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M ANUFACTURED S UBSTANCES
S ULPHURIC A CID
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
S ULPHURIC A CID
CONTACT PROCESS
1 2 3 4
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
1ST
STAGE
2ND
STAGE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
3RD
STAGE
4TH
STAGE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
1ST
STAGE
2ND
STAGE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
S ULPHURIC A CID
CONTACT PROCESS
4TH
STAGE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
FERTILIZER
PESTICIDES
DETERGENT
SULPHURIC
A CI D U S E S
PAINT
SYNTHETIC
FIBRE
METAL
CLEANER ACCUMULATOR
ELECTROLYTE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ENVIRONMENTAL POLLUTION
ACID RAIN
EF FECTS
AIR
SOIL
POLLUTION
POLLUTION
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
AMMONIA
HABER PROCESS
N2 3H2 2NH3
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
AMMONIA
HABER PROCESS
H2& N2 Unreacted
uUnreacted
Coolant
out
2
H 2 + N2 3 4 Condenser
1
Compressor
Coolant
r
In
Reactor
@ NH3
Converter
Catalyst
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
AMMONIA
HABER PROCESS
1 STAGE 2
STAGE
1 volume of N2 gas and
In Haber process, nitrogen 3 volume of H2 is
gas, N2 from the air is compressed to a pressure
mixed with hydrogen gas, of 200 - 500 atm,
H2 derived mainly from Ratio N2 and H2 is 1 : 3
natural gas to form NH3 N2 (g) + 3H2 (g) → 2NH3
The mixture is scrubbed to (g)
get rid of impurities
STAGE 4
3
STAGE 3 The mixture of gases is cooled
until the ammonia condenses
The mixture is compressed The unreacted nitrogen
to a high pressure of 200 gas, N2 and hydrogen
atmospheres at a gas, H2 are recycled and
temperature of about pumped back into
450°C - 500°C. the reactor together with the
Iron is used as catalyst with new source of nitrogen gas,
alumina to speed up the N2, and hydrogen gas, H2.
rate of reaction.
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
AMMONIA
HABER PROCESS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
AMMONIA
HABER PROCESS
PROPERTIES OF AMMONIA
Alkaline gas
As an alkali, ammonia can react Change the red litmus paper
with acid in neutralization to to blue
form salt and water.
Soluble in water
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
AMMONIA
HABER PROCESS
Manufacturing
nitrogenous fertilizers
AMMONIA USES
As raw material to
manufacture of nitric acid via
Ostwald process
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
NITRIC ACID
OSTWALD PROCESS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
NITRIC ACID
OSTWALD PROCESS
1
PLATINUM
CATALYST
800◦C
OXYGEN NITROGEN
MONOXIDE
[NO]
2
OXYGEN
NITROGEN
DIOXIDE WATER
[NO2]
3
NITRIC ACID
HNO3
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
NITRIC ACID
OSTWALD PROCESS
STAGE 1
Initially, nitrogen (II) oxide will be formed from the catalytic
oxidation of ammonia using the transition metal platinum.
Ammonia + Oxygen → Nitrogen(II) Oxide + Steam
4NH3 (g) + 5O2 (g) → 4NO (g) + 6H2O (g) 1
STAGE 2
The nitrogen (II) oxide is rapidly cooled before combining with
oxygen (from excess air) to form nitrogen (IV) oxide.
2NO (g) + O2 (g) → 2NO2 (g) 2
STAGE 3
The nitrogen (IV) oxide, mixed with excess air, is then allowed
to react with water to form nitric acid.
Nitrogen(IV) Oxide + Oxygen (air) + Water → Nitric acid
4NO2 (g) + O2 (g) + 2H2O (1) → HNO3 (aq) 3
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ALLOY
Most pure metals are weak and soft. The properties of pure
metals can be improved by making them into alloys.
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ALLOY
PURE METAL
Foreign atom
In alloys of pure metal, foreign
atoms are present.
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ALLOY
Foreign
Atom
Pure
Metal
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
BRASS BRONZE
BRONZE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
IRON BASED
COPPER BASEDALLOY
ALLOY
STEEL STAINLESS
BRONZESTEEL
MANGANESE STEEL
Component:
Component: Fe 73%, Cr 18%,
Fe 99%, C 1%
Component: Ni 8%, C 1%
Applications: Fe 85%, C 1.2%
Vehicles, ships, Mn 13.8%, Applications:
bridges, Spoons, kitchen
buildings Applications: appliances,
Helmet, spring watches, machine
parts, knives, forks,
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ALUMINIUM BASES
COPPER BASED ALLOY
ALLOY
DURALUMIN MAGNALIUM
Component: Component:
Al 95%, Cu 4%, Mg 1% Al 70%, Mg 30%
Applications: Applications:
Aero plane parts, Tyre rim of racing cars,
electric cables, racing skeletal body of aero
bicycles planes
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ALLOY
STANUM ALLOY
STANUM / TIN
COPPER BASED
BASED ALLOY
ALLOY
SOLDER PEWTER
Component: Component:
Sn 50%, Pb 50% Sn 91%, Sb 7%, Cu 2%
Applications: Applications:
Welding and soldering Decorative items,
work souvenirs
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
ALLOY
PROPERTIES OF ALLOY
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYMERIZATION PROCESS
❶ Polymerizations by addition
❷ Polymerizations by condensation
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYMERIZATION ADDITION
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYMERIZATION BYADDITION
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYMERIZATION BY CONDENSATION
Amino Acid Amino Acid
Protein
+ H2O
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYMERIZATION CONDENSATION
Glucose Glucose
+ H2O
Starch @ Cellulose
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYMER
Polymer is a large molecule that is in the form of a long
chain with a high relative molecular mass (RMM).
