MONTHLY TEST

CLASS : XII
SUBJECT: CHEMISTRY -1 2015
TIME: 1 HOUR MM:30
NOTE: - Attempt all the question. Marks are indicated at the end of each question.

1. Analysis shows that a metal oxide has the empirical formula M0.96O1.00. Calculate the percentage of M2+
and M3+ions in this crystal. (2)
2. Give reasons: -a) At high altitude, people suffer from a disease called anoxia. In this disease, they become
weak and Can’t think clearly.
b) Why is glycol and water mixture used in car radiators in cold countries? (2)

3. Give one example each of miscible liquid pairs showing positive deviation and negative deviation from
Raoults law. Give one reason for each of such deviations. (2)

4. Describe the construction of a H2-O2 fuel cell and the reactions taking place in it. (2)

5. Predict the product of electrolysis of the following:-

a) An aqueous solution of cupric chloride with platinum electrode.
b) An aqueous solution of silver nitrate with silver electrode. (2)

6. A solution prepared from 1.25 g of oil of winter green (methyl salicylate) in 99.0g of benzene has a boiling
point of 80.310C .Determine the molar lass of this compound (Boiling point of pure benzene =80.100C and Kb
for benzene =2.530Kg/mol) (3)

7. Conductivity of 0.00241 M acetic acid is 7.896 x10 –5 Scm-1 Calculate its molar conductivity and if 0m for
acetic acid is 390.5Scm2mol-1, what is its dissociation constant? (3)

8. 100 mg of a protein is dissolved in just enough water to make 10.0 ml of solution. If this solution has an
osmotic pressure of 13.3 mmHg at 250c , what is the molar mass of the protein? (3)

9. The edge length of unit cell of a metal having molecular mass 75g/mol is 5A0.which crystallizes in cubic
lattice. If the density is, 2g/mol then find the radius of metal atom. (3)

10. Explain the following terms with suitable examples.

a) Ferromagnetism b) Paramagntism c) Ferrimagnetism (3)

11.a)What type of battery is the lead storage battery? Write the anodic and cathodic reactions and the overall
reaction occurring in operation of a lead storage battery .
b) Calculate the potential of half cell containing
0.10MK2Cr2O7(aq), 0.20MCr+3 (aq) and1.0x10 –4M H+ (aq) .The half cell reaction is :-
Cr2O72-(aq),+ 14H+ (aq) + 6e- 2Cr3+ (aq) + 7 H2O (l)
And the standard electrode potential is given as Eo =1.33V (5)