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SECTION – A
1. Out of AlCl3 and NaCl, which is more effective in causing coagulation of a negative sol and why
?
2. What percent of carbon content present in pig iron and cast iron?
3. Define: (1) Sorption
(2) CMC
4. Define Desorption and Peptisation?
5. What will be the order of reaction for halogenation of alkanes?
6. What is the ore for extracting sulphur?
7. What is the effect of adding a catalyst on
(a) Activation energy (Ea) and (b) Gibbs energy (∆G) of a reaction ?
SECTION – B
1. The reaction.
2 N 2 O5 ( g ) ⇌ 4No2 ( g ) o2 ( g ) Was studied in a closed vessel. It was found that the
2
concentration Of No 2 increases by 2.2 10 mol l 1 in five seconds
Calculate:-
(1) the rate of reaction
(2) the rate of change of concentration of N 2 O5
2. Write any 4 differences between order of reaction and molecularity of reaction?
3. (i) Name the method of refining which is based on the principle of adsorption.
(ii) What is the role of depressant in froth floatation process ?
(iii) What is the role of limestone in the extraction of iron from its oxides ?
4. What is Van Arkel method of obtaining Ultrapure Metals?
5. Why silica gel is used as a Dehumidizer?
SECTION – C
( Each of 3 mark each) Write in detail :-
1. A first order reaction is 50 % completed in 40 minutes at 300 K and in 20 minutes at 320
K. Calculate the activation energy of the reaction. (Given : log 2 = 0.3010, log 4 =
0.6021, R = 8.314 JK–1 mol–1)
2. (i) Explain Blast furnace method in detail with reactions?
(ii) Explain magnetic separation method?
3. Explain the process in detail with examples:
Leaching (2) Calcinations (3) Roasting
Concept By Sunny Roy Sir (8866617099)/8160759032 Shop no-206,City Light Shopping Centre,City light,
Surat
4.(a) Write any 6 differences between “Physisorption” and “Chemisorptions” with examples in
each?
6.Explain “Hall- Herolt “Process along with neat and clean diagram ?
SECTION – D
( Each of 5 mark each) Write in detail :-
2. (a) The following data were obtained during the first order thermal decomposition of N 2O5 ( g ) at
constant volume:
2 N 2O5 ( g )
2 N 2O4 ( g ) O2 ( g )
S. No. Time/s Total pressure (atm)
1 0 0.5
2 100 0.512
Calculate the rate constant.
(b) A first order reaction is found to have a rate constant, k 5.5 10 14 s 1 . Find the half-life of the
reaction.
Concept By Sunny Roy Sir (8866617099)/8160759032 Shop no-206,City Light Shopping Centre,City light,
Surat