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Experimental data obtained in a 1.2 m diameter distillation research column with a 14% hole area single path
cross-fiow sieve tray having 12.7 mm diameter hobs on 30.2 mm triangular centers are reported. The data include:
(1) capacity, (2) pressure drop, (3) tray efficiency, and (4) entrainment. The data were obtained on the following
systems: (1) cyclohexane-n-heptane at 34 and 165 kPa, and (2) isobutane-n-butane at 1138 kPa. The 14%
sieve tray data are also compared to the 8% sieve tray data obtained under identical experimental Conditions to
illustrate the effect of hole area on sieve tray perfomnce. In summary, the 14% hole area tray exhibited a slight
increase in vapor capacity by 5 to 10% over the 8% hole area tray for two of the three systems studied. In
addition, tray pressure drops were lower by 1 to 3 kPa and entrainment was also lower for the larger hole area
tray. Tray efficiency was slightly lower by about 10% for the 14% hole area tray at comparable conditions.
I* T O T A L REFLUX)
0 ISOBUTANE-N-BUTANE. 1138 k P l
\ -
0 CYCLOHEXANE-N+iEPTANE . 165 kPa
8 CYCLOHEXANE-N4lEPTANE .34 k P l
F, lW.1 0 . 8 2 F. (Enol.)
1 x lo+ m3/1 15.85 galimln
0 10 20 30 10
LIQUID R A T E (m3-s-') x l o 3
1.2 m COLUMN ID
Figure 2. Flooding capacity of 14% hole area sieve tray.
LL
w
>
4
a
80 c
c
d
d
Figure 1. Diagram of test tray.
40tc
4
a
w
described (Silvey and Keller, 1966). >
0
Efficiency. Efficiency studies were conducted at total I
reflux. Samples of the tray outlet liquid were obtained
0
from the bottom of the outlet downcomer and were ana- 0 20 40 60 80 100
lyzed by vapor phase chromatography for the isobutane- PERCENT FLOOD
n-butane mixture and by refractive index for the cyclo- Figure 3. Overall tray efficiency at total reflux.
hexane-n-heptane mixture. Accuracy of the analysis were
within 1% on a relative basis. From profiles of tray com- the vapor rate in a stepwise manner. Intervals were se-
positions in terms of smoothed semilogarithmic plots of lected to obtain at least three and preferably five en-
x/(l - x ) against tray location, overall tray efficiencies were trainment readings for each liquid load.
evaluated. The Fenske-Underwood equation (Fenske,
1932; Underwood, 1932) served as a basis of data inter- Discussion of Results
pretation where Capacity. The capacity of the 14% sieve tray with the
three systems tested is shown in Figure 2. It is evident
that the vapor capacity of sieve trays is complicated by
system property effects as well as the effect of liquid rate.
The capacity of the tray under most circumstances is
limited by one of two mechanisms; Le., a tray may flood
either due to downcomer limitation or massive entrain-
ment. Downcomer or liquid handling limitations usually
This method of interpreting the data serves as a means result under high liquid loads, especially with higher
to determine separation performance as well as to screen pressure systems due to the accumulative hydraulic re-
out inconsistent data (Silvey and Keller, 1966, 1969). sistances of tray pressure drop, downcomer exit loss, and
Pressure Drop. Tray pressure drop measurements the liquid head at the outlet of the downcomer. Flooding
were taken at total reflux conditions. Pressure drop taps due to massive entrainment or liquid carryover by the
were located to obtain readings over single trays and vapor from tray to tray usually occurs at lower liquid
groups of trays. These pressure drop readings were av- loadings and with lower pressure systems. The type of
eraged t o a per tray basis. mechanism causing flood results from a combination of
Entrainment. Measurements of entrainment were operating conditions, i.e., properties and rates as well as
obtained at total reflux and at several constant liquid load hardware design.
conditions. The following standardized procedure was Efficiency. The overall tray efficiencies for the three
used to obtain the entrainment data. (1) For a given systems tested are shown in Figure 3. An effect of
condition, the vapor rate was adjusted by incrementa until pressure is evident for the cyclohexane-n-heptane mixture
a high entrainment rate was obtained. (2) Conditions in over comparable percentages of flood.
the column were held constant until equilibrium was Pressure Drop. Tray pressure drop measurements are
reached and all necessary data were recorded. (3) The shown in Figure 4 at total reflux for the systems tested.
