) when the climate became drier and the shoot:root ratio declined to a
minimum of 0.4! Generally, it must be assumed that lignified roots of lycopods
are the source material for many telinites in Carboniferous coals. It is also
known that the thick cortex of lepidophytes played a much more important
role for vitrinite formation than lycopodean wood. According to Phillips et al.
(1985) the ratio periderm:wood is 8.5:1 in Westphalian coal balls which are
highly lycopod dominated and carry only small amounts of cordaitean remains.
Comparisons of petrified Carboniferous peats with the petrological compo-
sition of the surrounding coal are still very rare. Former studies (Teichmfitler,
1952; Teichm~iller and Schonefeld, 1955) have shown that:
(1) The most abundant and best preserved tissues in coal balls are from roots
that grew through the peat.
(2) Forest peats are precursors of coarsely banded bright coals with vitrites and
clarites.
(3)At least part of liptinite-rich durites is derived from highly decomposed
organic muds containing many spores and inertodetrinites. Neither the mi-
crinite nor the macrinite of these durites can be detected in the original
mud petrified in siderite concretions. The compaction ratio of these muds
is extremely high.
(4)The peat of the marine-influenced Katharina seam (Westphalian A/B
boundary) has been formed from a vegetation rich in ferns and pteridos-
perms, especially in Lyginopteris oldhamia (Plate I-l). Lycopodean root
appendices of a later vegetation are abundant. The coal formed from this
peat consists of finely laminated bright coal with vitrite and clarite. It is
poor in liptinites and inertinites, although micrinite (not present in the
peat) is a characteristic maceral.
In silicified coal balls of the Namurian, Teichmfiller and Schonefeld ( 1955 )
found small sticks, leaves and cones of calamites which are highly predominant
over fine remains from ferns and lycopods. No inrooting was observed. This
peat type represents the end of seam formation (of seam HauptflSz) and is
obviously derived from a calamitean marsh. It is shown in Plate II-8.
Recent comparative studies by Winston (1986) between coal balls and coals
from Pennsylvanian seams of Illinois showed that lycopod periderm from stems
and from roots, as well as Diaphorodendron cortex, Myeloxylon, Pennsylva-
nioxylon wood and bark, marrattialean fern leaves, Psaronius outer roots and
Stigmaria rootlets can all be traced from coal balls into vitrinite layers, whereas
tissues traced into fusinites include lycopod stem periderm, Myeloxylon, and
Psaronius inner roots, the latter pointing to charring of the peat (see p. 69 ).
Winston calculated compaction ratios from peat to coal in the range between
7:1 to 19:1, in the case of Stigmaria periderm even of 30:1. A ratio of 7:1 has
been estimated from a coal ball in the vitrinite-rich Katharina seam of the
Ruhr Carboniferous, and for a liptinite-rich durite a ratio of 20:1 was found
43
(Teichmiiller and Teichmiiller, 1982, pp. 17-18), the latter easily explainable
by the high water content of organic muds.
Irrespective of coal-ball studies, the evaluation of the literature has shown
that the opinions about the genesis of hard-coal lithotypes and microlithotypes
may vary, especially in regard to durites. Most coal petrologists agree that coals
rich in vitrite and liptinite-poor clarite have been deposited in wet-forest
swamps. It is also mostly acknowledged that cutinite-rich clarites (Plate III-
1 ) represent subaquatic deposits near lake banks, and that inertinite-rich dur-
ites ("grey durains"), same as inertites (Plate III-2) were derived from oxi-
dized peat surfaces. But there are great differences in concepts about the gen-
esis of dull coals with liptinite-rich (other than cutinite-rich) clarites and,
especially, with liptinite-rich durites ("black durains" ). One group considers
these microlithotypes as a product of oxidation which formed under relatively
dry conditions (Smith, 1962,1968; Littke, 1985,1987; Bartram, 1987) where
spore exines were enriched due to their chemical stability (see pp. 61-63).
Another group interprets spore-rich durites and clarites as subaquatic deposits
that formed in open water or in reed marshes, where, just as in sapropelic muds,
allochthonous pollen and spores ("pollen rain" ) were well protected from de-
cay under water, whereas in the forest canopy they were destroyed. This con-
cept is strengthened by observations that liptinite-rich dull coals are often
associated with clastic layers. Marchioni (1980, p. 49) found that dull coal
layers in the Liddell seam of the Sydney Basin (Australia) are closely associ-
ated with clastic bands, although these dull coals certainly do not contain the
Densospore-rich type of durites but rather belong to the inertinite-rich "grey
durains". Hower et al. (1987) report that in the western Kentucky No. 11 seam
(correlative of the Herrin No. 6 seam of Illinois) which is distinguished by a
very high vitrite content (85% vitrinitel), durites, vitrinertoliptites and pure
liptites become more common as the blue-band parting is approached. These
spore-rich microlithotypes occur below as well as above the blue band*.
It must be stressed that Smith (1962,1968) has distinguished between, on
the one hand, "black durain" comprising clean durite rich in spores and ma-
crinite and characterising his "densospore phase" and, on the other hand, "grey
durain" comprising durites with some mineral matter, fewer spores (tenui-
spores instead of crassispores) and semifusinite as the characteristic inertinite
maceral. The grey durain belongs to his "incursion phase" which is considered
to represent inundations with oxygenated water transporting poorly preserved
spores and inertinite (cf. pp. 61-62). Similarly, Smyth (1980a) found durites
below clay bands in Australian coal seams which she interpreted as oxidized
plant remains washed in by flowing water. According to Neavel (1981), durites
*On the other hand, at the edges of the same coal deposit striking concentrations of inertinites
occur, partly looking like the "steinkohlenartige Teilchen" of German brown coals which are in-
terpreted as redeposited particlesof oxidized peat (Teichmiiller,1982a, p. 281, figs.86a, b).
44
may come from peats deposited either under extreme wet or under extreme dry
conditions. Likewise, Styan and Bustin (1983b) concluded that precursors of'
durite in peats of the Frazer River delta may be deposited either under water
as organic muds or may be oxidation (dessication) products of sedge-grass
peats.
The uncertainty about the genesis of durites seems to be connected with the
uncertainty about the genesis of the typical inertinites of durites, namely ma-
crinite and semifusinite of the degrado-type. Both macerals are very rarely or
not at all found in peats and brown coals. From this point of view, studies of
differences in opacity and reflectance of huminites in recent peats carried out
by Cohen et al. (1987) are of great interest. These authors found that: (1) a
darkening process ("inertinization") of cell walls occurs under more oxygen-
ated conditions, mainly through fires, more seldom through microbial activity;
(2) that humocollinites (gels) are always higher reflecting than humotelinites
{cell walls); and (3) that gelification in peats takes place mainly in those types
which were deposited in a deeper water aquatic habitat, for example, in Nym-
phaea peat. These observations may permit the following explanation: the ba-
sis for the formation of inertinitic groundmasses in durites is founded already
in the peat stage, when gels with a relatively high, although still huminitic
reflectance did form, but the true inertinitic reflectance is attained later in the
hard-coal stage. This explanation is consistent with the concept of a secondary
inertinization during coalification (see pp. 25,29 and Fig. 1 ).
ence. Thus, acidic, oligotrophic and drier conditions are created in which, be-
sides Sphagnum, Ericaceae and small pines can live.
