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Steel is an alloy of iron and carbon and other elements. Because of its high tensile
strength and low cost, it is a major component used
in buildings, infrastructure, tools, ships, automobiles, machines, appliances, and weapons.
Iron is the base metal of steel. Iron is able to take on two crystalline forms (allotropic
forms), body centered cubic (BCC) and face centered cubic (FCC), depending on its
temperature. In the body-centred cubic arrangement, there is an iron atom in the centre and
eight atoms at the vertices of each cube; in the face-centred cubic, there is one atom at the
center of each of the six faces of the cube and eight atoms at the vertices. It is the interaction
of the allotropes of iron with the alloying elements, primarily carbon, that gives steel and cast
iron their range of unique properties.
In pure iron, the crystal structure has relatively little resistance to the iron atoms slipping past
one another, and so pure iron is quite ductile, or soft and easily formed. In steel, small
amounts of carbon, other elements, and inclusions within the iron act as hardening agents that
prevent the movement of dislocations that are common in the crystal lattices of iron atoms.
The carbon in typical steel alloys may contribute up to 2.14% of its weight. Varying the
amount of carbon and many other alloying elements, as well as controlling their chemical and
physical makeup in the final steel (either as solute elements, or as precipitated phases), slows
the movement of those dislocations that make pure iron ductile, and thus controls and
enhances its qualities. These qualities include such things as the hardness, quenching
behavior, need for annealing, tempering behavior, yield strength, and tensile strength of the
resulting steel. The increase in steel's strength compared to pure iron is possible only by
reducing iron's ductility.
Steel Categories
According to the American Iron & Steel Institute (AISI), Steel can be categorized into four
basic groups based on the chemical compositions:
1. Carbon Steel
2. Alloy Steel
3. Stainless Steel
4. Tool Steel
There are many different grades of steel that encompass varied properties. These properties
can be physical, chemical and environmental.
All steel is composed of iron and carbon. It is the amount of carbon, and the additional alloys
that determine the properties of each grade.
Classifications
Types of Steel can also be classified by a variety of different factors:
If the first digit is a one (1) in this designation it indicates a carbon steel. All carbon steels are
in this group (1xxx) in both the SAE & AISI system. They are also subdivided into four
categories due to particular underlying properties among them. See below:
Plain Carbon Steel is encompassed within the 10xx series (containing 1.00% Mn
maximum)
Re-Sulfurized Carbon steel is encompassed within the 11xx series
Re -Sulfurized and Re-Phosphorized Carbon Steel is encompassed within the 12xx
series
Non-Re-Sulfurized High-Manganese (up-to 1.65%) carbon steel is encompassed
within the 15xx series.
The first digit on all other alloy steels (under the SAE-AISI system), are then classified as
follows:
2 = Nickel steels.
3 = Nickel-chromium steels.
4 = Molybdenum steels.
5 = Chromium steels.
6 = Chromium-vanadium steels.
7 = Tungsten-chromium steels.
8 = Nickel-chromium-molybdenum steels
The second digit of the series (sometimes but not always) indicates the concentration of the
major element in percentiles (1 equals 1%).
The last two digits of the series indicate the carbon concentration to 0.01%.
For example: SAE 5130 is a chromium alloy steel containing about 1% of chromium and
approximately 0.30% of carbon.
Carbon Steel
Carbon Steel can be segregated into three main categories: Low carbon steel (sometimes
known as mild steel); Medium carbon steel; and High carbon steel.
Low Carbon Steel (Mild Steel): Typically contain 0.04% to 0.30% carbon content. This is
one of the largest groups of Carbon Steel. It covers a great diversity of shapes; from Flat
Sheet to Structural Beam. Depending on the desired properties needed, other elements are
added or increased. For example: Drawing Quality (DQ) – The carbon level is kept low and
Aluminum is added, and for Structural Steel the carbon level is higher and the manganese
content is increased.
Medium Carbon Steel: Typically has a carbon range of 0.31% to 0.60%, and a manganese
content ranging from .060% to 1.65%. This product is stronger than low carbon steel, and it is
more difficult to form, weld and cut. Medium carbon steels are quite often hardened and
tempered using heat treatment.
High Carbon Steel: Commonly known as “carbon tool steel” it typically has a carbon range
between 0.61% and 1.50%. High carbon steel is very difficult to cut, bend and weld. Once
heat treated it becomes extremely hard and brittle.
ALLOY STEEL
Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0%
and 50% by weight to improve its mechanical properties. Alloy steels are broken down
arbitrarily: Smith and Hashami define the difference at 4.0%, while Degarmo, et al., define it
at 8.0%. Most commonly, the phrase "alloy steel" refers to low-alloy steels.
Strictly speaking, every steel is an alloy, but not all steels are called "alloy steels". The
simplest steels are iron (Fe) alloyed with carbon (C) (about 0.1% to 1%, depending on type).