procedure was repeated a t regular intervals by reducing The effect of excessive weeping on the tray pressure drop
714 Ind. Eng. Chem. Process Des. Dev., Vol. 21, No. 4, 1982
5.0 I l 5 I 2.0 r 1 , I
0 ISOBUTANE-N.BUTAHE . I138 LPa
0 CYCLOHEXANE-N4lEPTAHE. 165 LPs
-
LIQUID L O A D O V E R W E I R
0 CYCLOHEXANE-HMPTAHE . 34 kPa
n
0
K
n -
w I
K - I
3 I
v)
v)
ENTRAINMENT AS
a PERCENT OF VAPOR
i
c ( D A S H E D L I N E S INDICATE
WEEPING IN PROGRESS)
0.01
0.01 0.1 1.0 5.0 W 1 2 3
SUPERFICIAL VAPOR VELOCITY (m.s-l) VAPOWBUBBLING AREA (kg-s-1-m-2)
Figure 4. Tray presaure drop at total reflux. Figure 6. Entrainment plots a t constant liquid loads for cyclo-
hexane-n-heptane at 35 kPa.
I I
I /o -I
a
W
It
a
a
Q
E-I 0.1
m m
m m
3
B
W
c ENTRAINMENT RATE
a 0 0.50 kgs-’m+
K
c
z
n 0.10
:
E
0 0.02
a
K
$
W
0.002 ‘
2 4 6 8
LIQUID LOAD OVER WEIR (m2.s-’) x lo3
VAPOR RATE/BUBBLING AREA (kg.s-’.m-*)
Figure 7. Crossplota of vapor rates at constant entrainment rates
Figure 5. Entrainment plots at constant liquid loads for cyclo- for cyclohexane-n-heptane a t 165 kPa.
hexane-n-heptane at 165 kPa.
for the C6-C, system at 165 kPa and the butane system
is clearly evident as a large reduction in pressure drop for
an incremental decrease in the superficial vapor rate. A 1
reduction in efficiency was observed for the corresponding i
points as illustrated in Figure 3. a
W
Entrainment. Effect of Vapor Rate. Entrainment K
a
measurements were obtained a t several constant liquid
rates. Sets of measured entrainment rates as a function
of vapor rate and liquid rate for the cyclohexanen-heptane
system at 165 and 34 kPa are illustrated in Figures 5 and ENTRAINMENT RATE
6. For reference, curves for entrainment rates as per- 0 0 . 5 0 kg.s-1m-2
centages of the vapor rate are also shown. The strong k
K
dependence of entrainment on the vapor rate is clearly
shown. At some conditions, a 10% change in vapor rate
results in a tenfold change in entrainment. >
Effect of Liquid Rate. From entrainment curves such 0 4 8 I2 16
as Figures 5 and 6, crossplots of the vapor rate against the LIQUID LOAD OVER WEIR (m2*s-’) X lo3
liquid rate at constant entrainment levels were obtained Figure 8. Crossplots of vapor rates at constant entrainment rates
for these systems. Although the figures are shown for for cyclohexane-n-heptane at 34 kPa.
constant mass flux rates of entrainment, similar plots can
be obtained for constant percent entrainment levels with level either increases or decreases with increasing liquid
similar trends. The complex nature of the effect of liquid rate. One plausible explanation is that at the low liquid
load on entrainment is shown in Figures 7 and 8. De- rates, there is less liquid head on the tray to impede the
pending on the liquid rate, entrainment rate and system, effects of vapor momentum and high entrainment rates
the vapor rate required to generate a given entrainment result. As the liquid rate is increased, the liquid head
Ind. Eng. Chem. Process Des. Dev., Vol. 21, No. 4, 1982 715
,
N
r
I .
0
E
+-b
r
2.0 -
‘?
E
1
N
,
c
g 1.0-
8 14%
m
,
5 A 8%
II
I n -
U Y
0
0 IO 20 30 40 0 IO 20 30 40
LIQUID RATE (m3.s-l) x lo3 LIQUID R A T E (m3.s-’) x lo3
Figure 9. Effect of hole area on flooding capacity for isobutanen- Figure 11. Effect of hole area on flooding capacity for cyclo-
butane at 1138 kPa. hexane-n-heptane at -30 kPa.
3.0 I 1 I I
1
N I 1
A ISOBUTANE-NWTANE . 1138 k h
8 0 A CVCLOHEXANE-N+lEPTLNE . 165 kPa
Ni i
r
>
W 601
u.
0
I 0
d b 4
0 IO 20 30 40
_.