As in North European mires (Koch, 1966,1969b; Grosse-Brauckmann,
1979a) woody plants indicate drier conditions of peat formation than do her-
baceous plants. Grosse-Brauckmann (1979a) even regarded alder (Alnus glu-
tinosa) peats as indicators of stillstand of peat formation. After the alder roots
have penetrated the peat, oxidation of the older peat takes place and may lead
to the destruction of older plant remains or to loss of a whole peat layer. Some-
times, concentrations of small sclerotia of the fungus Cenococcum geophilum,
which lives in peats above the water table, are the only relics of an older peat
layer.
Figure 12 shows various plant associations of mires in the Frazer River delta
with their peat types and the macerals and microlithotypes which might form
from them according to Styan and Bustin (1983a). These authors think that
"a high ratio of cellulose to lignin in marsh plants (sedges, grasses ) and limited
exposure of these tissues to dessication and oxidation produce primarily des-
mocollinite". Under freshwater conditions more telocollinite will form, under
marine conditions more desmocollinite. Together with the liptinite macerals
alginite, sporinite and "cerinite" (the latter from sedge lipids) clarites are
formed from sedge-grass peats. Flooding by oxygenated neutral-pH waters,
Fig. 12. Peat types in the Frazer River delta and the presumed macerals and microlithotypes which
will form from them. From Styan and Bustin (1983a).
47
resulting coal,
dark brown coal with coalified tree stems (xylilicl lighter brown coaJ dark. lough brown coal
megascopic:t~ with stump horizons les~ stems more stems without stems (detmall (delritall
Fig. 13. The presumed moor types and the relating petrograpmc compos~tlonot the Miocene
Rhenish brown coal. From Teichmiiller(1982a).
and peats. Figure 13 shows from the right to the left side, the horizontal se-
quence of different environments and plant communities from open water to
increasingly drier conditions: from submerged plants to a reed marsh, followed
by a wet Nyssa-Taxodium swamp, followed by a drier Myricaceae-Cyrillaceae
bush moor and a Sequoia forest as the driest, final peat-forming vegetation.
Although this scheme has been challenged by later authors (see below), the
author thinks that it still may be used to understand the main facies types of
the Rhenish brown coal which are indicated on Figure 13 according to their
megascopic and microscopic properties. Accordingly, open-water coals are dis-
tinguished by a dark, black colour (due to biochemical gelification) and high
amounts of humodetrinite and liptinite. Reed coals correspond to the "light
layers" of the Rhenish brown coal and carry the highest amounts of humode-
trinite ( > 90% ) and ten times more pollen than the forest coals (Plate III-3).
Forest coals are darker brown in colour, carry stems and stumps from trees,
and are microscopically distinguished by much more humotelinite (Plate III-
4 ) whose cell tissues are better preserved in the coniferous than in the angios-
permous forest coals. Sequoia coal is distinguished by thick stumps and espe-
cially well preserved wood-cell structures. Mukhopadhyay (1986) found sim-
ilar relationships in Tertiary lignites of Texas.
Nevertheless, the scheme of Figure 13 has been challenged by Von der Brelie
and Wolf (1981a,b) and Hagemann and Wolf (1987), the latter authors ap-
plying the combined palynological and coal petrological studies of the first
mentioned authors. Von der Brelie and Wolf (1981a) used the same methods
as Teichmiiller and Thomson (1958) but studied more single coal samples.
Their new interpretations are, however, based on three very short coal sections
with a total thickness of only ten metres (against 50-100 m for the whole
seam ). In contrast to Van der Burgh ( 1973 ) (see below ) the authors concluded
that the peat-forming vegetation consisted mainly of shrubs and trees from
angiosperms. Three types are distinguished on the basis of pollen: (1) a "mi-
crohenrici-type" with oak-like shrubs and trees; (2) a "megaexactus-exactus-
49
type with Cyrillaceae and Clethraceae; and (3) a "Triporates-type" with Myr-
icaceae. No indication of a Nyssa-Taxodium swamp or of reed marshes were
found. Instead, the reed coals of Teichmiiller and Thomson (1958) were inter-
preted as the oxidation product of the same peat that formed in the micro-
henrici-forest swamp with oak-like plants. Their high content of humodetrin-
ite and of pollen (which are of extrapaludal origin according to Teichmiiller
and Thomson, 1958) is regarded as the consequence of strong aerobic decom-
position. The microhenrici-forest is compared with "evergreen oak forests of
central Florida (which, however, grow on dry soils and not in mires ). Accord-
ing to Von der Brelie and Wolf (1981b) Sequoia peats were deposited in "very
moist to moist" environments and not under driest conditions as interpreted
originally by brown-coal palaeobotanists such as Jurasky (1940), Thomson
( 1950/1951 ) and Schneider (1986). The modern Sequoia sempervirens of the
U.S. Pacific coast (mentioned by Von der Brelie and Wolf, 1981b, to document
the requirement for wetness) grows on dry soils and not in mires. Moreover, it
is hard to understand why Sequoia-forest coals do not contain many well-pre-
served wood tissues, i.e., telinites (p. 184 of Von der Brelie and Wolf, 1981b),
because Sequoia wood is known as the most resistant wood of the present time.
Generally, Von der Brelie and Wolf (1981a) stressed the uniformity of the
flora throughout the time of peat formation and compared the vegetation of
the Rhenish brown coal with the uniform vegetation of modern topogenous
forest swamps ("Hochmoorwaldflachmoore") in Sumatra (see fig. 3, p. 152 of
their paper). On the other hand, they assumed a "more or less ombrogenous
origin" for the whole Rhenish brown coal (p. 150). Sphagnum spores were
found in the "Triporates"-forest type with Myricaceae.