However, the term "alloy steel" is the standard term referring to steels with other alloying
elements added deliberately in addition to the carbon. Common alloyants
include manganese (the most common
one), nickel, chromium, molybdenum, vanadium, silicon, and boron. Less common alloyants
include aluminium, cobalt, copper, cerium, niobium, titanium, tungsten, tin, zinc, lead,
and zirconium.
The following is a range of improved properties in alloy steels (as compared to carbon
steels): strength, hardness, toughness, wear resistance, corrosion resistance, hardenability,
and hot hardness. To achieve some of these improved properties the metal may require heat
treating.
Some of these find uses in exotic and highly-demanding applications, such as in the turbine
blades of jet engines, in spacecraft, and in nuclear reactors. Because of
the ferromagnetic properties of iron, some steel alloys find important applications where their
responses to magnetism are very important, including in electric motors and in transformers.
Low-alloy steels
D6AC
300M
256A
13xx Mn 1.75%
40xx Mo 0.20% or 0.25% or 0.25% Mo & 0.042% S
Material science
Alloying elements are added to achieve certain properties in the material. As a guideline,
alloying elements are added in lower percentages (less than 5%) to increase strength or
hardenability, or in larger percentages (over 5%) to achieve special properties, such as
corrosion resistance or extreme temperature stability.Manganese, silicon, or aluminium are
added during the steelmaking process to remove
dissolved oxygen, sulphur and phosphorus from the melt. Manganese, silicon, nickel, and
copper are added to increase strength by forming solid solutions in ferrite. Chromium,
vanadium, molybdenum, and tungsten increase strength by forming second-phase carbides.
Nickel and copper improve corrosion resistance in small quantities. Molybdenum helps to
resist embrittlement. Zirconium, cerium, and calcium increase toughness by controlling the
shape of inclusions. Sulphur (in the form of manganese sulphide) lead, bismuth, selenium,
and tellurium increase machinability. The alloying elements tend to form either solid
solutions or compounds or carbides. Nickel is very soluble in ferrite; therefore, it forms
compounds, usually Ni3Al. Aluminium dissolves in the ferrite and forms the compounds
Al2O3 and AlN. Silicon is also very soluble and usually forms the compound SiO2•MxOy.
Manganese mostly dissolves in ferrite forming the compounds MnS, MnO•SiO2, but will also
form carbides in the form of (Fe,Mn)3C. Chromium forms partitions between the ferrite and
carbide phases in steel, forming (Fe,Cr3)C, Cr7C3, and Cr23C6. The type of carbide that
chromium forms depends on the amount of carbon and other types of alloying elements
present. Tungsten and molybdenum form carbides if there is enough carbon and an absence
of stronger carbide forming elements (i.e., titanium & niobium), they form the carbides W2C
and Mo2C, respectively. Vanadium, titanium, and niobium are strong carbide forming
elements, forming vanadium carbide, titanium carbide, and niobium carbide,
respectively. Alloying elements also have an effect on the eutectoid temperature of the steel.
Manganese and nickel lower the eutectoid temperature and are known as austenite stabilizing
elements. With enough of these elements the austenitic structure may be obtained at room
temperature. Carbide-forming elements raise the eutectoid temperature; these elements are
known as ferrite stabilizing elements.
Combines with sulphur and with phosphorus to reduce the brittleness. Also
0.25–0.40
helps to remove excess oxygen from molten steel.
Manganese
Increases hardenability by lowering transformation points and causing
>1
transformations to be sluggish
Stable carbides; inhibits grain growth. Increases the toughness of steel, thus
making molybdenum a very valuable alloy metal for making the cutting
Molybdenum 0.2–5
parts of machine tools and also the turbine blades of turbojet engines. Also
used in rocket motors.
2–5 Toughener
Nickel
12–20 Increases corrosion resistance
0.2–0.7 Increases strength
Higher
Improves magnetic properties
percentages
STAINLESS STEEL
In metallurgy, stainless steel, also known as inox steel or inox from
French inoxydable (inoxidizable), is a steel alloy with a minimum of
10.5% chromium content by mass.
Stainless steels are notable for their corrosion resistance, which increases with increasing
chromium content. Additions of molybdenum increase corrosion resistance in reducing acids
and against pitting attack in chloride solutions. Thus, there are numerous grades of stainless
steel with varying chromium and molybdenum contents to suit the environment the alloy
must endure. Stainless steel’s resistance to corrosion and staining, low maintenance, and
familiar lustre make it an ideal material for many applications where both the strength of steel
and corrosion resistance are required.
Stainless steels are rolled into sheets, plates, bars, wire, and tubing to be used
in cookware, cutlery, surgical instruments, major appliances and as construction material in
large buildings, such as the Chrysler Building. As well as, industrial equipment (for example,
in paper mills, chemical plants, water treatment), and storage tanks and tankers for chemicals
and food products (for example, chemical tankers and road tankers). Stainless steel's
corrosion resistance, the ease with which it can be steam cleaned and sterilized and no need
for other surface coatings has also influenced its use in commercial kitchens and food
processing plants.
