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Related terms:
Rod, Turbines, Temperature, Goodman Diagram, Service Factor, Tensile Strength,
Maximum Stress, Allowable Stress, Rod String
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4.7. Maximum allowable stress values for ‘T22’ steel from ASME and METI Codes, and calculated values based on EN creep/proof strength values.
It is interesting to note in Fig. 4.7 that ASME and METI publish stress values up to 650°C, and Section II of the former code
states that T22 steel can be used at up to 649°C (for Section I applications). This temperature is well above the ‘oxidation
limit’ for steels with 2.25%Cr as their base, and therefore the ASME and METI limits need to be used with care.
High-temperature materials
B.A. Pint, R.G. Brese, in Fundamentals and Applications of Supercritical Carbon Dioxide (sCO₂) Based Power Cycles, 2017
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Figure 4.1. ASME Boiler and Pressure Vessel code allowable stresses as a function of operating temperature for several Fe- and Ni-base alloys.
Data from deBarbadillo, J.J., Baker, B.A., Gollihue, R.D., 2014, Nickel-base superalloys for advanced power systems – an alloy producer’s perspective. In:
Proceedings of the 4th International Symposium on Supercritical CO2 Power Cycles, Pittsburgh, PA, September 2014, Paper #3; Pint, B.A., DiStefano, J.R.,
Wright, I.G., 2006. Oxidation resistance: one barrier to moving beyond Ni-Base superalloys. Materials Science and Engineering A 415, 255–263.
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Figure 4.2. (a) Stress for creep rupture at 100,000 h as a function of temperature for several classes of structural alloys and (b) maximum use temperatures
for various alloy classes for two different sCO2 pressures and tube sizes (both with 6.35 mm wall thickness) (Wright et al., 2013). Both solid solution–
strengthened (SS) and precipitation-strengthened (PS) Ni-base alloys were evaluated. The higher strength PS alloy 740 is shown in (a). The dashed line in
(a) assumes a tube with 50.8 mm outer diameter and 6.35 mm wall thickness and 30 MPa pressure.
Table 4.1. Chemical composition of typical structural alloys investigated for this application
Alloy Fe Ni Cr Al Other
Gr.22 95.5 0.2 2.3 < 0.9 Mo, 0.6 Mn, 0.1 Si
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Alloy Fe Ni Cr Al Other
VM12 83.3 0.4 11.5 < 1.6 W, 1.5 Co, 0.4 Mo, 0.4 Mn, 0.4 Si, 0.2 V
EBrite 72.6 0.1 25.8 < 1.0 Mo, 0.2 Si, 0.1 V
201SS 70.8 4.1 16.2 < 6.7 Mn, 0.5 Si, 0.3 Mo, 0.9 Cu, 0.2 Co
304H 70.4 8.4 18.4 < 1.6 Mn, 0.3 Si, 0.3 Mo, 00.4 Cu, 0.1 Co
316 66.6 9.6 19.0 0.01 2.4 Mo, 1.7 Mn, 1.0 Si, 0.2 Cu, 0.1 Co, 0.1 W
347HFG 66.0 11.8 18.6 0.01 1.5 Mn, 0.8 Nb, 0.4 Si, 0.2 Mo, 0.2 Co
NF709 49.0 25.0 22.3 0.02 1.5 Mo, 1.0 Mn, 0.4 Si, 0.2 Nb, 0.2N
Sanicro 25 42.6 25.4 22.3 0.03 3.5 W, 3.0 Cu, 1.5 Co, 0.5 Nb, 0.5 Mn, 0.2 Mo, 0.2 Si, 0.2 N
AL6XN 48.2 24.1 20.4 0.01 6.0 Mo, 0.5 Mn, 0.3 Cu, 0.2 Co, 0.1 Si, 0.2 N
800H 43.2 33.8 19.7 0.7 1.0 Mn, 0.5 Ti, 0.3 Cu, 0.3 Si, 0.2 Mo
310HCbN 51.3 20.3 25.5 < 0.3 Co, 0.4 Nb, 1.2 Mn, 0.3 Si, 0.3 N
APMT 69.2 0.2 21.1 5.0 0.2 Hf, 0.1 Mn, 2.8 Mo, 0.6 Si, 0.3 Y, 0.1 Zr
PM2000 74.6 0.1 18.9 5.1 0.5 Ti, 0.4 Y, 0.1 Mn, 0.25 O
AFA-OC4 49.1 25.2 13.9 3.5 2.5 Nb, 2.0 Mo, 1.9 Mn, 1.0 W, 0.5 Cu, 0.2 Si
600 9.4 73.1 16.4 0.3 0.1 Mo, 0.2 Ti, 0.1 Si, 0.2 Mn
625 4.0 60.6 21.7 0.09 9.4 Mo, 3.6 Nb, 0.2 Ti, 0.2 Si, 0.1 Mn
230 1.5 60.5 22.6 0.3 12.3 W, 1.4 Mo, 0.5 Mn, 0.4 Si
C617 0.6 55.9 21.6 1.3 11.3 Co, 8.6 Mo, 0.4 Ti, 0.1 Si