The different results of Teichmfiller and Thomson (1958) on one side and
of Von der Brelie and Wolf (1981a,b) on the other side may be partly explained
by the different samples studied. For example, the latter authors (p. 154) ad-
mit that they probably did not study the same type of "light layers" that were
interpreted as reed coals by the earlier authors. This, indeed seems to be the
case. Moreover, in relation to the short profile studied by Von der Brelie and
Wolf (1981a) it must be assumed that only part of the facies of the Rhenish
brown coal has been included, particularly as environmental conditions and
plant associations normally vary in time and space (Cohen, 1968; Koch, 1966;
1970a; Styan and Bustin, 1983a,b). In addition, the present author thinks that
reconstructions of peat-forming vegetation cannot be founded solely on paly-
nological results (cf. p. 17). Thus, for example, it has to be considered that
pollen of Cyperaceae (sedges) and Gramineae (grasses) are easily decomposed
(Kilpper, 1960, p. 295) and that the amount of Cyperaceae-pollen in the sedge
peat of the Everglades is only 3-6% of the total pollen content (Riegel, 1965).
According to Figure 14, in the Everglades, Riegel (1965) found a good corre-
lation between peat-forming vegetations and pollen only in the case of Taxo-
dium-peat. No correlation was found for any other peat types. In the sedge
5/)
50
Site EE-11I
0
~ 40 Site 62-27I
I=
L_o Vt_-__ ~'~__ ~L ~-~
Chenopod Grami . . . . Cyp. . . . . . . ~agit~l~rla ' Compositoe ~voldites'
r~
~~'0~') 20
tl0 ~Type I
Pollen Type
-~ ~ 8
i
SITEE7 ~ L ~
20
I
SITE16
SITE16A
$awgrossenvlronmenti
Fig. 14. The abundance of pollen and spores in Taxodium-forest peats (a) and in marsh peats (b)
of the Everglades, southern Florida. From Riegel (1965). Note the scarcity of C~y]oeraceae and
Gramineae pollen (from the peat-forming vegetation) in the marsh peats.
52
Fig. 15. Scheme of the verticalsuccession of moor types and the resultinglithotypes in the Miocene
Lusatian brown coal (German Democratic Republic). From Schneider (1986). Conifers are in-
dicated sidewards, angiosperms are indicated at the top. Lithotypes are indicated by the following
signs: ~ ~ streakily banded, = = well banded, - - w e a k l y banded, empty white = non-banded.
H B = light band; Z M = bone coal; L = basal coal.
cause the leaves were deposited under still water so that, later, a gelified, well
stratified black band developed as a special lithotype ("sedimentary Glumi-
florae-facies", in contrast to the "sedentary Glumiflorae facies" of Schneider,
1980). At the boundary between the A-facies and the P-facies, Palmae occur
as characteristic plants. The P-facies generated in an oligotrophic, relatively
wet moor with Pinus, Lauraceae, Cyrilla and Myrica. It is represented by a
dark, gelified, well-layered brown coal lithotype with many inclusions of leaves,
barks and roots. The driest and final stage of seam formation (or of a cycle
within the seam) is the M-facies with Sciadopitys and Sequoia, and with (from
the angiosperms ) probably Sapotaceae and Apocynaceae. Most characteristic
of this facies is the abundance of Marcoduria, striking long bands, oriented
approximately parallel to the bedding, thus causing a well layered, streaky
lithotype which is also distinguished by stump horizons. The M-facies usually
is followed by a pale band rich in clastic minerals which represents the end of
seam formation or of a seam cycle.
The origin of Marcoduria has been discussed ever since Weyland ( 1957 ) who
erroneously interpreted the remains of this plant as the epidermis of an inun-
dated water plant (Helobiae). According to the most recent results of Schnei-
der (1989), however, it represents a tissue which separated aerenchymous tis-
sues from the cortex of certain coniferous roots. Marcoduria is a very striking
constituent of German Miocene brown coals, also as seen under the micro-
scope: the thick, sclerenchymatous walls of large, open cells are very low re-
flecting and highly fluorescent (Plate III-6). In thin sections they are aniso-
tropic, obviously due to high cellulose contents.
The brown coals of Victoria, Australia, although originating from types of
vegetation that were different from those of the German brown coals, have
53
,NOEX I I I I
I I I I
I I I
C Eaacfldaceoe/
B ®L2,1 N'::::
Fig. 16. Relations between the colour of lithotypes (A) and the presumed vegetation and deposi-
tional environments (B) in the Latrobe Valley brown coal of Australia. From Luly et al. ( 1980 ).
54
genera, pollen types) of the Latrobe Valley coals is closely associated with
lithotypes: the darker lithotypes generated from swamp forests while the lighter
layers were deposited in an open-water environment.
Very recently, Kershaw et al. (1988) evaluated palaeobotanical studies on
pollen and macrofossils as well as coal-petrological studies on the lithotypes
within all major coal seams of the Latrobe Valley. They found that in all seams
there is a development of hydrological stages from open water through swamp
forests to raised bogs, running parallel with increasing darkness of the litho-
types. The pale and light layers are interpreted as deposits in open water (see
Fig. 16).
Nevertheless, Mackay et al. (1985) offered another concept. They studied
the lithotypes of the Morwell No. I brown coal in dried core samples from four
boreholes covering a seam having a thickness of 100 m. In contrast to Von der
Brelie and Wolf (1981a) and Hagemann and Wolf (1987), they stress the value
of coal colour for the determination and correlation of lithotypes which they
regard as facies dependent. These Australian authors found that the Morwell
No. 1 seam tends to exhibit lightening in brown colour upwards, and that also
single cycles in the seam begin with a dark band and end with a light band.
These cycles are compared with the cycles that Smith (1962) and Smyth and
Cook (1976) suggested for hard coals and interpreted as a development from
wet to drier conditions of peat formation (see pp. 60-63). Referring to the
interpretion of light layers as products of aerobic decomposition of the same
peats that formed dark layers in the Rhenish brown coal (Von der Brelie and
Wolf, 1981a), Mackay et al. (1985) concluded from their soley megascopic
studies that "if the moisture condition....is indeed the dominant factor in de-
termining lithotype, then the most likely explanation for the environment of
formation of these sequences is a wet or waterlogged peat swamp commencing
the cycle, with the peat accumulating on a gradually drying surface." These
results are, however, not in accordance with geochemical findings of Chaffee
and Johns (1985) on a 100-m-thick section of bore cores. These authors state
a "strong support for the view that different lithotypes were derived from dif-
ferent, yet fairly specific palaeobotanical communities" (p. 349) "and are not
merely the result of varied mechanisms or conditions of post-depositional al-
teration upon similar organic source materials" (p. 363 ). Figure 17 shows ear-
lier results of Johns et al. (1981) : compared to the dark layers, the pale and
light layers of the Latrobe Valley brown coal are maximal in hydrocarbon po-
tential, H:C ratio, extracts of aromatic hydrocarbons, triterpenoids, carboxylic
acids and aliphatic carbon, whereas higher amounts of aromatic carbon, phen-
ols and methoxyl groups were found in the dark layers. Thus, the light layers
show a remarkable similarity with type II kerogen of oil shales. These findings
are not consistent with the concept of light layers representing oxidation
products.
