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PART : CHEMISTRY
COOCH2CH3
OCH2CH3 CO2CH2CH3
CH3
CH2CH3
CO2CH2CH3 COOCH2CH3
Ans. (2)
CH2–CH3
CH3
EtO
Sol. CH3 Cl C=CH
(E2 ) EtOOC CH3
COOEt
(Cis & Trans) ¼lei{k ,oa foi{k½
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
4. An open vessel at 27°C is heated until two fifth of the air (assumed as an ideal gas) in it has escaped
from the vessel. Assuming that the volume of the vessel remains constant, the temperature at which the
vessel has been heated is:
27°C ij fLFkr ,d [kqys ik=k dks rc rd xeZ fd;k tkrk gS tc rd blesa mifLFkr ok;q (vkn'kZ xSl ekurs gq,) ds
nks ik¡posa Hkkx (2/5) ik=k ls fudy ugha tkrkA ;g ekudj fd ik=k dk vk;ru fLFkj gS] rki ftl ij ik=k dks xeZ
fd;k x;k gS] og gS %
(1) 750 K (2) 750°C (3) 500 ºC (4) 500 K
Ans. (4)
Sol. n1T1 = n2T2
2n
n × 300 = n – T2
5
3
300 = T2
5
T2 = 500 K
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
7. Given :
(i) C(graphite) + O2(g) CO2(g); rH– = xkJ mol–1
1
(ii) C(graphite) + O2(g) CO2(g); rH– = ykJ mol–1
2
1
(iii) CO(g) + O2(g) CO2(g); rH– = zkJ mol–1
2
Based on the above thermochemical equations, find out which one of the following algebraic
relationship is correct?
fn;k x;k gS %
(i) C(xzsQkbV) + O2(g) CO2(g); rH– = xkJ mol–1
1
(ii) C(xzsQkbV) + O2(g) CO2(g); rH– = ykJ mol–1
2
1
(iii) CO(g) + O2(g) CO2(g); rH– = zkJ mol–1
2
mi;qZDr Å’"ekjklk;fud lehdj.kksa ds vk/kkj ij crkb;s fd uhps fn, x;s chtxf.krh; laca/kksa esa ls dkSulk lgh gS \
(1) x = y – z (2) y = 2z – x (3) x = y + z (4) z = x + y
Ans. (3)
Sol. Bonus can be claimed because question is incorrect due to misprint in second reaction ie CO 2 in palce
of CO(g).
cksul vad dk nkok dj ldrs gS D;ksafd f}rh; vfHkfØ;k esa CO(g) ds LFkku ij CO2 dh xyr NikbZ ds dkj.k iz'u
xyr gSA
8. The major product of the following reaction is:
fuEufyf[kr vfHkfØ;k dk eq[; mRikn gS %
H3C O (i) NaNO2/H
NH2
O (ii) CrO3/H
(iii) H2SO4(Conc.),
HO O
(1) (2) CH3 O
O O
O
CH3 O
(3) (4) O
O
O
Ans. (1)
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
O
O
O O
O
Sol. O
(1) NaNO2/H
NH2 CrO3/H
OH
OH
O
OH
H
NaBH
4
EtOH
O O OH OH
OEt OEt
Ans. (3)
O OH
NaBH
Sol.