282 0.2 58.0 19.3 1.5 10.3 Co, 8.3 Mo, 0.06 Si, 2.2 Ti, 0.1 Mn
740 1.9 48.2 23.4 0.8 20.2 Co, 2.1 Nb, 2.0 Ti, 0.3 Mn, 0.5 Si
214 3.5 75.9 15.6 4.3 0.2 Mn, 0.1 Si, 0.02 Zr
224 27.2 47.0 20.3 3.8 0.4 Ti, 0.3 Co, 0.3 Mn, 0.3 Si, 0.001 Zr, 0.00 1Y
247 0.07 59.5 8.5 5.7 9.8 Co, 9.9 W, 0.7 Mo, 3.1 Ta, 1.0 Ti, 1.4 Hf
Compositions were measured by inductively coupled plasma and combustion analyses in mass%.
< indicates less than 0.01%.
As mentioned earlier, sCO2 applications can draw many material design lessons from coal-fired boilers. However, it should
be noted that steam boilers achieved 613°C/34.5 MPa in 1960 at the Eddystone plant (Henry et al., 2007) and in 2013, the
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current state-of-the-art Turk plant was dedicated in Arkansas with 607°C/25.3 MPa maximum steam conditions (Pint, 2013).
Both used conventional stainless-steel tubes (e.g., 17/14 PH, 347H) for the hottest section of the superheater. Higher
temperature boilers using Ni-base alloys are still many years away. Currently, a demonstration of the performance of Ni-
base alloys for steam boilers and turbines is planned in a DOE sponsored component test (ComTEST), currently under
design (Romanosky et al., 2016). This project involves many of the same partners involved in the A-USC Consortiums.
Applying the A-USC understanding about the temperature-strength limitations, results of recent calculations are shown in
Fig. 4.2 to indicate the suggested ranges associated with specific pressure conditions in proposed sCO2 cycles (Wright et al.,
2013; Shingledecker and Wright, 2006). Fig. 4.2(a) shows maximum temperature capabilities for various alloy classes for a
50.8-mm outer diameter tube with 30 MPa sCO2. Fig. 4.2(b) shows similar temperature limits for two different tube sizes
and two different pressures. One thing to consider is that no allowances for environmental compatibility have been
included in Fig. 4.2 calculations.
More information can be obtained from API 579 (2001), Andersen (1991), and BSI (1999).
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Figure 5-26. The exhaust casing fabrication is stainless steel. In this picture, the bearing housing can be seen in the center of the casing. The inboard
(diffuser) end of the inlet casing will be bolted to the exhaust casing bellows.
2.5.2The exhaust casing supports (Figure 5-27) shall be designed for true centerline support at the horizontal centerline of
the exhaust casing. The support system shall be adequate for the total load, including one times the forces and
moments per NEMA SM23 paragraph 8.06, without affecting the rotor blade radial tip clearance.
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Figure 5-27. The exhaust casing is free-standing on it own wobble foot support. Axial expansion and vertical alignment are allowed by a centering key
at the bottom of the casing. The casing is free-floating within the constraints of the wobble feet, bottom key, backup plate, and bellows joint. This view
shows the discharge end of an axial compressor in the lower right. The expander rotor support system is pedestal-type with integral bearing housing,
independent of the inlet and exhaust casings.
2.5.3The exhaust flange shall be of the weldneck type with raised face designed in accordance with ASMEBPV Code Section
VIII. The flange shall be vertical up (Figure 5-28) with a surface finish of 150–250 micro inches. The gasket shall be of the
spiral-wound metal type with a seating stress of 10,000 psi.