55
Pale
Light
M. Lt.
H. Dk.
Dark
Evidence IR.SS IR.SS IR.Py IR.SS IR.SS Py. Ex Ex El Py.RE
SS Fn Fn Pr
ness, he ~'ound in the "Main Seam" (Hauptfl6z) 31 light layers that are 25-50
cm thick. They consist of a crumbling coal without visible plant remains, ex-
cept some fusinite and the upper part of stumps reaching from the underlying
stump horizons into the light layers. WSlk interpreted these light layers as
highly decomposed peats of the same vegetation that formed the dark layers.
Because he knew that oxidized peats generally are darker in colour he ex-
plained the colour of the light layers due to their higher content of bituminous
substances.
WSlk was obviously influenced by ideas of Gothan (1924) who regarded the
pale layers of German Eocene brown coals as oxidized peats, although, later,
Gothan (1937, p. 131) admitted that their formation might have been influ-
enced "by the kind of vegetation". In contrast to the light layers of the Miocene
German brown coals which differ from the dark layers by a merely slightly
lighter brown colour, when dried, the Eocene brown coals of Germany contain
much lighter layers that may attain a yellow tint. For a better differentiation,
these very light layers should be called "pale layers". Technologically, these
pale layers belong to the "Schwelkohlen" which were mined to produce montan
wax and low-temperature (500~C) tar. They are distinguished by high H:C
ratios, high yields of extract ! montan wax) and of tar and relatively high ash
contents. Under the microscope, these pale layers show a groundmass of bi-
tuminite in which are embedded high amounts of other liptinites, especially
sporinite, resinite (also wax), cutinite, suberinite and liptodetrinite, besides
some sclerotinite and inertodetrinite. Huminites are very rare and represented
almost only by ingrown roots (Plate III-8). Sponge spicules and high propor-
tions of clastic minerals indicate a subaquatic deposition.
According to Pflug ( 1957 ) the pale layers contain their own pollen spectrum.
The typical pollen, although very delicate, are well preserved. Laterally and
vertically the pale layers may change over into clay or silt bands. They have
been interpreted by Teichmtiller ( 1950, pp. 463,466-467 ), Pflug ( 1957 ), Koch
( 1969a, 1970a), Klein-Reesink et al. (1982) and Minnigerode and Riegel (1983)
as bituminous gyttjae, whereas Winkler (1986) regards these layers as dry,
oligotrophic forest peats (see below). Klein-Reesink et al. (1982) and Minni-
gerode and Riegel (1983) stated that colour and lightness (Helligkeit) corre-
late closely with the microscopic composition of lithotypes in Eocene brown
coals of Hessen. In the Borken coal, the pale layers are distinguished by a
"strongly fluorescing groundmass" (=bituminite), by high yields of extract-
able bitumen and large proportions of anemophilous pollen which are thought
to have been blown in. Klein-Reesink et al. (1982) found that the increase in
the proportion of bituminite in the pale layers correlates with a shift from the
"coal band" in the H:C/O:C diagram of Van Krevelen (1961) into the band
for organic matter type II (for example, of the Posidonia oil shale). The bitu-
minite groundmass is interpreted as of algal origin and the pale layers as limnic
deposits. On the other hand, the dark layers which are distinguished by a highly
57
gelified humic groundmass (densinite) and lack of well preserved tissues (hu-
motelinite ) were interpreted as the product of aerobic decomposition in a rel-
atively dry environment (Minnigerode and Riegel 1983, p. 315 ).
Winkler (1986) found that the pale layers of the Helmstedt Eocene brown
coal yield three times more extract than the dark layers, and that asphaltenes
and resins are the main components of the extracts. Although the increase of
n-C25-alkanes, fluctuations of homohopane yields, and the higher degree of
humification in the dark layers are considered to indicate a strong microbial
activity in the peat, Winkler interpreted the light layers as degradation prod-
ucts of the same peats that formed the dark layers.
The Eocene brown coals of Germany were deposited in a tropical climate
and, generally, reveal a much stronger decomposition of plant remains than
the Miocene brown coals of Germany which have been deposited in a sub-
t~opical to warm-temperate climate. Moreover, the Miocene brown coals con-
tain many plant remains that can still be correlated easily with modern plants,
living today in the southern United States or in southeastern Asia.
Whereas the pale layers of the Eocene brown coals are interpreted at present
as bituminous gyttjae by the great majority of coal petrologists, the origin of
the light layers in Miocene brown coals of Germany is still highly controversial.
The theory of oxidized peats (W51k, 1935) had been rejected for 25 years by
palaeobotanists and palynologists (such as Jurasky, 1940; Thomson, 1950,1951;
Hunger, 1953; Pflug, 1957 and others) in favour of the concept of a reed-marsh
peat or even of a subaquatic organic mud deposited in open lakes. TeichmiJller
and Thomson (1958) argued that the extremely high content of humodetrinite
(> 90 percent) (Plate III-3) was caused by the high cellulose and low lignin
content of the herbaceous reed vegetation, and that the amount of (well pre-
served!) pollen of the Quercoidites henrici and microhenrici type ( 10-times more
pollen than in the dark layers) came from extrapaludal forests, just as in the
pollen-rich gyttjae of the Rhenish brown coal (Plate III-5). The stumps and
the reworked material at the base of the light layers were regarded as indicators
of an inundation of the underlying forest peat and the initial cause for the reed-
marsh vegetation.
First objections came from Benda (1960) and Kilpper (1960) who both ap-
plied cuticular analysis to Rhenish brown coal. They found only sparse cuticles
of marsh plants in the light layers. Instead, well preserved monocotyledonous
cuticles were found in thin, very dark layers, distinguished by a high degree of
gelification, a pronounced stratification and, in part, by an appearance like
that of sapropelic coals. These dark layers contain plankton and allochthonous
pollen from a forest vegetation rich in conifers. Benda and Kilpper interpreted
these layers as representative of the reed-marsh facies in the Rhenish brown
coal. However, they did not take into account that ( 1 ) concentrations of well-
preserved leaves in finely laminated, dark and highly gelified brown coals are
characteristic of humic gyttjae (Teichmiiller, 1950; Schneider, 1980; Klein-
5~
Reesink and Riegel, 1983): whereas (2) reed-marsh peats like, for example,
~hose of the Okefenokee Swamp of Georgia (Cohen, 1973 ) and the sedge-grass
peats of the Everglades in Florida (Cohen and Spackman, 1977 ) do not contain
well preserved leaves. Instead, the surface litter of the reed plants breaks down
very rapidly, so that a fine granular material occurs just a few inches below the
surface. According to Cohen and Spackman (1977) the ratio between "f'rame-
work" (plant tissues) and "matrix" (detritus) is very low in marsh peats. Like-
wise, Koch (1969b, p.342) describes only root tissues from Holocene peats
deposited in marshes of Cyperaceae and Gramineae, and Styan and Bustin
(1983a) found high amounts of "amorphous" humic matter (humodetrinite),
together with high cellulose/tignin ratios in sedge-grass peats of the Frazer
River delta. Schneider (1980) distinguished between "sedentary" (autochtho-
nous) and "sedimentary" (allochthonous) Glumiflorae peats as facies of the
Lusatian brown coal, the first consisting of dense flat (German: Filz) from
unidentifiable plant remains in which only roots are preserved as tissues,
whereas the allochthonous Glumiflorae brown coals bear well preserved leaf
tissues of Glumiflorae and are distinguished by a dark black colour, high degree
of geliftcation, and pronounced stratification, i.e., the same properties that
Benda (1960) and Kilpper (1960) described for their "reed marsh facies" in
the Rhenish brown coal. Also in modern peats, Cohen et al. (1987) found ge-
lifted masses in deeper subaquatic habitats. The same authors point to the
allochthonous origin of finely layered peats. These examples may suffice to
show that, just as with the palynological results (see p. 50), the results of cu-
ticular analyses must be evaluated with caution when reconstructing vegeta-
tion and peat types of various coal facies.
