JEE Main 2019 Chemistry January Attempt Shift - 2 (11th January, 2019)

PAPER-1 (B.E./B. TECH.
JEE (Main) 2019

COMPUTER BASED TEST (CBT)
Date: 11 January, 2019 (SHIFT-2) | TIME : (2.30 p.m. to 5.30 p.m)
Duration: 3 Hours | Max. Marks: 360

SUBJECT : CHEMISTRY
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| JEE MAIN-2019 | DATE : 11-01-2019 (SHIFT-2) | CHEMISTRY
PART : CHEMISTRY
Straight Objective Type (lh/ks oLrqfu"B izdkj)

This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 30 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. The reaction that does NOT define calcination is :

vfHkfØ;k tks fuLrkiu dks ifjHkkf”"kr ugha djrh gS] gS %
 
(1) CaCO3. MgCO3  CaO + MgO + 2CO2 (2) 2Cu2S + 3O2  2Cu2O + 2SO2
 
(3) Fe2O3.XH2O  Fe2O3 + XH2O (4) ZnCO3  ZnO + CO2
Ans. (2)
Sol. Cu2S + O2 Cu2O + 2SO2 is roasting process HktZu izØe gSA
2. The major product obtained in the following reaction is :

fuEu vfHkfØ;k esa çkIr eq[; mRikn gS %
O OH
LiAlH4 LiAlH 4
excess
  
vkf/kD;

CH3
NO2 OH
OH OH OH OH
(1) (2) (3) (4)

CH3 CH3 CH3 CH3
NH2 OH NO2 OH NH2 OH NH2 OH
Ans. (1)
Sol. LiAlH4 reduces carboxylic acid, ketone, nitro group but it does not reduce alkenes.
LiAlH4, dkcksZfDlfyd vEy] dhVksu] ukbVªks lewg dks vipf;r dj nsrk gS fdUnq ,Ydhu dks vipf;r ugha djrk gSA
3. The correct option with respect to the Pauling, electronegativity values of the elements is :
rRoksa ds ikmfyax fo|qr _.kkRedrk eku dk lgh fodYi gS %
(1) Te > Se (2) Ga < Ge (3) Si < Al (4) P > S
Ans. (2)
Sol.
Element Al Si P S Ga Ge Se Te
E.N. 1.5 1.8 2.1 2.5 1.6 1.8 2.4 2.1

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4. The major product of the following reaction is :

fuEu vfHkfØ;k dk eq[; mRikn gS %
HO
(1) (2)
Cl
(3) (4)
Ans. (2)
OH
OH OH
(1)HCl
  (2) Anhy. futZy AlCl3
Sol.  
EAS(Friedel craft rxn)
Cl
5. The standard reaction Gibbs energuy for a chemical reaction at an absolute temperature T is given by
G° = A – BT
Where A and B are non-zero constants. Which of the following is TRUE about this reaction ?
(1) Endothermic if A > 0 (2) Exothermic if B < 0
(3) Exothermic if A > 0 and B < 0 (4) Endothermic if A < 0 and B > 0
ije rki T ij ,d jkl;fud vfHkfØ;k ds fy, ekud vfHkfØ;k fxCt ÅtkZ fuEu ds }kjk vfHkO;Dr dh tkrh gS
G° = A – BT
tgk¡ A rFkk B 'kwU; u gksus okys fLFkjkad gSA bl vfHkfØ;k ds fy, fuEu esa ls dkSu&lk lR; gS \
(1) Å"ek'kks"kh ;fn A > 0 (2) Å"ek{ksih ;fn B < 0
(3) Å"ek{ksih ;fn A > 0 rFkk B < 0 (4) Å"ek'kks"kh ;fn A < 0 rFkk B > 0
Ans. (1)
Sol. G = A – BT
= H – TS
A = H
H = A = +ve endothermic Å"ek'kks"kh