2.5.4The exhaust casing shall be provided with two valved view ports (Figure 5-29) located so their lines of sight intersect at
mid-height of the rotor blading. The valves shall be capable of withstanding the conditions specified, but not less than
Class 300, with a purge connection between the valve and the sight glass. The valve size shall be the Seller's standard but
not less than 4 in.
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Figure 5-29. This view shows the conical stainless-steel backup plate closing the exhaust casing. The two flanged connections on the right are for the
rotor blade viewing ports. The bearing housing is shielded from the backup plate by 3.5 in. (90 mm) of insulation.
2.5.5The exhaust casing shall be provided with at least one man-way opening with gasketed cover for internal casing access
by personnel.
2.5.6A drain shall be provided at the low point of the exhaust casing and be at least 1.5 in. in size, Class-300.
Mechanical Fastening
In Handbook of Plastics Joining (Second Edition), 2009
18.5.2 Design
Maximum pull-out forces are obtained by creating the greatest allowable interference between the parts, which is obviously
dependent on the strength of the materials used. Part geometry and design must ensure that hoop stresses produced do
not exceed the maximum allowable stress for the plastic material [10].
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Using the ASTM E-1681 test standard (ref. 38), the threshold stress intensity factor (KTH) in hydrogen environment
determined from a pre-cracked specimen, under static loading, can be a very time-consuming task. For instance, according
to work performed by Perra (ref. 36), a hydrogen test duration was typically 5000 hours (7 months) so that an average crack
velocity as small as 10− 11 m/s could be resolved. According to Chandler and Walter (ref. 25), for certain types of materials,
the KTH values are difficult to measure because of the basic problem in determination of actual crack growth versus crack
branching in gaseous hydrogen environment. Because of the intrinsic nature from the experimental setup to determine the
KTH by using a monitoring system for the ‘onset’ of crack initiation; theoretically, it appears that the KTH measurement may
be more sensitive as a hydrogen embrittlement indicator than the simple HEE index based on NTS or RA ratio. In reality,
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the KTH proves to be difficult to measure accurately for certain gaseous hydrogen temperature and pressure set up
conditions. According to Perra (ref. 36), the reported KTH values, as shown in Table 17.4, for superalloys such as A-286, JBK
75 and Incoloy 903 must be interpreted, in his own view as ‘on a relative rather than an absolute basis, and the apparent KTH
values within each sample group can vary as much as ± 15%’. Figure 17.4 shows the trend behavior of KTH values as a
function of hydrogen pressure for Inconel 718 and Incoloy 903 tested at room temperature (ref. 39).
17.4. Effects of hydrogen pressure on threshold stress intensity (KTH) for Inco 718 and 903 (ref. 39).
For material screening purpose, the KTH values can also be used as the HEE indexes according to the ASTM-G129 test
standard. There are two types of HEE indexes based on the KTH ratios relative to the fracture toughness KIC and KC:
Plane strain threshold stress intensity factor ratio,
HEEindex=KITH/KIC [17.7]
Threshold stress intensity factor ratio,
HEEindex=KTH/KC [17.8]
Notice that the denominators or the ‘normalizing factors’ for the first index is KIC and for the second index is KC, both
measured in air or inert environment. The values for KI(TH) and KTH are stress intensity factors measured in hydrogen for
plane strain and non-plane strain specimens, respectively. Accelerated test procedures for KTH measurement have also been
proposed in recent years to estimate the KTH values from a pre-cracked specimen, without spending a considerable amount
of time for the specimen to be under a constant static loading as baseline in ASTM-E1681 (ref. 38). These relatively rapid
test procedures are proposed in terms of using a minute incrementally rising load or displacement based on relatively slow
strain rates (SSR) on the pre-cracked specimens. According to ASTM-G129 and more importantly the ASTM-F1624-6 (ref.
40), ISO 7539-9 (ref. 41) and Dietzel (ref. 42, 43); the proposed incremental step loading technique and/or SSR for the
estimation of Kth are usually in the order of 1 to 10 μm/h. Notice that these SSR values for the pre-cracked specimens (the
determination for KTH) are much slower than the typical SSR values for notched and smooth tensile specimens (the
determinations for NTS and ductility, respectively). Additional information on modern test methods and quantitative-
accelerated testing for KTH in hydrogen can be found in Chapter 8 of this book.
During the process of determining the KTH values for A-286 superalloy using monitoring system for the ‘onset’ of crack
initiation under slow rising displacement, it has been reported by Chandler and Walter (ref. 25) that evidence of slow crack
growth did occur in hydrogen environment for A-286, which has been qualitatively classified as negligibly embrittled by
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hydrogen based on the NTS index ratio of 0.97 shown in Table 17.3. However, this crack growth observation occurred only
with loads large enough to cause yielding, and the crack growth for A-286 was considered to be very slow by Chandler. If the
material was tested under such large loads as to cause yielding, one may expect that the resulting KTH value could be high
and possibly approaching the KC value for A-286 as tested in air. For A-286, JBK-75 and Incoloy 903, under various ST + A
conditions as shown in Table 17.4, their KTH values are shown to be heavily affected by hydrogen. Therefore, the HEE index
based on smooth RA ratio for these materials in Table 17.3, for heat treatment in ST + A conditions, are in qualitative
agreement with the trend behavior for KTH values in hydrogen. As an illustration for the similar behaviors between the HEE
index derived from KI(TH)/KIC and RA ratio, Fig. 17.5 shows two HEE index trend lines for Inconel 718, tested in 34.5 MPa
hydrogen pressure for a wide range of temperature from -195 to 540 °C (− 320 to1000 °F). Surprisingly, the trend line for
HEE index from RA ratio appears to be of a better indicator or more sensitive than the HEE index from KI(TH)/KIC ratio, with
an exception for a single data point at -195 °C, where the KI(TH)/KIC ratio appears to be more sensitive to hydrogen
embrittlement detection (ref. 44). Both of these trend lines show that the maximum HEE effect occurs near room
temperature, and this effect is diminishing when the temperature is below − 200 °C and above 550 °C.
17.5. Trend lines for Inconel 718 based on HEE index from KIH/KIC and RA ratio (ref. 44).
BENDING
E.J. HEARN Ph.D., B.Sc. (Eng.) Hons., C.Eng., F.I.Mech.E., F.I.Prod.E., F.I.Diag.E., in Mechanics of Materials 1 (Third
Edition), 1997
Example 4.4
(a) A reinforced concrete beam is 240 mm wide and 450 mm deep to the centre of the reinforcing steel rods. The rods are
of total cross-sectional area 1.2 × 10−3 m2 and the maximum allowable stresses in the steel and concrete are 150 MN/m2
and 8 MN/m2 respectively. The modular ratio (steel : concrete) is 16. Determine the moment of resistance of the beam.
(b) If, after installation, it is required to up-rate the service loads by 30% and to replace the above beam with a second beam
of increased strength but retaining the same width of 240 mm, determine the new depth and area of steel for tension
reinforcement required.
Solution
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(a) From eqn. (4.16) moments of area about the N.A. of Fig. 4.19.
. Fig. 4.19
10−9(240×h×h2)=16×1.2×10−3(450−h)10−3
120h2=(8640−19.2h)103h2+160h−72000=0
From which
h = 200 mm
Substituting in eqn. (4.17),
momentofresistance(compressive)=(240×200×10−6)8×1062(450−66.7)10−3=73.6KNm
and from eqn. (4.18)
momentofresistance(tensile)=(16×1.2×10−3)150×10616(450−66.7)10−3=69.0KNm
Thus the safe moment which the beam can carry within both limiting stress values is 69 kN m.
(b) For this part of the question the dimensions of the new beam are required and it is necessary to assume a critical or
economic section. The position of the N.A. is then determined from eqn. (4.19) by consideration of the proportions of
the stress distribution (i.e. assuming that the maximum stresses in the streel and concrete occur together).
From (4.17)
M=bhc2(d−h3)=h2d(1−h3d)cbd2
A = 1.44 × 10−3 m2
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where R is the inside radius, S is the maximum allowable stress, P is the internal design pressure, t is the minimum
required thickness, and E is the joint efficiency factor. For spherical shells, the code requires that
t=PR/(2SE−0.2P)orP=2SEt/(R+0.2t) (18.4)
For ellipsoidal heads, the governing formulas are given as
t=PD/(2SE−0.2P)orP=2SEt/(D+0.2t) (18.5)
where α is half the included (apex) angle, and D is the inside diameter at the point under consideration.
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