Weyland (1958), Kilpper (1960), Benda (1960) and, partly, also Hittmann
(1976) assumed that the light layers of the Rhenish brown coal are the result
of large inundations leading to redeposition of detrital peat particles from the
underlying autochthonous peat layers. Jacob (1968) likewise interpreted the
light layers as peats deposited in a wet environment under oxygenated water.
A completely different origin is, however, proposed by Von der Brelie and Wolf
(1981a) and Hagemann and Wolf (1987). These authors returned to the idea
of WSlk (1935) who regarded the light layers as oxidized forest peats (see pp.
55 and 56 ). Hagemann and Wolf ( 1987 ) stated that "in coals with a high amount
of Quercoidites microhenrici pollen" (as those regarded as reed coals by Teich-
mfiller and Thomson, 1958) "the proportion of fine detrital groundmass in-
creases, a fact which points to drier conditions" (p.344) and "never was an
enrichment of the easy scattering Pinus pollen observed in the pale bands of
the so-called Reed-facies (i.e., open water facies)" (p.345). Another argument
is based on geochemical results of Hagemann and Hollerbach (1980): "assum-
ing that high amounts of homohopanes are equivalent to intense microbial
activity and low oxygen concentrations,..., the unbanded light bands show evi-
dence of aerobic decomposition" (p.342). Homohopanes are oxidation prod-
59
This subject has become a favoured one in recent times, especially in regard
to "ombrogenous coal". One of the first authors who studied the vertical se-
quence of lithotypes and microlithotypes in many seams of the Ruhr Carbon-
iferous was E. Hoffmann (1933). Carboniferous seams of the northern hemi-
sphere generally have a seat earth with Stigmaria, the roots of lycopod trees.
According to Hoffmann ( 1933 ) the lower part of the seam is rich in vitrite and
liptinite-poor clarite. The vitrite layers are thick and form megascopic bands
of bright coal, often representing single thick stems of lycopods. Dominating
spores in the clarites were derived from Lepidodendron, Lepidophloios and other
lycopod trees (Scott and King, 1981). Upwards, the vitrite content decreases
and the predominance of bright coal is followed by an increase in semi-dull
and dull layers consistiag of liptinite-rich clarites and durites. In the upper-
most part of the seam, the dull coal may contain more and more clay minerals,
ending in a dirt band. If sapropelic coals occur, they usually lie at or near the
top of the seam. But in many cases the amount of bright coal increases again
just below the top: vitrite and liptinite-poor clarite, associated with carbargilite
represent the end of seam formation. This overall sequence, described by Hoff-
mann (1933) (which may be interrupted by dirt bands) has been interpreted
as a development from drier (forests) to wetter (marshes, open-water) envi-
ronments (see Fig. 8).
It is to the great merit of Smith (1962,1968) (who first combined coal-pet-
rological with palynological methods in studying the sequence of facies in Eng-
lish Carboniferous coals) that he drew attention to a possible development
from initially eutrophic to eventually oligotrophic conditions of peat formation
in Carboniferous coals. Figure 18 shows the spore "phases" and the corre-
sponding microlithotypes within a seam according to Smith (1968). The seam
begins with the "lycospore phase" with vitrites and clarites, followed by a
"transition phase" with trimacerites, followed by the "densospore phase" with
durites rich in spores and in macrinite ("massive micrinite"). This sequence
is interpreted as the development from a wet, eutrophic forest swamp with
61
lycopod trees, through a less wet mire with a more open vegetation rich in
species (sphenopsids, ferns, pteridosperms, and herbaceous lycopods ) to a rel-
atively dry, oligotrophic high moor (raised bog) with an unknown, stunted
vegetation. The characteristic microspore of the densospore phase, namely
Densosporites sphaerotriangularis may have been derived from a lycophyte tree.
Nemejc (1931) and Chaloner (1955) have recovered megaspores of the type
usually found with densospores from species of Sporangiostrobus. Recently,
Wagner (1985) has isolated microspores of the Densosporites type from a large
species of Sporangiostrobus with sigillarian affinites.
A reversal of the plant successions after the densospore phase is thought to
be due to subsidence. The "incursion phase" may be present anywhere within
Phases Petroqraph/
(llcrolithotypes)
Roof
Lycospore Vitrite
and
Clarite
Transition Duroclarite
Clarodurite
Ourite
Densospore (Inertinite mainly massive
micrlnite)
Transition Clarodurite
Duroclarite
VItrite
Lycospore and
Clarite
Seat-earth
Fig. 18. Microspore phases and the related microlithotypes in Carboniferous coal seams from
Yorkshire, England. From Smith (1968).
62
the seam, usually combined with spores either of the "lycospore phase" or the
"'transition phase". It represents temporary flooding of the peat and is char-
acterized by mineral sediment and by thin spores ("tenuispores"), often
weathered, and by assemblages rich in species and partly of allochthonous or-
igin. According to Smith (1962,1968) "crassidurite" (the raised-bog facies) is
distinguished by a low ash content and lack of' pyrite. It occurs preferentially
in relatively thick seams in which peat formation was not interrupted, and
nutrient deficiency could develop. Interestingly, Westphalian C coals do not
contain these crassidurites; according to Smith, this was probably a conse-
quence of a drier climate.