6. Given the equilibrium constant : KC of the reaction Cu(s) + 2Ag+(aq)  Cu2+ (aq) + 2Ag(s) is 10 × 1015,
 RT 
caluclate the E 0cell of this reaction at 298 K : 2.303 at298K  0.059 V 
 F 
Cu(s) + 2Ag+(aq)  Cu2+ (aq) + 2Ag(s) vfHkfØ;k dk fn;k x;k lkE; fLFkjkad] KC, 10 × 1015 gSA 298 K ij
 RT 
bl vfHkfØ;k ds E0cell dh x.kuk dhft,A 2.303 at298K  0.059 V 
 F 
(1) 0.4736 mV (2) 0.04736 V (3) 0.4736 V (4) 0.04736 mV
Ans. (3)
0.0591 0.0591
Sol. E°cell = log Kc = log(1 1016 ) = 0.4728 V
n 2
7. K2HgI4 is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is :
K2HgI4 tyh; foy;u esa 40% vk;fur gSA okUVgkWQ xq.kkad (i) dk eku gksxk :
(1) 1.8 (2) 1.6 (3) 2.0 (4) 2.2
Ans. (1)
Sol. K2[HgI4] 2K+ + [HgI4]–2 ; n = 3
i = 1 + (3 – 1) × 0.4
= 1 + 2 × 0.4 = 1.8
8. Among the colloids cheese (C), milk (M) and smoke (S), the correct combination of the dispered phase
and dispersion medium, respectively is :
(1) C : liquid in solid; M : liquid in liquid; S : solid in gas
(2) C : solid in liquid; M : liquid in liquid; S : gas in solid
(3) C : solid in liquid; M : solid in liquid; S : solid in gas
(4) C : liquid in solid; M : liquid in solid; S : solid in gas
dksykbM+ksa] tSls iuhj (C), nw/k (M) rFkk /kwvka (S) ds fo"k; esa ifjf{kIr çkoLFkk rFkk ifj{ksi.k ek/;e dk lgh esy
Øe'k% gksxk %
(1) C : Bksl esa nzo ; M : nzo esa nzo; S : xSl esa Bksl (2) C : nzo esa Bksl ; M : nzo esa nzo ; S : Bksl esa xSl
(3) C : nzo esa Bksl ; M : nzo esa Bksl; S : xSl esa Bksl (4) C : Bksl esa nzo ; M : Bksl esa nzo ; S : xSl esa Bksl
Ans. (1)
Sol. Cheese liquid in solid
Milk liquid in liquid
Smoke Solid in gas
Sol. iuhj Bksl esa nzo
nw/k nzo esa nzo
/kqvk¡ xSl es Bksl

9. Match the following item in column I with the corresponding item in column II.
Column I Column II
(i) Na2CO3.10H2O (A) Portand cement ingredient
(ii) Mg(HCO3)2 (B) Castner-Kellner process
(iii) NaOH (C) Solvay process
(iv) Ca3Al2O6 (D) Temporary hardness
dkWye I esa fn;s x;s fuEu enksa dks muds laxr dkWye II esa fn;s x;s enksa ls lqesfyr dhft,A
dkWye I dkWye II
(i) Na2CO3.10H2O (A) iksVZySaM lhesaV dk la?kVd
(ii) Mg(HCO3)2 (B) dSLVuj dsyuj çØe
(iii) NaOH (C) lkYos çØe
(iv) Ca3Al2O6 (D) vLFkk;h dBksjrk
(1) (i)  (C); (ii)  (D); (iii)  (B); (iv)  (A) (2) (i)  (C); (ii)  (B); (iii)  (D); (iv)  (A)
(3) (i)  (D); (ii)  (A); (iii)  (B); (iv)  (C) (4) (i)  (B); (ii)  (C); (iii)  (A); (iv)  (D)
Ans. (1)
10. The higher concentration of which gas in air can cause stiffness of flower buds?
gok esa fdldh mPp lkUnzrk Qwy dh dfy;ksa esa l’[riu yk ldrh gS \
(1) NO2 (2) CO (3) SO2 (4) CO2
Ans. (3)
Sol. Fact based
The higher concentration of SO2 gas in air can cause stiffness of flower bonds.
rF;kRed
ok;q esa SO2 xSl dh mPp lkUnzrk ds dkj.k iq"i dfydkvksa esa dBksjrk vk ldrh gSA
11. The hydride that is NOT electron different is :

gkbMªkbM tks bysDVªkWu U;wu ughs gS] og gS %
(1) GaH3 (2) SiH4 (3) AlH3 (4) B2H6
Ans. (2)
Sol. Octet complete in SiH4
SiH4 esa v"Vd iw.kZ

12. The coordination number of Th in K4[Th(C2O4)4(OH2)2] is :

C2O24– = Oxalato 
K4[Th(C2O4)4(OH2)2] esa Th dh leUo; la[;k gS :
C2O24– = Oxalato 
(1) 14 (2) 10 (3) 6 (4) 8
Ans. (2)
Sol. C.No. = 4 × 2 + 2× 1 = 10
C2O4–2 bidentate f}nUrqd
OH– monodentate ,dynUrqd
13. The homopolymer formed from 4-hydroxy-butanoic acid is :

4-gkbMªkDlh C;wVsuksbd vEy ls cuus okyk lecgqyd gS %
(1) (2) (3) (4)
Ans. (4)
O
Sol. Polymerisation
HO–CH2–CH2–CH2–COOH   (O–(CH2)3–C)n
(PHB)
PHB is biodegradable polymer
O
cgqydhdj.k
Sol. HO–CH2–CH2–CH2–COOH   (O–(CH2)3–C)n
(PHB)
PHB ,d ckW;ksfMxzsMscy cgqyd gSA
14. The correct match between Item I and Item II is :

Item I Item II
(A) Ester test (P) Tyr
(B) Carbylamine test (Q) Asp
(C) Phthalein dye test (C) Ser
(D) Lys
en I rFkk II ds chp lgh lqesy gS :
en I en II
(A) ,LVj ijh{k.k (P) Tyr
(B) dkchZy,sehy tkap (Q) Asp
(C) FkSyhu Mkb VsLV (R) Ser
(S) Lys
(1) (A)  (Q); (B)  (S); (C)  (R) (2) (A)  (R); (B)  (Q); (C)  (P)
(3) (A)  (R); (B)  (S); (C)  (Q) (4) (A)  (Q); (B)  (S); (C)  (P)
Ans. (4)
Sol. Phthalein test is given by phenolic ring that is present in Tyrosine.
fQuksfyd oy; }kjk FkSfyu ijh{k.k fn;k tkrk gS tks fd Vk;jkslhu esa mifLFkr gSA

15. The major product obtained in the following conversion is :

fuEu :ikUrj.k esa çkIr gksus okyk eq[; mRikn gS %
(1) (2)
(3) (4)
Ans. (2)
CH3 O O
CH3 O C CH3
C C
O
O CH3
Br2 (1eq.)
Sol.   Br 
MeOH
O C Br
O O
4KOH, O
16. A 
2
 2B + 2H2O
(Green)
4HCl
3 B  2C + MnO2 + 2H2O
(Purple)
H O, KI
2 C 2   2A + 2 KOH + D
In the above sequenec of reactions,
A and D , respectively, are :
(1) KIO3 and MnO2 (2) MnO2 and KIO3 (3) KI and K2MnO4 (4) KI and KMnO4

4KOH, O
A 
2
 2B + 2H2O
(gjk)
4HCl
3 B  2C + MnO2 + 2H2O
(cSaxuh)
H O, KI
2 C 2 
 2A + 2 KOH + D
vfHkfØ;kvksa ds mijksDr Øe esa] A rFkk D Øe'k% gS %
(1) KIO3 rFkk MnO2 (2) MnO2 rFkk KIO3 (3) KI rFkk K2MnO4 (4) KI rFkk KMnO4
Ans. (2)
Sol. 2MnO2 + 4KOH + O2 K2MnO4 + 2H2O
(A) (Green) (B)
3K2MnO4 + 4HCl  2KMnO4 + MnO2 + 4KCl + 2H2O
(B) (Purple) (C)
2KMnO4 + K + H2O  2MnO2 + KO3 + 2KOH
(C) (A) (C)
17. For the equilibrium 2H2O H3O+ + OH–, the value of G° at 298 K is approximately :
2H2O H3O+ + OH– lkE; ds fy,] 298 K ij G° dk eku yxHkx gS %
(1) 80 kJ mol–1 (2) –100 kJ mol–1 (3) –80 kJ mol–1 (4) 100 kJ mol–1
Ans. (1)
Sol. G° = – 2.303 RT log K
= – 2.303 × 8.314 × 298 log (10–14)
kJ
= + 80
mol
18. A compound 'X' on treatment with Br2/NaOH, provided C3H9N, which gives positive cabylamine test.
Compound 'X' is :
,d ;kSfxd 'X' dks Br2/NaOH ds lkFk vfHkd`r djus ij C3H9N fn;k tks /kukRed dkfcZy,ehu tk¡p nsrk gSA ;kSfxd
'X' dh lajpuk gS %
(1) CH3COCH2NHCH3 (2) CH3CON(CH3)2
(3) CH3CH2COCH2NH2 (4) CH3CH2CH2CONH2
Ans. (4)
Br NaOH
Sol. CH3CH2CH2CONH2 (A) 
2
 B(CH3CH2CH2NH2 )
Primary amines give positive carbyl amine test

izkFkfed ,ehu /kukRed dkfcZy ,ehu ijh{k.k nsrs gSA
19. The reaction, MgO(s) + C(s)  Mg(s) + CO(g), for which rH° = +491.1 kJ mol–1 and rS° = 198.0 JK–1
mol–1, is not feasible at 298 K. Temperature above which reaction will be feasible is :
vfHkfØ;k] MgO(s) + C(s)  Mg(s) + CO(g), ftldk rH° = +491.1 kJ mol–1 rFkk rS° = 198.0 JK–1 mol–1 gS]
298 K ij lEHko ugha gSA og rki ftlds Åij vfHkfØ;k lEHko gksxh] gS %
(1) 2380.5 K (2) 1890.0 K (3) 2040.5 K (4) 2480.3 K

Ans. (4)
Sol. H–TS < O
H
T>
S
491.1 1000
T>
198
T > 2480.3 K
20. The relative stability of +1 oxidation state of group 13 elements follows the order :
xqzi 13 rRoksa dh +1 vkWDlhdj.k voLFkk dk vkisf{kd LFkkf;Ro bl Øe esa gS %
(1) TI < ln < Ga < Al (2) Ga < Al < In < TI (3) Al < Ga < Tl < In (4) Al < Ga < In < TI
Ans. (4)
Sol. Due to inert pair effect
vfØ; ;qXe izHkko ds dkj.k
21. The number of bridging CO ligand(s) and Co-Co bond (s) in Co2(CO)8, respetively are :
(1) 4 and 0 (2) 0 and 2 (3) 2 and 1 (4) 2 and 0
Co2(CO)8 esa lsrq ca/ku CO fyxUM rFkk Co-Co vkcU/k@vkcU/kksa dh la[;k Øe'k% gS %
(1) 4 rFkk 0 (2) 0 rFkk 2 (3) 2 rFkk 1 (4) 2 rFkk 0
Ans. (3)
CO CO CO
Sol. CO Co Co CO
CO CO CO
No of Co–Co bond = 1
no of briding carbonyl = 2
Co–Co cU/k dh la[;k = 1
lsrq dkcksfZ uy dh la[;k = 2
22. The radius of the largest sphere which fits properly at the centre of the edge of a body centred cubic
unit cell is : (Edge length is represented by 'a')
dk; dsfUnzr ?ku ,dy lsy ds dksj ds dsUnz esa cSBus okys ¼fQV gksus okys½ lcls cM+s xksys dh f=kT;k gksxh :
(dksj yEckbZ dks 'a' }kjk O;Dr fd;k x;k gS) :
(1) 0.047 a (2) 0.027 a (3) 0.134 a (4) 0.067 a
Ans. (4)
a
Sol. =R+r
2
3a = 4R
0.5 a = 0.433 a + r
r = 0.067 a

23. The de Broglie wavelength () associated with a photoelectron varies with the frequency () of the
incident radiation as, [0 is threshold frequency] :
izdkf'kd bysDVªkWu ls lEcfU/kr fM&czkWXyh rjaxnS/;Z (), vkifrr fofdj.k dh vko`fr () ds lkFk bl çdkj ifjofrZr
gksrh gS [0 = nsgyh vko`fr] :
1 1 1 1
(1)   (2)  (3)   (4) 
v – 
3
v0 2
v 0 – v 0  v – 
1
v0 2
1
v – v 0 4
Ans. (3)
1
Sol. h   h 0  mv 2
2
1
h(  – 0 )  mv 2
2
1/ 2
 2h(  – 0 ) 
v 
 m 
h h m h
  
mv m 2h( – 0 ) m( – 0 )
1

( – 0 )1/ 2
24. Which of the following compounds reacts with ethyl magnesium bromide and also decolourizes bromine
water solution :
fuEufyf[kr esa ls dkSu&lk ;kSfxd ,fFky eSXuhf’k;e czksekbM ls vfHkfØ;k djrk gS rFkk czksehu ty dks jaxghu Hkh
djrk gS %
(1) (2)
(3) (4)
Ans. (3)
25. Taj Mahal is being slowly disfigured and discoloured. This is primarily due to :
(1) water pollution (2) acid rain (3) soil pollution (4) global warming
rktegy /khjs&/khjs fo:i rFkk csjax gksrk tk jgk gSA ;g eq[; :i ls bl dkj.k ls gS %
(1) ty çnw"k.k (2) vEy o”"kkZ (3) e`nk çnw"k.k (4) Xykscy okfeZx
Ans. (2)
Sol. Fact based rF;kRedA

26. 25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume
of this HCl solution required to titrate 30 mL of 0.2 M aqqueous NaOH solution?
25 mL HCl foy;u ds fy;s 0.1 M lksfM;e dkcksZusV foy;u dk 30 mL vko’';d gksrk gS] 0.2 M tyh; NaOH ds
foy;u dks vuqekfir djus ds fy;s bl HCl foy;u ds fdrus vk;ru dh vko’';drk gksxh \
(1) 12.5 mL (2) 75 mL (3) 50 mL (4) 25 mL
Ans. (4)
Sol. eq. of HCl = eq. of Na2CO3
25 × N = 2 × 0.1 × 30
HCl = 0.24 N
eq. of HCl = eq. of NaOH
0.24 × V = 30 × 0.2
V = 25mL
Sol. HCl ds rqY;kad = Na2CO3 ds rqY;kad
25 × N = 2 × 0.1 × 30
HCl = 0.24 N
HCl ds rqY;kad = NaOH ds rqY;kad
0.24 × V = 30 × 0.2
V = 25mL
27. The correct match between Item I and Item II is :

