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PART : CHEMISTRY
O
OCOCH3 O NH2 O
O H N
N N H OH
(1) OH (2) H3C
H3C N H O
H O NH2 OCOCH3
O
OCOCH3
NHCOCH3
O O O O
N N
OH H OH
(3) H3C N H (4) H3C N
H H O NHCOCH3
O
OCOCH3
O
Ans. (2)
O O
O O O
2. Consider the given plots for a reaction obeying Arrhenius equation (0°C < T < 300°C) : (k and E a are
rate constant and activation energy, respectively)
Ea
(I)
Choose the correct option :
(1) is right but II is wrong (2) Both and are wrong
(3) is wrong but is right (4) Both and are correct
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
vkgsZfu;l lehdj.k dks ekuus okyh ,d vfHkfØ;k ds fy, vkjs[kksa ij fopkj dhft, (0°C < T < 300°C), (k rFkk Ea
Øe'k% nj fu;rkad rFkk laØe.k ÅtkZ gSa)
Ea
(I)
lgh fodYi pqfu;s :
(1) lgh gS ijUrq II xyr gS (2) rFkk nksuksa xyr gSa
(3) xyr gS ijUrq lgh gS (4) rFkk nksuksa lgh gSa
Ans. (4)
Sol. k Ae–Ea / RT
k decreases exponentially with Ea
First graph is correct.
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4. Which hydrogen in compound (E) is easily replaceable during bromination reaction in presence of light?
CH3–CH2–CH=CH2
(E)
(1) –hydrogen (2) –hydrogen (3) –hydrogen (4) –hydrogen
;kSfxd (E) esa izdk'k dh mifLFkfr esa czksehus'ku vfHkfØ;k ds chp dkSu gkbMªkstu vklkuh ls foLFkkfir fd;k tk
ldrk gS ?
CH3–CH2–CH=CH2
(E)
(1) –gkbMªkstu (2) –gkbMªkstu (3) –gkbMªkstu (4) –gkbMªkstu
Ans. (2)
Sol. Allylic radical is more stable.
,ykbfyd ewyd vf/kd LFkk;h gksrk gSA
5. Wilkinson catalyst is :
foyfdUlu mRizsjd gS&
(1) [(Et3P)3rCl] (Et = C2H5) (2) [(Et3P)3RhCl]
(3) [(Ph3P)3RhCl] (4) [(Ph3P)3rCl]
Ans. (3)
Sol. Refer Notes uksV~l nsa[ksA
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
6. Which of the graphs shown below does not represent the relationship between incident light and the
electron ejected from metal surface ?
0 0 Frequency
Energy of Light
of Light
K.E. of K.E. of
Electron Electron
(3) (4)
0 0
Frequency of Light Intensity of Light
uhps iznf'kZr xzkQ esa ls dkSu&lk vkifrr izdk'k rFkk /kkrq i`"B ls fu"dkflr bysDVªkWu ds chp dk lEcU/k lgh <ax ls
ugha vfHkO;Dr djrk gS \
bysDVªkWu dh bysDVªkWu dh
xfrt ÅtkZ la[;k
(1) (2)
0 0
izdk'k dh ÅtkZ izdk'k dh vko`fr
bysDVªkWu dh
bysDVªkWu dh xfrt ÅtkZ
xfrt ÅtkZ
(3) (4)
0
0 izdk'k dh rhozrk
izdk'k dh vko`fr
Ans. (3)
Frequency of Light
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
bysDVªkWu dh
xfrt ÅtkZ KEmax = h–h0
tan= h
Sol.
Intercept = –h0
izdk'k dh vko`fr
7. Which dicarboxylic acid in presence of a dehydrating agent is least reactive to give an anhydride ?
fuEu esa ls dkSu MkbdkckZfDlfyd vEy futZyhdkjd dh mifLFkfr esa ,d ,ugkbMªkbM nsus ds fy, lcls de
vfHkfØ;k’'khy gS \
CH2 O
CO2H
H2 C COOH COOH
H2C OH
(1) (2) COOH (3) (4)
CO2H H2C COOH
CH2 H2C OH
O
Ans. (2)
O
CH2—CH2—COOH CH2—CH2—C
H O
Sol. 2 O
CH2—CH2—COOH CH2—CH2—C
O
7 member cyclic anhydride is less stable.
7 lnL; pØh; ,ugkbMªkbM de LFkk;h gSA
8. The type of hybridisation and number of lone pair(s) of electrons of Xe in XeOF 4, respectively, are :
(1) sp3d2 and 1 (2) sp3d2 and 2 (3) sp3d and 1 (4) sp3d and 2
XeOF4 esa Xe ds ladj.k rFkk ,dkdh bysDVªkWu ;qXeksa dh la[;k Øe'k% gSa&
(1) sp3d2 rFkk 1 (2) sp3d2 rFkk 2 (3) sp3d rFkk 1 (4) sp3d rFkk 2
Ans. (1)
O
F F
Sol. Xe
..
F F
9. The decreasing order of ease of alkaline hydrolysis for the following esters is
fuEu ,LVjksa ds fy, {kkjh; ty vi?kVu ds vklkuh ls gksus dk ?kVrk Øe gS]
COOC2H5 Cl COOC2H5
() ()
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
11. Liquids A and B form an ideal solution in the entire composition range. At 350 K, the vapor pressures of
pure A and pure B are 7 × 103 Pa and 12 × 103 Pa, respectively. The composition of the vapor in
equilibrium with a solution containing 40 mole percent of A at this temperature is :
nzo A rFkk B iwjs la?kVu ds ijkl esa ,d vkn'kZ foy;u cukrs gSaA 350 K ij 'kq) A dk ok”"i nkc rFkk 'kq) B dk
ok"i nkc Øe'k% 7 × 103 Pa rFkk 12 × 103 Pa gSA bl rki ij] ml ok"i dk la?kVu D;k gksxk tks A ds 40 eksy
izfr'kr foy;u ds lkFk lkE; esa gS&
(1) xA = 0.28 ; xB = 0.72 (2) xA = 0.76 ; xB = 0.24
(3) xA = 0.37 ; xB = 0.63 (4) xA = 0.4 ; xB = 0.6
Ans. (1)
xA PA 0 x 'A 7 103 0.4 28 7
Sol. = = = =
xB 0
PB x 'B 12 10 0.6 72 18
3
12. The effect of lanthanoid contraction in the lanthanoid series of elements by an and large means :
(1) increase in atomic radii and decrease in ionic radii
(2) decrease in both atomic and ionic radii
(3) increase in both atomic and ionic radii
(4) decrease in atomic radii and increase in ionic radii
rRoksa ds ySUFksukbM J`a[kyk esa ySUFksukbM ladqpu lkekU;r;k n'kkZrk gS&
(1) ijekf.od f=kT;k esa o`f) rFkk vk;fud f=kT;k es deh
(2) ijkek.kqd f=kT;kvksa rFkk vk;fud f=kT;kvksa nksuksa dk ?kVuk
(3) ijek.kqd f=kT;kvksa rFkk vk;fud f=kT;kvksa nksuksa dk c<+rk
(4) ijekf.od f=kT;k esa deh rFkk vk;fud f=kT;k es o`f)
Ans. (2)
Sol. Decrease in both atomic and ionic radii
ijekf.od f=kT;k ,oa vk;fud f=kT;k nksuksa es deh
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
13. The increasing order of the pKa values of the following compounds is :
fuEu ;kSfxdksa ds pKa dk c<+rk gqvk Øe gS]
OH OH OH OH
NO2
NO2 OMe
A B C D
(1) C < B < A < D (2) B < C < D < A (3) B < C < A < D (4) D < A < C < B
Ans. (3)
Sol. Electron withdrawing group increases acidic strength and Electron releasing group decreases acidic
strength.
bysDVªkWu xzkgh lewg vEyh;rk c<+krk gS vkSj bysDVªkWu nkrk lewg vEyh;rk de djrk gSA
14. The total number of isomers for a square planar complex [M(F) (Cl) (SCN) (NO 2)] is :
oxZ leryh ladqy [M(F) (Cl) (SCN) (NO2)] ds fy;s leko;fo;ksa (vkblksejksa) dh dqy la[;k gksxh&
(1) 16 (2) 4 (3) 12 (4) 8
Ans. (3)
Sol. No. of Isomers lekofo;ksa dh la[;k
[M(F) (Cl) (SCN) (NO2)] 3
[M(F) (Cl) (NCS) (NO2)] 3
[M(F) (Cl) (SCN) (ONO)] 3
[M(F) (Cl) (NCS) (ONO)] 3
dqy Total = 12
15. Which premitive unit cell has unequal edge lengths (a b c) and all axial angles different from 90º ?
(1) Monoclinic (2) Triclinic (3) Hexagonal (4) Tetragonal
fdl vHkkT; ,dd dksf"Bdk esa vleku dksj yEckbZ (a b c) gksrh gS rFkk lHkh v{kh; dks.k 90º ls fHkUu gksrs gS?
(1) f}leyEck{k (2) f=kurk{k (3) "kVdks.kh; (4) ,durk{k
Ans. (2)
Sol. Factual rF;kRedA
16. The values of KP/KC for the following reactions at 300 K are, respectively : (At 300 K, RT = 24.62 dm 3
atm mol–1)
300 K ij] fuEu vfHkfØ;kvksa ds fy, KP/KC ds eku Øe'k% gksaxs (300 K ij RT = 24.62 dm3 atm mol–1)
N2(g) + O2(g) 2NO(g)
N2O4(g) 2NO2(g)
N2(g) + 3H2(g) 2NH3(g)
(1) 1,4.1 × 10–2 dm–3 atm–1 mol, 606 dm6 atm2mol–2
(2) 1,24.62 dm3 atm–1 mol–1, 1.65 × 10–3 dm–6 atm2mol–2
(3) 24.62 dm3 atm mol–1 606.0 dm6 atm2 mol–2, 1.65 × 10–3 dm–6 atm–2 mol2
(4) 1,24.62 dm3 atm mol–1, 606.0 dm6 atm2mol–2
Ans. (2)
ng
Sol. kP /k c = (RT)
kp
(1) ng = 0 ; =1
kc
kp
(2) ng = 2 – 1 = 1 ; = (RT)1 = (24.62)1
kc
kp
(3) ng = 2 – 4 = –2 ; = (RT)–2 = (24.62)–2 = 1.65 × 10–3
kc
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
CH3O CH3O
(1) (2)
OCH3
CH3O
CH3
(3) (4)
CH3
Ans. (1)
MeO MeO
CH2–Cl
AlCl3
Sol.
MeO
MeO
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20. A process has H = 200 J mol–1 and S = 40 JK–1 mol–1. Out of the values given below, choose the
minimum temperature above which the process will be spontaneous :
,d izØe esa H = 200 J mol–1 rFkk S = 40 JK–1 mol–1 gSA uhps fn;s x;s vk¡dM+ksa esa ls ml fuEure rki dk
pquko dfj;s ftlds Åij izØe Lor% gksxk&
(1) 5 K (2) 12 K (3) 4 K (4) 20 K
Ans. (1)
Sol. G = H – TS = 0
H 200
T= = = 5 K.
S 40
21. Water filled in two glasses A and B have BOD values of 10 and 20, respectively. The correct statement
regarding them, is :
(1) A is more polluted than B. (2) Both A and B are suitable for drinking.
(3) A is suitable for drinking, whereas B is not. (4) B is more polluted than A
nks fxyklksa A rFkk B, esa Hkjs gq, ikuh ds BOD dk eku Øe'k% 10 rFkk 20 gSA lgh dFku dks igpkfu;s&
(1) A, B dh rqyuk esa T;knk iznwf"kr gSA (2) A rFkk B, nksuksa gh ihus ds fy, mi;qDr gSaA
(3) A ihus ds fy, mi;qDr gS tcfd B ugha gSA (4) B, A dh rqyuk esa T;knk iznwf"kr gSA
Ans. (4)
Sol. Clean water would have BOD value of less than 5 ppm whereas highly polluted water could have a
BOD value of 17 ppm or more.
LoPN ty esa BOD dk eku 5 ppm ls de gksxk tcfd vR;f/kd iznwf"kr ty esa BOD dk eku 17 ppm ;k mlls
vf/kd gks ldrk gSA
22. The major product formed in the reaction given below will be :
uhps nh xbZ vfHkfØ;k esa cuus okyk eq[; mRikn gksxk&
NH2
NaNO2
Aq. HCl, 0 – 5 ºC
OH
(1) (2) OH
NO2
(3) (4) NO2
Ans. (BONUS)
23. The total number of isotopes of hydrogen and number of radioactive isotopes among, them,
respectively, are :
(1) 3 and 2 (2) 2 and 0 (3) 3 and 1 (4) 2 and 1
gkbMªkstu ds leLFkkfudksa dh dqy la[;k rFkk muesa jsfM;ks/kehZ leLFkkfudksa dh la[;k Øe'k% gSa :
(1) 3 rFkk 2 (2) 2 rFkk 0 (3) 3 rFkk 1 (4) 2 rFkk 1
Ans. (3)
Sol. Protium, Deuterium, Tritium are three isotopes of hydrogen out of which tritium is radioactive.
izksfV;e] M~;wVsfj;e rFkk VªkbfV;e gkbMªkstu ds rhu leko;oh gSaA buesa ls VªkbfV;e jsfM;ks lfØ; gSA
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
25. If dicxhloromethane (DCM) and water (H2O) are used for differential extraction, which one of the
following statements is correct ?
(1) DCM and H2O will make turbid/colloidal mixture
(2) DCM and H2O will be miscible clearly
(3) DCM and H2O would stay as lower and upper layer respectively in the S.F.
(4) DCM and H2O would stay as upper and lower layer respectively in the separating funnel (S.F.)
;fn MkbDyksjksesFksu (DCM) rFkk ty (H2O) dks vody fu"d"kZ.k esa iz;ksx fd;k tkrk gS rks fuEu esa ls dkSu lk
dFku lgh gS \
(1) DCM rFkk H2O ,d vkfoy@dksykbMh foy;u cuk;saxs
(2) DCM rFkk H2O Li"V :i ls feJ.kh; gksaxs
(3) DCM rFkk H2O i`FkDdkjh Qusy esa Øe'k% fuEu rFkk mPp lrgksa esa :dsaxs
(4) DCM rFkk H2O i`FkDdkjh Qusy esa Øe'k% Åijh rFkk fupys Hkkx esa :dsaxs
Ans. (3)
(1) (2)
Ph Ph
(3) (4)
Ph Ph
Ans. (1)
Br
Alc. KOHexcess
Sol. Ph Ph Ph
Br Conjugated diene la;qfXer MkbbZu
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| JEE MAIN-2019 | DATE : 10-01-2019 (SHIFT-1) | CHEMISTRY
28. A mixture of 100 m mol of Ca(OH)2 and 2 g of sodium sulphate was dissolved in water and the volume
was made up to 100 mL. The mass of calcium sulphate formed and the concentration of OH– in
resulting solution, respectively, are : (Molar mass of Ca(OH) 2, Na2SO4 and CaSO4 are 74, 143 and 136
g mol–1, respectively; Ksp of Ca(OH)2 is 5.5 × 10–6)
100 m mol Ca(OH)2 rFkk 2 g lksfM;e lYQsV ds ,d feJ.k dks ty esa ?kksydj mldk vk;ru 100 mL rd fd;k
x;kA cus gq, foy;u esa dSfY'k;e lYQsV dk nzO;eku rFkk OH– dh lkUnzrk Øe'k% gSa] (Ca(OH)2, Na2SO4 rFkk
CaSO4 ds eksyj nzO;eku gSa Øe'k% 74, 143 rFkk 136 g mol–1, Ca(OH)2 dk Ksp = 5.5 × 10–6)
(1) 13.6 g, 0.14 mol L–1 (2) 13.6 g, 0.28 mol L–1
(3) 1.9 g, 0.28 mol L–1 (4) 1.9 g, 0.14 mol L–1
Ans. (3)
Sol. Ca(OH)2 + Na2SO4 CaSO4 + 2 OH–
2000
100 mmol
142
= 13.986 14 milimol 14 mmol 28 mmol
14 136
mass of CaSO4= = 1.9 g
1000
14 136
CaSO4 dk nzzO;eku = = 1.9 g
1000
28
[OH–] = = 0.28 M
100
OH OH
CH2CH2OH CH2CH2OH
(1) (2)
O O
OH O
CH2–C–OCH3 CH2–C–H
(3) (4)
Ans. (3)
Sol. Ester and alkene are not reduced by NaBH4.
NaBH4 ,LVj rFkk ,Ydhu dk vip;u ugha djrk gSA
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