Littke (1985,1987) studied 20 seams of the Ruhr Carboniferous (of' which
10 seams were of Westphalian C age!) using coal petrological (only one seam
also palynological) methods. Four seams showed a sequence similar to that
described by Smith from English Carboniferous coals, and only six seams con-
tained more than 5% macrinite, the maceral which is regarded to be charac-
teristic of the oligotrophic phase. Likewise, Hacquebard and Donaldson ( 1969 )
did not find crassidurite in Canadian Carboniferous coals that are of West-
phalian C and D age. According to detailed coal petrological and palynological
studies in the thick Harbour seam of Nova Scotia, the vertical sequence of
facies is the same as described from Ruhr coals by Hoffmann (1933) (see
above): in the lower part bright coal with vitrites and clarites thought to be
deposited in wet forest swamps (more seldom in reed marshes) predominate,
whereas the upper part of the seam contains more dull layers with spore-rich
clarites, durites and clay partings which were deposited in reed marshes and
open water, respectively. A certain coal band with much degradofusinite and
macrinite is interpreted as a period of dessication, although without assuming
oligotrophic conditions.
On the other hand, recently Bartram (1987), on the basis of the succession
of lycopod megaspores, distinguished in one British Westphalian B coal five
phases that are broadly related to petrographic types, although most changes
in spore phases and petrography are not coincident. At the base of the seam,
carbominerites with vitrites and clarites, containing megaspores of Lepidod-
endron and Lepidophloios predominate. They are interpreted as peat deposits
below the water table in a nutrient-rich environment. Phase 2, with vitrite,
clarite, and cutinite-rich clarite, bears the megaspores (Triangulatissporites,
Valvisisporites) of a herbaceous lycopod vegetation (SellagineUites, Chalo-
neria) and is thought to be nutrient-poor. Phase 3, with trimacerite (i.e. with
increasing amounts of inertinite), is assumed to be formed just at the ground
water table; and phase 4, with durite and trimacerite, containing Zonalesspor-
ires, is interpreted as a peat formed in a raised bog under ombrogenous condi-
tions. Megaspores of the Zonalessporites type occur with the microspores of
the Densosporites type in heterosporous cones of Sporangiostrobus type (Wag-
63
] SANDSTONE
Fig. 19. Presumed moor types of the lower bench of the Upper Hance seam, Kentucky (U.S.A.),
with an ombrogenous domed bog in the centre. From Esterle and Ferm (1986).
Bartram based her conclusions on new coal petrological and palynological data
( see pp. 62,63 ).
According to Fulton (1987), Anderson (1964) differentiated freshwater
"rheotrophic" ( = topogenous) peats with ash contents of > 25 and pH-values
of > 4 from "ombrotrophic" ( = ombrogenous ) peats with < 25% ash and pH-
values of < 4. This would imply that most mineable coal seams have been de-
posited in domed bogs under ombrogenous, oligotrophic and relatively dry con-
ditions. This concept, however, cannot be accepted unreservedly by coal geol-
ogists and coal petrologists because the development from topogenic to
ombrogenic requires that peat formation exceeds subsidence which is possible
only under stable geological conditions. However, such conditions are lacking
in foredeeps and other unstable areas where most coals have been deposited.
Foredeep coals are rich in vitrites and liptinite-poor clarites (Smith, 1962),
often associated with clastic layers and with pyrite inclusions, particularly in
the numerous thin, often unmineable seams of the Hercynian foredeep. In most
cases, periods of stability were apparently too short for a bog surface to build
up high enough above the groundwater table. Consequently, the oligotrophic
"densospore phase" known from English Carboniferous coals (Smith,
1962,1968) could develop only occasionally. Nevertheless, at least ten seams
have substantial beds of crassidurite in the Westphalian A and B of Yorkshire
(pers. commun, of Dr. A.H.V. Smith, Sheffield University).
According to Grosse-Brauckmann (1979b) who investigated many modern
peats in the temperate-climatic zone, "the successional direction from + eu-
trophic to + oligotrophic peat types seems to be an endogenous tendency of all
peat-forming vegetations, but the real process of such successions is highly
65
Fig. 20. Lycopod (mostly sigillarian) forest swamp with calamites in the undergrowth. Recon-
struction on the basis of cast molds of upright stems mapped in the WestphalianA of a quarry
near Essen/Ruhr. See Klusemannand Teichmiiller (1954).
ceous phytoliths and sponge spicules may disappear completely and detrital
mineral matter may be dissolved too by water circulating in peats. Thus, coals
poor in ash may not necessarily be of ombrogenous origin.
Undoubtedly, the problem concerning the recognition, properties and the
significance of coals t h a t have been deposited under oligotrophic and ombro-
genous conditions remains one of the most interesting to be solved in the future.
67
Acidity has a great influence on the bacterial activity in peats. Most bacteria
thrive best under neutral to weakly alkaline conditions (pH 7-7.5). Because
most peats are acid (due to the formation of humic acids), bacterial life in
peats is much less intensive than in "normal" soils. Sphagnum peats have
especially low pH values (3.3-4.6), due to: (1) certain acid secretions of the
Sphagnum plant; (2) to more oxidative conditions of peat formation in a raised
bog; and (3) to higher concentrations of humic acids because water exchange
is lacking. Moreover, the substrata of these peats are commonly represented
by other peat types or sandy (acid) subsoils. The peat of raised forest bogs in
Indonesia is similarly distinguished by low pH values (3.5-4.5), but, whereas
Sphagnum peats of the temperate climate contain excellent preserved plant
tissues, most ombrogenous forest peats of the tropics are strongly decomposed,
due to the high peat temperatures that favour fungal and bacterial decompo-
sition. This should be considered when interpreting Carboniferous coals of
Euramerica as of ombrogenous and oligotrophic origin.
Marine influences on coal facies have been discussed for many years and in
detail (Teichmiiller and Teichmiiller, 1982, pp. 27-30). It is well known that
coals that are covered by marine clastic rocks are rich in sulfur-organic sulfur
as well as pyrite. Only part of the sulfur stems from the peat-forming plants,
most of it comes from SO4-ions of the seawater. According to Neavel (1981)
organic sulfur as well as pyrite owe their emplacement in the seam to the ac-
tivity of sulfur-reducing bacteria. Desulfovibria desulfuricans reduces sulfate
to HeS which is needed for pyrite formation. The iron most likely enters the
swamp adsorbed on clays. Therefore, pyrite is often found adjacent to clay-rich
zones which, for their part, are mostly associated with vitrites and clarites.
According to Westgate and Anderson ( 1984 ), organic sulfur is enriched in 34S
unlike pyritic sulfur.