Item I Item II
(A) Allosteric effect (P) Molecule binding to the active site of enzyme
(B) competitive inhibitor (Q) Molecule crucial for communication in the body
(C) Receptor (R) Molecule binding to a site other than the active site of enzyme
(D) Poison (S) Molecule binding to the enzyme covalently
en I rFkk en II ds chp lgh lqesy gS %
en I en II
(A) ,syksLVsfjd çHkkj (P) ,Utkbe ds lfØ; Hkkx ls v.kq dk ca/ku
(B) çfr;ksxh fujks/kd (Q) 'kjhj esa ladVdkyhu lalwpd v.kq
(C) xzkgh (R) ,Utkbe ds lfØ; Hkkx ds vykok v.kq dk ca/ku
(D) fo"k (S) v.kq tks ,Utkbe ls lgla;kstd :i ls vkcaf/kr gS
(1) (A)  (P); (B)  (R); (C)  (Q) ; (D)  (S) (2) (A)  (R); (B)  (P); (C)  (S) ; (D)  (Q)
(3) (A)  (P); (B)  (R); (C)  (S) ; (D)  (Q) (4) (A)  (R); (B)  (P); (C)  (Q) ; (D)  (S)
Ans. (4)
Sol. Fact rF;A
28. The reaction 2X  B is a zeroth order reaction. If the intial concentration of X is 0.2 M, the half-life is 6
h. When the initial concentration of X is 0.5 M, the time required to reach its final concentration of 0.2 M
will be :
vfHkfØ;k] 2X  B ,d 'kwU; dksfV dh vfHkfØ;k gSA 0.2 M dh çkjfEHkd lkUnzrk ds fy,] v)Zvk;q 6 h gSA ;fn X dh
çkjfEHkd lkUnzrk 0.5 M gks] rks 0.2 M dh vafre lkUnzrk igqpus esa yxus okyk le; gksxk %
(1) 18.0 h (2) 12.0 h (3) 7.2 h (4) 9.0 h

Ans. (1)
C0 0.2 1
Sol. t1  6 k 
2
2k 2k 60
Now vc, Ct = C0 – Rk
1
0.2 = 0.5 – t
60
t
0.3 =  t  18hrs
60
29. Which of the following compounds will produce a precipitate with AgNO 3 ?
AgNO3 ds lkFk fuEu ;kSfxdksa esa ls dkSulk vo{ksi nsxk %
(1) (2) (3) (4)
Ans. (2)
Br

AgNO
Sol. 
3
 + AgBr(Yellow ppt ihyk vo{ksi)
Intermediate carbocation is resonance stabilised and aromatic.

e/;orhZ dkcZ/kuk;u vuqukn LFkk;hd`r ,oa ,sjkseSfVd gSA
30. In the following compound.
the favourable site/s for protonation is /are :

(1) (a) and (e) (2) (a) and (d) (3) (b), (c) and (d) (4) (a)
fuEu ;kSfxd esa]
çksVuhdj.k ds fy, vuqdwy LFky gS@gSa %

(1) (a) rFkk (e) (2) (a) rFkk (d) (3) (b), (c) rFkk (d) (4) (a)
Ans. (3)
Sol. Lone pair of electons in 'a' and 'e' are used in delocalisation.
'a' vkSj 'e' ds ,dkdh ;qXe bysDVªkWu foLFkkiu es iz;ksx gks jgs gSA


JEE Main 2019 Chemistry January Attempt Shift - 2 (11th January, 2019)

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JEE Main 2019 Chemistry January Attempt Shift - 2 (11th January, 2019)

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PAPER-1 (B.E./B. TECH.

JEE (Main) 2019

Duration: 3 Hours | Max. Marks: 360

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Straight Objective Type (lh/ks oLrqfu"B izdkj)

1. The reaction that does NOT define calcination is :

2. The major product obtained in the following reaction is :

(1) (2) (3) (4)

NH2 OH NO2 OH NH2 OH NH2 OH

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4. The major product of the following reaction is :

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(ii) Mg(HCO3)2 (B) Castner-Kellner process

(iii) NaOH (C) Solvay process

(iv) Ca3Al2O6 (D) Temporary hardness

11. The hydride that is NOT electron different is :

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12. The coordination number of Th in K4[Th(C2O4)4(OH2)2] is :

13. The homopolymer formed from 4-hydroxy-butanoic acid is :

(1) (2) (3) (4)

14. The correct match between Item I and Item II is :

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15. The major product obtained in the following conversion is :

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Primary amines give positive carbyl amine test

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27. The correct match between Item I and Item II is :

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(1) (2) (3) (4)

Intermediate carbocation is resonance stabilised and aromatic.

30. In the following compound.

the favourable site/s for protonation is /are :

çksVuhdj.k ds fy, vuqdwy LFky gS@gSa %

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