4
EtOH
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
H
H3C CH2–Cl CH3
CH3
(1) (2)
H H
Cl
H3C CH3
CH2–Cl
(3) CH3 (4) Cl
H H
Ans. (4)
H3C CH3
CH3 CH3
HCl
Sol. C=CH2
C–CH3 Cl
H
12. Molecules of benzoic acid (C6H5COOH) dimerise in benzene. ‘w’ g of the acid dissolved in 30 g of
benzene shows a depression in freezing point equal to 2 K. If the percentage association of the acid to
form dimer in the solution is 80, then w is :
(Given that Kf = 5 kg mol–1, Molar mass of benzoic acid = 122 g mol–1)
csUtksbd vEy (C6H5COOH) ds v.kq csUthu esa f}rf;d gksrs gSaA 30 g csUthu esa ?kqfyr ‘w’ g vEy 2 K ds cjkcj
fgekad esa voueu iznf'kZr djrk gSA ;fn foy;u esa vEy ds laxq.ku dk izfr'kr 80 gS rks w dk eku gS %
(fn;k x;k gS] Kf = 5 kg mol–1, csUtksbd ,flM dk eksyj nzO;eku = 122 g mol–1)
(1) 2.4 g (2) 1.8 g (3) 1.0 g (4) 1.5 g
Ans. (1)
Sol. 2A – (A)2
1 –
0.8
1–0.8
2
Tf = Kf × i × m
w 1000
2 = 5 × 0.6 × × w = 2.44 g
122 30
13. 8 g of NaOH is dissolved in 18 g of H2O. Mole fraction of NaOH in solution and molality (in mol kg –1) of
the solution respectively are :
8 g NaOH dks 18 g H2O esa ?kksyk x;k gSA foy;u esa NaOH dk eksyka'k rFkk foy;u dh eksykfyVh (eksy izfr
fdyksxzke) Øe'k% gS %
(1) 0.2, 11.11 (2) 0.167, 11.11 (3) 0.167, 22.20 (4) 0.2, 22.20
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
Ans. (2)
8
Sol. n1 = 0.2
40
18
n2 = 1
18
0.2
mole fraction of NaOH = 0.167
1.2
0.2
NaOH dk eksy izHkkt = 0.167
1.2
8 1000
molality eksyyrk = 11.11
40 18
14. m for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm 2mol–1, respectively. If the conductivity of
0.001 M HA is 5 × 10–5 S cm–1, degree of dissociation of HA is:
NaCl, HCl rFkk NaA ds fy, m Øe'k% 126.4, 425.9 rFkk 100.5 S cm2mol–1 gSaA ;fn 0.001 M HA dh
pkydrk 5 × 10–5 S cm–1 gks rks HA dh fo;kstu ek=kk gS %
(1) 0.125 (2) 0.50 (3) 0.75 (4) 0.25
Ans. (1)
Sol. °m(HA) = °m(HCl) + °m(NaA) – °(NaCl)
= 425.9 + 100.5 – 126.4
= 400
K 1000 5 10 –5 103
m = 50
M 10 –3
50
0.125
400
15. The volume strength of 1M H2O is: (Molar mass of H2O2 = 34 g mol–1)
1M H2O dk vk;ru lkeF;Z gS (H2O2 dk eksyj nzO;eku = 34 xzk- eksy–1)
(1) 11.35 (2) 22.4 (3) 16. 8 (4) 5.6
Ans. (1)
Sol. Volume strength vk;ru lkeF;Z = 11.35 × M = 11.35 (STP)
17. The element that shows greater ability to form p-p multiple bonds, is:
p-p cgqca/k cukus dh izcy ;ksX;rk j[kus okyk rRo gS %
(1) Ge (2) Sn (3) C (4) Si
Ans. (3)
Sol. C form most stable p-p bonds.
C lokZf/kd LFkk;h p-pcU/k cukrk gSA
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
18. The compound that is NOT a common component of photochemical smog is:
izdk'k jklk;fud /kwedqgk dk tks lkekU; la?kVd ugha gS] og ;kSfxd gS %
(1) H3C–C–OONO2 (2) O3 (3) CF2Cl2 (4) CH2=CHCHO
O
Ans. (3)
Sol. Fact rF;kRed
20. The correct structure of histidine in a strongly acidic solution (pH = 2) is:
,d lkUnz vEyh; foy;u (pH = 2) esa] fgLVhMhu dh lgh lajpuk gS %
H3N–CH–COOH
H3N–CH–COOH
(1) NH (2)
NH2
N
H N
H3N–CH–COO
H3N–CH–COO
NH2
(3) (4)
NH2
N
N H
Ans. (1)
Sol. Only the basic "N" get pronated.
dsoy {kkjh; "N" dk izksVksuhdj.k gksrk gSA
21. If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to 1.5 a0
(a0 is Bohr radius), then the value of n/z is:
;fn ,d gkbMªkstu ijek.kq esa] nosa (nth) cksj d{kd esa fLFkr bysDVªkWu dk ns czkXyh rjaxnS/;Z 1.5 a0 ds cjkcj gS] rks
n/z dk eku gS % (a0 cksj f=kT;k gS)
(1) 0.75 (2) 0.40 (3) 1.0 (4) 1. 50
Ans. (1)
Sol. 2r = n
n2
2a0 n
Z
n2
2a0 n1.5 a0
Z
n 1.5 3
= 0.75
Z 2 4
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
22. The correct statement(s) among, I to III with respect to potassium ions that are abundant within the cell
fluids is/are:
I. They activate many enzymes.
II. They participate in the oxidation of glucose to produce ATP
III. Along with sodium ions, they are responsible for the transmission of nerve signals
(1) I and III only (2) III only (3) I and II only (4) I, II and III
dksf'”kdk rjy esa ckgqY; :i esa ik;s tkus okys iksVsf'k;e vk;uksa ds laca/k esa I ls III esa ls lgh dFku gS@gSa\
I. os dbZ ,atkbeksa dks lfØ; djrs gSaA
II. os Xywdksl ds vkDlhdj.k }kjk ATP ds cukus esa Hkkxhnkjh djrs gSaA
III. lksfM;e vk;u ds lkFk] raf=kdkvksa ds ladsrksa ds lapj.k ds fy, ftEesnkj gksrs gS\
(1) dsoy I rFkk III (2) dsoy III (3) dsoy I rFkk II (4) I, II rFkk III
Ans. (4)
Sol. Fact rF;A
23. The upper stratosphere consisting of the ozone layer protects us from the sun’s radiation that falls in
the wavelength region of :
Åijh lerkieaMy ftlesa mifLFkr vkstksu ijr gesa lw;Z ds fofdj.k ls cpkrh gS] mldk rjaxnS/;Z {ks=k gS %
(1) 0.8 – 1.5 nm (2) 400 – 550 nm (3) 200 – 315 nm (4) 600 – 750 nm
Ans. (3)
Sol. Fact rF;A
25. The combination of plots which does not represents isothermal expansion of an ideal gas is:
P
P
(A) (B)
O 1/Vm O
Vm
PVm
(C) (D) U
O O
P Vm
(1) (B) and (C) (2) (A) and (C) (3) (A) and (D) (4) (B) and (D)
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
,d vkn'kZ xSl ds lerkih; izlj.k dks ugha fu:fir djus okys IykVksa dk la;kstu gS %
P
P
(A) (B)
O 1/Vm O
Vm
PVm
(C) (D) U
O O
P Vm
(1) (B) rFkk (C) (2) (A) rFkk (C) (3) (A) rFkk (D) (4) (B) rFkk (D)
Ans. (4)
26. The increasing order of the reactivity of the following with LiAlH 4 is:
fuEufyf[kr dh LiAlH4 ds lkFk vfHkfØ;k'khyrk dk c<+rk Øe gS %
O O
(A) (B)
C2H5 NH2 C2H5 OCH3
O O O
(C) (D)
C2H5 Cl C2H5 O C2H5
(1) (A) < (B) < (C) < (D) (2) (A) < (B) < (D) < (C)
(3) (B) < (A) < (D) < (C) (4) (B) < (A) < (C) < (D)
Ans. (2)
O
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
27. For a reaction, consider the plot of ln k versus 1/T given in the figure. If the rate constant of this reaction
at 400 K is 10–5 s–1, then the rate constant at 500 K is:
,d vfHkfØ;k ds fy, fn;s x;s fp=k esas ln k vs 1/T ds IykV ij fopkj dhft,A ;fn bl vfHkfØ;k dk nj fu;rkad
400 K ij 10–5 s–1 gS] rks 500 K ij mldk nj fu;rkad gS %
nk
Slope = –4606 K
1/T
(1) 10–4 s–1 (2) 4 × 10–4 s–1 (3) 2 × 10–4 s–1 (4) 10–6 s–1
Ans. (1)
Ea 4606 E A
Sol. nk = nA – nA – R 4606
RT T
k E 500 – 400
n –5 a
10 R 500 400
k 1
n –5 4606 2.303
10 2000
k
n –5 n10
10
k 10–4 s–1
28. The aldehydes which will not form Grignard product with the equivalent Grignard reagents are:
,d lerqY; fxzxukMZ vfHkfØ;k ds lkFk fxzxukMZ mRikn ugha nsus okys ,sfYMgkbM gSa %
CHO CHO CHO CHO
29. The magnetic moment of an octahedral homoleptic Mn(II) complex is 5.9 BM. The suitable ligand for
this complex is:
(1) Ethylenediamine (2) CN– (3) NCS– (4) CO
,d v"VQyd gkseksysfIVd Mn(II) ds ladqy dk pqEcdh; vk?kw.kZ 5.9 BM gSA bl ladqy ds fy, mi;qDr layXuh gS %
(1) Ethylenediamine (2) CN– (3) NCS– (4) CO
Ans. (3)
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| JEE (Main) 2019 | DATE : 12-01-2019 (SHIFT-2) | CHEMISTRY
Br
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