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
NATURAL POLYMERS
These occur naturally in living things. Some examples of
natural polymers are:
❶ Natural rubber
❷ Protein in meat, leather, silk, hair and fur
❸ Carbohydrates in cellulose, starch and sugar
Or
Or
NATURAL RUBBER
OR
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Or
Or
MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
NATURAL POLYMERS
STARCH @ CELLULOSE
PROTEIN
PROTEIN
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
Synthetic Polymers
Synthetic polymer is a polymer that is manufactured in
industry from chemical substances through the
polymerization process.
❶ Plastics
❷ Synthetic fibers
❸ Elastomers / Rubber
❶ Polymerization by addition
❷ Polymerization by condensation
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
POLYTHENE (POLYETHYLENE)
Monomer : Ethene
Polymerization : Addition
Uses : Plastic bags containers and cups
Advantages : Light and strong
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
Monomer : Chloroethene
Polymerization : Addition
Uses : Raincoat, Pipes to insulate electric
wires
Advantages : Can be coloured; heat resistant
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
Monomer : Phenylethene
Polymerization : Addition
Uses : Packaging materials, children
toys, ball-point pens, as heat and
electric insulators
Advantages : Light and strong
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
Monomer : Methyl-2-methylpropenoate
Polymerization : Addition
Uses : Aeroplane window panes,
Lenses, car lamp covers
Advantages : Light, strong, translucent, stable
towards sunlight
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
Monomer : Propene
Polymerization : Addition
Uses : Plastics, Bottles, plastic tables and
chairs
Advantages : Strong and light
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
Monomer : Tetrafluoroethene
Polymerization : Addition
Uses : To make non-sticky pots and pans
Advantages : Hard, can withstand high
temperatures and corrosives
chemicals
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
NEOPRENE
Monomer : Chloroprene
Polymerization : Addition
Uses : To make rubber gloves and to
insulate electric wires.
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
STYRENE-BUTADIENE OR SBR
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
SYNTHETIC POLYMERS
SYNTHETIC FIBRE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
POLYMER
ISSUE IN USING SYNTHETIC POLYMERS
M ANUFACTURED S UBSTANCES
GLASS
PROPERTIES OF GLASS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
GLASS
❷ PROPERTIES :
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
GLASS
❷ PROPERTIES :
50
MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
GLASS
❷ PROPERTIES :
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
GLASS
❷ PROPERTIES :
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
CERAMICS
PROPERTIES OF CERAMICS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
CERAMICS
Good
electrical
insulators
Resistant of
Resistant
chemical
of heat
reaction
Rust proof
54
MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
CERAMICS USES
ORNAMENT CONSTRUCTION
ARTICLES MATERIALS
Bowls Tiles
Cups Cement
Plates Bricks
Vase Pipes
Porcelain
SEMICONDUCTORS
ELECTRICAL
INSULATORS
Microchips in
Spark Plugs televisions,
Fuses computers,
Insulator in iron, radios,
oven & toasters telephones &
calculators
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
PHOTOCHROMIC GLASS
CONDUCTIVE GLASS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
SUPERCONDUCTORS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
COMPOSITE MATERIALS
❶ Composite materials are substances which contain 2 or
more materials that combine to produce new
substances with different physical properties & better
than from the original substances.
Reinforced
Concrete
Photochromic Optical
Glass Fibre
COMPOSITE
MATERIALS
Fibre Super
Glass Conductor
58
MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
COMPOSITE MATERIALS
REINFORCED CONCRETE
PHOTOCHROMIC GLASS
59
MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
COMPOSITE MATERIALS
OPTICAL FIBRE
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
COMPOSITE MATERIALS
FIBREGLASS
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MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
COMPOSITE MATERIALS
SUPERCONDUCTOR
62
MANUFACTURED SUBSTANCES
M ANUFACTURED S UBSTANCES
COMPOSITE MATERIALS
Photochromic Reinforced
Glass Concrete Optical
Fibre
USES
USES
Construction of large USES
To make optical
structure like Transmitted data,
lenses, car
highways, building, voice and images in
windshields,
bridges, oil digital format …..
window, lens in
platforms….
cameras…
Super
Fibre Conductor
Glass
USES
Uses Bullet trains, magnetic
Badminton racket, resonance imaging [MRI],
water tank, helmets, transformer, computer,
boats, skis….. electric cables…..
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