Stainless steel families
There are five main families, which are primarily classified by their crystalline structure:
Austenitic stainless steel:
Austenitic stainless steel is the largest family of stainless steels, making up about two-thirds
of all stainless steel production. They possess an austenitic microstructure, which is a face-
centered cubic crystal structure. This microstructure is achieved by alloying with sufficient
nickel and/or manganese and nitrogen to maintain an austenitic microstructure at all
temperatures from the cryogenic region to the melting point. Thus austenitic stainless steels
are not hardenable by heat treatment since they possess the same microstructure at all
temperatures. Though they can be strengthened by cold working, but this is limited to thin
sheet and small diameter bar. Their austenitic microstructure gives them excellent formability
and weldability and they are essentially non-magnetic and maintain their ductility at
cryogenic temperatures.
They can be further subdivided into two sub-groups, 200 series and 300 series:
Grades:
There are over 150 grades of stainless steel, of which 15 are most commonly used.
There are a number of systems for grading stainless and other steels, including
US SAE steel grades.
Comparison of standardized steels
EN-standard EN-standard
SAE grade UNS
Steel name
Steel no. k.h.s DIN
410 S41000
440F S44020
X5CrNi30-9 312
1) 200 Series:
The 200 series is a class of austenitic (highly corrosion-resistant) stainless steels that are
characterized by having low nickel content. These are also referred to as chrome-manganese
(CrMn) stainless steel.
Austenitic steels, which includes both the 200 and 300 series stainless steels, are defined by
their face-centered cubic structure. That is, the crystal structure has one atom at each corner
of the cube and one in the middle of each face.
Nickel is the most commonly used element to produce this crystal structure, but a post-World
War II nickel shortage led to the substitution of nitrogen for nickel in the production of some
austenitic corrosion-resistant steels. The 200 series of stainless steels was born.
While nitrogen alloyed in steel will also form a face-centered cubic structure, it results in
harmful chromium nitrides and increases gas porosity. The addition of manganese allows
more nitrogen to be safely added, but nickel cannot be completely removed from the alloy.
The 200 series stainless steels are, consequently, characterized by their nitrogen and
manganese content.
Production and demand for low-nickel stainless steels surged in the 1980s as nickel prices
soared and, again, efforts were made to reduce the use of the metal.
This led to the development of a huge production increase in India. Asia is now a major
source for, and consumer of, this family of steels.
While corrosion resistant, the 200 series has a lower ability than 300 series to protect against
pitting corrosion, which occurs in environments that have high moisture and chlorine
contents, as well as crevice corrosion, which results in stagnant liquid and high acid
environments.
This is because, in order to decrease the nickel content, the chromium content must also be
reduced, thereby lowering corrosion resistance.
Series 200 stainless steels have excellent impact resistance and toughness, even in low (even
cryogenic) temperatures. They are generally harder and stronger than 300 series steels,
primarily due to their higher nitrogen content, which acts as a strengthener. Because they are
austenitic, both the 200 and 300 series of stainless steels are not magnetic.
Although austenitic steels are more expensive than their ferritic counterparts, the 200 series is
cheaper to produce than 300 series steels because of their lower nickel content.
The 200 series, however, suffer from lower formability (ductility) than 300 series grades,
although this can be improved with the addition of copper.
Due to its lower corrosion resistance, the range of applications for 200 series stainless steels
is narrower than 300 series steels. It is not recommended for use in chemical
environments but has found its way into many household items.
AISI UNS Cr Ni Mn N Cu
The 300 series consist of austenitic chromium-nickel alloys. Austentic contains a maximum
of 0.15% carbon and a minimum of 16% chromium, and nickel is the important alloying
element. This creates superior corrosion resistance and ease of fabrication. Austentic stainless
steel has a wide range of mechanical properties and can withstand a wide range of
temperatures. Austenitic grades are the most commonly used stainless steels, and are not
hardenable by heat treatment.
Automotive industry
Aerospace industry
Construction industry
The table below shows common types of 300 series steel:
one of the most common steels, with the ability to be used in a variety of applications.
superior corrosion resistant properties
developed for applications requiring extensive machining operations
non-magnetic properties
scratch resistant
many Finishing options: polishing, beveling, etc
3) 400 Series:
The 400 series group of stainless steels has an 11 percent chromium and 1-percent
manganese increase, above the 300 series group. The 400 series is susceptible to rust and
corrosion under some conditions. Heat-treating will harden the 400 series. The 400 series
of stainless steels have higher carbon content, giving it a martensitic crystalline structure.
This provides high strength and high wear resistance. Martensitic stainless steels aren’t as
corrosion resistant as the austenitic types.
Ferritic steels: non-hardening steels, ideal for conditions in elevated temperatures. Typical
applications for ferritic stainless steels include petrochemical, automotive exhaust systems,
heat exchanges, furnaces, appliances and food equipment to name a few.
Martensitic steels: able to be hardened, ideal for a wide variety of common uses. Martensitic
stainless steels are used extensively in cutlery, sport knives and multi-purpose tools.
Martensitic, or hardenable stainless steels, are classified in the 400 series. This series is
known for: