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Applied Thermal Engineering 29 (2009) 2484–2490

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Applied Thermal Engineering


journal homepage: www.elsevier.com/locate/apthermeng

Experimental investigation on the performance and emissions of a diesel


engine fuelled with ethanol–diesel blends
Jincheng Huang a, Yaodong Wang a,b,*, Shuangding Li a, Anthony P. Roskilly b, Hongdong Yu a, Huifen Li a
a
Mechanical Engineering College, Guangxi University, Nanning 530004, China
b
The Sir Joseph Swan Institute for Energy Research, Newcastle University, Newcastle upon Tyne NE1 7RU, United Kingdom

a r t i c l e i n f o a b s t r a c t

Article history: An experimental investigation on the application of the blends of ethanol with diesel to a diesel engine
Received 6 January 2008 was carried out. First, the solubility of ethanol and diesel was conducted with and without the additive of
Accepted 17 December 2008 normal butanol (n-butanol). Furthermore, experimental tests were carried out to study the performance
Available online 25 December 2008
and emissions of the engine fuelled with the blends compared with those fuelled by diesel. The test
results show that it is feasible and applicable for the blends with n-butanol to replace pure diesel as
Keywords: the fuel for diesel engine; the thermal efficiencies of the engine fuelled by the blends were comparable
Ethanol
with that fuelled by diesel, with some increase of fuel consumptions, which is due to the lower heating
Diesel fuel
Blends
value of ethanol. The characteristics of the emissions were also studied. Fuelled by the blends, it is found
Diesel engine that the smoke emissions from the engine fuelled by the blends were all lower than that fuelled by diesel;
Performance the carbon monoxide (CO) were reduced when the engine ran at and above its half loads, but were
Emissions increased at low loads and low speed; the hydrocarbon (HC) emissions were all higher except for the
top loads at high speed; the nitrogen oxides (NOx) emissions were different for different speeds, loads
and blends.
Ó 2008 Elsevier Ltd. All rights reserved.

1. Introduction These characters of ethanol make it difficult to mix with diesel.


Therefore, further studies are necessary to find the way to make
The environmental concern of the global warming and climate ethanol be mixable with diesel and then applicable to diesel
change has greatly increased the interests of the application study engines.
of renewable fuels to internal combustion engines. The sharply ris- The objective of this study is to carry out an experimental study
ing petroleum price on the markets worldwide has also boosted to investigate the solubility of diesel with ethanol, the blends the
the studies and applications of renewable fuels in the area. Previ- two mixed with the additive of normal butanol (n-butanol); and
ous research and studies on different kinds of renewable fuels such the performance and emissions from diesel engine when fuelled
as raw vegetable oil, waste cooking oil, biodiesel, methanol and by the blends compared with that fuelled by pure diesel.
ethanol. The first three are able to be applied to diesel engines
[1–8] and the last two are mostly applied to petrol engines [9–
12]. Ethanol is regarded as a kind of renewable fuel because it 2. The experimental study
can be made from many kinds of raw materials such as corn, maize,
sugar beets, sugar cane, cassava, etc. [13,14]. It is has been success- The experimental study was carried out in two stages: the first
fully used to mix with petrol as part of the alternative to reduce the stage was to test the blends of ethanol and diesel with and without
consumption of fossil fuel in Brazil since 1975 [15–17]. But ethanol the additive of n-butanol. And then the fuels are used to run a die-
has not been commercially used to replace part of the diesel fuel to sel engine to test its characteristics of the performance and
diesel engines. Some investigation of the potential application of emissions.
ethanol to fuel diesel engine have been done but the barriers for
the application have not been overcome yet, due to the special 2.1. Tests of the solubility of the blends of diesel with ethanol
properties of the ethanol [18–20], as can be seen in Table 1. Com-
pared to diesel, ethanol has lower density and lower viscosity. Diesel, ethanol were used as the materials to form the blends
with and without the additive of n-butanol. The properties of die-
sel, ethanol and n-butanol are shown in Table 1. The purity of the
* Corresponding author. Address: Mechanical Engineering College, Guangxi ethanol used is of 99.7%. A series of tests was performed to observe
University, Nanning 530004, China.
E-mail address: y.d.wang@ncl.ac.uk (Y. Wang).
the solubility of the two fuels in different mixing ratios. Diesel and

1359-4311/$ - see front matter Ó 2008 Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2008.12.016
J. Huang et al. / Applied Thermal Engineering 29 (2009) 2484–2490 2485

Table 1
Properties of diesel, ethanol and n-butanol.

Formula Mole Density at Oxygen Carbon Hydrogen Viscosity at Cetane Lower heat
weight 20 °C content (wt%) content (wt%) content (wt%) 20 °C (106 v/m2/s) number value (MJ/kg)
Diesel C12H23 (C10H20  C15H28) 190–220 0.840 0 86 14 3.35 4050 42.5
Ethanol C2H5OH 46.07 0.789 34.8 52.2 13 1.2 89 26.4
n-Butanol C4H10O 74.12 0.810 21.58 64.82 13.60 3.0 17 33.2

ethanol were mixed into a homogeneous blend in a container by butanol were all lasted longer before the stratification happened.
stirring it. The blends were kept in a glass container for observing The blend of Z5E10D85 was of the best stability with very little
the solubility and the physical stability. The volume percentages and almost unseen stratification.
tested were 10%, 20%, 25% and 30% of ethanol with 90%, 80%, 75%
and 70% of diesel, respectively, which were named as E10D90, 2.2. Experimental test rig set-up and test plan
E20D80, E25D75 and E30D70.
Table 2 and Fig. 1 show the test results of the solubility and the 2.2.1. The engine
physical stability of the blends. From the figure and the table it can The engine used in the experiments is a S195 diesel engine
be seen that that all of the blends were stratified into two layers for made by Nanji Machinery Ltd. It is a single-cylinder, four-stroke,
the blend of ethanol with diesel after some times. E10D90 lasted water-cooled, direct injection (DI) compression-ignition engine,
72 h when it became separated; E20D80 maintained 24 h before compression ratio 1:20, having a swept volume of 815 cm3, rated
separating; E25D75 and E30D70 were separated after 2 h or power 8.82 kW at rated speed 2000 r/min. Dimensions of the en-
5 min after mixing. The results show that the blends of ethanol
with diesel were not stable and were all separated.
In order to solve the problem of phase separation, n-butanol
was selected as an additive for further tests. The same processes
for the mixing were performed with the blends of ethanol, diesel
and n-butanol, the volume percentages were 10%, 20%, 25% and
30% of ethanol with 85%, 75%, 70% and 65% of diesel, respectively,
and with a fixed percentage of 5% of n-butanol as a solvent, which
were named as Z5E10D85, Z5E20D75, Z5E25D70 and Z5E30D65.
Table 2 and Fig. 2 show the test fuels and the test results of the
solubility and the physical stability of the blends. Fig. 2a shows the
status when ethanol and diesel were added into the containers. It
showed that the liquids in the containers were stratified into two
layers. Fig. 2b shows the states when the blends were formed after
the n-butanol were added in and stirred. The photos showed that
ethanol and diesel were mixed well with the aid of n-butanol.
Fig. 2c shows the states of the blends after being mixed for some
days. It showed that the blends of the last three were separated
after 11–14 days. The results show that all of the blends with n-

Table 2
Stratification of ethanol–diesel fuel blends without and with 5% solvent.

Fuel blend E10D90 E20D80 E25D75 E30D70


Time for stratification 72 (h) 24 (h) 2 (h) 5 (min)
Fuel blend Z5E10D85 Z5E20D75 Z5E25D70 Z5E30D65
Time for stratification – 14 (days) 14 (days) 11 (days)

Fig. 2. (a) Stratification of ethanol–diesel blends before adding solvent and stirring.
(b) Ethanol–diesel blends with 5% solvent (after stirring and mixed). (c) Ethanol–
Fig. 1. Stratification of ethanol–diesel after mixed. diesel blends with 5% solvent (phase separation after mixed 11–14 days).
2486 J. Huang et al. / Applied Thermal Engineering 29 (2009) 2484–2490

gine are: the bore D = 95 mm and the stroke H = 115 mm. The data 2.2.4. Experimental plan
of the fuel inject system of the engine are: the fuel injection pres- A test plan was designed to carry out the engine tests on the
sure is 16 MPa, the fuel-delivery angle is 18° before the top dead original diesel fuel and the blends of Z5E10D85, Z5E20D75,
centre, the fuel nozzle diameter is 0.3 mm and the fuel nozzle hole Z5E25D70 and Z5E30D65. For comparison, the experimental plan
number is 4. for the engine tests were designed to run at two typical speeds of
1500 (maximum-torque speed) and 2000 r/min (rated power
2.2.2. The instruments speed) at different loads to test the engine load characteristics.
The main instruments used in the tests are: There were no changes for the engine running parameters. The
whole experimental plan was realized in two stages: (i) running
 A hydro-dynamometer was used for measuring the torque of engine with diesel; and (ii) running engine with the blends. Each
engine output; the model is D110, made by Jiangsu Qice Dyna- test was repeated three times to make sure the data were reli-
mometer Co. Ltd. able. The relative standard deviations of the repeated test results
 Exhaust gas analyser was used for measuring the emissions of are: <3.1% for fuel consumption (BSFC), <3.2% for thermal effi-
CO, CO2, HC, NOx, O2 from the engine; the model is AVL DiGas ciency (get), <24% for CO, <29% for HC, <9% for NOx and <30%
4000 light, made by Austria AVL Company. for smoke.
 A smokemeter, model FTY-100, made by Foshan Analytical
Instrument Co. Ltd., is used for measuring the smoke emission 3. Test results and discussion
from engine.
 A fuel Consumption meter, model FC2210, made by Changsha As stated above, the experimental tests were carried out on the
Pulian Power Testing Instrument Co., Ltd., is used for measuring diesel engine using diesel and the blended fuels on two specified
the specific fuel consumptions of the engine. speeds. The relevant parameters such as engine speeds, torques,
and fuel consumptions of engine were recorded and the specific
fuel consumption and thermal efficiency were calculated. The en-
2.2.3. The test rig gine emissions of CO, unburned HC, NOx and smoke were analysed
The schematic diagram of the experimental test rig and the using the exhaust gas analysers and recorded. The results are
completed test rig is shown in Fig. 3a and b, respectively. shown as follows.

a Fuel tank Fuel Consumption


meter

Tachometer Smokemeter Exhaust gas analyser

195
Hydro- Diesel
dynamo- engine
meter
Exhaust Water temperature
temperature meter meter

Fig. 3. (a) The Schematic diagram of test rig. (b) The completed test rig.
J. Huang et al. / Applied Thermal Engineering 29 (2009) 2484–2490 2487

3.1. Engine performance the engine low loads from 1.5 to 4.5 kW, but at the high loads from
6.0 to 10 kW the thermal efficiencies were increased by 1.5–4.1%,
Fig. 4 shows the test results of the brake specific fuel consump- respectively; similar trends can be found for the blends of
tions (BSFCs) with the engine power outputs, when the engine Z5E25D70, the decreases were from 1.1% to 6.6% and the increases
fuelled by different fuel blends and diesel. From the results, it were from 0.4% to 3.5%; and for Z5E30D65, the decreases were
can be seen that the engine power could be maintained at the same from 0.2% to 12.8% at the low loads of the engine (from 1.5 to
level when fuelled by different fuel blends with some extent in- 6 kW), the increases were from 1.3% to 3.2% at the high loads of
creases of fuel consumption; the more ethanol was added in, the the engine (from 7.5 to 10.0 kW). These results show the differ-
more fuel consumption was found, compared with those fuelled ences of the thermal efficiencies between the blends and diesel
by pure diesel. When the engine ran at 2000 r/min on different en- were relatively small; they were comparable with each other, with
gine loads, for the blend of Z5E10D85, the BSFCs were increased some extent increases or decreases at different loads.
from 5.2% to 11.4%; for the blend of Z5E20D75, the BSFCs were in- When the engine ran at 1500 r/min, as shown in Fig. 5a, a sim-
creased from 5.7% to 16.8%; for the blend of Z5E25D70, the BSFCs ilar trend can be seen as those of 2000 r/min; the maximal differ-
were increased from 8.5% to 20.2%; for the blend of Z5E30D65, ence was 6.1% when the engines worked at the range between
the BSFCs were increased from 11.1% to 31.5%. These increases of half and full load. The results are also comparable to those reported
fuel consumption are due to the lower heating value of ethanol by Agarwal [21].
than that of pure diesel. The results show the trend of the increase
of fuel consumption with the increase percentage of ethanol in the 3.2. The carbon monoxide (CO) emissions from the engine
blends. Similar results and trend can be seen when the engine ran
at 1500 r/min on different engine loads. The trend of these fuel Fig. 6 shows the CO emissions from the engine at the speeds of
consumption results coincides with the previous work reported 1500 and 2000 r/min when fuelled by different fuels. When the en-
by Agarwal [21]. gine ran at 2000 r/min and at lower loads, the CO emissions from
Fig. 5 shows the results of the thermal efficiencies of engine the engine fuelled by the blends were higher than those fuelled
with the engine power on two tested speeds when fuelled by dif- by pure diesel. The higher percentages of the ethanol were, the
ferent fuel blends and the pure diesel. The test results show that more CO emissions happened. But at the engine higher loads –
there are some differences for the brake thermal efficiencies for which were above half of the engine load, the CO emissions be-
different blends compared with those of diesel. When the engine came lower than that fuelled by diesel for all the blend fuels. At
ran at the speed of 2000 r/min, for the blend of Z5E10D85, the ther- the highest engine loads tested, the reductions of CO emissions
mal efficiency were decreased by 1.6–5.1%; for the blend of from the blend fuels were from 31.7% (for the blend of
Z5E20D75, the thermal efficiencies were reduced by 0.5–5.8% at Z5E10D85) to 43.9% (for the blend of Z5E30D65). The reductions

a 560 n=1500r/min b 600


D100 550 n=2000r/min
520 Z5E10D85 D100
BSFC/(g/Kwh)
BSFC/(g/Kwh)

480 Z5E20D75 500 Z5E10D85


Z5E25D70 Z5E20D75
440 Z5E30D65 450 Z5E25D70
Z5E30D65
400 400
360 350
320
300
280
250
240
200
1 2 3 4 5 6 7 0 2 4 6 8 10
Pe/(Kw) Pe/(Kw)
n=1500r/min n=2000r/min

Fig. 4. Brake specific fuel consumption (BSFC) of the engine.

a 0.40
b 0.40
0.36 0.36
0.32
0.32
n=2000r/min
n=1500r/min 0.28 D100
η et
η et

D100
0.28 Z5E10D85
Z5E10D85 0.24 Z5E20D75
Z5E20D75
Z5E25D70
0.24 Z5E25D70 0.20
Z5E30D65
Z5E30D65
0.16
0.20
0.12
0.16
1 2 3 4 5 6 7 0 2 4 6 8 10
Pe/(kW) Pe/(kW)
n=1500r/min n=2000r/min

Fig. 5. Brake thermal efficiency (get) of the engine.


2488 J. Huang et al. / Applied Thermal Engineering 29 (2009) 2484–2490

a b 0.45 n=2000r/m in
0.30 D100 0.40 D100
Z5E10D85 Z5E10D85
0.35
0.25 Z5E20D75 Z5E20D75
Z5E25D70 0.30 Z5E25D70

CO/(%)
CO/(%)
0.20 Z5E30D65 Z5E30D65
0.25
0.15 0.20
0.15
0.10 0.10
0.05 0.05
0.00
0.00 0 2 4 6 8 10
1 2 3 4 5 6 7
Pe/(Kw)
Pe/(Kw)
n=2000r/min
n=1500r/min

Fig. 6. CO emission.

of CO emissions at full loads are due to the more complete combus- 1.125 and 2.250, the NOx emissions were reduced by 15.8% and
tion [22,23]. 0.8%, respectively.
A similar trend and results can been seen when the engine ran The NOx emissions from the engine were all lower than those of
on the speed of 1500 r/min. This phenomenon or trend is due to diesel when fuelled by the other blends: the reductions were be-
that ethanol contains oxygen element in it. When the engine above tween 6.4% and 34.4% for the blend of Z5E20D75; the reductions
its half load, the temperatures in the cylinder were high, which were between 0.0% and 44.7% for the blend of Z5E25D70; the
made the chemical reaction of fuel with oxygen be easier and the reductions were between 3.6% and 75.6% for the blend of
combustion became more complete. Z5E30D65.
When the engine ran at 2000 r/min, the NOx emissions from the
3.3. The unburned hydrocarbon (HC) emissions from the engine engine were reduced by 5.4–17.5% for different engine loads, when
fuelled by Z5E10D85; the NOx emissions from the engine were re-
The test results for the unburned HC from the engine are duced by 0.8–13.9% for different engine loads, when fuelled by
shown in Fig. 7. The results showed that the HC emissions from Z5E20D75.
the engine for the blend fuels were all higher when the engine When fuelled by Z5E25D70, the NOx emissions from the engine
ran on the speed of 1500 r/min, as shown in Fig. 7a; and the were not stable, at different engine loads, the increases and de-
HC emissions became less as the loads increased. A similar trend creases are between 0.9% and 5.2% in absolute value, except at
can be seen for the engine ran on 2000 r/min, except at the point the point of the lowest load – the reduction was 29.1%. Similar
of top power output, as shown in Fig. 7b. At this point, the HC trend can be seen for that fuelled by Z5E30D65, the NOx emissions
emissions for all blends were lower than that fuelled by diesel, from the engine were not stable for different engine loads, the in-
i.e. from 4.2% for the blend of Z5E30D65, to 33.3% for the blend creases and decreases are between 2.8% and 8.1%, except for the
of Z5E20D75. This is due to the high temperature in the engine two lowest loads – the reductions were 31.7% and 59.0%,
cylinder to make the fuel be easier to react with oxygen when respectively.
the engine ran on the top load and high speed. Similar trends From the results, it can be seen that the NOx emissions from the
at full load can be found in the results from the other researchers engine were reduced at the low speed when fuelled by blended
[22,24]. fuels; but at the high speed, there is not a stable trend for the
NOx emissions. From the results, it can be seen that the NOx emis-
3.4. The nitrogen oxides (NOx) emissions from the engine sions from the blends and diesel were almost in the same level.
The trends of NOx emissions from different blends may be ex-
The test results for the NOx emissions from the engine are plained as following. Generally speaking, there are three primary
shown in Fig. 8. When the engine ran at the speed of 1500 r/min sources of NOx in combustion processes: thermal NOx, fuel NOx
and above half of the engine load (3.375 kW); the NOx emissions and prompt NOx. Thermal NOx formation, which is highly temper-
from the engine were higher than those of diesel when fuelled ature dependent, is recognized as the most relevant source from
by Z5E10D85, from 1.1% to 8.4%; when the engine loads were engine combustion.

a 100 n=1500r/min b 90 n=2000r/m in


90 D100 80
D100
Z5E10D85 Z5E10D85
80 Z5E20D75
HC/(ppm)

HC/(ppm)

Z5E20D75 70
Z5E25D70 Z5E25D70
70
Z5E30D65 60 Z5E30D65
60
50
50
40 40
30 30
20 20
1 2 3 4 5 6 7 0 2 4 6 8 10
Pe/(Kw) Pe/(Kw)
n=1500r/min n=2000 r/min
Fig. 7. HC emission.
J. Huang et al. / Applied Thermal Engineering 29 (2009) 2484–2490 2489

a n=1500r/min b
1400 D100 1400 n=2000r/min
Z5E10D85 D100
1200 1200 Z5E10D85
Z5E20D75

NOx/(ppm)

NOx/(ppm)
Z5E25D70 Z5E20D75
1000 1000 Z5E25D70
Z5E30D65
Z5E30D65
800 800
600 600
400 400
200 200

1 2 3 4 5 6 7 0 2 4 6 8 10
Pe/(Kw) Pe/(Kw)
n=1500r/min n=2000 r/min

Fig. 8. NOx emissions.

a 1.0 b 2.0
n=1500r/min 1.8 n=2000r/m in
0.8 D100 1.6 D100
Z5E10D85 Z5E10D85
Z5E20D75 1.4 Z5E20D75
k /(1/m)

0.6

k /(1/m)
Z5E25D70 1.2 Z5E25D70
Z5E30D65 Z5E30D65
1.0
0.4 0.8
0.6
0.2 0.4
0.2
0.0
0.0
1 2 3 4 5 6 7 0 2 4 6 8 10
Pe/(Kw) Pe/(Kw)
n=1500r/min n=2000 r/min

Fig. 9. Smoke emissions.

Thermal NOx refers to NOx formed through high temperature when less fuel was injected into the engine cylinder at the low en-
oxidation of nitrogen (N2) in combustion chamber. The formation gine loads; another is that the lower calorific value of ethanol, n-
rate of NOx is primarily a function of combustion (flame) tempera- butanol and its blends, which caused lower combustion
ture, the residence time of nitrogen at that temperature, and the temperature.
contents of oxygen in the reaction regions in the combustion With the increasing of engine load, due to more fuel injections
chamber. At high combustion (flame) temperatures, nitrogen (N2) and then higher combustion temperature, the effect of evaporation
and oxygen (O2) in the combustion chamber disassociate into their of ethanol may not be a dominating factor; the contents of oxygen
atomic states and participate in a series of reactions. The three in the reaction regions had an increased effect on the NOx forma-
principal reactions producing thermal NOx are described in Zeldo- tion. So the NOx emissions for blends were not so stable (a little
vich Mechanism: more or a little less for different blends), compared with that from
the pure diesel.
N2 þ O ! NO þ N
N þ O2 ! NO þ O 3.5. The smoke emissions from the engine
N þ OH ! NO þ H
Fig. 9 shows the test results of smoke emissions from the engine
The main NOx emission trends can be seen from Fig. 8. NOx
when fuelled by different fuels. The results show that the smokes
emissions increased with the engine load for all fuel blends at both
from the engine were all lowered down at the two tested speeds
engine speeds. This is due to more fuel was injected and com-
using blends. When the engine was run at the speed of 2000 r/
busted in the cylinder when engine load increased, which caused
min, the reduction rates were from 16.7% to 65.3% for the blend
higher gas temperature and resulted in more NOx formation in
of Z5E10D85; from 45.2% to 82.9% for the blend of Z5E20D75; from
the engine cylinder and then higher NOx emission from the engine.
45.2% to 86.5% for the blend of Z5E25D70; and from 33.3% to 87.5%
This also proves that one the most important factors for the emis-
for the blend of Z5E30D65. A similar trend can be found in Fig. 9a,
sions of NOx is the combustion temperature in the engine cylinder.
which shows the smoke emissions when the engine ran at the
Although the main trends of the NOx emissions were similar
speed of 1500 r/min. From the figures, it can be seen that the more
with each other for different fuel blends, they were different more
ethanol added in, the more reduction of smoke emissions were.
or less at different loads when looked into the details. From Fig. 8,
This result is similar as those from other researchers [24–26].
it can be seen that the NOx emissions were reduced at the low
loads when fuelled by blended fuels; this is possibly due to two
reasons: one is that the evaporation of ethanol in the blends, after 4. Conclusions
being injected into the combustion chamber, caused the lower gas
temperature in the cylinder (ethanol has higher latent heat of An experimental investigation was conducted on the solubility
vaporization 840 kJ/kg, compared with that of 270 kJ/kg for diesel), and physical properties of the blends of ethanol with diesel and the
and the temperature in the cylinder was also lower after com- effects of the application of these blends on the engine perfor-
busted; this caused less NOx formation and it had an obvious effect mance parameters and emissions. The tested blends were from
2490 J. Huang et al. / Applied Thermal Engineering 29 (2009) 2484–2490

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