Recent studies of various peats in the southern United States and in British
Columbia carried out by Cohen et al. (1984), Given and Miller (1985) and
Styan and Bustin (1983a) confirmed that brackish and marine peats are en-
riched in organic and pyritic sulfur. Of course, mangrove peats are extremely
rich in sulfur. According to Cohen et al. (1984), burial of freshwater peat be-
neath marine or brackish peat also leads to an increase of sulfur in the fresh-
water peat, particularly if clay-rich deposits overlie it. Given and Miller (1985)
found total sulfur contents of up to 6% in dried peats of coastal swamps in
Florida. They report that sulfate-reducing bacteria prefer fatty acids of chain
C3 and up, and grow in association with the anaerobic bacterium Clostridium
which can ferment cellulose, thereby converting it to lower fatty acids. Casa-
grande et al. (1977) reported that sulfate-reducing bacteria grow best at high
pH values (6.5-8). In the peat from the Frazer River delta the abundance of
H2S generally correlates with these pH values (Styan and Bustin, 1983a):
t3~
whereas Sphagnum peats have the lowest S-contents (0.22%) brackish peats
are rich in sulfhr (2.9%) and reach maxima of 5.6% S, 70~; of it as organic
sulfur.
Marine-influenced coals are not only enriched in sulfur. The Katharina seam
of the Ruhr Carboniferous, which is overlain by a dark marine or brackish
claystone, is also distinguished by relatively high amounts of hydrogen, nitro-
gen and volatile matter. The characteristic microlithotype is a liptinite-poor,
micrinite-bearing clarite with a perhydrous collinitic groundmass (Teich-
mfiller, 1955). Alteb~iumer (1983) found in the 10 uppermost centimetres of
the Katharina seam, which was studied at 15 different localities, high amounts
of micrinite-bearing bituminite (probably of bacterial origin) as well as abun-
dant exsudatinite and "oil expulsions" in the strongly fluorescing vitrinites,
all indications of intense oil generation from the perhydrous coal which, cor-
respondingly, yields high amounts of extract. The well-known anomalous cok-
ing properties of the Katharina seam (high fluidity, strong swelling) are a
consequence of its high bitumen content. It seems that marine-influenced coals
are especially suited to be oil source rocks (Teichmfiller, 1987, p.143).
Like marine-influenced coals, coals deposited in a calcareous, non-marine
environment show similar petrographic and chemical properties. They are rich
in sulfur (organic sulfur and pyritic), their vitrinites tend to be perhydrous
and their coking behaviour is anomalous and distinguished by low softening
temperatures and high swelling indices. Calcareous solutions from the floor or
the roof, or from partings within the seams cause neutral or alkaline conditions
for a strong bacterial activity which resulted in the formation of fatty acids
(see above) and of other finely divided lipoid substances within the humic
groundmass.
According to Cohen (1974) and Cohen et al. (1987) severe fires in the swamps
of Florida and Georgia may cause the death of the peat-forming vegetation.
During such fires the uppermost part of the peat may burn too. In these cases
the whole peat-forming environment changes suddenly from, for example, a
dense forest swamp to an open-lake or a reed marsh. Plate IV-4 shows such a
situation in the Okefenokee Swamp of Georgia. Such an event would be marked
in the case of hard coal by the appearance of a layer of fusain, underlain by a
bright coal rich in vitrite and clarite {forest peat) and overlain by a dull coal
with liptinite-rich clarites and durites (subaquatic muds or marsh peats) or by
a clastic band. Accordingly, Phillips and DiMichele ( 1981 ) found in the Herrin
No. 6. coal of Illinois the maximum fusain zone just below a shale parting, and
Scott and Collinson (1978) refer to fusain concentrations in English Carbon-
iferous coals that are overlain by lake deposits.
Styan and Bustin (1983a) observed a rapid increase of pyrofusinite (and
69
degradofusinite) in peat types of the Frazer River delta which were deposited
marginal to levees. Small ponds on the peat surface resulted from periodic fires
that burned into the peat and formed depressions (Bustin et al., 1985). Char-
ring of peat was observed after a very dry summer (1959) in a mire in the
Netherlands (Teichmiiller, 1961). Although the fire had been extinguished,
charring was going on locally down to 50 cm below the burned peat surface,
and at some places less than 1 m away from small open-water sinks. During
charring, peat-coke and pyrofusinite did form, the latter with excellent pres-
ervation of cell tissues from roots of living plants. Plate I-9 shows a fusinized
root tissue of a birch that still existed at the surface but was totally dried. The
observations suggest that relatively large pyrofusinites with especially well-
preserved cell tissues represent charred roots. The recent pyrofusinites that
had formed above the peat surface were smaller, fragile and often like fine dust
in size. They are easily blown away by the wind, just like the very fine ash that
formed during the surface burn. Therefore, small particles of fusinite, known
as inertodetrinite, are found in almost all sedimentary rocks where they have
been blown in or washed in. It is surprising that layers or patches of peat coke
seem to be practically unknown from coals. The charred peat is very fragile
because of an enormous porosity (Plate I-8) and, therefore, obviously only
small particles of it remain preserved in coals, mainly as macrinite and
inertodetrinite.
The influence of fires on the succession of plant associations and of litho-
types in Australian brown coals has been stressed by Blackburn (1981) as well
as by Kershaw et al. (1988). Fusinite is enriched in the dark layers but may be
washed into the open-water muds of the light layers as well. The maximum of
fusinite content was found in the darkest layer of the Yallourn brown coal
which is interpreted as a raised-bog peat.
3 CONCLUSIONSAND FURTHERWORK
Since the era of descriptive coal petrography is more or less over, modern
coal petrologists attempt to elucidate the origin of the microscopic entities
("macerals") of coal, by working in cooperation with palaeobotanists and or-
ganic geochemists. Some macerals still show their origin from certain plant
parts ("phyterals"); others do not due to a severe decomposition before or
during the peat stage. Therefore, microscopic studies of peat constituents are
very important in understanding the origin of macerals, which depends on the
source material as well as on its fate during peatification and coalification.
Over the last 15 years coal petrology has greatly profited from results ob-
tained through the microscopic investigation of oil-source rocks and has broad-
ened to "organic petrology" which deals with the microscopic investigation of
organic constituents in all rocks. It is mainly on the basis of organic petrology,
in combination with organic geochemistry, that new insights have been ob-
7(}
tained into the genesis and the coalification/maturation of" macerals. One im-
portant result is the distinction between primary and seconda©' macerals, the
latter generating through disproportional reactions within primary macerals
during coalification/maturation, especially as a result of bituminization. Bi-
tuminization is part of the coalification process and is comparable with the
generation of petroleum in clastic oil-source rocks.
Coal as a source rock [or oil t not only for gas ) has become an important new
subject for coal petrologists (as well as for hydrocarbon exploration! ). It has
been found that not only the H-rich liptinites but also perhydrous vitrinites
generate bitumen, even earlier than many liptinites. These findings were pos-
sible mainly by the use of' fluorescence microscopy. Close relationships were
found between vitrinite fluorescence and coking behaviour, and, in more recent
times, also between the fluorescence of some inertinites and their coking ability.
Microscopic studies of modern peats, partly combined with chemical and
microbiological studies, contributed to the understanding of the genesis and
early fate of huminites/vitrinites which formed from the tissues of higher plants.
Humification takes place in the peat and brown-coal stages. It is a microbial
and chemical process. Although cellulose is much more easily attacked by mi-
croorganisms than lignin, there remain cellulose-rich tissues preserved up to
the brown-coal stage. The question of whether their later coalification prod-
ucts are vitrinites or fusinites is not yet solved. Coalification experiments un-
der water and at elevated temperatures and pressures have shown that cellu-
lose generates bitumen very early, possibly leaving behind secondary "rank
fusinite". The causes of biochemicalgelification in peats and brown coals which
leads to the formation of various kinds of gelinite remain doubtful, although it
has been learnt that this process is promoted in subaquatic muds.
Electron microscopical studies allowed the recognition of tiny lipoid parti-
cles in huminites/vitrinites. These particles are not visible under the light mi-
croscope, but they obviously cause the relatively low reflectance and high flu-
orescence of perhydrous vitrinites. These lipoid inclusions were found to be
associated with indications of fungal and bacterial activity around huminites/
vitrinites.
Geochemicalgelification converts huminites of the peat and brown-coal stages
into the vitrinites of hard coals. It causes the most striking petrographic changes
during the whole coalification process and is obviously related to the early
generation of bitumen (beginning of the "oil window"). The hydrogel brown
coal is converted into the bitumogel hard coal.
For the liptinite maceral group, fluorescence microscopy allowed new results.
This method showed that many liptinites cannot be properly classified when
using the Stopes-Heerlen system of maceral classification. Some new liptinite
macerals were detected by the use of fluorescence microscopy but there remain
other liptinitic constituents (distinguished by a low reflectance and a high
fluorescence ) whose classification and origin remain doubtful. Although there
71
from case to case. For instance, the well-known types of Gondwana coals that
are distinguished by extremely high amounts of inertinites seem to contain
submicroscopic algal remains according to recent studies under the electron
microscope. This would indicate deposition under water (and not dry, oxida-
tive conditions). Not only artificial coalification but also artificial peatifica-
tion experiments may lead to a better understanding of the origin of macerals,
especially of the amorphous types. An ideal example is the work of Masran and
Pocock (1981) who subjected tissues of specific plants to physical, chemical
and biological breakdown under varying laboratory conditions. Electron mi-
croscopical (TEM) studies as applied recently by Taylor and Liu (1987) cer-
tainly will become another method to clarify the (sub-light-)microscopical
composition of macerals and, thereby, possibly, their origin.
Lithotypes and microlithotypes, that is typical maceral associations, may be
regarded as the different coal facies. Modern coal petrology tends to draw con-
clusions from the type and the succession of coal facies to the palaeogeographic
position of peat formation, the peat-forming vegetation, the water and the nu-
trient supply, the peat acidity, the climate of peat formation and accidents like
crevasses and fires. For such studies the cooperation with sedimentotogists,
palaeobotanists and peat experts is necessary. Such studies have shown that
mineable coal seams have been deposited usually in upper delta plains or in
back-barrier areas of coastal plains, and less commonly in limnic environ-
ments along rivers and lakes. Following the pioneering work of Hacquebard
and Donaldson (1969), Australian coal petrologists, especially, tried to find
relationships between coal facies and sites of deposition such as lower and upper
deltaic, fluvial, lacustrine (Smyth 1984) or lower and upper deltaic and pied-
mont plain (Diessel, 1986), using indicators like the ratio vitrite+clarite :
durite + inertite, or a "Gelification Index" and a "Tissue Preservation Index",
respectively. Generally coals rich in vitrite and clarite are thought to have been
deposited in wet and more anoxic environments, for example of foredeeps,
whereas the inertites of Gondwana coals are assumed to have been deposited
in small basins on a stable craton or in piedmont plains. Fluviatile environ-
ments lead to coals rich in vitrites and clarites but also rich in mineral matter.
Lacustrine deposits are distinguished by microlayered clarites and durites,
usually with high liptinite contents and perhydrous collinites.
Vegetation, climate and water supply play a major role in the development of
the various coal facies. The literature of recent decades is full of papers treating
the genesis of lithotypes (of brown coals mainly) and microlithotypes (of hard
coals) in relation to their provenance from plant associations like forests, reeds
with sedges and grasses and submerged and not submerged water plants. Most
authors agree that vitrite and liptinite-poor clarites formed from an arbores-
cent vegetation, that liptinite-rich clarites represent organic muds deposited
in still-water lakes and ponds, and that inertinite-rich durites represent rela-
73
PLATE V
ACKNOWLEDGEMENTS
The author would like to thank the following authors for their permission
to reproduce published figures: R.M. Bustin, C.F.K. Diessel, J.S. Esterle, R.D.
77
Harvey, R.B. Johns, A.P. Kershaw, T.L. Phillips, W. Riegel, A.H.V. Smith, W.
Schneider, M. Smyth and G.H. Taylor. A.M. George was very helpful in pro-
viding literature on Australian brown coals.
The author is very grateful to B. Alpern, and especially to P.C. Lyons, D.G.
Murchison and A.H.V. Smith who revised the manuscript and improved the
English language. Finally, she would like to thank the President of the Geo-
logisches Landesamt Nordrhein-Westfalen, Krefeld, for facilities to prepare
this paper.
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CONTENTS
Abstract 1
Introduction 2
I. Origin of macerals 3
I.I Genesis of huminites/vitrinites 4
1.1.1 Humification and biochemical gelification 4
1.1.2 Macerals of the huminite/vitrinite group 9
1.1.3 Coalification of huminites/vitrinites 13
1.2 Genesis of liptinites 16
1.2.1 Macerals of the liptinite group 17
1.2.2 Coalification of liptinites 22
1.3 Genesis of inertinites 23
1.3.1 Macerals of the inertinite group 23
1.3.2 Coalification of inertinites 29
2. Origin of coal facies (microlithotypes and lithotypes) 29
2.1 Distinction of coal facies 29
2.2 Influence ofdepositional (palaeogeographic)environment 30
2.3 Influence of climate, vegetation and water supply 35
2.3.1 Carboniferous hard coals of Euramerica 35
2.3.2 Gondwana coals (and peats of cool climates) 44
2.3.3 Tertiary brown coals of Germany and Australia 47
2.3.4 Origin of "light layers" in Tertiary brown coals 55
2.4 Vertical succession of coal facies and the influence of nutrient supply (eutrophic- 60
oligotrophic)
2.5 Influence of acidity and of marine and calcareous conditions 67
2.6 Influence of fires 68
3. Conclusions und further work 69
4. References 77