0 1 .o 2.0 3.0
LIQUID R A T E (m3-s-‘) x io3
Figure 10. Effect of hole area on flooding capacity for cyclo- Fs = Vsp,1/2 (m.~-~)*(kg~m-~)”*
hexanen-heptane at 165 kPa. Figure 12. Effect of hole area on tray efficiency.
increases to increasingly dampen the effects of the mo- 5.0
mentum of the vapor, thus more vapor is required tQ attain - M E I
1
fn
Comparisons to 8% Sieve Tray W -
a 0.1 i
The data obtained with the 14% sieve tray with 12.7 mm n
diameter holes are compared to data obtained with an 8%
sieve tray with an identical hole diameter of 12.7 mm
a
I- /
d (DASHED LINES INDICATE
/. WEEPING IN PROGRESS)
(Sakata and Yanagi, 1979) to examine the effect of hole
area on the performance of sieve trays. Both trays were d
tested in the same 1.2-m low-pressure distillation research
column under identical test conditions and the same test
systems. The hardware configurations were similar for
both tests with the main difference being the tray panels
used for the respective hole area tray.
Capacity. The capacities of the two trays with the
systems tested are shown in Figures 9, 10, and 11. The
14% sieve tray exhibited approximately 5 to 10% higher
capacity with the C6-C, system at both pressures; however,
the capacities of both trays were nearly identical with the
butane system. This similarity in capacities for the butane
system may be attributable to the mechanism for the ca-
.
716 Ind. Eng. Chem. Process Des. Dev., Vol. 21, No. 4, 1982
-
N
8, I Table 111. Sample of Typical F R I Distillation Unit
Experimental DataC for
E Cyclohexane-n-Heptane System, 34 KPa
?
-
-
0
X run number
run typea
624
A
625
A,B,C
628
B,C
726
D
4
w
conditions based o n 4 4 4 5
I
a CYCLOHEXANE-N+IEPTANE. 165 kPa
tray no.
4
vapor density, 1.20 1.12 1.03 0.95
c1
I-I kg/m3
m liquid density, 686 703 718 705
a kg/m3
? vapor rate, kg/s 2.60 2.82 1.69 1.95
W
I-
liquid rate, m 3 / h 56.78 14.45 8.47 2.66
4
CYCLOHEXANE-NdlEPTANE . -30 kPa
entrainment, kg/s 0.365
a
a j tray pressure 1.024 0.858 0.393
0 r drop, kPa
n 0.50 kg.s.'.m'2 ENTRAINMENT RATE
4
>
i overall tray efficiency, 41.1 70.8
%
0 IO 20 30 visual observations 4 4 4
o n tray no.
LIQUID LOAD OVER WEIR (m2.s-') x l o 3 spray height, m m 610 610 17 8
Figure 14. Effect of hole area on the entrainment characteristics linkage o n t o tray none none Mod
(vapor rate at constant entrainment rate). temperature, "C
overhead vapor 52.9 47.1 45.7 50.6
reflux 33.3 36.5 38.3 36.3
efficiency of the 8% sieve tray was consistently higher by tray 9 outlet 54.4 48.7 46.4
about 10% on a relative basis than that of the 14% sieve tray 8 outlet 55.5 50.1 47.2
tray for the three test systems. tray 7 outlet 56.4 51.1 47.8
tray 6 outlet 57.5 52.4 48.7
Pressure Drop. The tray pressure drop at total reflux tray 5 outlet 58.4 53.9 49.7 51.1
of the two trays are compared in Figure 13. As expected, tray 4 outlet 59.2 55.4 51.2
the tray with the higher hole area had a lower pressure tray 3 outlet 59.9 57.2 52.9 53.5
drop at all of the conditions tested. Pressure drops for the tray 2 outlet 60.5 59.4 55.1
14% hole area tray ranged from 1to 3 kPa lower than the tray 1 outlet 55.1
reboiler vapor 62.2 64.0 60.6 55.3
8% tray. reboiler liquid 62.5 64.3 60.2 55.8
Entrainment. Figure 14 compares the entrainment composition of liquid,
characteristics of the 14% sieve tray against the 8% sieve mole % cyclohexane
tray on the C,&, system at the two pressures tested. Both reflux 59.6 88.05 98.8 74.05
trays exhibited similar trends in entrainment character- tray 1 0 outlet 86.9 97.4
istics; however, the 14% tray required more vapor by about tray 9 outlet 85.15 95.7
tray 8 outlet 49.0 83.35 93.7
10% for liquid loadings up to 0.01 m2 s-l to attain a fixed tray 7 outlet 80.7
level of entrainment at any given liquid rate compared to tray 6 outlet 76.5
the 8% sieve tray; i.e., the 14% tray entrains less than the tray 5 outlet 81.9 62.05
8% tray. tray 4 outlet 49.0 63.55 73.2
A sample of typical data obtained with the FRI distil- tray 3 outlet 56.5
lation unit is given in Table 111. tray 1 outlet 50.0
reboiler liquid 44.5 29.4 28.4 48.4
Sakata, M.; Yanagi, T. In “Dlstilletion-l979”;Institution of Chemical Engi- stitution of Chemlcal Englneers: London, 1969.
neers Symposium Series No. 56; Institution of Chemical Engineers: Rug
by, 1979, Vol. I , p 3.2121. Received for review November 9, 1981
S k y . F. C.; Keller, 0. J. Chem. Eng. Prog. 1988, 62(1). 66. Accepted May 10, 1982
Silvey. F. C.; Keller, 0. J. in “Distillation-1969”;Institution of Chemical EngC
neers Symposlum Series No. 32; Institution of Chemical Engineers: Lon- Presented at the AIChE Spring National Meeting, Symposium
don, 1969; p 4:18.
Underwood, A. J. V. Trans. Inst. Chem. Eng. 1932, 70, 112. No. 44, ‘The Effects of Mass Transfer and Hydraulics on Dis-
Zuiderweg, F. J. ”RecommendedText Mixtures for Dlstiilation Columns”; In- tillation Tray Performance”,Houston, April 1981.
This paper reports on preliminary experiments with a new type of valve for shutting off or for controlling the flow
of solids In vertical plpes. It can also be used as a distributor plate plus downcomer for fluidized beds. However,
the stream of solids must be magnetic or must contain some magnetic particles. The grate arrangement was
studied in detail. This device has no moving parts or mechanical action and does not require much power to operate
(-30 W for a 6-in. pipe). The results give promise for the development of new types of gas-solid contactors
with close to plug flow of solids and for multistage fluidized beds which completely avoid and bypass downcomer
problems.
Introduction Theory
Suppose an electrical conductor such as a copper rod Let us see how the spacing of a set of parallel copper
passes through a crowd of magnetic particles. When an conductors, as shown in Figure 2, influences the holding
electric current flows through the conductor then from the current of the MVS. For this, consider a single conductor
laws of electromagnetism the particles will become X, with flowing current I , surrounded by its blanket of
magnetized, will line up, and will also be attracted to the frozen magnetic particles. Focus attention on the outer-
conductor. This is shown in Figure 1. From this principle most particle Y in the lateral direction, the one which is
comes the idea for a device for arresting or controlling the most weakly held (see Figure 3).
flow of solids in pipes. This particle is affected by four kinds of forces, namely
Suppose we insert a set of copper tubes across the flow the interaction F1and F2 with its magnetic neighbors,
path of a stream of raining magnetic solids in a vertical attraction to the conductor F,, gravity Fg,and the frictional
pipe (see Figure 2a). When an electric current is passed resistance to sliding Ff.
through the copper tubes and is high enough, the falling Forces F1and F2 are equal to each other in magnitude
particles will be attracted to the conductors and freeze in but are opposed in direction: hence there is no tendency
place, eventually blocking the flow channel (see Figure 2b). to move up or down. The frictional force Ff is directly
After this the solids will pile up above the blocked zone proportional to the force pressing the particle in toward
(see Figure 2c). Thus we have the makings of a shutoff the conductor F, and related to it by the coefficient of
valve for the flow of solids. And if the current is switched friction. Finally, this frictional resistance just overcomes
on and off at controlled intervals, we have a flow controller the force of gravity Fgsince this particle is still being held.
for solids, all with no moving parta and no mechanical In mathematical terms the force between particle and
action. Fitzgerald and Levenspiel (1982) have coined the conductor is deduced from Jackson (1962) as
term magnetic valve for solids (MVS) for this device.
If air is passed upward through the frozen solids at a
high enough velocity the solids resting on the frozen layer
will fluidize (see Figure 2d); thus we have the makings of where H is the magnetic field intensity. Note that the
a distributor plate and of a solids flow controller for a attractive force is also dependent on the gradient of the
fluidized bed. This is called the magnetic distributor- field intensity dHf dr. For a straight line conductor the
downcomer (MDD). field strength in its vicinity is
This paper reporta on preliminary studies with the MVS, H = I/2ar (2)
the different geometries that can be used, the current
needed to freeze the particles in place and block the flow where I is the current intensity. Hence
channel, called the holding current, and the energy re- -dH/dr = I / 2 a r 2 (3)
quirement of the device. Combining eq 1, 2, and 3 then gives
(4)
‘On leave from The Institute of Coal Chemistry, Chinese
Academy of Sciences, Taiyuan, Shanxi, China. The friction force is proportional to F, or
On leave from University of Salamanca, Spain.
3TRW, Inc., Redondo Beach, CA 90278. Ff= k’F, (5)